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Regulating crystal phase of TiO_(2) to enhance catalytic activity of Ni/TiO_(2) for solar-driven dry reforming of methane

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燃料化学学报（中英文） 2024年第9期52卷 1203-1213页

作者： HE Zhanjun gong Kun DAI Yuanyuan NIU qiang LIN Tiejun ZHONG Liangshu Key Laboratory of Low-Carbon Conversion Science and Engineering Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201210China University of Chinese Academy of Sciences Beijing 100049China National Enterprise Technology Center Inner Mongolia Erdos Electric Power and Metallurgy Group Co.LtdOrdos 016064China

Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains *** this work,the rutile/anatase ratio in supports was successfully controlled by varying the calcination temperature of anatase-TiO_(2).Structural characterizations revealed that a distinct TiO_(x) coating on the Ni nanoparticles(NPs)was evident for Ni/TiO_(2)-700 catalyst due to strong metal-support *** is observed that the TiOx overlayer gradually disappeared as the ratio of rutile/anatase increased,thereby enhancing the exposure of Ni active *** exposed Ni sites enhanced visible light absorption and boosted the dissociation capability of CH4,which led to the much elevated catalytic activity for Ni/TiO_(2)-950 in which rutile ***,the catalytic activity of solar-driven DRM reaction was significantly influenced by the rutile/anatase ***/TiO_(2)-950,characterized by a predominant rutile phase,exhibited the highest DRM reactivity,with remarkable H_(2) and CO production rates reaching as high as 87.4 and 220.2 mmol/(g·h),*** rates were approximately 257 and 130 times higher,respectively,compared to those obtained on Ni/TiO_(2)-700 with *** study suggests that the optimization of crystal structure of TiO_(2) support can effectively enhance the performance of photothermal DRM reaction.

关键词： dry reforming of methane photothermal catalysis crystal phase TiO_(2) metal-support interaction

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Achieving high carrier mobility and low lattice thermal conductivity in GeTe-based alloys by cationic/anionic co-doping

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Rare Metals 2024年第6期43卷 2784-2795页

作者： Xiao-qiang Wang Xiao-Quan Hu Jun-Yan Lin Chu-Bin Li Xiao-Tong Yu Qi-yong Chen Li-Li Xi Qi-Shuo Yang Han Li Ji-Ye Zhang Shuan-Kui Li Kai Guo School of Physics and Materials Science Guangzhou UniversityGuangzhou 510006China Research Center for Advanced Information Materials(CAIM) Huangpu Research&Graduate School of Guangzhou UniversitySino-Singapore Guangzhou Knowledge CityGuangzhou510555China School of Materials Science and Engineering Shanghai UniversityShanghai 200444China Materials Genome Institute Shanghai UniversityShanghai 200444China School of Mechanical and Mining Engineering University of QueenslandBrisbaneQLD 4072Australia Key Laboratory of Si-Based Information Materials&Devices and Integrated Circuits Design Department of Education of Guangdong ProvinceGuangzhou 510006China

TheⅣ-Ⅵcompound GeTe is considered as a promising alternative to the toxic PbTe for high-efficiency mid-temperature thermoelectric ***,pristine GeTe suffers from a high concentration of Ge vacancies,resulting in an excessively high hole concentration(>1×10^(21)cm^(-3)),which greatly limits its thermoelectric *** address this issue,CuBiTe_(2)alloying is introduced to increase the formation energy of Ge vacancies in GeTe,thereby inhibiting the high carrier *** carrier scattering caused by the electronegativity difference between different elements is suppressed due to the similar electronegativity of Cu and Ge atoms.A relatively high hole mobility is obtained,which ultimately leads to a high power ***,by introducing Se as an alloying element at the anionic site in GeTe,dense point defects with mass/strainfield fluctuations are *** contributes to the strengthening of phonon scattering,thereby reducing the lattice thermal conductivity from 1.44 W·m^(-1)·K^(-1)for pristine GeTe to 0.28 W·m^(-1)·K^(-1)for Ge_(0.95)Cu_(0.05)Bi_(0.05)Te_(0.9)Se_(0.15)compound at 623 K.

关键词： GeTe Carrier mobility CuBiTe_(2)alloying Lattice thermal conductivity Thermoelectric properties

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Rapid development of double-hit mRNA antibody cocktail against orthopoxviruses

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Signal Transduction and Targeted Therapy 2024年第4期9卷 1768-1776页

作者： Hang Chi Suo-Qun Zhao Ru-Yi Chen Xing-Xing Suo Rong-Rong Zhang Wen-Hui Yang Dong-Sheng Zhou Min Fang Bo Ying yong-qiang Deng Cheng-Feng Qin State Key Laboratory of Pathogen and Biosecurity Beijing Institute of Microbiology and EpidemiologyAMMS100071BeijingChina College of Life Sciences Inner Mongolia Agricultural UniversityHohhot010018Inner MongoliaChina School of Life Sciences Henan UniversityKaifeng475004HenanChina Suzhou Abogen Biosciences Co. LtdSuzhou215123JiangsuChina Research Unit of Discovery and Tracing of Natural Focus Diseases Chinese Academy of Medical Sciences100071BeijingChina

The Orthopoxvirus genus,especially variola virus(VARV),monkeypox virus(MPXV),remains a significant public health threat *** development of therapeutic antibodies against orthopoxviruses is largely hampered by the high cost of antibody engineering and manufacturing ***-encoded antibodies have emerged as a powerful and universal platform for rapid antibody ***,by using the established lipid nanoparticle(LNP)-encapsulated mRNA platform,we constructed four mRNA combinations that encode monoclonal antibodies with broad neutralization activities against *** vivo characterization demonstrated that a single intravenous injection of each LNP-encapsulated mRNA antibody in mice resulted in the rapid production of neutralizing *** importantly,mRNA antibody treatments showed significant protection from weight loss and mortality in the vaccinia virus(VACV)lethal challenge mouse model,and a unique mRNA antibody cocktail,Mix2a,exhibited superior in vivo protection by targeting both intracellular mature virus(IMV)-form and extracellular enveloped virus(EEV)-form *** summary,our results demonstrate the proof-of-concept production of orthopoxvirus antibodies via the LNP-mRNA platform,highlighting the great potential of tailored mRNA antibody combinations as a universal strategy to combat orthopoxvirus as well as otheremerging viruses.

关键词： proof universal neutral

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Pathological diagnosis and immunohistochemical analysis of giant retrosternal goiter in the elderly: A case report

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World Journal of Clinical Cases 2024年第3期12卷 643-649页

作者： yong-Chang Meng Liu-Sheng Wu Ning Li Hong-Wei Li Jing Zhao Jun Yan Xiao-qiang Li Peng Li Jiang-Qi Wei Department of Cardiothoracic Surgery Xinxiang First People's HospitalXinxiang 453000Henan ProvinceChina School of Clinical Medicine Tsinghua UniversityBeijing 100084China Graduate School Qinghai UniversityXining 810016Qinghai ProvinceChina Department of Pathology Xinxiang First People's HospitalXinxiang 453000Henan ProvinceChina Department of Thoracic Surgery Peking University Shenzhen HospitalShenzhen 518036Guangdong ProvinceChina

BACKGROUND Elderly giant retrosternal thyroid goiter is a rare yet significant medical condition,often presenting clinical symptoms that can be confused with other diseases,posing diagnostic and therapeutic *** study aims to delve into the characteristics and potential mechanisms of this ailment through pathological diagnosis and immunohistochemical analysis,providing clinicians with more precise diagnostic and treatment strategies.A 77-year-old male,was admitted to hospital with the chief complaint of finding a goiter in the semilunar month during physical examination,accompanied by *** protruding into the superior mediastinum,the adjacent structure was compressed,the trachea was compressed to the right,and the local lumen was slightly *** patient was diagnosed with giant retrosternal *** dyspnea caused by trachea compression,our department planned to perform giant retrosternal *** results:Tg(+),TTF-1(+),Calcitonin(CT)(I),Ki-67(+,about 20%),CD34(-).Retrosternal goiter means that more than 50%of the volume of the thyroid gland is below the upper margin of the *** retrosternal goiter disease is a relatively rare disease,once the disease is diagnosed,it should be timely surgical treatment,and the treatment is more difficult,the need for professional medical team for comprehensive *** The imaging manifestations of giant retrosternal goiter are atypical,histomorphology and immunohistochemistry can assist in its *** article reviews the relevant literature of giant retrosternal goiter immunohisto-chemistry and shows that giant retrosternal goiter is positive for Tg,TTF-1,and Ki-67.

关键词： Giant retrosternal goiter Pathology Immunohistochemistry Case report

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基于模型算法的注塑制品质量预测控制研究进展

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中国塑料 2024年第4期38卷 98-102页

作者：龚强金志明北京化工大学机电工程学院北京100029

介绍了模型算法在注射成型技术中的应用,综述了相关模型算法在注射成型各阶段的预测控制成效,最后提出模型算法在注塑制品质量预测控制中的未来研究方向和相关技术发展趋势。

关键词：注塑制品预测控制模型构建大数据算法

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基于多目标遗传算法的8×8 S盒的优化设计方法

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西南交通大学学报 2024年第3期59卷 519-527,538页

作者：王永王明月龚建重庆邮电大学计算机科学与技术学院重庆400065 桂林电子科技大学广西密码学与信息安全重点实验室广西桂林541004

混沌系统具有非线性、伪随机性、初始值敏感等特性,为基于动力系统构造性能良好的S盒提供了基础,进一步保证了分组加密算法安全性.目前,基于混沌构造S盒的方法大多数针对单个性能指标进行优化,难以获得全面的性能提升.针对此问题,结合... 详细信息

混沌系统具有非线性、伪随机性、初始值敏感等特性,为基于动力系统构造性能良好的S盒提供了基础,进一步保证了分组加密算法安全性.目前,基于混沌构造S盒的方法大多数针对单个性能指标进行优化,难以获得全面的性能提升.针对此问题,结合混沌映射与多目标遗传算法,提出了一种新的S盒设计方法.首先,利用混沌映射的特性产生初始S盒种群;然后,以S盒的非线性度和差分均匀性为优化目标,基于遗传算法框架对上述两指标进行优化.针对S盒的特点,在优化算法中引入了交换操作,设计了新的变异操作以及非支配序集计算,有效提升了S盒的非线性度和差分均匀性.实验结果表明该算法产生的S盒其差分均匀度为6,非线性度值至少为110,有效提升了S盒的综合性能.

关键词： S盒非线性度差分均匀度多目标遗传算法混沌映射

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基于注意力机制和价值强化学习的WRSN一对多充电调度方法

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传感技术学报 2024年第8期37卷 1411-1423页

作者：龚政冯勇昆明理工大学云南省计算机技术应用重点实验室云南昆明650500

在大规模无线可充电传感器网络(WRSN)中,一对一充电模型难以满足节点巨大能量需求,充电效率更高的一对多充电成为更合理选择。提出了一种基于注意力机制和价值强化学习的WRSN在线一对多充电调度方法(MAQRL),从充电序列和充电时长两方面... 详细信息

在大规模无线可充电传感器网络(WRSN)中,一对一充电模型难以满足节点巨大能量需求,充电效率更高的一对多充电成为更合理选择。提出了一种基于注意力机制和价值强化学习的WRSN在线一对多充电调度方法(MAQRL),从充电序列和充电时长两方面优化移动充电设备(MC)调度。首先,基于MC有效充电范围覆盖最多节点对网络内节点进行分簇处理,并基于价值强化学习优化充电序列。MAQRL结合注意力机制和价值强化学习,利用注意力机制提取特征和MC对节点的注意力,利用双价值强化学习来减少高估,以提高充电方法的充电性能;其次,通过分析整个网络中节点的平均剩余生存时长和MC平均移动延迟,动态优化充电时间,减少后续节点因等待时间过长而导致的死亡。大量的仿真实验表明,与现有几种充电方法相比,MAQRL在降低节点死亡率和充电延迟方面具有显著优势。

关键词：无线可充电传感器网络充电调度一对多充电注意力机制价值强化学习

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考虑能耗与负载因素的抓取机械臂运动轨迹规划算法

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吉林大学学报（工学版） 2024年第7期54卷 1862-1868页

作者：汤小红龚永健中南林业科技大学机电工程学院长沙410000

针对抓取机械臂运动轨迹规划不合理导致的运动路程增加及能耗加剧问题,提出了考虑能耗与负载因素的抓取机械臂运动轨迹规划算法。根据运动学原理建立抓取机械臂运动学模型,通过齐次变换矩阵求解各环节空间位置、姿态,利用时间间隔序列... 详细信息

针对抓取机械臂运动轨迹规划不合理导致的运动路程增加及能耗加剧问题,提出了考虑能耗与负载因素的抓取机械臂运动轨迹规划算法。根据运动学原理建立抓取机械臂运动学模型,通过齐次变换矩阵求解各环节空间位置、姿态,利用时间间隔序列、三次非均匀B样条插值算法约束各个关节角度、速度及其加速度,使其运动轨迹能耗、负载最优;采用线性回归分析方程生成新的群体,找出该群体最优粒子并将其替换原群体中任意一个粒子,反复该过程,即可找出群体最优运动轨迹。实验结果表明,本文算法收敛速度快,且运动轨迹能耗最低。

关键词：能耗计算负载平衡抓取机械臂运动轨迹运动学混沌群体粒子群算法

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Analysis and comparison of retinal vascular parameters under different glucose metabolic status based on deep learning

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International Journal of Ophthalmology(English edition) 2024年第9期17卷 1581-1591页

作者： Yan Jiang Di gong Xiao-Hong Chen Lin Yang Jing-Jing Xu Qi-Jie Wei Bin-Bin Chen yong-Jiang Cai Wen-Qun Xi Zhe Zhang Departments of Laboratory Medicine the Second Affiliated HospitalZhejiang University School of MedicineHangzhou 310009Zhejiang ProvinceChina Shenzhen Eye Hospital Jinan UniversityShenzhen 518040Guangdong ProvinceChina Center of Health Management Peking University Shenzhen HospitalShenzhen 518036Guangdong ProvinceChina Visionary Intelligence Ltd. Beijing 100080China Ophthalmology Center the Second Affiliated HospitalZhejiang University School of MedicineHangzhou 310009Zhejiang ProvinceChina

AIM:To develop a deep learning-based model for automatic retinal vascular segmentation,analyzing and comparing parameters under diverse glucose metabolic status(normal,prediabetes,diabetes)and to assess the potential of artificial intelligence(AI)in image segmentation and retinal vascular parameters for predicting prediabetes and ***:Retinal fundus photos from 200 normal individuals,200 prediabetic patients,and 200 diabetic patients(600 eyes in total)were *** U-Net network served as the foundational architecture for retinal arteryvein *** automatic segmentation and evaluation system for retinal vascular parameters was trained,encompassing 26 ***:Significant differences were found in retinal vascular parameters across normal,prediabetes,and diabetes groups,including artery diameter(P=0.008),fractal dimension(P=0.000),vein curvature(P=0.003),C-zone artery branching vessel count(P=0.049),C-zone vein branching vessel count(P=0.041),artery branching angle(P=0.005),vein branching angle(P=0.001),artery angle asymmetry degree(P=0.003),vessel length density(P=0.000),and vessel area density(P=0.000),totaling 10 ***:The deep learning-based model facilitates retinal vascular parameter identification and quantification,revealing significant *** parameters exhibit potential as biomarkers for prediabetes and diabetes.

关键词： deep learning retinal vascular parameters segmentation model diabetes prediabetes

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Why we need a new journal in diversity and conservation

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Zoological Research(Diversity and Conservation) 2024年第1期1卷 1-2页

作者： yong-Gang Yao Xue-Long Jiang Shu-qiang Li Kunming institute of Zoology Chinese Academy of SciencesKunmingYunnan 650223China Institute of Zoology Chinese Academy of SciencesBeijing 100101China

It is not difficult to imagine humankind as stewards and custodians of the vast,complex,unique,and awe-inspiring property called Planet *** are duty-bound to take good care of this priceless property,for our own well-being,and for the well-being of our future *** take stock of the value of our property by understanding its fragile biodiversity;and we safeguard its value by monitoring and protecting *** as a piece of real estate is livable only if it is wellsupported by utilities and other municipal services,we have a duty to ensure that the natural habitats and the crucial ecological services they provide are in tip-top *** requires a deep understanding how an intricate,vibrant,and resilient ecosystem works,and how natural forces and manmade decisions can impact its sustainability,both positively and negatively.

关键词： property journal services

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