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Improving Li reversibility in Li metal batteries through uniform dispersion of Ag nanoparticles on graphene

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Rare Metals 2022年第10期41卷 3391-3400页

作者： Yu Gao Bing-Feng Cui Jia-Jun Wang Zhao-Yong Sun Qiang Chen yi-da deng Xiao-Peng Han Wen-Bin Hu School of Materials Science and Engineering Tianjin Key Laboratory of Composite and Functional Materials Key Laboratory of Advanced Ceramics and Machining TechnologyTianjin UniversityTianjin300350China Joint School of National University of Singapore and Tianjin University International Campus of Tianjin UniversityFuzhou350207China China Energy Lithium Co. LtdTianjin300072China State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and EngineeringHainan UniversityHaikou570228China

Li metal is the most attractive and promising anode material for next-generation high-energy ***,uncontrolled Li dendrite growth during cycling remains a highly challenging *** solve this problem,silver-coated graphene(Ag/GH)was prepared via a simple liquid-phase reduction *** effect of Ag/GH on Li deposition behavior was investigated by adjusting the dispersion of Ag nanoparticles(Ag NPs).Subsequently,a composite electrode was fabricated via uniform deposition of metallic Li on Ag/*** was used as a lithiophilic nucleating agent to ensure uniform deposition of Li and inhibit the growth of Li dendrites on the *** prepared composite anode showed a significantly improved performance compared to the unmodified *** symmetric cell comprising this composite electrode exhibited a stable cycling performance with a low hysteresis of~40 mV and a lifetime of>2000 h at a current density of 0.5 mA·cm^(-2).Meanwhile,the discharge capacity reached 0.5 mAh·cm^(-2).In addition,Ag/GH was found to be amenable to large-scale ***,the composite Ag/GH anode exhibited improved performance and the preparation method showed significant potential for application in the manufacture of Li metal batteries.

关键词： Ag/graphene composite Uniform Li deposition Li anodes Li metal batteries

Size-controllable synthesis and high-performance formic acid oxidation of polycrystalline Pd nanoparticles

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Rare Metals 2019年第2期38卷 115-121页

作者： Hui-Hui Wang Jin-Feng Zhang Ze-Lin Chen Meng-Meng Zhang Xiao-Peng Han Cheng Zhong yi-da deng Wen-Bin Hu Tianjin Key Laboratory of Composites and Functional Materials and Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education) Tianjin University

A facile approach was developed for the synthesis of polycrystalline palladium nanoparticles(Pd NPs)by using tannic acid(TA) as green reagent and stabilizer in a 30 ℃ water bath. The size of Pd NPs can be tuned in a range of 10–60 nm simply by adjusting the concentration of Pd precursor. The catalytic activity and stability of the as-obtained Pd NPs toward formic acid oxidation were analyzed. It is found that these Pd NPs with different sizes exhibit size-dependent and enhanced formic acid oxidation performance compared to the commercial Pd black catalyst. It should be noted that the Pd catalysts with an average size of 24 nm demonstrate the best catalytic activity and stability among the other prepared Pd NPs, which can be ascribed to its larger electrochemical surface area(ECSA)and polycrystalline structure with defects.

关键词： Polycrystalline palladium nanoparticle Size controllable Tannic acid: Room temperature Formic acid oxidation

Spontaneous anchoring Cl intoα-Co(OH)_(2) as efficient and stable oxygen reduction electrocatalysts for seawater battery

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Rare Metals 2024年第7期43卷 3074-3083页

作者： Wang Zheng Xue-Rong Zheng Qi Lu Yan-Hui Cao Yang Wang Hai-Peng Fu Jin-Feng Zhang yi-da deng Wen-Bin Hu School of Materials Science and Engineering Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of EducationTianjin UniversityTianjin 300072China State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and EngineeringHainan UniversityHaikou 570228China Key Laboratory of Electromagnetic Processing of Materials Ministry of EducationNortheastern UniversityShenyang 110819China

Seawater battery is an advanced energy storage system that enables conversion of chemical energy to electricity by consuming metals,dissolved oxygen and seawater in anode,cathode and electrolyte,***,the oxygen reduction reaction(ORR)activity and stability of electrocatalysts can be easily deactivated due to the severe Cl~-permeation and corrosion in seawater ***,we developed a structural buffer engineering strategy by spontaneously anchoring Cl~-intoα-Co(OH)_(2) as efficient and stable ORR electrocatalysts,in which the ultrathinα-Co(OH)_(2) nanosheets were synthesized using an ultrafast solution high-temperature shock(SHTS)*** large lattice space(~0.8 nm)of layeredα-Co(OH)_(2) ensured the spontaneously penetration of Cl~-into the lattice structure and replaced part of OH~-to formα-Co(OH)_(2-x)Cl_*** continuous leaching and compensating of saturated Cl inα-Co(OH)_(2-x)Cl_x could enhance the Cl~-corrosion resistance and modulate electronic structure of Co metallic sites,thus improving the ORR electrocatalytic activity and stability in seawater ***α-Co(OH)_(2-x)Cl_x seawater batteries display superior onset and half-wave potentials of 0.71 and 0.66 V,respectively,which are much better than the counterparts ofα-Co(OH)_(2) and ofβ-Co(OH)_(2) with no Cl~-penetrating and no buffer ***α-Co(OH)_(2-x)Cl_x-based seawater batteries display stable open-circuit potential of 1.69 V and outstanding specific capacity of 1345 mAh·g^(-1).

关键词： Seawater battery Oxygen reduction electrocatalyst Solution high-temperature shock Structural buffer engineering

A review of non-noble metal-based electrocatalysts for CO_(2)electroreduction

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Rare Metals 2021年第11期40卷 3019-3037页

作者： Jia-Jun Wang Xiao-Peng Li Bing-Feng Cui Zhao Zhang Xiao-Fei Hu Jia Ding yi-da deng Xiao-Peng Han Wen-Bin Hu School of Materials Science and Engineering Tianjin Key Laboratory of Composite and Functional MaterialsKey Laboratory of Advanced Ceramics and Processing Technology(Ministry of Education)Tianjin UniversityTianjin 300072China Thayer School of Engineering Dartmouth CollegeHanover NH 03755USA Joint School of National University of Singapore and Tianjin University International Campus of Tianjin UniversityFuzhou 350207China

The excessive emission of CO_(2) has caused many environmental issues and is severely threatening the ***_(2) electroreduction reaction(CO_(2) RR) that driven by sustainable power is an ideal route for realizing the net reduction of CO_(2) and carbon *** efficient electrocatalysts with low cost and high performance is critical for the wide applications of CO_(2) RR *** the various explored CO_(2) RR catalysts,non-noble metal(NNM)-based nanomaterials have drawn increasing attentions due to the remarkable performance and low *** this mini-review,the recent advances of NNM-based CO_(2) RR catalysts are summarized,and the catalysts are classified based on their corresponding reduction *** preparation strategies for engineering the electrocatalysts are introduced,and the relevant CO_(2) RR mechanisms are discussed in ***,the current challenges in CO_(2) RR research are presented,and some perspectives are proposed for the future development of CO_(2) RR *** mini-review introduces the recent advances and frontiers of NNM-based CO_(2) RR catalysts,which should shed light on the further exploration of efficient CO_(2) RR electrocatalysts.

关键词： CO_(2)electroreduction Non-noble metals Reaction mechanism Heterogeneous catalysis Structural-function relationship

Sp/sp^(2)carbon ratio-driven high-throughput screening of electrocatalytic nitrogen reduction performance on transition metal single-atom catalysts

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Rare Metals 2024年第11期43卷 5781-5791页

作者： Ze-Xiang yin Yu-dan Li Yu-Huan Ye Yuan Liu Mian-Feng Li Zi-Jun Yang Xue-Rong Zheng Hao-Zhi Wang Yang Wang yi-da deng State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and EngineeringHainan UniversityHaikou 570100China School of Materials Science and Engineering Tianjin Key Laboratory of Composite and Functional MaterialsKey Laboratory of Advanced Ceramics and Machining Technology(Ministry of Education)Tianjin UniversityTianjin 300072China

Single-atom catalysts(SACs)have been widely utilized in electrochemical nitrogen reduction reactions(NRR)due to their high atomic utilization and *** to the unique sp/sp^(2)co-hybridization,graphyne materials can offer stable adsorption sites for single metal *** investigate the influence of the sp/sp^(2)hybrid carbon ratio on the electrocatalytic NRR performance of graphyne,a high-throughput screening of 81 catalysts,with27 transition metals loaded on graphyne(GY1),graphdiyne(GY2),and graphtriyne(GY3),was conducted using firstprinciples *** results of the screening revealed that Ti@GY3 exhibits the lowest energy barrier for the rate-determining step(0.32 eV)in ***,to explore the impact of different sp/sp^(2)-hybridized carbon ratios on the catalytic activity of SACs,the mechanism of nitrogen(N_(2))adsorption,activation,and the comprehensive pathway of NRR on Ti@GY1,Ti@GY2,and Ti@GY3 was systematically *** was found that the ratio of sp/sp^(2)-hybridized carbon can significantly modulate the d-band center of the metal,thus affecting the energy barrier of the rate-determining step in NRR,decreasing from Ti@GY1(0.59 eV)to Ti@GY2(0.49 eV);and further to Ti@GY3(0.32 eV).Additionally,the Hall conductance was found to increase with the bias voltage in the range of 0.4-1 V,as calculated by Nanodcal software,demonstrating an improvement in the conductivity of the *** summary,this work provides theoretical guidance for modulating the electrocatalytic nitrogen reduction activity of SACs by varying the ratio of sp/sp^(2)hybrid carbon,with Ti@GY3 showing potential as an excellent NRR catalyst.

关键词： Nitrogen reduction reactions Single-atom catalysts Graphyne Ratio of sp/sp^(2)hybrid carbon High-throughput screening

Recent advances in Ir/Ru-based perovskite electrocatalysts for oxygen evolution reaction

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Rare Metals 2024年第7期43卷 2891-2912页

作者： Zhi-Qi Jiang Cheng-Zhen Fan Jun-Yu Pan Li Shao Hao Chen Erum Pervaiz Yan Dong Tong-Zhou Wang Xue-Rong Zheng Ji-Hong Li yi-da deng School of Materials Science and Engineering Hainan UniversityHaikou570228Chin Department of Chemical Engineering School of Chemical and Materials Engineering(SCME)National University of Sciences&Technology(NUST)Islamabad 44000Pakistan Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071Chin

Oxygen evolution reaction(OER)is a kinetically harsh four-electron anode reaction that requires a large overpotential to provide current and is of great importance in renewable electrochemical ***/Rubased perovskite oxides hold great significance for application as OER electrocatalysts,due to that their multimetal-oxide forms can reduce the use of noble metals,and their compositional tunability can modulate the electronic structure and optimize OER ***,high operating potentials and corrosive environments pose a serious challenge to the development of durable Ir-based and Ru-based perovskite *** efforts have been dedicated to improving the Ir/Ru-based perovskite activity to enhance the efficiency;however,progress in improving the durability of Ir/Ru-based perovskite electrocatalysts has been rather *** this review,the recent research progress of Ir/Ru-based perovskites is reviewed from the perspective of heteroatom doping,structural modulation,and formation of *** dissolution mechanism studies of Ir/Ru and experimental attempts to improve the durability of Ir/Ru-based perovskite electrocatalysts are *** and outlooks for further developing Ru-and Irbased perovskite oxygen electrocatalysts are also presented.

关键词： Oxygen evolution reaction Ir/Ru-based perovskites Stability Electrocatalysts

Tungsten disulfide-based nanomaterials for energy conversion and storage

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Tungsten 2020年第2期2卷 109-133页

作者： Chang‑Bin Sun Yu‑Wei Zhong Wen‑Jie Fu Ze‑Quan Zhao Jie Liu Jia Ding Xiao‑Peng Han yi‑da deng Wen‑Bin Hu Cheng Zhong School of Materials Science and Engineering Tianjin UniversityTianjin 300072China Joint School of National University of Singapore and Tianjin University International Campus of Tianjin UniversityFuzhou 350207China

Energy and environmental issues received widespread attentions due to the fast growth of world population and rapid development of social *** a transition metal dichalcogenide,tungsten disulfide(WS_(2))nanomaterials make important research progress in the field of energy conversion and *** view of the versatile and rich microstructure of these mate-rials,the modification and controllable synthesis of WS_(2) nanomaterials also inspire a research *** review mainly focuses on WS_(2)-based nanomaterials in the application of energy conversion and storage as well as discusses some basic characteristics and modification strategies of ***,the research progress of WS_(2)-based nanomaterials is reviewed and some prospects for future research directions are *** review is expected to be beneficial to the future study of WS_(2) nanomaterials used in the field of energy conversion and storage.

关键词： Nanomaterials Tungsten disulfide Controlled synthesis Energy conversion Energy storage

MoS2 synaptic transistor with one-step manufacture

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Science China(Information Sciences) 2025年第1期68卷 357-365页

作者： yihao GUO Yang WANG Wenjie deng yi WU Jingtao LI Kexin LI Yuehui ZHAO Songlin YU Xiaoting WANG Yongzhe ZHANG Hui YAN Key Laboratory of Optoelectronics Technology of Education Ministry of China Faculty of Information TechnologyBeijing University of Technology Key Laboratory of Advanced Functional Materials Ministry of Education Faculty of Materials and ManufacturingBeijing University of Technology The 11th Research Institute of Electronics Technology Group Corporation

The synaptic transistor,which is a neuromorphic device with brain-like functions,has garnered significant attention due to characteristics such as low energy consumption,high integration,multiple functions,and high computational ***,the current synaptic transistor possesses a complicated structure and involves complex manufacturing steps,which is not conducive to low-cost,large-scale bionic ***,we introduce a simple MoS2synaptic transistor exhibiting robust synaptic *** transistor utilizes magnetron sputtering manufacture to combine the process of device metal electrode deposition and the introduction of defect states,which helps streamline the manufacturing process into a single *** long-term potentiation and long-term depression in photoelectric coordination are initially ***,biological functions,such as double pulse facilitation and the transformation behavior of short-term memory to long-term memory,are thoroughly evaluated,along with learning-forgetting-relearning ***,the device exhibits robust synaptic plasticity until incident light angles down to 30° to imitate the multi-to-one axon-cellular ***,a classical simulation of Pavlov's dog conditioned reflex is demonstrated along with the multiview extraction *** experimental results demonstrate a promising synaptic transistor with a simple structure,manufacturing technique,and excellent *** further indicates the potential for large-scale integration of bionic neuromorphic systems.

关键词： process optimization artificial synaptic device one-stepmanufacture synaptic plasticity bionic simulation

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Inter‑Skeleton Conductive Routes Tuning Multifunctional Conductive Foam for Electromagnetic Interference Shielding,Sensing and Thermal Management

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Nano-Micro Letters 2025年第3期17卷 19-36页

作者： Xufeng Li Chunyan Chen Zhenyang Li Peng yi Haihan Zou Gao deng Ming Fang Junzhe He Xin Sun Ronghai Yu Jianglan Shui Caofeng Pan Xiaofang Liu School of Materials Science and Engineering Beihang UniversityBeijing 100191People’s Republic of China Institute of Atomic Manufacturing Beihang UniversityBeijing 100191People’s Republic of China Tianmushan Laboratory Xixi Octagon CityYuhang DistrictHangzhou 310023People’s Republic of China Science and Technology On Electromagnetic Scattering Laboratory Beijing Institute of Environmental FeaturesBeijing 100854People’s Republic of China

Conductive polymer foam(CPF)with excellent compressibility and variable resistance has promising applications in electromagnetic interference(EMI)shielding and other integrated functions for wearable ***,its insufficient change amplitude of resistance with compressive strain generally leads to a degradation of shielding performance during ***,an innovative loading strategy of conductive materials on polymer foam is proposed to significantly increase the contact probability and contact area of conductive components under *** inter-skeleton conductive films are constructed by loading alginate-decorated magnetic liquid metal on the polymethacrylate films hanged between the foam skeleton(denoted as AMLM-PM foam).Traditional point contact between conductive skeletons under compression is upgraded to planar contact between conductive ***,the resistance change of AMLM-PM reaches four orders of magnitude under ***,the inter-skeleton conductive films can improve the mechanical strength of foam,prevent the leakage of liquid metal and increase the scattering area of EM ***-PM foam has strain-adaptive EMI shielding performance and shows compression-enhanced shielding effectiveness,solving the problem of traditional CPFs upon *** upgrade of resistance response also enables foam to achieve sensitive pressure sensing over a wide pressure range and compression-regulated Joule heating function.

关键词： Inter-skeleton conductive films Conductive polymer foam Liquid metal Electromagnetic interference shielding