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Carbon coated LaFe_(0.92)Pd_(0.08)O_(3) composites for catalytic transfer hydrogenation:Balance in the ability of substrates adsorption and conversion

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Nano Research 2024年第5期17卷 3724-3732页

作者： Bowen Wang Nan Zhang Ping Xiao Jian Zhang Sónia A.C.Carabineiro Junjiang Zhu Hubei Key Laboratory of Biomass Fibers and Eco-dyeing&Finishing College of Chemistry and Chemical EngineeringWuhan Textile UniversityWuhan 430200China College of Chemistry and Materials Engineering Wenzhou UniversityWenzhou 325035China LAQV-REQUIMTE Department of ChemistryNOVA School of Science and TechnologyUniversidade NOVA de LisboaLargo da Torre2829-516 CaparicaPortugal

Catalytic transfer hydrogenation(CTH)is a green and efficient pathway for selective hydrogenation of unsaturated aldehydes and ***,managing the abilities of solid catalysts to adsorb substrates and to convert them into desired products is a challenging ***,we report the synthesis of carbon coated LaFe_(0.92)Pd_(0.08)O_(3) composites(LFPO-8@C)for CTH of benzaldehyde(BzH)into benzyl alcohol(BzOH),using isopropanol(IPA)as hydrogen *** coating with carbon improves the ability to adsorb/transfer reactants from solution to active sites,and the doping of Pd2+at Fe3+site strengthens the ability of LaFeO_(3) to convert BzH into BzOH.A balanced point between them(i.e.,abilities to adsorb BzH and to convert BzH into BzOH)is obtained at LFPO-8@C,which exhibits a BzOH formation rate of 3.88 mmol·gcat^(-1)·h^(-1) at 180℃ for 3 h,which is 1.50 and 2.72 times faster than those of LFPO-8 and LaFeO_(3)@C.A reaction mechanism is proposed,in which the acidic sites(e.g.,Fe^(4+),oxygen vacancy)are used for the activation of C=O bond of BzH and O-H bond of IPA,and the basic sites(e.g.,lattice oxygen)for the activation ofα-H(O-H)bond of IPA.

关键词： LaFe_(0.92)Pd_(0.08)O_(3) porous carbon catalytic transfer hydrogenation isopropanol reaction mechanism

Enhancing visible-light-driven NO oxidation through molecular‐level insights of dye-loaded sea sands

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Rare Metals 2024年第2期43卷 543-554页

作者： Yu-Han Li Bang-Fu Chen Sónia A.C.Carabineiro You-Yu Duan Ping Tan Wing-Kei Ho Fan Dong Engineering Research Center for Waste Oil Recovery Technology and Equipment Ministry of EducationChongqing Key Laboratory of Catalysis and New Environmental MaterialsChongqing Technology and Business UniversityChongqing400067China Nanchang Institute of Technology Nanchang33044China LAQV-REQUIMTE Department of ChemistryNOVA School of Science and TechnologyUniversidade NOVA de Lisboa2829-516CaparicaPortugal College of Physics and Center of Quantum Materials and Devices Chongqing UniversityChongqing401331China Department of Science and Environmental Studies The Education University of Hong KongHong Kong999077China

Natural minerals,abundant and easily obtained through simple physical processing,offer a cost-effective and environmentally friendly solution for dyeing wastewater disposal and air pollution *** study investigates the photocatalytic removal of NO using natural different types of dyes,loaded on natural sand,under visible light *** examining various coating concentrations of dyes and sand weights,we discovered that sand loaded with Rhodamine B(RhB)exhibits high activity for the photo-oxidation of NO.A combination results of X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),Fourier transform infrared spectroscopy(FTIR)and thermogravimetric(TG)analyses confirm the presence of SiO_(2),CaCO_(3),Al_(2)O_(3)and iron oxides as the main components of the ***,studying RhB-loaded individual components reveals that CaCO_(3)plays a crucial role in enhancing the NO removal *** results and theoretical calculations demonstrate the establishment of a directional charge transfer channel from CaCO_(3)to RhB,facilitating the adsorption and activation of molecular NO and O_(2).This work not only promotes the utilization of natural mineral resources but also enriches the fields of environmental photochemistry and semiconductor photocatalysis.

关键词： Sand dyes Rhodamine B Photo-oxidation of NO Visible light illumination

环氧树脂涂层中添加含铝复合粉增强碳钢基材的防腐性

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Journal of Central South University 2024年第3期31卷 723-736页

作者： Meysam TOOZANDEHJANI Pooria MOOZARM nia Ebrahim ABOUZARI LOTF Farhad OSTOVAN Mahnaz SHAMSHIRSAZ New Technologies Research Center Amirkabir University of TechnologyTehran Polytechnic424 Hafez Ave.P.B.15875-4413TehranIran Section for Surface Physics and Catalysis Department of PhysicsTechnicFysikvejBygning 311Kongens LyngbyDK-2800Denmark Institute of Nanotechnology and Institute of Quantum Materials and Technology Karlsruhe Institute of TechnologyP.O.Box 364076021 KarlsruheGermany Department of Materials Science and Engineering Bandar Abbas BranchIslamic Azad UniversityBandar AbbasIran

采用电化学阻抗谱(EIS)和电位极化(Tafel)试验,研究了在环氧树脂涂层中添加含铝粉末以增强碳钢基材的防腐性,含铝粉末包括纯铝、Al/CNT、Al/Al_(2)O_(3)、Al/CNT/Al_(2)O_(3)。用球磨法合成含2 wt.%碳纳米管、2 wt.%氧化铝纳米颗粒的复... 详细信息

采用电化学阻抗谱(EIS)和电位极化(Tafel)试验,研究了在环氧树脂涂层中添加含铝粉末以增强碳钢基材的防腐性,含铝粉末包括纯铝、Al/CNT、Al/Al_(2)O_(3)、Al/CNT/Al_(2)O_(3)。用球磨法合成含2 wt.%碳纳米管、2 wt.%氧化铝纳米颗粒的复合粉末,然后以1 wt.%的浓度加入到环氧树脂涂层中。结果表明,由于环氧树脂复合涂层的防护性能增强,从而提高了其耐腐蚀性。研究还发现,Al/CNT/Al_(2)O_(3)复合添加剂的保护性能比其他添加剂更显著,因为其颗粒尺寸的减小和具有某些形状的颗粒,进一步减少了腐蚀环境通过涂层渗透的路径,避免了金属基底/涂层界面可能发生的反应。EP-Al/CNT/Al_(2)O_(3)保持了一次时间常数特性,并在整个暴露时间内表现出最高的阻抗和最强的稳定性。这些添加剂的存在增强了涂层,从而改善了涂层的屏障性能。

关键词：铝复合材料环氧树脂复合材料涂层腐蚀电化学阻抗图谱(EIS) Tafel极化

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叶谦,一个独立设计师的十年

艺术与设计 2024年第3期291卷 106-109页

作者：冀靖轩 yes BY yesIR(图) 不详

中国古代道家哲学“道生一,一生二,二生三,三生万物”道出万物发展本末,矛盾对立,但又和谐统一的共生关系。这与中国时装设计师叶谦给人的第一印象不谋而合。身为设计师,他却保有最理性的处事方法;学习西方系统的服装设计.

关键词：时装设计师服装设计第一印象三生万物道生一共生关系道家哲学矛盾对立

BIM Improved with RV and AR Technologies

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Journal of Software Engineering and Applications 2024年第6期17卷 508-521页

作者： Alcínia Zita Sampaio Raquel S. Sarmento Augusto M. Gomes Department of Civil Engineering University of Lisbon Lisbon Portugal CERISCivil Engineering Research and Innovation for Sustainability IST University of Lisbon Lisbon Portugal

The study addresses the integration of the Building Information Modelling (BIM) methodology with Virtual Reality (VR) and Augmented Reality (AR) technologies in the context of the development of a multidisciplinary project, involving architecture, structures, water network and electrical system components. In order to cover in detail the various design features, the case study was limited to a specific area of a house, the sanitary rooms, as it presents sufficient complexity in modeling and the application of VR and AR software. The VR/AR functionalities applied over the BIM model increase the potential of BIM in the construction sector, contributing to the achievement of a high level of collaboration and control of the project based on an immersive and interactive environment. The elaboration of the different phases of a BIM design requires the transfer of models between BIM and VR/AR systems, allowing us to analyze the main advantages that BIM/VR/AR integration can introduce in the construction industry. The study contributes positively to achieving new knowledge in BIM, being disseminated in an academic research work and illustrated in a practical context.

关键词： BIM Multi-Disciplines Modeling Virtual Reality Augmented Reality Integration BIM/VR/AR Collaboration

Electrocatalytic synthesis of C-N coupling compounds from CO_(2) and nitrogenous species

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SusMat 2024年第2期4卷 51-74页

作者： Zheng Zhang Danyang Li Yunchuan Tu Jiao Deng Huiting Bi Yongchao Yao Yan Wang Tingshuai Li Yongsong Luo Shengjun Sun Dongdong Zheng Sónia A.C.Carabineiro Zhou Chen Junjiang Zhu Xuping Sun Hubei Key Laboratory of Biomass Fibers and Eco-Dyeing&Finishing College of Chemistry and Chemical EngineeringWuhan Textile UniversityWuhanHubeiChina School of Chemistry and Chemical Engineering Chongqing UniversityChongqingChina i-Lab Vacuum Interconnected NanotechWorkstation(Nano-X)Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhouJiangsuChina Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengduSichuanChina College of Chemistry Chemical Engineering and Materials ScienceShandong Normal UniversityJinanShandongChina LAQV-REQUIMTE Department of ChemistryNOVA School of Science and TechnologyUniversidade NOVA de Lisboa2829-516 CaparicaPortugal College of Materials Xiamen UniversityXiamenFujianChina

The electrocatalytic synthesis of C-N coupling compounds from CO_(2) and nitrogenous species not only offers an effective avenue to achieve carbon neutral-ity and reduce environmental pollution,but also establishes a route to synthesize valuable chemicals,such as urea,amide,and *** innovative approach expands the application range and product categories beyond simple carbona-ceous species in electrocatalytic CO_(2) reduction,which is becoming a rapidly advancing *** review summarizes the research progress in electrocatalytic urea synthesis,using N_(2),NO_(2)^(-),and NO_(3)^(-)as nitrogenous species,and explores emerging trends in the electrosynthesis of amide and amine from CO_(2) and nitro-gen ***,the future opportunities in this field are highlighted,including electrosynthesis of amino acids and other compounds containing C-N bonds,anodic C-N coupling reactions beyond water oxidation,and the catalytic mechanism of corresponding *** critical review also captures the insights aimed at accelerating the development of electrochemical C-N coupling reactions,confirming the superiority of this electrochemical method over the traditional techniques.

关键词： C-N coupling CO_(2) reduction electrocatalysis nitrogenous species reaction mechanism

Emergency Care for Children and Adolescents after Sexual Violence, in Brazil’s Capital, Brasilia

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Open Journal of Epidemiology 2024年第2期14卷 397-403页

作者： Evaldo Lima Da Costa Karla Simônia de Pádua Aníbal Faúndes Rui Nunes Bioethics at the School of Medicine University of Porto/Federal Council of Medicine Porto Portugal Center for Research in Women’ s Reproductive Health (CEMICAMP) Center for Integral Attention to Women (CAISM) State University of Campinas Campinas Brazil Center for Research in Women’ s Reproductive Health (CEMICAMP) State University of Campinas (UNICAMP) Campinas Brazil. The Centre of Bioethics Faculty of Medicine University of Porto Porto Portugal

Objective: Sexual violence affects women of all ages but, more commonly, children and adolescents. This study aimed to identify the extent to which services are being provided at the hospitals responsible for the emergency care of children and adolescents who have suffered sexual violence and to determine whether there is any difference in the provision of such services as a function of the victim’s age. Method: This cross-sectional study investigated differences in the care received by female children and adolescents who are victims of sexual violence in a capital city, comparing the treatment given to girls under 15 with that given to adolescents of 15 to 19 years of age. The data were extracted from the State Department of Health database between 01/01/2012 and 31/12/2016. Results: Children under 15 were much less likely to receive prophylaxis against HIV, sexually transmitted infections and hepatitis B, with the number of adolescent girls treated adequately corresponding to between twice and almost three times the number of children treated prophylactically. Only 10% of girls under 15 received emergency contraception. Conclusion: The lack of standard care established by the Ministry of Health highlights the need for urgent debates both locally and probably throughout the country, as the situation may be similar in other regions of the country.

关键词： Aggressors Children Sexual Violence Teenagers

Methionine sources and genotype affect embryonic intestinal development,antioxidants,tight junctions,and growth-related gene expression in chickens

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Animal Nutrition 2024年第1期16卷 218-230页

作者： James K.Lugata Sawadi F.Ndunguru Gebrehaweria K.Reda Xénia E.Ozsváth Eszter Angyal Levente Czeglédi Gabriella Gulyás Renáta Knop János Oláh Zoltán Mészár Rita Varga Brigitta Csernus Csaba Szabó Department of Animal Nutrition and Physiology Faculty of Agriculture and Food Sciences and Environmental ManagementUniversity of DebrecenDebrecenHungary Department of Animal Husbandry Faculty of Agriculture and Food Sciences and Environmental ManagementUniversity of DebrecenDebrecenHungary Faculty of Agriculture and Food Sciences and Environmental Management Doctoral School of Animal ScienceUniversity of DebrecenDebrecenHungary Institutes for Agricultural Research and Educational Farm University of DebrecenDebrecenHungary Department of Anatomy Histology and EmbryologyFaculty of MedicineUniversity of DebrecenDebrecenHungary Department of Evolutionary Zoology and Human Biology Faculty of Science and TechnologyUniversity of DebrecenDebrecenHungary

Methionine(Met)is an essential and first limiting amino acid in the poultry diet that plays a significant role in chicken embryonic development and *** present study examined the effect of in ovo injection of DL-Met and L-Met sources and genotypes on chicken embryonic-intestinal development and *** eggs of the two genotypes,TETRA-SL layer hybrid(TSL)—commercial layer hybrid and Hungarian Partridge colored hen breed(HPC)—a native genotype,were randomly distributed into four treatments for each *** treatment groups include the following:1)control non-injected eggs(NoIn);2)saline-injected(SaIn);3)DL-Met injected(DLM);and 4)L-Met injected(LM).The in ovo injection was carried out on 17.5 d of embryonic development;after hatching,eight chicks per group were sacrificed,and the jejunum was extracted for *** results showed that both DLM and LM groups had enhanced intestinal development as evidenced by increased villus width,villus height,and villus area(P<0.05)compared to the *** DLM group had significantly reduced crypt depth,glutathione(GSH)content,glutathione S-transferase 3 alpha(GST3),occludin(OCLN)gene expression and increased villus height to crypt depth ratio in the TSL genotype than the LM group(P<0.05).The HPC genotype has overexpressed insulin-like growth factor 1(IGF1)gene,tricellulin(MD2),occludin(OCLN),superoxide dismutase 1(SOD1),and GST3 genes than the TSL genotype(P<0.05).In conclusion,these findings showed that in ovo injection of Met enhanced intestinal development,and function,with genotypes responding differently under normal *** also influenced the expression of intestinal antioxidants,tight junction,and growth-related genes.

关键词： DL-Methionine L-Methionine In ovo injection Intestinal development Poultry

Effects of different friction stir welding conditions on the microstructure and mechanical properties of copper plates

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International Journal of Minerals,Metallurgy and Materials 2016年第7期23卷 799-809页

作者： Ali Alavi nia Ali Shirazi Department of Mechanical Engineering Bu-Ali Sina University

Friction stir welding is a new and innovative welding method used to fuse materials. In this welding method, the heat generated by friction and plastic flow causes significant changes in the microstructure of the material, which leads to local changes in the mechanical properties of the weld. In this study, the effects of various welding parameters such as the rotational and traverse speeds of the tool on the microstructural and mechanical properties of copper plates were investigated; additionally, Charpy tests were performed on copper plates for the first time. Also, the effect of the number of welding passes on the aforementioned properties has not been investigated in previous studies. The results indicated that better welds with superior properties are produced when less heat is transferred to the workpiece during the welding process. It was also found that although the properties of the stir zone improved with an increasing number of weld passes, the properties of its weakest zone, the heat-affected zone, deteriorated.

关键词： copper friction stir welding mechanical properties microstructure