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Novel fabrication of copper oxides on AC and its enhanced catalytic performance on oxidative carbonylation of methanol

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Chinese Chemical Letters 2017年第1期28卷 70-74页

作者： Ke Shi Shou-Ying Huang zhong-yao zhang Sheng-Ping Wang Xin-Bin Ma Key Laboratory for Green Chemical Technology School of Chemical Engineering and Technology Tianjin University Collaborative Innovation Center of Chemical Science and Engineering Tianjin 300072 China

Copper oxides（CuOx） nanoparticles dispersed on activated carbon（AC） were prepared by using vaporphase methanol as the reducing agent. The CuOx/AC as prepared exhibited an enhanced catalytic activity in oxidative carbonylation of methanol to dimethyl carbonate（DMC）. The catalytic performance was significantly influenced by reduction conditions including temperature and time. With the similar selectivity of DMC, the space time yield（STY） under optimal reduction conditions reached up to 408 mg g^-1h^-1, which is superior to conventional methods such as thermolysis and solvothermal reduction. Based on the characterization results of XRD, TEM and XPS, the good copper dispersion and high Cu^＋ content obtained by vapor-phase methanol reduction were mainly responsible for the high catalytic activity.

关键词： Dimethyl carbonate Oxidative carbonylation Copper oxides Vapor-phase methanol reduction Activated carbon

MicroRNA-98 can serve as a diagnostic marker for congenital heart disease-associated pulmonary artery hypertension

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Chinese Medical Journal 2020年第24期133卷 3007-3009页

作者： yao-zhong zhang Gang Li Dao-Le Yan Ying-Long Liu Pediatric Cardiac Center Beijing Anzhen HospitalCapital Medical UniversityBeijing Institute of Heart Lung and Blood Vessel DiseasesBeijing 100029China

Congenital heart disease(CHD)has become the leading mortal cause for an infant from congenital *** artery hypertension(PAH)is one of the complications of CHD.[1]It has also been reported that upregulation of microRNA-98(miR-98)could mediate the suppression of cardiac hypertrophy,which implies that miR-98 might play an important role in CHD.[2]In this study,the clinical data from hospitalized patients were retrospectively analyzed to identify if there is any evidence of diagnosis of circulating miR-98 on CHD patients with PAH.

关键词： hypertension diagnosis artery infant

Finite dimensional irreducible representations of Lie superalgebra D(2,1;α)

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Communications in Theoretical Physics 2024年第2期76卷 14-28页

作者：陈曦杨文力丁祥茂张耀中 College of Intelligent Systems Science and Engineering Hubei Minzu University 445000China Institute of Modern Physics Northwest UniversityXian 710069China Institute of Applied Mathematics Academy of Mathematics and Systems ScienceChinese Academy of SciencesBeijing 100080China School of Mathematics and Physics The University of QueenslandBrisbaneQLD 4072Australia

This paper focuses on the finite dimensional irreducible representations of Lie superalgebra D(2,1;α).We explicitly construct the finite dimensional representations of the superalgebra D(2,1;α)by using the shift operator and differential operator *** ordinary Lie algebra representation,there are typical and atypical representations for most ***,its typical and atypical representation conditions are also *** results are expected to be useful for the construction of primary fields of the corresponding current superalgebra of D(2,1;α).

关键词： superalgebra representations shift operator conformal field theory

Highly conductive and stable iodine doped argyrodite electrolyte for all-solid-state lithium batteries

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Journal of Energy Chemistry 2025年第1期100卷 50-58页

作者： Gaozhan Liu Jing zhang Jing Yang Jinghui Chen Xingyue Xiao Xiayin yao Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences

Lithium argyrodites with high ionic conductivity and low cost are considered as one of the most prospective solid electrolytes for all-solid-state lithium ***,the poor chemical stability and compatibility with lithium metal limit their ***,Li5.4PS4.4Cl1.4I0.2solid electrolyte with high ionic conductivity of 11.49 m S cm-1and improved chemical stability is synthesized by iodine *** ultra-thin Li5.4PS4.4Cl1.4I0.2membrane with thickness of 10μm can be obtained by wet coating process,exhibiting a high ionic conductivity of 2.09 mS cm-1and low areal resistance of 1.17Ω***,iodine doping could in-situ form LiI at the lithium/electrolyte interface and improve the critical current density of Li5.4PS4.4Cl1.6from 0.8 to 1.35 mA *** resultant LiCoO2/Li5.4PS4.4Cl1.4I0.2/Li battery shows excellent cycling stability at 1 C,with a reversible specific capacity of 110.1 mA h g-1and a retention of 80.5% after 1000 *** addition,the assembled LiCoO2/Li5.4PS4.4Cl1.4I0.2membrane/Li pouch cell delivers an initial discharge capacity of 110.4 mA h g-1and 80.5% capacity retention after 100 cycles.

关键词： Argyrodite electrolytes Iodine doping Ionic conductivity Stability All-solid-state lithium battery

Recent progress on photoactive nonprecious transition-metal complexes

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Science China Chemistry 2025年第1期 46-95页

作者： zhong-Liang Gong Hong-Jie zhang Yan Cheng Jianxun Liu Yuhan Ai Yaqin Li Zhihui Feng Qiong zhang Shaolong Gong Yong Chen Chang-Jiang yao Yuan-Yuan Zhu Liang-Jin Xu Yu-Wu zhong CAS Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences State Key Laboratory of Structural Cemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences School of Chemistry and Chemical Engineering Anhui Key Laboratory of Advanced Catalytic Materials and Reaction EngineeringHefei University of Technology State Key Laboratory of Explosion Science and Safety Protection School of Mechatronical Engineering Beijing Institute of Technology College of Chemistry and Molecular Sciences Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Wuhan University School of Chemistry and Chemical Engineering Anhui University Key Laboratory of Photochemical Conversion and Optoelectronic Materials & CAS-HKU Joint Laboratory on New Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences

Photoactive complexes of nonprecious transition metals, mainly including those in the first-row and partially the second-row of the Periodic table of elements, have received increasing attention in view of their low cost and long-term sustainability. They are recognized as promising alternatives to noble transition metal complex congeners that have been extensively studied in optoelectronic devices, artificial photosynthesis, photocatalysis, biodiagnostics, and therapeutics, etc. This review is devoted to a comprehensive summary on the classical and recent advances on photoactive nonprecious transition metal complexes, including photoactive Zr, V, Cr, Mo, and W complexes, Mn complexes and hybrids, Fe, Co, Ni, and Cu complexes, and Zn and Cd complexes and hybrids. A particular focus is given on the molecular design, modulation of photophysical and photochemical properties, and applications of the representative and lately-developed nonprecious metal complexes. In addition, a perspective on the future development in this field is provided at the end of this review.

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Glycolytic dysregulation in Alzheimer's disease:unveiling new avenues for understanding pathogenesis and improving therapy

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Neural Regeneration Research 2025年第8期20卷 2264-2278页

作者： You Wu Lijie Yang Wanrong Jiang Xinyuan zhang Zhaohui yao Department of Geriatrics Renmin Hospital of Wuhan UniversityWuhanHubei ProvinceChina

Alzheimer's disease poses a significant global health challenge owing to the progressive cognitive decline of patients and absence of curative *** current therapeutic strategies,primarily based on cholinesterase inhibitors and N-methyl-Daspartate receptor antagonists,offer limited symptomatic relief without halting disease progression,highlighting an urgent need for novel research directions that address the key mechanisms underlying Alzheimer's *** studies have provided insights into the critical role of glycolysis,a fundamental energy metabolism pathway in the brain,in the pathogenesis of Alzheimer's *** in glycolytic processes within neurons and glial cells,including microglia,astrocytes,and oligodendrocytes,have been identified as significant contributors to the pathological landscape of Alzheimer's *** changes impact neuronal health and function,thus offering promising targets for therapeutic *** purpose of this review is to consolidate current knowledge on the modifications in glycolysis associated with Alzheimer's disease and explore the mechanisms by which these abnormalities contribute to disease onset and *** focus on the pathways through which glycolytic dysfunction influences Alzheimer's disease pathology should provide insights into potential therapeutic targets and strategies that pave the way for groundbreaking treatments,emphasizing the importance of understanding metabolic processes in the quest for clarification and management of Alzheimer's disease.

关键词： Alzheimer’s disease glial cells glycolysis neuronal metabolism pathogenesis therapeutic targets

一种改进CSA算法的UAV多任务区侦察决策问题研究

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电光与控制 2018年第5期25卷 1-6页

作者：张耀中陈岚张蕾谢松岩西北工业大学电子信息学院西安710129

针对不确定性环境下的多任务区遍历侦察决策问题,将整个任务执行过程分为两个阶段,首先根据侦察任务区的信息及UAV自身性能,采用离散布谷鸟搜索算法解决侦察路径最优化问题,使遍历侦察全部任务区的航路最短。然后根据任务载荷及待侦察... 详细信息

针对不确定性环境下的多任务区遍历侦察决策问题,将整个任务执行过程分为两个阶段,首先根据侦察任务区的信息及UAV自身性能,采用离散布谷鸟搜索算法解决侦察路径最优化问题,使遍历侦察全部任务区的航路最短。然后根据任务载荷及待侦察任务区的特性,在确保遍历侦察全部任务区及满足最小侦察收益的前提下,利用改进的布谷鸟搜索算法为每个待侦察任务区分配最优的任务侦察时间,从而使整个侦察任务过程的信息收益最大化。最后通过仿真验证了决策方案的有效性和可行性,通过与传统遗传算法的对比分析,证明改进的布谷鸟搜索算法对此类侦察决策问题的运行效率与传统遗传算法相比有较大提高,从而为UAV多任务区的最优化遍历侦察问题提供了科学的决策依据。

关键词： UAV 航路规划侦察收益布谷鸟算法离散布谷鸟算法

明心见性，悟透成空：符号互动论视域下的《黑神话：悟空》传播逻辑

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未来传播 2024年第6期31卷 67-79+134-135页

作者：姚旭钟祥铭钟耀樟浙江传媒学院动画与数字艺术学院浙江传媒学院新闻与传播学院江西应用技术职业学院设计工程学院

随着《黑神话：悟空》等国产游戏迅速崛起，游戏行业的创作模式正经历着根本性变革，传统的游戏体验逐渐向“沉浸式互动”演进。玩家通过参与电子游戏，进行角色扮演和故事体验，重塑虚拟世界中的社交互动和文化意义的构建。电子游戏所... 详细信息

随着《黑神话：悟空》等国产游戏迅速崛起，游戏行业的创作模式正经历着根本性变革，传统的游戏体验逐渐向“沉浸式互动”演进。玩家通过参与电子游戏，进行角色扮演和故事体验，重塑虚拟世界中的社交互动和文化意义的构建。电子游戏所带来的文化热，已成为传播领域的新焦点。本研究从符号互动论的视角出发，从作品的剧情、场景、音乐及角色等符号深入探讨《黑神话：悟空》的传播逻辑，分析游戏如何作为文化传播的新媒介，对促进玩家身份认同和文化价值观念的传播所产生的正向作用，为理解数字游戏在当代文化传播中树立文化自信的新角色提供参照，并对游戏文化空间的建设与治理提供理论支持和实践借鉴。

关键词：符号互动论数字游戏沉浸式互动《黑神话:悟空》文化自信

Identifying the dynamic behaviors in complete reconstruction of Co-based complex precatalysts during electrocatalytic oxygen evolution

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Journal of Energy Chemistry 2025年第1期100卷 226-233页

作者： Jingfang zhang Danyang Wu Linke Cai Youluan Lu Fanpeng Cheng Lijuan Shi Qun Yi yao Liu Yi Huang Key Laboratory of Green Chemical Engineering Process of Ministry of Education Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education Hubei Key Laboratory of Novel Reactor and Green Chemical Technology School of Chemical Engineering & Pharmacy Wuhan Institute of Technology Key Laboratory of Pesticide & Chemical Biology of Ministry of Education Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of Education College of Chemistry Central China Normal University College of Materials Science and Engineering Fuzhou University

Transition metal-based nanomaterials have emerged as promising electrocatalysts for oxygen evolution reaction（OER）. Considerable research efforts have shown that self-reconstruction occurs on these nanomaterials under operating conditions of OER process. However, most of them undergo incomplete reconstruction with limited thickness of reconstruction layer, leading to low component utilization and arduous exploration of real catalytic mechanism. Herein, we identify the dynamic behaviors in complete reconstruction of Co-based complexes during OER. The hollow phytic acid（PA） cross-linked CoFe-based complex nanoboxes with porous nanowalls are designed because of their good electrolyte penetration and mass transport ability, in favor of the fast and complete reconstruction. A series of experiment characterizations demonstrate that the reconstruction process includes the fast substitution of PA by OH-to form Co（Fe）(OH)xand subsequent potential-driven oxidation to Co（Fe）OOH. The obtained CoFeOOH delivers a low overpotential of 290 mV at a current density of 10 mA cm-2and a long-term *** experiment results together with theory calculations reveal that the Fe incorporation can result in the electron rearrangement of reconstructed CoFeOOH and optimization of their electronic structure,accounting for the enhanced OER activity. The work provides new insights into complete reconstruction of metal-based complexes during OER and offers guidelines for rational design of high-performance electrocatalysts.

关键词： Complete reconstruction Co-based complex Precatalysts Oxygen evolution reaction