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Unsaturated bi-heterometal clusters in metal-vacancy sites of 2D MoS2 for efficient hydrogen evolution

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Carbon Energy 2024年第3期6卷 264-275页

作者： Gonglei Shao Jie Xu Shasha Gao zhang zhang Song Liu Xu zhang Zhen Zhou Interdisciplinary Research Center for Sustainable Energy Science and Engineering(IRC4SE2) School of Chemical EngineeringZhengzhou UniversityZhengzhouHenanChina College of Chemistry and Materials Engineering Wenzhou UniversityWenzhouZhejiangChina Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) College of ChemistryNankai UniversityTianjinChina State Key Laboratory of Chemo/Biosensing and Chemometrics Institute of Chemical Biology and Nanomedicine(ICBN)College of Chemistry and Chemical EngineeringHunan UniversityChangshaHunanChina Institute of New Energy Material Chemistry School of Materials Science and EngineeringNankai UniversityTianjinChina

The valence states and coordination structures of doped heterometal atoms in two-dimensional(2D)nanomaterials lack predictable regulation ***,a robust method is proposed to form unsaturated heteroatom clusters via the metal-vacancy restraint mechanism,which can precisely regulate the bonding and valence state of heterometal atoms doped in 2D molybdenum *** unsaturated valence state of heterometal Pt and Ru cluster atoms form a spatial coordination structure with Pt–S and Ru–O–S as catalytically active *** them,the strong binding energy of negatively charged suspended S and O sites for H+,as well as the weak adsorption of positively charged unsaturated heterometal atoms for H*,reduces the energy barrier of the hydrogen evolution reaction proved by theoretical ***,the electrocatalytic hydrogen evolution performance is markedly improved by the ensemble effect of unsaturated heterometal atoms and highlighted with an overpotential of 84 mV and Tafel slope of 68.5 mV dec^(−1).In brief,this metal vacancy-induced valence state regulation of heterometal can manipulate the coordination structure and catalytic activity of heterometal atoms doped in the 2D atomic lattice but not limited to 2D nanomaterials.

关键词： clusters hydrogen evolution reaction metal vacancy MoS2 unsaturated heterometal

Orthogonal waveform design with fractional programming on the ambiguity suppression of SAR systems

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Science China(Information Sciences) 2024年第9期67卷 263-279页

作者： Yunkai DENG Yongwei zhang Zhimin zhang Wei WANG Heng zhang Department of Space Microwave Remote Sensing System Aerospace Information Research InstituteChinese Academy of Sciences

Waveform diversity(WD) represents a dynamic and transformative technology widely used in radar systems to enhance sensitivity and discrimination capabilities. Recently, WD techniques have been extensively explored for their potential ambiguity suppression within synthetic aperture radar(SAR) *** these, the alternate transmitting mode combined with orthogonal waveforms emerges as a particularly promising solution. This study focuses on optimizing the power spectrum density(PSD) of signals to design and generate an orthogonal waveform pair that achieves both a low cross-correlation-to-autocorrelation ratio(CAR) and satisfactory imaging performance. Initially, we construct a fractional programming model with convex constraints to minimize the CAR. To address this challenge, we introduce an iterative optimization procedure for the PSD variable, which sequentially reduces the CAR. Each optimization step can be efficiently solved using a quadratically constrained quadratic program, ensuring that the resulting computational complexity remains low. Building on the optimized PSD, we established a parametric piecewise linear model to generate an orthogonal waveform pair. This model not only maintains a low CAR but achieves satisfactory imaging performance in real-time applications. Consequently, this orthogonal waveform pair effectively suppresses range ambiguity in SAR systems. Finally, we demonstrated the practicability and effectiveness of the proposed orthogonal waveforms through detailed simulation experiments, specifically targeting ambiguity suppression in conventional quad-polarization SAR systems.

关键词： synthetic aperture radar (SAR) waveform diversity (WD) ambiguity suppression orthogonal waveform fractional programming power spectrum density (PSD)

Single Fe atom-anchored manganese dioxide for efficient removal of volatile organic compounds in refrigerator

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Nano Research 2024年第5期17卷 3927-3933页

作者： Yiwen Wang Jun zhang Yongfei zhang Yu zhang Zhe Wang Jing Wang Yuen Wu Department of Endocrinology the First Affiliated Hospital of USTCDivision of Life Science and MedicineUniversity of Science and Technology of ChinaHefei 230001China School of Chemistry and Materials Science University of Science and Technology of ChinaHefei 230026China Hefei Hualing Co. LtdHefei 230088China Linkway Technology Co. LtdResearch Institute of Single Atom Catalysts Industry TechnologyNanning 530000China

The efficient and rapid removal of volatile organic compounds(VOCs)holds significant importance for ensuring food quality and human health,particularly within the low-temperature confined spaces in ***,achieving effective VOCs degradation under such conditions poses challenges in terms of activating inert bonds and facilitating mass *** this study,we propose a novel solution by designing a cleaner module that incorporates 1.07%single Fe atom-anchored manganese dioxide catalysts(FeSAs-MnO_(2)).The combination of single Fe atoms and defect-rich MnO_(2) substrate efficiently activates molecular oxygen,leading to enhanced generation of highly reactive oxygen species(ROS).Non-thermal plasma(NTP)and circulating fan are introduced to facilitate the regeneration of catalytic activity and improve mass *** FeSAs-MnO_(2) cleaner module demonstrates exceptional performance in trimethylamine(TMA)removal,achieving a conversion efficiency of 98.9%for 9 ppm within just 9 ***,accelerated aging tests predict an extended service life of up to 45 years for the FeSAs-MnO_(2) cleaner module,surpassing the expected lifespan of refrigerators significantly.

关键词： single atom catalysts volatile organic compounds(VOCs) trimethylamine(TMA) non-thermal plasma(NTP) refrigerator

Self-assembly of perovskite nanocrystals:From driving forces to applications

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Journal of Energy Chemistry 2024年第1期88卷 561-578,I0013页

作者： Yi Li Fei zhang School of Chemical Engineering and Technology Tianjin UniversityTianjin 300072China Collaborative Innovation Center of Chemical Science and Engineering(Tianjin) Tianjin 300072China

Self-assembly of metal halide perovskite nanocrystals(NCs)into superlattices can exhibit unique collective properties,which have significant application values in the display,detector,and solar cell *** review discusses the driving forces behind the self-assembly process of perovskite NCs,and the commonly used self-assembly methods and different self-assembly structures are ***,we summarize the collective optoelectronic properties and application areas of perovskite superlattice ***,we conclude with an outlook on the potential issues and future challenges in developing perovskite NCs.

关键词： Self-assembly Metal halide perovskite Nanocrystals Driving forces

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Analytical modeling and approaches of multihelix cables incorporating with interwire mutual contacts

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Applied Mathematics and Mechanics(English Edition) 2024年第9期45卷 1633-1654页

作者： Zhichao zhang Xingzhe WANG Key Laboratory of Mechanics on Disaster and Environment in Western China The Ministry of Education of ChinaCollege of Civil Engineering and MechanicsKey Laboratory of Special Function Materials and Structure Design of Ministry of EducationLanzhou UniversityLanzhou 730000China College of Civil Science and Engineering Yangzhou UniversityYangzhou 225127Jiangsu ProvinceChina

This study aims to develop an analytical model based on the curve beam theory to capture the mechanical response of a multihelix cable considering the internal contact ***,a double-helix cable subjected to axial tension and torsion is analyzed,and both the line and point contacts between the neighboring wires and strands are considered via an equivalent homogenized ***,the proposed theoretical model is extended to a hierarchical multihelix cable with mutual contact displacements by constructing a recursive relationship between the high-and low-level multihelix *** global tensile stiffness and torsional stiffness of the double-helix cable are successfully *** results are validated by a finite element(FE)model,and are found to be consistent with the findings of previous *** is shown that the contact deformations in multihelix cables significantly affect their equivalent mechanical stiffness,and the contact displacements are remarkably enhanced as the helix angles *** study provides insights into the interwire/interstrand mutual contact effects on global and local responses.

关键词： wordshierarchical multihelix cable mutual contact effect mechanical response effective stiffness

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Study on Coded Permutation Entropy of Finite Length Gaussian White Noise Time Series

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Chinese Journal of Electronics 2024年第1期33卷 185-194页

作者： Huihui SUN Xiaofeng zhang School of Physics and Information Technology Shaanxi Normal University

As an extension of permutation entropy(PE), coded permutation entropy(CPE) improves the performance of PE by making a secondary division for ordinal patterns defined in PE. In this study, we provide an exploration of the statistical properties of CPE using a finite length Gaussian white noise time series theoretically. By means of the Taylor series expansion, the approximate expressions of the expected value and variance of CPE are deduced and the Cramér-Rao low bound(CRLB) is obtained to evaluate the performance of the CPE estimator. The results indicate that CPE is a biased estimator, but the bias only depends on relevant parameters of CPE and it can be easily corrected for an arbitrary time series. The variance of CPE is related to the encoding patterns distribution,and the value converges to the CRLB of the CPE estimator when the time series length is large enough. For a finitelength Gaussian white noise time series model, the predicted values can match well with the actual values, which further validates the statistic theory of CPE. Using the theoretical expressions of CPE, it is possible to better understand the behavior of CPE for most of the time series.

关键词： Time series analysis White noise Predictive models Taylor series Entropy Encoding Time measurement

Recent advances in multifunctional shape memory photonic crystals and practical applications

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Nano Research 2024年第1期17卷 79-96页

作者： Yong Qi Shufen zhang State Key Laboratory of Fine Chemicals Frontier Science Center for Smart MaterialsDalian University of TechnologyDalian 116024China

Shape memory photonic crystals(SMPCs)are smart composite materials with changeable structural color integrated by shape memory polymer and photonic *** can produce one or more temporary shapes through nanoscale deformation,memorizing current *** can be recovered to their original shapes or some intermediate states under external stimuli,accompanied by the variation of structural *** porous carriers with built-in sensing properties,SMPCs promoted the interdisciplinary development of nanophotonic technology in materials science,environmental engineering,biomedicine,chemical engineering,and ***,the recent progress on multifunctional SMPCs and practical applications,including traditional and cold programmable SMPCs,is summarized and *** primary concern is shape programming at the nanoscale that has demonstrated numerous attractive functions,including smart sensing,ink-free printing,solvent detection,reprogrammable gradient wetting,and controllable bubble transportation,under variations of the surface *** aims to figure out the nanoscale shape memory effects on structural color conversion and additional performance,inspiring the fabrication of the next generation of ***,perspectives on future research directions and applications are also *** is believed that multifunctional SMPCs are powerful nanophotonic tools for the interdisciplinary development of numerous disciplines in the future.

关键词： photonic crystal shape memory structural color cold programmable shape recovery

Indispensable gutter layers in thin-film composite membranes for carbon capture

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Green Energy & Environment 2024年第8期9卷 1220-1238页

作者： Gengyi zhang Haiqing Lin Department of Chemical and Biological Engineering University at Buffalo The State University at New York

Industrial thin-film composite(TFC) membranes achieve superior gas separation properties from high-performance selective layer materials,while the success of membrane technology relies on high-performance gutter layers to achieve production scalability and low-cost manufacturing. However, the current literature predominantly focuses on the design of polymer architectures to obtain high permeability and selectivity, while the art of fabricating gutter layers is usually safeguarded by industrial manufacturers and appears lackluster to academic researchers. This is the first report aiming to provide a comprehensive and critical review of state-of-the-art gutter layer materials and their design and modification to enable TFC membranes with superior separation performance. We first elucidate the importance of the gutter layer on membrane performance through modeling and experimental results. Then various gutter layer materials used to obtain high-performance composite membranes are critically reviewed, and the strategies to improve their compatibility with the selective layer are highlighted, such as oxygen plasma treatment, polydopamine deposition, and surface grafting. Finally, we present the opportunities of the gutter layer design for practical applications.

关键词： Thin-film composite membranes Gutter layer Gas separation Carbon capture

Robust adaptive radar beamforming based on iterative training sample selection using kurtosis of generalized inner product statistics

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Journal of Systems Engineering and Electronics 2024年第1期35卷 24-30页

作者： TIAN Jing zhang Wei School of Information and Electronics Beijing Institute of TechnologyBeijing 100081China National Key Laboratory of Electromagnetic Space Security Chengdu 610036China

In engineering application,there is only one adaptive weights estimated by most of traditional early warning radars for adaptive interference suppression in a pulse reputation interval(PRI).Therefore,if the training samples used to calculate the weight vector does not contain the jamming,then the jamming cannot be removed by adaptive spatial *** the weight vector is constantly updated in the range dimension,the training data may contain target echo signals,resulting in signal cancellation *** cope with the situation that the training samples are contaminated by target signal,an iterative training sample selection method based on non-homogeneous detector(NHD)is proposed in this paper for updating the weight vector in entire range *** principle is presented,and the validity is proven by simulation results.

关键词： adaptive radar beamforming training sample selection non-homogeneous detector electronic jamming jamming suppression

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