检索结果-南通市图书馆

Enhanced electrocatalytic CO_(2)reduction to formic acid using nanocomposites of In_(2)O_(3)@C with graphene

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第6期17卷 5031-5039页

作者： Wenxiang Li Shuo gao Chuanruo yang Juntao yang Amjad Nisar Guolei Xiang Junsu Jin Beijing Key Laboratory of Membrane Science and Technology Beijing University of Chemical TechnologyBeijing 100029China Nanomaterials Research Group PDPINSTECHIslamabad 44000Pakistan Institute of Industrial Chemistry College of ChemistryBeijing University of Chemical TechnologyBeijing 100029China

In_(2)O_(3)is an effective electrocatalyst to convert CO_(2)to formic acid(HCOOH),but its inherent poor electrical conductivity limits the efficient charge transfer during the ***,the tendency of In_(2)O_(3)particles to agglomerate during synthesis further limits the exposure of active *** we address these issues by leveraging the template effect of graphene oxide and employing InBDC as a self-sacrificing template for the pyrolysis synthesis of In_(2)O_(3)@*** resulting In_(2)O_(3)@C/rGO-600 material features In_(2)O_(3)@C nanocubes uniformly anchored on a support of reduced graphene oxide(rGO),significantly enhancing the active sites *** conductive rGO network facilitates charge transfer during electrocatalysis,and the presence of oxygen vacancies generated during pyrolysis,combined with the strong electron-donating ability of rGO,enhances the adsorption and activation of CO_(2).In performance evaluation,In_(2)O_(3)@C/rGO-600 exhibits a remarkable HCOOH Faradaic efficiency exceeding 94.0%over a broad potential window of−0.7 to−1.0 V(*** hydrogen electrode(RHE)),with the highest value of 97.9%at−0.9 V(***)in a ***,the material demonstrates an excellent cathodic energy efficiency of 71.6%at−0.7 V(***).The study underscores the efficacy of uniformly anchoring metal oxide nanoparticles onto rGO for enhancing the electrocatalytic CO_(2)reduction performance of materials.

关键词： In_(2)O_(3)@C nanocomposite electrochemical CO_(2)reduction reduced graphene oxide oxygen vacancy

Predicting the Mechanical Behavior of a Bioinspired Nanocomposite through Machine Learning

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Computer Modeling in Engineering & Sciences 2024年第8期140卷 1299-1313页

作者： Xingzi yang Wei gao Xiaodu Wang Xiaowei Zeng Department of Mechanical Engineering University of Texas at San AntonioSan AntonioTX78249USA Department of Mechanical Engineering Texas A&M UniversityCollege StationTX77843USA

The bioinspired nacre or bone structure represents a remarkable example of tough,strong,lightweight,and multifunctional structures in biological materials that can be an inspiration to design bioinspired high-performance *** bioinspired structure consists of hard grains and soft material *** the material interface has a very low volume percentage,its property has the ability to determine the bulk material *** learning technology nowadays is widely used in material science.A machine learning model was utilized to predict the material response based on the material interface properties in a bioinspired *** model was trained on a comprehensive dataset of material response and interface properties,allowing it to make accurate *** results of this study demonstrate the efficiency and high accuracy of the machine learning *** successful application of machine learning into the material property prediction process has the potential to greatly enhance both the efficiency and accuracy of the material design process.

关键词： Bioinspired nanocomposite computational model machine learning finite element material interface

ControlService: a containerized solution for control-algorithm-as-a-service in cloud control systems

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China(Information Sciences) 2024年第8期67卷 172-189页

作者： Chenggang SHAN Runze gao Zhen yang Wei ZHANG Yuanqing XIA School of Artificial Intelligence Zaozhuang University School of Automation Beijing Institute of Technology

As an extension of networked control systems, cloud control systems(CCSs) have emerged as a new control paradigm to improve the service quality of emerging control missions, such as data-driven modeling and automated vehicles. Existing studies have used the workflow-based restructured method to optimize the computation-intensive algorithms in the CCSs. However, the challenges here are how to define and submit these algorithms' workflows as cloud services and execute these algorithms' workflows in a containerized manner. Based on these challenges, we propose a containerized solution for the control-algorithm-as-a-service(C3aS) in the CCSs, namely Control Service. It offers the control algorithm as a cloud workflow service and uses a customized workflow engine to realize the containerized execution. First, we employ a cloud workflow representation method to define a control algorithm into an abstract cloud workflow form. Afterward, we provide a cloud service representation of the abstract cloud workflow. Next, we design a workflow engine and submit the cloud service to this workflow engine to implement containerized execution of this cloud service in the CCSs. In the experiment, we discuss the cloud service form and containerized implementation of the subspace identification method. Experimental results show that the proposed Control Service has significant performance advantages in computational time, reduction percentage, and speedup ratio compared with the baseline method.

关键词： cloud control systems control-algorithm-as-a-service containerization workflow engine cloud workflow service subspace identification

Mn-modified nitrogen-doped Pt-based electrocatalyst for efficient oxygen reduction in aluminum-air batteries

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第8期17卷 7126-7135页

作者： Li gao yang Song Xuebing Xu Chang Li Chaoquan Hu State Key Laboratory of Mesoscience and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Zhongke Nanjing Institute of Green Manufacturing Industry Nanjing 211135China

In this study,a Mn-modified Pt-based catalyst loaded on nitrogen-doped Ketjen black(Mn-Pt/NKB)is prepared using a simple ethylene glycol reduction *** size of Pt nanoparticles(NPs)is effectively controlled by doping with Mn and *** the smallest average particle size of 1.7 nm,Mn-Pt/NKB demonstrates half-wave potentials of 0.890 and 0.688 V in the alkaline and neutral electrolytes,respectively,which are superior to those of commercial platinum on activated carbon(Pt/C).When applied as an air cathode in aluminum-air battery,it exhibits ultra-high power densities of 190(alkaline)and 26.2 mW·cm^(−2)(neutral).Moreover,the voltage remains stable after 5 h of *** practical application performance of the Mn-Pt/NKB catalyst in an aluminum-air battery is better than that of commercial Pt/***,the oxygen reduction reaction(ORR)mechanism on surfaces with different particle sizes is analyzed using density functional *** cracking is the major pathway on the surface of the small particles with lower energy consumption of 0.5 eV,while water molecule cleavage is the major pathway on the surface of the large particles with higher energy consumption of 0.97 *** lower energy consumption of the oxygen cracking pathway further confirms the ORR mechanism for higher activity on small-sized *** study provides a direction for the rational design of Pt-based catalysts for ORR and sheds light on the commercial development of aluminum-air batteries.

关键词： oxygen reduction reaction precious metal catalysts aluminum-air battery density functional theory(DFT)calculations reaction pathway

Morphology-Tailored Dynamic State Transition in Active-Passive Colloidal Assemblies

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Research 2024年第3期2024卷 751-760页

作者： Nan Yu Zameer H.Shah Mingcheng yang Yongxiang gao Institute for Advanced Study Shenzhen University518060ShenzhenChina Key Laboratory of Optoelectronic Device and Systems of Ministry of Education and Guangdong Province College of Optoelectronic EngineeringShenzhen University518060ShenzhenChina Beijing National Laboratory for Condensed Matter Physics and Laboratory of Soft Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100190China School of Physical Sciences University of Chinese Academy of SciencesBeijing 100049China Songshan Lake Materials Laboratory DongguanGuangdong 523808China.

Mixtures of active self-propelled and passive colloidal particles promise rich assembly and dynamic states that are beyond reach via equilibrium ***,controllable transition between different dynamic states remains ***,we reveal a plethora of dynamic behaviors emerging in assemblies of chemically propelled snowman-like active colloids and passive spherical particles as the particle shape,size,and composition are *** example,assembles of one or more active colloids with one passive particle exhibit distinct translating or orbiting states while those composed of one active colloid with 2 passive particles display persistent“8”-like cyclic motion or hopping between circling states around one passive particle in the plane and around the waist of 2 passive ones out of the plane,controlled by the shape of the active colloid and the size of the passive particles,*** morphology-tailored dynamic transitions are in excellent agreement with state diagrams predicted by mesoscale dynamics *** work discloses new dynamic states and corresponding transition strategies,which promise new applications of active systems such as micromachines with functions that are otherwise impossible.

关键词： Transition otherwise transitions

Dynamic ocean inverse modeling based on differentiable rendering

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Computational Visual Media 2024年第2期10卷 279-294页

作者： Xueguang Xie yang gao Fei Hou Aimin Hao Hong Qin State Key Lab of Virtual Reality Technology and Systems Beihang UniversityBeijing 100191China Qingdao Research Institute Beihang UniversityQingdao 266100Chinaand Peng Cheng LabShenzhen 518000China SKLCS Institute of SoftwareChinese Academy of SciencesBeijing 100190Chinaand University of Chinese Academy of SciencesBeijing 100049China Department of Computer Science Stony Brook University(SUNY at Stony Brook)Stony BrookNew York 11794-2424USA

Learning and inferring underlying motion patterns of captured 2D scenes and then re-creating dynamic evolution consistent with the real-world natural phenomena have high appeal for graphics and *** bridge the technical gap between virtual and real environments,we focus on the inverse modeling and reconstruction of visually consistent and property-verifiable oceans,taking advantage of deep learning and differentiable physics to learn geometry and constitute waves in a self-supervised ***,we infer hierarchical geometry using two networks,which are optimized via the differentiable *** extract wave components from the sequence of inferred geometry through a network equipped with a differentiable ocean ***,ocean dynamics can be evolved using the reconstructed wave *** extensive experiments,we verify that our new method yields satisfactory results for both geometry reconstruction and wave ***,the new framework has the inverse modeling potential to facilitate a host of graphics applications,such as the rapid production of physically accurate scene animation and editing guided by real ocean scenes.

关键词： inverse modeling surface reconstruction wave modeling ocean waves differentiable rendering(DR)

Unveiling the chemistry behind the electrolytic production of hydrogen peroxide by oxygenated carbon

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第9期96卷 49-58页

作者： Pan Xiang Kunshang yang Qihao yang yang gao Wenwen Xu Zhiyi Lu Liang Chen Zhiming Wang Ziqi Tian Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054SichuanChina Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201ZhejiangChina Institute for Advanced Study Chengdu UniversityChengdu 610106SichuanChina

Oxygenated carbon materials exhibit outstanding electrocatalytic performance in the production of hydrogen peroxide(H2O2)through a two-electron oxygen reduction *** nature of the active functional group and underlying reaction mechanism,however,remain ***,a comprehensive workflow was established to identify the active sites from the numerous possible *** common hydroxyl group at the notched edge demonstrates a key role in the two-electron *** local chemical environment weakens the binding of OOH intermediate to substrate while enhancing interaction with solution,thereby promoting the H_(2)O_(2)*** increasing pH,the intramolecular hydrogen bond between OOH intermediate and hydroxyl decreases,facilitating OOH ***,the rise in selectivity with increasing potential stems from the suppression of the four-electron *** active site was further validated through *** by theoretical understanding,optimal performance was achieved with high selectivity(>95%)and current density(2.06 mA/cm^(2))in experiment.

关键词： First-principles calculation Oxygen reductionreaction Hydrogen peroxide production Fixed-potential method Oxygenated carbon materials

The degradation of cathodic Fe/N/C catalyst in PEMFCs:The evolution of remanent active sites after demetallation

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Journal of Materials Science & Technology 2024年第6期173卷 100-106页

作者： Xiaohua yang Wentao Sun Jiatang Chen yang gao Rongxian Zhang Qun Luo Tao Lyu Lei Du Institut National de la Recherche Scientifique-Énergie Matériaux et Télécommunications J3X 1P7 VarennesQCCanada School of Chemistry and Chemical Engineering Jiangsu UniversityZhenjiang 212013China State Key Laboratory of Advanced Special Steels&Shanghai Key Laboratory of Advanced Ferrometallurgy School of Materials Science and EngineeringShanghai UniversityShanghai 200444China Huangpu Hydrogen Energy Innovation Center School of Chemistry and Chemical EngineeringGuangzhou UniversityGuangzhou 510006China

The state-of-the-art Fe/N/C catalyst has presented comparable initial cathode performance to the benchmark Pt/C catalyst in proton exchange membrane fuel cells(PEMFCs).However,the major bottleneck is its significant activity decay in real-world PEMFC *** superposed“fast decay”and“slow decay”have been well documented to describe the degradation process of Fe/N/C catalysts during PEMFC *** fast decay has been well understood in close relation to the demetallation at the initial 15-h stability ***,it is still unclear how the remanent active sites evolve after *** this end,the catalyst performance and evolution of a typical Fe/N/C active site were herein investigated through postmortem characterizations of the membrane electrode assemblies(MEAs)after different *** is presented that 1 bar pressure and 80℃ temperature are the optimized conditions for Fe/N/C ***,the“fast decay”in the initial 15 h is immune to the various operating parameters,while the“slow decay”highly depends on the applied temperature and *** to the X-ray absorption spectra(XAS)analysis and stability test of MEA,the gradual evolution of Fe-N coordination to Fe-O is found correlated with the“slow decay”and accounts for the catalyst decay after the demetallation process.

关键词： Fe/N/C Stability Decay mechanism Metal oxidation PEMFCs

Strain-promoted S-arylation and alkenylation of sulfinamides using arynes and cyclic alkynes

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China Chemistry 2024年第3期67卷 928-935页

作者： Xi Zou Boming Shen gao-lin Li Qian Liang Yanhua Ouyang Binghe yang Peiyuan Yu Bing gao State Key Laboratory of Chemo/Bio-Sensing and Chemometrics College of Chemistry and Chemical EngineeringInstitute of Chemical Biology and NanomedicineHunan UniversityChangsha 410082China Department of Chemistry and Shenzhen Grubbs Institute Guangdong Provincial Key Laboratory of CatalysisSouthern University of Science and TechnologyShenzhen 518055China

The conversion of commercially available chiral sulfinamides into pharmaceutically useful chiral sulfoximines via direct SIVfunctionalization is synthetically attractive but challenging due to the competitive reaction of N-functionalization. Herein, we disclose a novel strain-release strategy to access stereospecific and chemoselective SIV-arylation and alkenylation of sulfinamides using arynes and strained cyclic alkynes. This method tolerates an unprecedented chemical diversity of functional groups attached to the nitrogen center(N-R). The origin of the high SIV-selectivity is elucidated by density functional theory calculations, suggesting a stepwise mechanism for the aryne substrates and a concerted mechanism for the cyclic alkynes.

关键词： arylation alkenylation sulfoximines sulfinamides arynes