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富氮气调--磷化氢的可供替换技术

粮油食品科技 2024年第3期32卷 55-68页

作者： Manjree AGARWAL James NEWMAN yan-yu li li GU Bei-bei li Yong-lin REN 李燕羽(译) 西澳大利亚政府化学中心澳大利亚珀斯WA 6102 CBH澳大利亚谷物有限公司澳大利亚珀斯WA 6000 默多克大学环境和生命科学学院澳大利亚珀斯WA 6150 国家粮食和物资储备局科学研究院粮食储运研究所北京100037 国家粮食和物资储备局科学研究院粮食储运研究所

在粮食储藏上利用氮气的方法已经有30多年的历史,但直到最近经济有效的变压吸附(PSA)和膜分离(MS)制氮设备的出现,才使得该技术在储粮上使用成为可能。本研究首先在25、30和35℃、99%、98%和97%氮气的环境下,对小麦、大麦、燕麦、羽扇... 详细信息

在粮食储藏上利用氮气的方法已经有30多年的历史,但直到最近经济有效的变压吸附(PSA)和膜分离(MS)制氮设备的出现,才使得该技术在储粮上使用成为可能。本研究首先在25、30和35℃、99%、98%和97%氮气的环境下,对小麦、大麦、燕麦、羽扇豆和油菜籽中的花斑皮蠹、赤拟谷盗、谷蠹和米象成虫和非成虫虫态进行了为期4、3和2周的实验室生物测定。然后在终端用户LakeGrace和CBH(Cooperative BulkHandling)谷物进出口公司Albany出口港码头开展实仓验证,测定小麦、大麦和油菜籽中不同储粮害虫虫种和油菜籽瓢虫和肖叶甲类两种田间害虫的防治效果。同时对处理后的粮食品质进行了测定。实验结果表明,害虫死亡率随着氧气浓度降低、暴露时间和温度的增加而增加,富氮低氧在低温条件下不能100%致死花斑皮蠹幼虫。氮气处理对磷化氢抗性和敏感品系储粮害虫防治效果没有差异。与其他粮种相比,在油菜籽中的防治效果更好。各种粮种的水分含量、蛋白质、含油量、淀粉和籽粒颜色品质指标均未受到影响。成功开发了富氮低氧商业规模应用模式,为磷化氢高抗性害虫治理提供了解决方案,满足市场日益增长对无害虫和无化学残留粮食的需求。

关键词：气调储藏害虫治理磷化氢抗药性粮食品质应用模式

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富氮低氧+磷化氢防治储粮害虫技术的实仓应用研究

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粮油食品科技 2024年第3期32卷 39-54页

作者： Manjree AGARWAL James NEWMAN yan-yu li li GU Bei-bei li Sucharita BASAVARAJAPP Yong-lin REN 李燕羽(译) 西澳大利亚州政府化学中心澳大利亚珀斯WA 6102 CBH澳大利亚谷物有限公司澳大利亚珀斯WA 6000 默多克大学环境和生命科学学院澳大利亚珀斯WA 6150 国家粮食和物资储备局科学研究院粮食储运研究所北京100037 国家粮食和物资储备局科学研究院粮食储运研究所

为防治澳大利亚主要仓储害虫,开发富氮气调技术作为熏蒸剂的辅助手段。然而,由于成本问题,一直影响其在行业推广应用。本研究利用中国长顺安达公司的先进膜分离技术,与传统的制氮技术(变压吸附/PSA)进行性能比较,在西澳Kwinana的CBH粮食... 详细信息

为防治澳大利亚主要仓储害虫,开发富氮气调技术作为熏蒸剂的辅助手段。然而,由于成本问题,一直影响其在行业推广应用。本研究利用中国长顺安达公司的先进膜分离技术,与传统的制氮技术(变压吸附/PSA)进行性能比较,在西澳Kwinana的CBH粮食港,开展实仓应用实验,以解决阻碍其推广的运营和成本问题。为满足澳大利亚严格的标准操作条件,长顺安达专业团队对港口设备进行了升级改造,目标消杀成本设定为0.50澳元/吨粮(磷化氢的高端熏蒸成本)。研究表明,旧的PSA技术的运营成本为2.43澳元/吨粮,该技术在产生和维持控制害虫所需的99%氮气浓度水平方面也显示出操作局限性。相比之下,使用膜技术制氮的成本为0.99澳元/吨粮,其他性能增益还包括运行4.5天内即可产生所需的氮气浓度,且可维持14天以完全控制害虫。

关键词：粮食储藏储粮害虫管理氮气储藏变压吸附制氮机膜分离制氮机

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基于TiO_(2)纳米柱的多波段响应Cs_(2)AgBiBr_(6)双钙钛矿光电探测器

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物理学报 2024年第7期73卷 333-343页

作者：孙堂友余燕丽覃祖彬陈赞辉陈均丽江玥张法碧桂林电子科技大学广西精密导航技术与应用重点实验室桂林541004

全无机无铅双钙钛矿材料(Cs_(2)AgBiBr_(6))具有载流子寿命长、稳定性高和禁带宽度适中等优点,近年来在光电探测器的应用研究上受到广泛关注.本文通过将水热法生长的TiO_(2)纳米柱阵列嵌入到Cs_(2)AgBiBr_(6)层中形成紧密的核壳结构,增... 详细信息

全无机无铅双钙钛矿材料(Cs_(2)AgBiBr_(6))具有载流子寿命长、稳定性高和禁带宽度适中等优点,近年来在光电探测器的应用研究上受到广泛关注.本文通过将水热法生长的TiO_(2)纳米柱阵列嵌入到Cs_(2)AgBiBr_(6)层中形成紧密的核壳结构,增大两者的物理接触面积,提高光电探测器电子注入与电荷分离的效率.此外,TiO_(2)纳米柱阵列还可以有效减小光在器件表面的反射损耗,增强Cs_(2)AgBiBr_(6)薄膜的光捕获能力.实验结果表明,基于TiO_(2)纳米柱的多波段响应Cs_(2)AgBiBr_(6)双钙钛矿光电探测器在365 nm及405 nm多个波长均能激发高光响应且有良好稳定性和重复性,所得平均开关比分别为522和2090,以0.056 W/cm^(2)固定光强激发,响应度分别为0.019 A/W和0.057 A/W,比探测率分别为1.9×10^(10)Jones和5.6×10^(10)Jones.相比于传统TiO_(2)薄膜型Cs_(2)AgBiBr_(6)光电探测器,平均开关比分别提升65倍和110倍,响应度分别提升35%和256%,比探测率分别提升6.9倍和25倍.上述结果表明,基于TiO_(2)纳米柱的多波段响应Cs_(2)AgBiBr_(6)双钙钛矿光电探测器可为提高光电器件的效率提供参考方案.

关键词： Cs_(2)AgBiBr_(6) 光电探测器 TiO_(2)纳米柱多波段响应

Flow stress model considering the transformation-induced plasticity effect and the inelastic strain recovery behavior

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International Journal of Minerals,Metallurgy and Materials 2011年第2期18卷 185-191页

作者： Hai-yan yu li Bao School of Automotive Engineering Tongji University Shanghai 200092 China

On the basis of continuum mechanics and the Mori-Tanaka mean field theory, a micro-mechanical flow stress model that considered both the transformation-induced plasticity （TRIP） effect and the inelastic strain recovery behavior of TRIP multiphase steels was presented. The relation between the volume fraction of constituent phases and plastic strain was introduced to characterize the transformation-induced plasticity effect of TRIP steels. Loading-unloading-reloading uniaxial tension tests of TRIP600 steel were carried out and the strain recovery behavior after unloading was analyzed. From the experimental data, an empirical elastic modulus expression is extracted to characterize the inelastic strain recovery. A comparison of the predicted flow stress with the experimental data shows a good agreement. The mechanism of the transformation-induced plasticity effect and the inelastic recovery effect acting on the flow stress is also discussed in detail.

关键词： flow stress transformation-induced plasticity inelastic strain elastic modulus

Comparison of 1.5% lidocaine and 0.5% ropivacaine epidural anesthesia combined with propofol general anesthesia guided by bispectral index

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2007年第6期8卷 428-434页

作者： XIANG yan li yu-hong Department of Anesthesiology the First Affiliated Hospital School of Medicine Zhejiang University Hangzhou 310003 China

Objective： To compare the effects of epidural anesthesia with 1.5% lidocaine and 0.5% ropivacaine on propofol requirements, the time to loss of consciousness （LOC）, effect-site propofol concentrations, and the hemodynamic variables during induction of general anesthesia guided by bispectral index （BIS） were studied. Methods： Forty-five patients were divided into three groups to receive epidurally administered saline （Group S）, 1.5% （w/w） lidocaine （Group L）, or 0,5% （w/w） ropivacaine （Group R） Propofol infusion was started to produce blood concentration of 4 lag/ml. Once the BIS value reached 40-50, endotracheal intubation was facilitated by 0.1 mg/kg vecuronium. Measurements included the time to LOC, effect-site propofol concentrations, total propofol dose, mean arterial blood pressure （MABP）, and heart rate （HR） at different study time points. Results： During induction of anesthesia, both Groups L and R were similar for the time to LOC, effect-site propofol concentrations, total propofol dose, MABP, HR, and BIS. The total doses of propofol administered until 1 min post-intubation were significantly less in patients of Groups R and L compared with Group S. MABP and HR were significantly lower following propofol induction compared with baseline values in the three groups, or MABP was significantly increased following intubation as compared with that prior to intubation in Group S but not in Groups R and L while HR was significantly increased following intubation in the three groups. Conclusion： Epidural anesthesia with 1.5% lidocaine and 0.5% ropivacaine has similar effects on the time to LOC, effect-site propofol concentrations, total propofol dose, and the hemodynamic variables during induction of general anesthesia.

关键词： Propofol lidocaine Ropivacaine Epidural anethesia Bispectral index

Studies on the flame propagation characteristic and thermal hazard of the premixed N2O/fuel mixtures

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Defence Technology（防务技术） 2020年第3期16卷 564-570页

作者： yu-yan li Rong-pei Jiang Zhi-peng li Sen Xu Feng Pan li-feng Xie School of Chemical Engineering Nanjing University of Science and TechnologyNanjingJiangsu 210094PR China Beijing Insitute of Aerospace Testing Technology Beijing Key Laboratory of Research and Application for Aerospace Green PropellantsBeijing 100074PR China National Quality Supervision and Inspection Center for Industrial Explosive Materials NanjingJiangsu 210094PR China

An experimental study was carried out to investigate the flame propagation and thermal hazard of the premixed N2O/fuel mixtures,including NH3,C3H8 and *** study provided the high speed video images and data about the flame locations,propagation patterns,overpressures and the quenching diameters during the course of combustion in different channels to elucidate the dynamics of various combustion *** onset decomposition temperature was determined using high-performance adiabatic *** was shown that the order of the flame acceleration rate and thermal hazard was N2O/C2H4>N2O/C3H8>N2O/NH3.

关键词： Flame propagation Flame acceleration rate Quenching diameter Thermal hazard

Synthesis and antitumor activity of 9-methyl-10-hydroxycamptothecin

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Chinese Chemical Letters 2008年第8期19卷 918-920页

作者： Sheng Wang yu yan li Qi Dong You Department of Medicinal Chemistry China Pharmaceutical University Nanjing 210009 China

A novel camptothecin analogue, 9-methyl-10-hydroxycamptothecin （4）, was unexpectedly synthesized from 10-hydroxycamptothecin in two steps. The key step included an efficient Mannich-type reaction. The overall yield was 47.2%. An ether analogue of 4, 9-methyl-10-benzylaminomethoxycamptothecin （5）, was also prepared. These new camptothecin analogues were evaluated for in vitro cytotoxicity against four human cancer cell lines, and exhibited more potent antitumor activities than contrals camptothecin and topotecan against several cancer cells.

关键词： Synthesis Camptothecin 10-Hydroxycamptothecin Cytotoxicity

Identification of differential gene expression for microarray data using recursive random forest

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Chinese Medical Journal 2008年第24期121卷 2492-2496页

作者： WU Xiao-yan WU Zhen-yu li Kang Department of Biostatistics College of Public Health Harbin Medical University Harbin Heilongjiang 150081 China

Background The major difficulty in the research of DNA microarray data is the large number of genes compared with the relatively small number of samples as well as the complex data structure. Random forest has received much attention recently; its primary characteristic is that it can form a classification model from the data with high dimensionality. However, optimal results can not be obtained for gene selection since it is still affected by undifferentiated genes. We proposed recursive random forest analysis and applied it to gene selection. Methods Recursive random forest, which is an improvement of random forest, obtains optimal differentiated genes after step by step dropping of genes which, according to a certain algorithm, have no effects on classification. The method has the advantage of random forest and provides a gene importance scale as well. The value of the area under the curve （AUC） of the receiver operating characteristic （ROC） curve, which synthesizes the information of sensitivity and specificity, is adopted as the key standard for evaluating the performance of this method. The focus of the paper is to validate the effectiveness of gene selection using recursive random forest through the analysis of five microarray datasets; colon, prostate, leukemia, breast and skin data. Results Five microarray datasets were analyzed and better classification results have been attained using only a few genes after gene selection. The biological information of the selected genes from breast and skin data was confirmed according to the National Center for Biotechnology Information （NCBI）. The results prove that the genes associated with diseases can be effectively retained by recursive random forest. Conclusions Recursive random forest can be effectively applied to microarray data analysis and gene selection. The retained genes in the optimal model provide important information for clinical diagnoses and research of the biological mechanism of diseases.

关键词： microarray gene selection recursive random forest

An Extended Extrinsic Mechanism for Anomalous Hall Effect

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Communications in Theoretical Physics 2009年第12期52卷 1129-1133页

作者： yan yu-Zhen li Hui-Wu HU liang-Bin Laboratory of Quantum Information Technology School of Physics and Telecommunication Engineering South China Normal University Guangzhou 510631 China

The extrinsic mechanism for anomalous Hall effect in ferromagnets is extended to include the contributions both from spin-orbit-dependent impurity scattering and from the spin-orbit coupling induced by external electric fields. The results obtained suggest that, within the framework of the extrinsic mechanisms, the anomalous Hall current in a ferromagnet may also contain a substantial amount of dissipationless contribution independent of impurity scattering. After the contribution from the spin-orbit coupling induced by external electric fields is included, the total anomalous Hall conductivity is about two times larger than that due to soin-orbit dependent impurity scatterings.

关键词： anomalous Hall effect extrinsic mechanism spin-orbit coupling induced by external electric fields