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Differences in Toxicokinetics and Maternal Transfer between Lipophilic and Proteinophilic Halogenated Organic Pollutants in Laying Hens

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Environment & Health 2024年第10期2卷 712-720页

作者： Xiao-Jun Luo Qun-Jie Feng Chu-hong Zhu Xi Chen Peng-Peng Chen yan-hong zeng Bi-Xian Mai State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Resources Utilization and Protection and Guangdong-hong Kong-Macao Joint Laboratory for Environmental Pollution and Control Guangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou 510640P.R.China State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Resources Utilization and Protection Guangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou 510640P.R.China University of Chinese Academy of Sciences Beijing 100049P.R.China

In this study,we conducted exposure experiments on egg-laying hens to explore the toxicokinetics and maternal transfer characteristics of lipophilic and proteinophilic halogenated organic pollutants(HOPs).The lipophilic HOPs included polychlorinated biphenyls(PCBs),polybrominated diphenyl ethers(PBDEs),and dechlorane plus(DPs),while the proteinophilic HOPs included perfluorocarboxylic acids(PFCAs).The results revealed that most of lipophilic HOPs exhibit lower depuration rate(kd)than *** kd of lipophilic HOPs correlated with the octanol−water partition coefficient(log KOW)values in a V-shaped curve,whereas that of PFCAs correlated with the protein−water partition coefficient(log KPW)values in an inverted V-shaped *** depuration rate,rather than the uptake rate,was a leading factor in determining the bioaccumulation potential of HOPs in *** the dominant factors determining the tissue distribution of the two types of compounds were explicit(fats vs phospholipids),chemical-specific tissue distribution was still *** egg-maternal concentration ratio was dependent on the exposure status,concentration,and maternal tissue *** a single maternal tissue may not be an appropriate method for assessing chemical maternal transfer *** have a greater maternal transfer potential(>80%of the total body burden)than lipophilic HOPs(approximately 30%for BDE209 and DPs,and less than 10%for the others).Their lipophilic and partly proteinophilic nature makes the toxicokinetics and maternal transfer characteristics of BDE209 and DPs different from those of other lipophilic *** findings are crucial for enhancing our understanding of the behavior and fate of HOPs in egg-laying hens.

关键词： halogenated organic pollutants laying hens toxicokinetic maternal transfer

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Bacterial diversity in soils around a lead and zinc mine

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Journal of Environmental Sciences 2007年第1期19卷 74-79页

作者： HU Qing QI hong-yan zeng Jing-hai ZHANG hong-xun Department of Environmental Biotechnology Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China

Five samples of soil collected from a lead and zinc mine were used to assess the effect of combined contamination of heavy metals on soil bacterial communities using a polyphasic approach including characterization of isolates by culture method, community level catabolic profiling in BIOLOG GN microplates, and genetic community fingerprinting by denaturing gradient gel electrophoresis of 16S rDNA fragments amplified by PCR from community DNA （PCR-DGGE）. The structure of the bacterial community was affected to a certain extent by heavy metals. The PCR-DGGE analysis of 16S rRNA genes showed that there were significant differences in the structure of the microbial community among the soil samples, which were related to the contamination levels. The number of bacteria and the number of denaturing gradient gel electrophoresis （DGGE） bands in the soils increased with increasing distance from the lead and zinc mine tailing, whereas the concentration of lead （Pb） and cadmium （Cd） was decreased. Heavily polluted soils could be characterized by a community that differs from those of lightly polluted soils in richness and structure of dominating bacterial populations. The clustering analysis of the DGGE profiles showed that the bacteria in all the five samples of soil belonged to three clusters. The data from the BIOLOG analysis also showed the same result. This study showed that heavy metal contamination decreased both the biomass and diversity of the bacterial community in soil.

关键词： BIOLOG system DGGE heavy metal microbial diversity soils

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Enhancing the intrinsic properties of flower-like BiOI by S-doping toward excellent photocatalytic performances

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Journal of Materials Science & Technology 2022年第23期118卷 190-198页

作者： Jie Xiong hong-yan zeng Sheng Xu Jin-Feng Peng Fang-Yuan Liu Li-Hui Wang College of Chemical Engineering Xiangtan UniversityXiangtan 411105China School of Mechanical Engineering Xiangtan UniversityXiangtan 411105China

A facile strategy was proposed to fabricate the S-doped flower-like BiOI microspheres(S-BiOI) for boosting the photocatalytic performance of BiOI via engineering the surface oxygen vacancy and exposed {001}crystal *** S-doping generated oxygen vacancies in BiOI lattice structure to create point defects and exposed {001} crystal planes,resulting in a decrease in bandgap and an enhancement in charges separation,which could significantly hasten the photocatalytic *** concentration of CH_(4) N_(2) S was a key factor to promote the Cr(Ⅵ) reduction *** optimized S-BiOI_(1.25) presented a superior Cr(Ⅵ) removal efficiency of 100% for 60 min,which Cr(Ⅵ) reduction rate was 11.3 times higher than the pristine BiOI and still remained 97.5% Cr(Ⅵ) removal after 5 *** calculation confirmed that the bandgap of the S-BiOI was narrowed compared to that of BiOI,but the S-BiOI still remained the intrinsic band structure of the pristine BiOI.

关键词： BiOI Sulfide doping Oxygen vacancy Photocatalyst Optical absorption

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Preparation of NiCoFe-hydroxide/polyaniline composite for enhanced-performance supercapacitors

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Journal of Materials Science & Technology 2019年第8期35卷 1691-1699页

作者： Lu Liu Xi Hu hong-yan zeng Mo-Yu Yi Shi-Gen Shen Sheng Xu Xi Cao Jin-Ze Du College of Chemical Engineering Xiangtan University

Ternary NiCoFe layer hydroxides with different Ni/Co/Fe molar ratios were prepared using simple urea *** finely tuning Ni/Co/Fe molar ratio,the optimized hydroxide(LDH(2.0)),a Ni/Co/Fe molar ratio of 2.0/1.0/1.0,provided high specific capacitance(408 F g^-1at 2.0 A g^-1)and good stability(90.9%retention over 1000 cycles)due to maximum crystallinity(91.35%crystallinity)and specific surface area(160 m^2g^-1).In order to further improve the electrochemical performances,the LDH(2.0)was made into a composite(LDH/PANI)with polyaniline(PANI)via in situ polymerization of aniline *** LDH/PANI composite had a much higher specific capacitance(717 F g^-1at 2.0 A g^-1)compared with the LDH(2.0),and a significant improvement of cycleability(84.7%retention over 1000 cycles).The results indicated that the LDH/PANI had a synergistic effect of both components due to the complementary properties,which guaranteed a good electric contact and consequently increased the specific *** provided a new approach for designing organic-inorganic composite materials with potential application in supercapacitors.

关键词： NiCoFe hydroxide Polyaniline Composite Supercapacitors

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Reliability of DC-link capacitor in pulsed power supply for accelerator magnet

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Nuclear Science and Techniques 2024年第9期35卷 28-40页

作者： Jie Wang Da-Qing Gao Wan-zeng Shen hong-Bin yan Li-Jun Mao Institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China School of Nuclear Science and Technology Lanzhou UniversityLanzhou 730000China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China

Capacitors are widely used in pulsed magnet power supplies to reduce ripple voltage,store energy,and decrease power *** this study,DC-link capacitors in pulsed power supplies were *** deriving an analytical method for the capacitor current on the H-bridge topology side,the root-mean-square value of the capacitor current was calculated,which helps in selecting the DC-link *** proposed method solves this problem quickly and with high *** current reconstruction of the DC-link capacitor is proposed to avoid structural damage in the capacitor’s current measurement,and the capacitor’s hotspot temperature and temperature rise are calculated using the FFT *** test results showed that the error between the calculated and measured temperature increases was within 1.5℃.Finally,the lifetime of DC-link capacitors was predicted based on Monte Carlo *** proposed method can evaluate the reliability of DC-link capacitors in a non-isolated switching pulsed power supply for accelerators and is also applicable to film capacitors.

关键词： Aluminum electrolytic capacitor DC-link current DC–DC power converter Hotspot temperature

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CFD-DEM study of impacts of the porous distributor medium on fluidization characteristics of a 2D-fluidized bed

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Particuology 2024年第4期87卷 54-73页

作者： Fei Wang Yishan zeng Hao yan School of Mechanical Engineering Hefei University of TechnologyHefei230009China

Gas-solid bubbling fluidized beds are widely used in chemical,energy,construction,and other industrial fields due to their excellent fluidization performance.2D-fluidized beds with planar rectangular columns of finite thickness are widely used in fluidized bed studies,and it is essential for understanding the hydrodynamics of gas-particle ***,the distributor(porous medium)at the bottom of the bed has a crucial influence on the fluidization performance of the 2D-fluidized *** this work,the fluidization mechanism and gas-solid dynamic characteristics of the fluidized bed under three porous media are studied by CFD-DEM coupled with the porous medium model,and the accuracy of numerical simulation is verified by a high-speed photography *** show that with the increase in the flow resistance of the porous medium,the average and standard deviation of the bubble diameter decrease,and the time and position of particles in the dead zone to participate in the core-annular flow *** a low fluidization velocity,the dead zone in the bed can be considerably reduced by increasing the flow resistance.

关键词： Fluidized bed CFD-DEM Porous medium Bubble dynamics Solid mixing

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High photoluminescence Ag-In-Ga-S quantum dots based on ZnX_(2)-treated surface passivation

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Nano Research 2024年第8期17卷 7533-7541页

作者： Danni yan Yuhui Dong Naiwei Wei Shuai yang hong Zhu Wanzhong Gu Yousheng Zou Haibo zeng MIIT Key Laboratory of Advanced Display Materials and Devices Institute of Optoelectronics&NanomaterialsSchool of Materials Science and EngineeringNanjing University of Science and TechnologyNanjing 210094China

Quaternary Ag-In-Ga-S(AIGS)quantum dot(QD)is considered a promising,spectral-tunable,and environmentally friendly luminescent display ***,the more complex surface defect states of AIGS QDs resulting from the coexistence of multiple elements lead to a low(<60%)photoluminescence quantum yield(PLQY).Here,we develop a novel convenient method to introduce Z-type ligands ZnX_(2)(X=Cl,Br,I)for passivating the surface defects of AIGS QDs to dramatically enhance the PLQY and stability without affecting the crystalline structure and *** show that the addition of ZnCl_(2) during the purified process of AIGS QDs leads to a 3-fold increase of PLQY(from 28.5% to 87%).Impressively,the highest PLQY is up to a recorded value of 92%,which is comparable to typical heavy metal *** dynamics studies have shown that the rapid annihilation process of excitons in treated QDs is *** also confirm that the improvement in PLQY is a result of the effective passivation of the non-coordinating atom on the QD surface by building a new bonding between sulfur dangling and Zn2+.The realization of high PLQY will further promote the application of AIGS QDs in luminescent displays.

关键词： I-III-VI quantum dots Ag-In-Ga-S surface defect passivation Z-type ligand photoluminescence quantum yield

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Sustainable and practical semi-heterogeneous photosynthesis of 5-amino-1,2,4-thiadiazoles over WS_(2)/TEMPO

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Chinese Chemical Letters 2024年第8期35卷 250-253页

作者： Jia-Cheng Hou hong-Tao Ji Yu-Han Lu Jia-Sheng Wang Yao-Dan Xu yan-yan zeng Wei-Min He School of Chemistry and Chemical Engineering University of South ChinaHengyang 421001China

An eco-friendly and practical method for the clean preparation of 5-amino-1,2,4-thiadiazoles was *** WS_(2)as the semiconductor photocatalyst,both TEMPO and O_(2)(in air)as the redox catalysts,a variety of thiadiazoles were semi-heterogeneously formed in high to quantitative yields and could be easily collected by CPME extraction and ***,the catalytic system can be reusable for at least 5 reaction runs.

关键词： Green chemistry Thiadiazoles Heterogeneous catalyst Redox catalyst Extraction

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The critical role of energetic fluctuations in charge separation for efficient molecular doping of organic semiconductors

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Science China Chemistry 2024年第11期67卷 3675-3680页

作者： yan zeng Guangchao Han Yuanping Yi Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences University of Chinese Academy of Sciences

Molecular doping is essential to improve the electrical conductivity of organic semiconductors for high-performance organic electronic devices. However, the doping efficiency is influenced by several factors, such as the energy levels, energetic fluctuations, dielectric properties, and molecular packing structures of the doped films, and the underlying mechanisms for highefficiency doping are still unclear. Here, through multi-level theoretical simulations on a series of fullerene derivatives, we identify that the energetic fluctuations can play a decisive role in activating charge separation for molecular doping. In particular,the doping efficiency appears to be exponentially increased with the fluctuation of charge polarization energies. Therefore,although the charge mobility is somewhat decreased, the experimental electrical conductivity is improved with the increased energetic fluctuation. Moreover, it has been found that polarization energy fluctuation can be effectively enhanced by simply introducing side chains with greater flexibility into organic semiconductors. This article paves the way towards high-efficiency molecular doping of organic semiconductors.

关键词： doping efficiency polarization energies energetic fluctuations organic semiconductors

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Effects of formal credit on pastoral household expense: Evidence from the Qinghai-Xizang Plateau of China

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Journal of Integrative Agriculture 2024年第5期23卷 1774-1785页

作者： yan Zhang Yi Huang Fan Zhang zeng Tang State Key Laboratory of Herbage Improvement and Grassland Agro-ecosystems College of Pastoral Agriculture Science and TechnologyLanzhou UniversityLanzhou 730020China

Formal credit is critical in agricultural production,allowing more expenditure and productive input,thereby improving farmers'*** pastoral China,formal financial institutions are gradually ***,a limited understanding remains of how formal credit affects herders'household *** on a survey of 544 herders from the Qinghai-Xizang Plateau of China,this study adopted the propensity score matching approach to identify the effect of formal credit on herders'total household expenses,daily expenses,and productive *** results found that average age,grassland mortgage,and other variables significantly affected herders'participation in formal *** credit could significantly improve household expenses,especially productive expenses.A heterogeneity analysis showed that formal credit had a greater impact on the household total expense for those at higher levels of wealth;however,it significantly affected the productive expense of herders at lower wealth ***,the mediating effect indicated that formal credit could affect herders'household income,thus influencing their household ***,this study suggests that policies should improve herders'accessibility to formal credit.

关键词： formal credit herders expense Qinghai-Xizang Plateau

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