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Effect of Progressive Substitution of Cement and Lime by Powdered Shells Used as a Curing Agent for Dredged Soil in a Port Area

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 88-102页

作者： sun yang WANG Faxin SU yaying LI yiwei HE Feng College of Harbour Coastal and Offshore EngineeringHohai UniversityNanjing 210098China Huai'an Research Institute Hohai UniversityHuai'an 223025China Jiangsu Fangyang Industrial Investment Corp.Ltd. Lianyungang 210098China

This study aimed to address the challenges of solid waste utilization,cost reduction,and carbon reduction in the treatment of deep-dredged soil at Xuwei Port in Lianyungang city of *** research in this area was ***,a curing agent made from powdered shells was used to solidify the dredged soil in *** employed laboratory orthogonal tests to investigate the physical and mechanical properties of the powdered shell-based curing *** was collected by conducting experiments to assess the role of powdered shells in the curing process and to determine the optimal ratios of powdered shells to solidified soil for different *** development of strength in solidified soil was studied in both seawater and pure water *** study revealed that the strength of the solidified soil was influenced by the substitution rate of powdered shells and their interaction with *** cement content had a positive effect on *** high-strength solidified soil,the recommended ratio of wet soil:cement:lime:powdered shells were 100:16:4:4,while for low-strength solidified soil,the recommended ratio was 100:5.4:2.4:***,under appropriate conditions,improved short-term strength by promoting the formation of expansive ettringite minerals that contributed to cementation and *** findings suggest that the combination of cement and powdered shells is synergistic,positively affecting the strength of solidified *** recommended ratios provide practical guidance for achieving desired strength levels while considering factors such as cost and carbon *** role of seawater in enhancing short-term strength through crystal formation is noteworthy and can be advantageous for certain *** conclusion,this research demonstrates the potential of using a powdered shell-based curing agent for solidifying dredged soil in an environmentally friendly and cost-effective *** recommended ratios for different str

关键词： carbon reduction and solidification dredged soil abandoned shells orthogonal test chemical additives(lime and cement) unconfined compressive strength(UCS)

Dual‑Donor‑Induced Crystallinity Modulation Enables 19.23% Efficiency Organic Solar Cells

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Nano-Micro Letters 2025年第3期17卷 376-388页

作者： Anhai Liang yuqing sun Sein Chung Jiyeong Shin Kangbo sun Chaofeng Zhu Jingjing Zhao Zhenmin Zhao yufei Zhong Guangye Zhang Kilwon Cho Zhipeng Kan Center On Nanoenergy Research Institute of Science and Technology for Carbon Peak&NeutralitySchool of Physical Science&TechnologyGuangxi UniversityNanning 530004People’s Republic of China Department of Chemical Engineering Pohang University of Science and TechnologyPohang 37673South Korea College of New Materials and New Energies Shenzhen Technology UniversityShenzhen 518118People’s Republic of China Zhejiang Engineering Research Center for Fabrication and Application of Advanced Photovoltaic Materials School of Materials Science and EngineeringNingboTech UniversityNingbo 315100People’s Republic of China State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures Nanning 530004People’s Republic of China

Trap-assisted charge recombination is one of the primary limitationsof restricting the performance of organic solar cells. However, effectivelyreducing the presence of traps in the photoactive layer remains ***, wide bandgap polymer donor PTzBI-dF is demonstrated as an effectivemodulator for enhancing the crystallinity of the bulk heterojunction active layerscomposed of D18 derivatives blended with y6, leading to dense and orderedmolecular packings, and thus, improves photoluminescence quenching *** a result, the photovoltaic devices exhibit reduced trap-assisted charge recombinationlosses, achieving an optimized power conversion efficiency of over 19%.Besides the efficiency enhancement, the devices comprised of PTzBI-dF as athird component simultaneously attain decreased current leakage, improved chargecarrier mobilities, and suppressed bimolecular charge recombination, leading toreduced energy losses. The advanced crystalline structures induced by PTzBI-dFand its characteristics, such as well-aligned energy level, and complementaryabsorption spectra, are ascribed to the promising performance *** findings suggest that donor phase engineering is a feasible approach to tuning the molecular packings in the active layer, providingguidelines for designing effective morphology modulators for high-performance organic solar cells.

关键词： Trap-assisted charge recombination Photoluminescence Miscibility Current leakage Power conversion efficiency

Interaction of Nicotine and Bovine Serum Albumin

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Chinese Chemical Letters 2000年第3期11卷 247-250页

作者： Wang, y Cheng, y sun, HF Peking Univ Dept Tech Phys Div Appl Chem Beijing 100871 Peoples R China

The binding of nicotine to bovine serum albumin (BSA) was studied by UV absorption. fluorescence, and H-1 NMR methods. With the addition of nicotine, the absorption band of BSA at about 210 nm decreased gradually, moved to longer wavelengths, and narrowed. BSA fluorescence of tryptophan residue was quenched by nicotine. The H-1 NMR peaks of nicotine moved to downfield by the addition of BSA. The experimental results showed that nicotine was capable of binding with BSA to form a 1:1 complex. BSA's high selectivity for nicotine binding suggests a unique role for this protein in the detoxification and/or transport of nicotine.

关键词： nicotine BSA UV absorption fluorescence H-1 NMR

Effect of post-bond heat treatment on the microstructure and high temperature mechanical property of a TLP bonded γ'-strengthened co-based single crystal superalloy

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Journal of Materials Science & Technology 2021年第21期80卷 244-258页

作者： S.y.Wang y.sun C.y.Cui X.F.sun y.Z Zhou y.M.Ma H.L.An Institute of Metal Research Chinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaHefei 230026China Harbin Welding Institute China Academy of Machinery Science and TechnologyHarbin 150028China

Post-bond heat treatment(PBHT) applied to a transient liquid phase(TLP) bonding joint is an effective approach to remove the brittle borides and improve its ***,we proposed two types of PBHT strategies to obtain a TLP bonded γ'-strengthened Co-based single crystal superalloy,and the microstructural characteristics and tensile properties of the two heat treated joints were compared to identify the optimal PBHT *** evolution of the brittle boride in the joint after the PBHT was studied by using in-situ *** experimental results allowed to provide a theoretic model to quantitatively evaluate the distribution of the brittle phase after the optimal PBHT and analyze the joint fractures to understand the failure *** obtained results revealed that a post-bond solid solution treatment performed to the joint at a high temperature(over 1275℃) could decrease the area fraction of the boride from 7.2 % to 1.4 % and increase the elongation from 1.9 % to 7.8 %.This work emphasizes the relevance of solid solution temperature when a PBHT strategy is applied.

关键词： Transient liquid phase(TLP) γ'-strengthened co-based single crystal superalloy Heat treatment sequence Brittle boride Tensile property

Numerical Simulation of Wave Field at the Kemena River Mouth in Kalimantan Island

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China Ocean Engineering 1999年第2期14卷 217-224页

作者： Chen, y sun, JS Tianjin Res Inst Water Transport Engn Tianjin 300456 Peoples R China

By use of the parabolic equation of numerical simulation of wave which is suitable for large-angle propagation anti Crank-Nicolson differential method, the wave field at the Kemema River mouth has been studied for analysis of sediment movement in the area. In order to reflect wave energy loss accurately, the Bretchneider-Reid formula is quoted and the friction coefficient in the formula is discussed in this paper. The calculation results indicate that the wave becomes a little damped at the mouth of Kemena River influenced by the topography and bottom friction, and the wave at the east beach is higher than that at the west beach, because the east beach extends out.

关键词： parabolic equation wave field numerical simulation river mouth sediment movement

Friction stir spot welding of SPCC low carbon steel plates at extremely low welding temperature

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Journal of Materials Science & Technology 2019年第5期35卷 733-741页

作者： y.F.sun H.Fujii y.Sato y.Morisada Joining and Welding Research Institute Osaka University 11-1 Mihogaoka Ibaraki 567-004Japan School of Materials Science and Engineering Zhengzhou University Zhengzhou 450001 China

Friction stir spot welding (FSSW) was applied to 2.0 mm thick steel plate cold-rolled commercial (SPCC) low carbon steel plates at a very low rotation speed that ranged from 5 to 50rpm, which was much lower than that generally used for the conventional FSSW technique. Due to the very low heat input, the welding processes could therefore be completed at a peak welding temperature below 160℃. As a result, a significantly refined microstructure with an average grain size of about 0.41μm was formed in the stir zone of the joints and the JI {0-11 } and J2{1-1O} shear textures were the dominant components, which are different from the D1{11-2} and D2{-1-12} shear textures formed in the conventional FSSW joints. In addition, no heat affected zone could be detected along the crosssectional plane of the joints. Although a few void-like non-bonded areas were still observed along the interface between the upper and lower steel plates, the shear tensile loads of the joints increased to about 10.0 kN when welded at a condition of 8t, 20rpm and 30 s, and the joints fractured through the plug failure mode.

关键词： Friction stir spot welding Dynamic recrystallization Microstructure Steel

A Hybrid Low Temperature Surface Alloying Process for Austenitic Stainless Steels

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材料热处理学报 2004年第5期25卷 307-310页

作者： y.sun SchoolofMaterialsEngineering NanyangTechnologicalUniversitySingapore639798

This paper describes a novel, hybrid process developed to engineer the surfaces of austenitic stainless steels at temperatures below 450°C for the improvement in wear and corrosion resistance. The process is carried out in the plasma of a glow discharge containing both nitrogen and carbon reactive species, and facilitates the incorporation of both nitrogen and carbon into the austenite surface to form a dual-layer structure comprising a nitrogen-rich layer on top of a carbon-rich layer. Both layers can be precipitation-free at sufficiently low processing temperatures, and contain nitrogen and carbon respectively in supersaturated fee austenite solid solutions. The resultant hybrid structure offers several advantages over the conventional low temperature nitriding and the newly developed carburizing processes in terms of mechanical and chemical properties, including higher surface hardness, a hardness gradient from the surface towards the layer-core interface, uniform layer thickness, and much enhanced corrosion resistance. This paper discusses the main features of this hybrid process and the various structural and properties characteristics of the resultant engineered surfaces.

关键词：奥氏体不锈钢表面铸合等离子体渗氮等离子体渗碳磨损腐蚀

Vibration analysis of hard-coated composite beam considering the strain dependent characteristic of coating material

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Acta Mechanica Sinica 2016年第4期32卷 731-742页

作者： W.sun y.Liu School of Mechanical Engineering and Automation Northeastern University State Key Laboratory of Mechanical System and Vibration Institute of Vibration Shock and Noise Shanghai Jiao Tong University

The strain dependent characteristics of hard coatings make the vibration analysis of hard-coated composite structure become a challenging task. In this study, the modeling and the analysis method of a hard-coated composite beam was developed considering the strain dependent characteristics of coating material. Firstly, based on analyzing the properties of hard-coating material, a high order polynomial was adopted to characterize the strain dependent characteristics of coating materials. Then, the analytical model of a hard-coated composite beam was created by the energy method. Next, using the numerical method to solve the vibration response and the resonance frequencies of the composite beam, a specific calculation flow was also proposed. Finally,a cantilever beam coated with Mg O ＋ Al2_O_3 hard coating was chosen as the study case; under different excitation levels, the resonance region responses and the resonance frequencies of the composite beam were calculated using the proposed method. The calculation results were compared with the experiment and the linear calculation, and the correctness of the created model was verified. The study shows that compared with the general linear calculation, the proposed method can still maintain an acceptable precision when the excitation level is larger.

关键词： coated excitation modulus verified challenging characterize created considering acceptable polynomial

Constructing Donor–Acceptor‑Linked COFs Electrolytes to Regulate Electron Density and Accelerate the Li^(+)Migration in Quasi‑Solid‑State Battery

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Nano-Micro Letters 2025年第1期17卷 456-471页

作者： Genfu Zhao Hang Ma Conghui Zhang yongxin yang Shuyuan yu Haiye Zhu yongjiang sun Hong Guo School of Materials and Energy International Joint Research Center for Advanced Energy Materials of Yunnan ProvinceYunnan UniversityKunming 650091People’s Republic of China yunnan yuntianhua Co. LtdR&D CenterKunming 650228People’s Republic of China Southwest United Graduate School Kunming 650091People’s Republic of China

Regulation the electronic density of solid-state electrolyte by donor–acceptor(D–A)system can achieve highly-selective Li^(+)transportation and conduction in solid-state Li metal *** study reports a high-performance solid-state electrolyte thorough D–A-linked covalent organic frameworks(COFs)based on intramolecular charge transfer *** other reported COFbased solid-state electrolyte,the developed concept with D–A-linked COFs not only achieves electronic modulation to promote highly-selective Li^(+)migration and inhibit Li dendrite,but also offers a crucial opportunity to understand the role of electronic density in solid-state Li metal *** introduced strong electronegativity F-based ligand in COF electrolyte results in highlyselective Li^(+)(transference number 0.83),high ionic conductivity(6.7×10^(-4)S cm^(−1)),excellent cyclic ability(1000 h)in Li metal symmetric cell and high-capacity retention in Li/LiFePO_(4)cell(90.8%for 300 cycles at 5C)than substituted C-and N-based *** is ascribed to outstanding D–A interaction between donor porphyrin and acceptor F atoms,which effectively expedites electron transferring from porphyrin to F-based ligand and enhances Li^(+)***,we anticipate that this work creates insight into the strategy for accelerating Li^(+)conduction in high-performance solid-state Li metal batteries through D–A system.

关键词： Electronic modulation engineering Donor-acceptor-linked covalent organic frameworks Quasi-solid-state Li metal battery