检索结果-南通市图书馆

Low-temperature chlorination roasting technology for the simultaneous recovery of valuable metals from spent LiCoO_(2)cathode material

引用

International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 80-91页

作者： Junjie Shi Changle Hou Jingjing dong dong Chen Jianzhong Li Key Laboratory for Ecological Metallurgy of Multimetallic Mineral(Ministry of Education) Northeastern UniversityShenyang 110819China School of Metallurgy Northeastern UniversityShenyang 110819China

With the continuous increase in the disposal volume of spent lithium-ion batteries(LIBs),properly recycling spent LIBs has become essential for the advancement of the circular *** study presents a systematic analysis of the chlorination roasting kinetics and proposes a new two-step chlorination roasting process that integrates thermodynamics for the recycling of LIB cathode *** activation energy for the chloride reaction was 88.41 kJ/mol according to thermogravimetric analysis–derivative thermogravimetry data obtained by using model-free,model-fitting,and Z(α)function(αis conversion rate).Results indicated that the reaction was dominated by the first-order(F1)model when the conversion rate was less than or equal to 0.5 and shifted to the second-order(F2)model when the conversion rate exceeded *** conditions were determined by thoroughly investigating the effects of roasting temperature,roasting time,and the mass ratio of nH_(4)Cl to LiCoO_(2).Under the optimal conditions,namely 400℃,20 min,and nH_(4)Cl/LiCoO_(2)mass ratio of 3:1,the leaching efficiency of Li and Co reached 99.43% and 99.05%,*** of the roasted products revealed that valuable metals in LiCoO_(2)transformed into CoCl_(2) and ***,the reaction mechanism was elucidated,providing insights for the establishment of a novel low-temperature chlorination roasting technology based on a crystal structure *** technology can guide the development of LIB recycling processes with low energy consumption,low secondary pollution,high recovery efficiency,and high added value.

关键词： spent lithium-ion battery thermodynamics chlorination roasting kinetics circular economy

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Alkaline leaching mechanism of MSWI bottom ash: the pivotal role of Si(Al) chemical bonding environments

引用

Science China Technological Sciences 2025年

作者： ningning SHAO Zekun JIAO Weipeng FEnG yu JIn Fanlong KOnG Zhijun dong Zuotai ZHAnG Institute of Technology for Marine Civil Engineering Shenzhen Institute of Information Technology (SZIIT) Guizhou nASH Ecological Technology Co. LTD School of Environmental Science and Engineering Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City Southern University of Science and Technology (SUSTech)

Municipal solid waste incineration bottom ash(MSWIBA) is a complex assemblage of aluminosilicate materials encompassing diverse solid wastes. Thus, its complexity poses great challenges to their resource utilization. For the sake of the alkali activation use of MSWIBA, this work focused on the characterizations and alkaline leaching experiments of various classified MSWIBA after sorting. Among the different categories of MSWIBA, waste glass(BA-G) and other unidentified slags(BA-O) were identified as potential precursors for alkali activation use. The alkaline leaching experiments proved that alkaline concentration, reaction temperature, reaction time, and raw material classification influenced the leaching process and results. Among these, the Si/Al chemical bonding environments from the material type played a pivotal role. When the materials had Qn(n>2) as the primary bonding structure, steric hindrance by the chain frameworks affected the alkali dissolution process, resulting in gradual disintegration from the outer layers inward. For the materials dominated by Q1frameworks, OH-could penetrate the frameworks, leading to their rapid depolymerization and outward dissolution. Overall, the Si/Al bonding environment played a crucial role in alkaline dissolution, providing theoretical guidance for classify.ng the alkali-activation utilization of MSWIBA and other aluminosilicate solid wastes.

关键词：

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

THERMAL IMAGInG STUDy OF SCALAR TRAnSPORT In SHALLOW WAKES

引用

Journal of Hydrodynamics 2012年第1期24卷 17-24页

作者： CHOnG K.J.y UKTHUSy.nTHAn n.I. LIAnG dong-fang TAnG Hong-wu Department of Engineering University of CambridgeCambridge KW Ltd FetchamSurreyUK College of Water Conservancy and I tydropowcr Engineering Hohai University Nanjing 210098 China

The thermal imaging technique relies on the usage of infrared signal to detect the temperature *** temperature as a flow tracer,thermography is used to investigate the scalar transport in the shallow-water wake generated by an emergent circular *** imaging is demonstrated to be a good quantitative flow visualization technique for study.ng turbulent mixing phenomena in shallow waters.A key advantage of the thermal imaging method over other scalar measurement techniques,such as the Laser Induced Fluorescence（LIF）and Planar Concentration Analysis（PCA）methods,is that it involves a very simple experimental *** dispersion characteristics captured with this technique are found to be similar to past studies with traditional measurement techniques.

关键词： environmental hydraulics shallow wake turbulent mixing thermal imaging vortex street

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

CRySTALLOGRAPHIC AnALySIS OF THE LATH MARTEnSITE TRAnSFORMATIOn In Fe-ni-Mn ALLOy

引用

Acta Metallurgica Sinica(English Letters) 2004年第6期17卷 862-869页

作者： X.P.Lin y.dong X.M.Cao y.Zhang n.J.Gu X.L.Ma DepartmentofMaterialsScienceandTechnology HebeiUniversityofTechnologyTianjin300130ChinaManuscriptreceived18November2003 inrevisedform1June2004

Habit plane rotation of lath martensite transformation in Fe-ni-Mn alloy was predicted by means of Displacement Vector Theory. Its surface relief effect was observed and a math model for the quantitative analysis of habit plane rotation of lath martensite transformation was established by means of atomic force microscopy (AFM). The experiment showed that the largest rotation of habit plane of lath martensite transformation predicted by means of Displacement Vector Theory is 13.50°, and it's incompatible with the concept of invariant plane strain (IPS); surface relief of lath martensite revealed no character of IPS, i.e. it exhibited irregular 'n'-shaped 'surface relief packet', and 'surface relief packet' was composed of layers of several small surface reliefs, the AFM quantitative analysis of habit plane rotation of lath martensite transformation was 11.11°, which was in agreement with the prediction of Displacement Vector Theory (13.50°) and it firmly confirmed the habit plane rotation of lath martensite transformation and the correctness of Displacement Vector Theory.

关键词： atomic force microscope (AFM) surface relief invariant plane strain (IPS) relief angle shear angle

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Potassium ions and cy.no group modified g-C3n4 for effective generation of H2O2 through two-electron oxygen reduction

引用

Science China Chemistry 2025年第1期 192-200页

作者： dongy.ng Wang Shulan Pu y.ngmin Chen Ke Lei yujie Duan Linjiao Mao Xuhui Zeng Xi Luo y.ntao Zhang yuqin dong Jin Zhong Zhang y.n Sun School of Mechanical Engineering Chengdu University Department of Chemistry and Biochemistry University of California

Potassium ions （K+） doped graphitic carbon nitride （g-C3n4） was prepared by a thermal etching method using potassium hydroxide （KOH） as an ion *** transform infrared spectroscopy （FTIR） and X-ray photoelectron spectroscopy （XPS）results showed that the generation of the cy.no group was detected while introducing K+.Under simulated sunlight irradiation,the sample with a K+doping amount of 10%showed the highest hydrogen peroxide （H2O2） generation rate of2,140.2μmol *** apparent quantum yield （AQy） at 400 nm and the solar-to-chemical conversion （SCC） are 4.35%and1.23%,respectively.K+acted as a bridge between g-C3n4layers,which enhanced charge transfer ***,the cy.no group enhanced the adsorption capacity of protons （H+） and promoted the yield of *** catalyst exhibited excellent photocatalytic stability based on four-cycle *** addition,a mechanism study showed that superoxide radicals （·O2-）were the most important active species in the reaction *** production of H2O2was achieved through consecutive single-electron *** study deepens the understanding of the oxygen reduction reaction process and opens up a new venue for improving H2O2generation.

关键词：

来源：

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Small modifications of endo-functionalized cavities lead to large changes in molecular interaction in water

引用

Science China Chemistry 2025年第1期 369-376页

作者： Song-Meng Wang Hao nian y.n-Fang Wang Li-Shuo Zheng yu-Tao Zheng yi-Wei dong Liping Huang Xiaoping Wang Wei Jiang Liu-Pan y.ng Department of Chemistry Southern University of Science and Technology School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal ResourcesGuangxi Normal University School of Pharmaceutical Science Hengyang Medical School University of South China

Study.ng molecular recognition in aqueous environments is crucial for understanding biological processes. Herein, we present a series of n-doped endo-functionalized anthracene-based cavities by introducing inward-directed pyridine units. The subtle modifications can significantly affect the binding properties of these receptors, which is similar to the mutations in biological systems. Combining theoretical calculations and molecular recognition experiments demonstrated that these “mutations” have an impact on the hydrophobicity and charge distribution of the hosts, consequently significantly influencing molecular *** is crucial for understanding the intricate mechanisms of molecular-level interactions in biological receptors.

关键词：

来源：

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

极端洪水导致的外源营养和水位升高对黑藻(Hydrillaverticillata)、附着藻类和水质的影响

引用

湖泊科学 2025年第1期37卷 184-193,I0018,I0019页

作者：罗东黄文强丁明明黎磊南昌大学鄱阳湖环境与资源利用教育部重点实验室南昌大学生命科学学院南昌330031 江西鄱阳湖湿地保护与恢复国家长期科研基地江西鄱阳湖湿地生态系统国家定位观测研究站南昌330031 鄱阳湖流域生态水文监测研究江西省重点实验室南昌330002

极端洪水显著地影响水生植物的生存环境,带来的连锁效应可能是导致沉水植物大规模衰退的原因之一。极端洪水导致的外源营养、水位升高是影响沉水植物生长和繁殖的重要因素,因此以湖泊代表性沉水植物黑藻(Hydrilla verticillata)为对象,... 详细信息

极端洪水显著地影响水生植物的生存环境,带来的连锁效应可能是导致沉水植物大规模衰退的原因之一。极端洪水导致的外源营养、水位升高是影响沉水植物生长和繁殖的重要因素,因此以湖泊代表性沉水植物黑藻(Hydrilla verticillata)为对象,通过模拟研究探讨极端洪水事件导致的水位波动(水位在短时间内升高)及营养脉冲(营养物质在短时间内增加)对沉水植物、附着藻类和水体理化性质的影响。设置4种水位及营养盐负荷情景:对照(水位保持在75 cm)、水位由75 cm逐步上升到150 cm+氮磷输入、水位由75 cm急剧上升到150 cm+氮磷输入以及水位保持75 cm+氮磷输入,其中后3项处理氮、磷输入量相同,90 d内同步监测了浮游植物、附着藻类以及水体氮、磷浓度的变化。结果表明,对照组中,黑藻雌株相较于雄株个体更大,而极端降水(水位急剧上升)处理下,雄株的相对生长速率(RGR)、根生物量和繁殖器官数均大于雌株,表现出明显的性别二态性。雌性个体对水位波动(水位急剧上升和逐步上升)和营养脉冲的响应比雄性个体响应更为敏感。水位急剧上升和逐步上升均抑制了黑藻根生物量积累、RGR和主枝数,但株高、地上生物量和繁殖生物量保持稳定,水位急剧上升同时抑制了附着藻类的生长。营养脉冲提高了上覆水氮浓度,促进浮游植物和周丛藻类生长,对黑藻地上部分、根和繁殖生物量均有显著抑制作用。实验设置的水位范围内,水位升高对黑藻的地上部分生长及繁殖的影响不明显,而氮、磷输入增加及水位波动的联合作用抑制了其地上部分生物量及繁殖输出,因此营养脉冲增强了水位升高对黑藻的影响效应。由此可以认为,极端洪水事件引起的水位波动叠加营养脉冲的复合效应可能会对沉水植物产生明显的抑制作用,随着未来降水强度和频率增加,水生态系统将受到较大的冲击。

关键词：浅水湖泊沉水植物水位波动富营养化气候变化有性繁殖

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

企业视角下的当代工业建筑设计探索与实践

引用

城市建筑 2025年第1期22卷 167-172页

作者：闫冬北京首钢国际工程技术有限公司

随着社会生产力的提高和社会认识的转变,传统工业建筑的设计方法及设计理念已不能满足如今企业的建设需求。文章首先分析了工业建筑设计的发展过程和现阶段设计中存在的问题,从社会认识、生产能力、审美观念等角度总结了制约工业建筑发... 详细信息

随着社会生产力的提高和社会认识的转变,传统工业建筑的设计方法及设计理念已不能满足如今企业的建设需求。文章首先分析了工业建筑设计的发展过程和现阶段设计中存在的问题,从社会认识、生产能力、审美观念等角度总结了制约工业建筑发展的原因。结合实际项目案例和经验,针对当下企业在工业建筑设计建设中所关注的要点,从生产能力保障、内外因素融合、建设成本控制三个方面对当代工业建筑的设计方法和策略进行了探索和研究。从缩短建设周期、提供可变空间、彰显地域特征和企业文化、降低建造成本等方面为工业建筑的设计提供了有价值的参考和帮助。

关键词：工业建筑企业视角产能保障元素融合成本控制设计探索

来源：

维普期刊数据库博看期刊

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Designs to Improve Capability of neural networks to Make Structural Predictions

引用

Chinese Journal of Polymer Science 2023年第9期41卷 1477-1485,I0009页

作者： Tian-yao Wang Jian-Feng Li Hong-dong Zhang Jeff Z.y.Chen Department of Macromolecular Science State Key Laboratory of Macromolecular Engineering of PolymersFudan UniversityShanghai200438China Department of Physics and Astronomy University of WaterlooWaterlooN2L 3G1Canada

A deep neural network model generally consists of different modules that play essential roles in performing a *** optimal design of a module for use in modeling a physical problem is directly related to the success of the *** this work,the effectiveness of a number of special modules,the self-attention mechanism for recognizing the importance of molecular sequence information in a polymer,as well as the big-stride representation and conditional random field for enhancing the network ability to produce desired local configurations,is numerically *** models containing these modules are trained by using the well documented data of the native structures of the HP model and assessed according to their capability in making structural predictions of unseen *** specific network design of self-attention mechanism adopted here is modified from a similar idea in natural language *** big-stride representation module introduced in this work is shown to drastically improve network's capability to model polymer segments of strong lattice position correlations.

关键词： Deep neural network Self-attention mechanism Big-stride representation Conditional random methods

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Magneto optics and time resolved terahertz spectrocopy

引用

Chinese Physics B 2018年第7期27卷 112-119页

作者： T dong Z G Chen n L Wang International Center for Quantum Materials School of PhysicsPeking UniversityBeijing 100871China Institute of Physics Chinese Academy of SciencesBeijing 100190China

Exploring, manipulating, and understanding new exotic quantum phenomena in condensed-matter systems have gen- erated great interest in the scientific community. Static and time resolved optical spectroscopies after photoexcitations are important experimental tools for probing charge dynamics and quasiparticle excitations in quantum materials. In Syner- getic Extreme Condition User Facility （SECUF）, we shall construct magneto-infrared and terahertz measurement systems and develop a number of ultrafast femtosecond laser based systems, including intense near to mid-infrared pump terahertz probe. In this article, we shall describe several systems to be constructed and developed in the facilities, then present some examples explaining the application of magneto optics and time resolved spectroscopy techniques.

关键词： magneto-optics infrared spectroscopy mid-infrared pump terahertz probe

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：