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EFFECT OF Cu-Ni CONTENT ON THE CORROSION RESISTANCE OF(Cu-Ni)/(10NiO-90NiFe_2O_4)CERMET INERT ANODE FOR ALUMINUM ELECTROLySIS

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Acta Metallurgica Sinica(English Letters) 2008年第1期21卷 72-78页

作者： Z.L. Tian y.Q. Lai J. Li y.x. liu School of Metallurgical Science and Engineering Central South University Changsha 410083 China

（Cu-Ni）/（10NiO-90NiFe204） cermet inert anodes containing metal Cu-Ni0, 5, 10, 15 and 20 wt pct were prepared and their corrosion resistance to Na3AlF6-Al2O3 melts was investigated. The results indicate that the content of metal Cu-Ni has little effect on the steady-state concentration of Ni in the electrolyte and the values could not be used to effectively differentiate their corrosion resistance. The steady-state concentration of Fe decreases from 304×10^-6 to 168×10^-6 and that of Cu increases from 21×10^-6 to 71×10^-6 with the content of metal Cu-Ni increasing from 0 to 20 wt pct. Post-examination shows that metallic phase Cu-Ni is corroded preferentially during electrolysis and many pores are left at the anode surface. Considering the corrosion resistance and electrical conductivity, the cermet containing metal Cu-Ni 5 wt pct should be selected and studied further.

关键词： Aluminum electrolysis Inert anode NiFe2O4 based cermet Corrosion resistance

THERMAL STRESSES RELAxATION DESIGN OF Ni/NiFe_(2)O_(4) SySTEM FUNCTIONALLy GRADED CERMET INERT ANODE

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Acta Metallurgica Sinica(English Letters) 2005年第5期18卷 635-641页

作者： J. Li Q.S. Zhang y.Q. Lai S.L. ye y.x. liu School of Metallurgy Science and Engineering Central South University Changsha 410083 China

The thermal stresses relaxation of Ni/NiFe2O4 system functionally graded cermet inert anode for aluminum electrolysis was optimally designed. The transient thermal stresses of the inert anode under complex boundary condition during high-temp （955℃） electrolysis were calculated using the finite-element software ANSyS, the influence of different parameters on the distribution of the thermal stresses were analyzed. The results showed that, during the process of thermal shock, the thermal hoop tensile stress on the surface of the anode is very large, which is possibly the major cause of anode crack; when the radius of the anode is between 0.05-0.15m, a range that can be realized by recent manufacturing technology, the optimum composition distribution exponent p is 0.25; The hoop tensile stresses reduce with the decrease of anode scale and also decrease with the decrease of the convection coefficient between the electrolyte and the anode.

关键词： functionally graded material (FGM) transient thermal stresses ANSyS inert anode aluminum electrolysis

INVESTIGATION OF MULTI-STEP THERMO-MECHANICALTREATMENT OF CAN-FORGED TiAl-BASED ALLOy

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Acta Metallurgica Sinica(English Letters) 1997年第4期10卷 369-374页

作者： y.H. He B. y. Huang y. liu and y.x. liu (Powder Metallurgy Research Institute, Central South University of Technology, Changsha 410083, China) Central South Univ of Technology Changsha China

The effects of a new technology, multi-step thermo-mechanical treatment, on the microstructure, deformation substructure and mechanical properties at ambient and elevated tempemture of can-forged Ti-33 Al-3 Cr-0.5Mo (wt%) Alloy were *** results show that, after multi-step thermo-mechanical treatment of can-forged specimens, homogeneous, fine microstructures can be obtained in the whole TiAl-based alloy specimens. Furthermore, the specimen with homogeneous and fine full lamellae microstructure demonstrutes excellent comprehensive mechanical properties at ambient and elevated temperature.

关键词： TiAl-based alloy mechanical property heat treatment

THE EFFECT OF POWERFUL OxyGEN EVOLUTION METAL-OxIDE ON THE ELECTROOxIDATION OF METHANOL

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Acta Metallurgica Sinica(English Letters) 2001年第2期14卷 103-108页

作者： x.C. Chen, y.x. liu, J. Li, J.J. Chen and H.Z. liu (Department of Metallurgy Science and Engineering, Central South University, Changsha 410083, China) Department of Metallurgy Science and Engineering Central South University

An improved thermal decomposition method is used to prepare modified titanium base anodes. Some researches have been carried out to learn about the oxygen evolution properties of RuMn, RuCo and RuEu etc. in H2SO4 solution and their effect on the electrooxidation of methanol if they are added into the catalytic layers of Pt/Ti electrodes. The result indicates that the Pt/Ti electrodes containing RuMn, RuCo, RuCe and RuEu, etc. metal oxide catalysts with the powerful evolution property exhibit a higher electro-catalytic activity towards methanol electrooxidation than Pt/Ti electrodes without composite metal oxide catalysts.

关键词： Anodes Decomposition Methanol Oxidation Titanium

CRySTAL DEFECTS IN PLASMA NITRIDED LAyER CATALyZED By RARE EARTH

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Acta Metallurgica Sinica(English Letters) 2002年第2期15卷 243-247页

作者： F.S.Chen, y.x. liu, D.K. Liang and L.M. xiao School of Materials Science and Technology, Shandong University, Jinan 250061, China School of Materials Science and Technology Shandong UniversityJinan 250061China

The microstructure of plasma nitrided layer catalyzed by rare-earth elementshas been studied with TEM. The results show that the grains of gamma ft-Fe_4N phase are refined byrare-earth elements and the plane defects in boundary are increased by rare-earth elements. Theaddition of rare-earth element increases the bombardment effect and the number of crystal defectssuch as vacancies, dislocation loops, twins and stacking faults in gamma ft -Fe_4N phase and canproduce the high-density dislocations in the ferrite of diffusion layer at a distance 0.08mm fromthe surface. The production of a number of crystal defects is one of important reasons whyrare-earth element accelerates the diffusion of nitrogen atoms during plasma-nitriding.

关键词： rare-earth element plasma-nitriding crystal defect

Rational modulation of fluorophosphate cathode by anionic groups to reduce the polarization behavior for fast-charging sodium-ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 509-521页

作者： xinyuan Wang Fan Zhang xingyu Zhou Qian Wang Changyu liu yangyang liu Hui Wang xiaojie liu Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education College of Chemistry & Materials Science Northwest University

Na3V2（PO4）2O2F （VP） is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific *** functional theory （DFT） and finite element simulations show that incorporating SO42-into VP decreases its band gap,lowers the migration energy barrier,and ensures a uniform Na+concentration gradient and stress distribution during charge and discharge ***,the average Na+diffusion coefficient of Na3V2（PO4）1.95（SO4）0.05O2F（VPS-1） is roughly double that of VP,leading to enhanced rate capability (80 C,75.5 mAh g-1) and cycling stability (111.0 mAh g-1capacity after 1000 cycles at 10 C current density) for ***-1 exhibits outstanding fast-charging capabilities,achieving an 80%state of charge in just 8.1 *** assembled VPS-1//SbSn/NPC full cell demonstrated stable cycling over 200 cycles at a high 5 C current,maintaining an average coulombic efficiency of 95.35%.

关键词： Anionic group modulation Polarization behavior Fast-charging Sodium-ion battery Fluorophosphate Cathode

Role of the Greenland Sea ice anomaly in the late-spring drought over Northwest China

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Atmospheric and Oceanic Science Letters 2025年第1期18卷 1-5页

作者： yang liu Huopo Chen Nansen-Zhu International Research Centre Institute of Atmospheric Physics Chinese Academy of SciencesBeijingChina Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters Nanjing University for Information Science and TechnologyNanjingChina

Drought across Northwest China in late spring has exerted a vital effect on the local climate and agricultural production,and has been alleviated during the past *** study explored the influence of the preceding Arctic sea ice on the May drought in Northwest China caused by the precipitation *** analysis indicated that when the Greenland Sea ice concentration is abnormally high during February to April,the dry conditions in Northwest China tend to be *** increase of sea ice in the Greenland Sea can excite a meridional circulation,which causes sea surface temperature(SST)anomalies in the North Atlantic via the sea-air interaction,manifested as significant warm SST anomalies over the south of Greenland and the subtropical North Atlantic,but negative SST anomalies over the west of the *** abnormal SST pattern maintains to May and triggers a zonal wave train from the North Atlantic through Scandinavia and Central Asia to Northwest China,leading to abnormal cyclones in Northwest ***,Northwest China experiences a more humid climate than usual.

关键词： Arctic sea ice Greenland Sea North Atlantic SST Drought Northwest China

Low-cost and fluoride-free synthesis of MFI zeolite nanosheets with enhanced stability for benzene alkylation with ethanol

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Journal of Energy Chemistry 2025年第1期100卷 458-468页

作者： Peng Zhu Cun liu yiren yu Guoshu Gao yumeng Zhao xiongfu Zhang Guodong liu Guohui yang State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences

Zeolite nanosheets with a short b-axis thickness are highly desirable in lots of catalytic reactions due to their reduced diffusion resistance. Nevertheless, conventional synthesis methods usually require expensive structure-directing agents(SDAs), pricey raw materials, and eco-unfriendly fluorine-containing additives. Here, we contributed a cost-effective and fluoride-free synthesis method for synthesizing high-quality MFI zeolite nanosheets through a Silicalite-1(Sil-1) seed suspension and urea cooperative strategy, only with inexpensive colloidal silica as the Si source. Our approach was effective for synthesizing both Sil-1 and aluminum-containing ZSM-5 nanosheets. By optimizing key synthesis parameters,including seed aging time, seed quantity, and urea concentration, we achieved precise control over the crystal face aspect ratio and b-axis thickness. We also revealed a non-classical oriented nanosheet growth mechanism, where Sil-1 seeds induced the formation of quasi-ordered precursor particles, and the(010)crystal planes of these particles facilitated urea adsorption, thereby promoting c-axis-oriented *** obtained ZSM-5 nanosheets exhibited exceptional catalytic performance in the benzene alkylation with ethanol, maintaining stability for over 500 h, which is 5 times longer than traditional ZSM-5 catalysts. Furthermore, large-scale production of ZSM-5 nanosheets was successfully carried out in a 3 L highpressure autoclave, yielding samples consistent with those from laboratory-scale synthesis. This work marks a significant step forward in the sustainable and efficient production of MFI nanosheets using inexpensive and environmentally friendly raw materials, offering the broad applicability in catalysis.

关键词： MFI zeolite ZSM-5 Nanosheets Scale-up synthesis Aromatic alkylation

In-plane crushing behavior and energy absorption design of composite honeycombs

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Acta Mechanica Sinica 2018年第6期34卷 1108-1123页

作者： H.x.Wu y.liu x.C.Zhang School of Civil Engineering Northeast Forestry UniversityHarbin 150040China Institute of Mechanics Beijing Jiaotong UniversityBeijing 100044China Department of Mechanical Engineering North China Electric Power UniversityBaoding 071003China

Theoretical analysis and numerical simulation methods were used to study the in-plane crushing behavior of single-cell structures and regular and composite ***,hexagonal,and circular honeycombs were selected as honeycomb layers to establish composite honeycomb models in the form of composite structures and realize the complementary advantages of honeycombs with type Ⅰ and type Ⅱ *** effects of honeycomb layer arrangement,plastic collapse strength,relative density,and crushing velocity on the deformation mode,plateau stress,load uniformity,and energy absorption performance of the composite honeycombs were mainly considered.A semi-empirical formula for plateau stress and energy absorption rate per unit mass for the composite honeycombs was *** results showed that the arrangement mode of honeycomb layers is an important factor that affects their mechanical *** selecting the arrangement of honeycomb layers and the proportion of honeycomb layers with different structures in a composite honeycomb can effectively improve its load uniformity and control the magnitude of plateau stress and energy absorption capacity.

关键词： Composite honeycombs Dynamic crushing Load uniformity Energy absorption Finite element analysis