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Rational modulation of fluorophosphate cathode by anionic groups to reduce the polarization behavior for fast-charging sodium-ion batteries

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journal of Energy Chemistry 2025年第1期100卷 509-521页

作者： Xinyuan Wang Fan Zhang Xingyu Zhou qian Wang Changyu Liu yangyang Liu Hui Wang Xiaojie Liu Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education College of Chemistry & Materials Science Northwest University

Na3V2（PO4）2O2F （VP） is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific *** functional theory （DFT） and finite element simulations show that incorporating SO42-into VP decreases its band gap,lowers the migration energy barrier,and ensures a uniform Na+concentration gradient and stress distribution during charge and discharge ***,the average Na+diffusion coefficient of Na3V2（PO4）1.95（SO4）0.05O2F（VPS-1） is roughly double that of VP,leading to enhanced rate capability (80 C,75.5 mAh g-1) and cycling stability (111.0 mAh g-1capacity after 1000 cycles at 10 C current density) for ***-1 exhibits outstanding fast-charging capabilities,achieving an 80%state of charge in just 8.1 *** assembled VPS-1//SbSn/NPC full cell demonstrated stable cycling over 200 cycles at a high 5 C current,maintaining an average coulombic efficiency of 95.35%.

关键词： Anionic group modulation Polarization behavior Fast-charging Sodium-ion battery Fluorophosphate Cathode

Synergistically enhanced ORR and HER performance on Co-N-C coupled in-situ generated PtCo intermetallic

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journal of Energy Chemistry 2025年第1期100卷 721-729页

作者： Guanyu Luo Min Song Lulu An Xiao Huang qian Zhang Chenhao Zhang Tao Shen Shuang Wang Deli Wang Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology) Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology

Integrating multi-scale sites in a composite catalyst is vital to realize efficient ***,a synergistic composite catalyst consisting of Co atomic sites and in-situ generated PtCo intermetallic compounds （IMCs）(o-PtCo@CoNC) is proposed through Co pre-anchoring and subsequent impregnation-reduction *** loading of Co atoms provides a chance for in-situ generating PtCo ordered intermetallic *** remaining Co single atoms and PtCo IMCs construct synergistic electrocatalytic *** from the ordered structure,synergistic effect of Pt Co IMCs and Co single atoms,o-PtCo@CoNC exhibits excellent electrocatalytic performance for oxygen reduction reaction （ORR） and hydrogen evolution reaction （HER） with mass activity of 1.21 A mgPt-1（at 0.9 V） and5.70 A mgPt-1（at an overpotential of 100 mV）,***,o-PtCo@CoNC delivers negligible loss of half-wave potential and overpotential during long-term stability test in acid solutions,with 13 mV decay after 50,000 potential cycles for ORR and a 2.7 mV decay after 20,000 potential cycles for *** integration strategy of single-atomic sites coupled IMCs paves the way for enhancing the activity and durability of Pt-based electrocatalysts.

关键词： Synergistic effect Intermetallics Single atomic sites Oxygen reduction reaction Hydrogen evolution reaction

Atmospheric reductive catalytic fractionation of lignocellulose integrated with one-pot catalytic conversion of carbohydrate yielding valuable lignin monomers and platform chemicals from corn straw

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Green Energy & Environment 2025年第1期10卷 161-172页

作者： Meng-ying Liu Zhe-Hui Zhang Xue-Qi Wang qian Sun Chen Zhang yu Li Zhuohua Sun Katalin Barta Feng Peng Tong-Qi yuan State Key Laboratory of Efficient Production of Forest Resources Beijing Forestry UniversityBeijing100083China Beijing Key Laboratory of Lignocellulosic Chemistry Beijing Forestry UniversityBeijing100083China Department of Chemistry Organic and Bioorganic ChemistryUniversity of GrazHeinrichstrasse 28/II8010 GrazAustria

Developing a cost-effective and environmentally friendly process for the production of valuable chemicals from abundant herbal biomass receives great attentions in recent ***,taking advantage of the“lignin first”strategy,corn straw is converted to valuable chemicals including lignin monomers,furfural and 5-methoxymethylfurfural via a two steps *** key of this research lies in the development of a green and low-cost catalytic process utilizing magnetic Raney Ni catalyst and high boiling point ethylene *** utilization of neat ethylene glycol as the sole slovent under atmospheric conditions obviates the need for additional additives,thereby facilitating the entire process to be conducted in glass flasks and rendering it highly convenient for scaling *** the initial step,depolymerization of corn straw lignin resulted in a monomer yield of 18.1 wt%.Subsequently,in a dimethyl carbonate system,the carbohydrate component underwent complete conversion in a one-pot process,yielding furfural and 5-methoxymethylfurfural as the primary products with an impressive yield of 47.7%.

关键词： Atmospheric reductive catalytic fractionation Corn straw Ethylene glycol Raney Ni 5-Methoxymethylfurfural

Thermally triggered topological polymerization in diacetylene-functionalized covalent organic framework toward enhanced memristive properties

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Science China Chemistry 2025年

作者： Panke Zhou yuxing Huang Ziyue yu Cong Zhang qian Chen yiping Li Chao Lin Xiong Chen State Key Laboratory of Photocatalysis on Energy and Environment Key Laboratory of Advanced Carbon-Based Functional MaterialsCollege of Chemistry Fuzhou University

The development of stimuli-responsive switching memory devices and the elucidation of their switching mechanisms in specific environments are crucial for advancing the field of molecular electronics. Herein, we propose two distinct two-dimensional covalent organic frameworks (COFs), namely Py-EDA and Py-BDA, incorporating acetylene (-C≡C-) or diacetylene(-C≡C-C≡C-) moieties, respectively, targeting fabricate memory devices exhibiting stimuli-responsive switching *** findings demonstrate that the incorporation of acetylene units effectively modulates the electronic band structure and enhances the degree ofπ-conjugation, resulting in devices that exhibit typical bipolar nonvolatile memory performance. Notably,upon thermal treatment, the memory behavior of the ITO/Py-BDA/Ag device transitions to a write-once-read-many-times(WORM) mode, displaying decreased SET voltage, increased ON/OFF current ratio, and remarkable retention reliability and cycle stability. This switching behavior is attributed to the occurrence of interlayer solid-state topological polymerization at 350℃, leading to the transformation of diacetylene columnar arrays into enyne chains within Py-BDA, thereby further promoting interlayer charge transfer and separation.

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Selective G6PDH inactivation for Helicobacter pylori eradication with transformed polysulfide

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Science China Life Sciences 2025年

作者： Xiaonan Wang Ning Zhou Xuejiao j.Gao Zijing Zhu Minmin Sun qian Wang Haolin Cao Xuetong Wu Caiyu Zhou Qingkang Zheng ye yuan yuan Liu Lei Chen jing jiang Pengcheng Bu Lizeng Gao CAS Engineering Laboratory for Nanozyme Key Laboratory of Biomacromolecules Institute of Biophysics Chinese Academy of Sciences School of Life Sciences University of Chinese Academy of Sciences College of Chemistry and Chemical Engineering Jiangxi Normal University Key Laboratory of Epigenetic Regulation and Intervention Institute of Biophysics Chinese Academy of Sciences Nanozyme Laboratory in Zhongyuan School of Basic Medical Sciences Zhengzhou University Nanozyme Laboratory in Zhongyuan Henan Academy of Innovations in Medical Science

Alternative treatment for the highly prevalent Helicobacter pylori infection is imperative due to rising antibiotic resistance. We unexpectedly discovered that the anti-H. pylori component in garlic is hydrogen polysulfide（H2S_n, n≥2）, not organic polysulfides. Studies on the mechanism of action（MoA） show that H2S_nspecifically inactivates H. pylori glucose-6-phosphate dehydrogenase（G6PDH） by interfering with electron transfer from glucose-6-phosphate（G6P） to nicotinamide adenine dinucleotide phosphate（NADP+）. However, low H2S_nyield makes garlic derivatives hard to be a reliable donor of H2S_nto treat H. pylori infection. To address this challenge, we established a polysulfide transformation process from garlic organosulfur compounds into Fe3S4that generates H2S_nwith a 25–58 times increase in *** chitosan encapsulation, we designed a gastric-adaptive H2S_nmicroreactor（GAPSR） that eradicates H. pylori with 250 times higher efficiency under gastric conditions. A single GAPSR achieves more rapid H. pylori eradication than combined antibiotics therapy without disturbing the gut microbiota. These findings indicate a distinct MoA transformation mediated by polysulfide as an alternative candidate to treat H. pylori infection.

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带拼接板螺栓连接耗能梁段的可恢复功能钢框筒结构抗震性能研究

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Interannual variability of boreal summer intraseasonal oscillation over the northwestern Pacific influenced by the Pacific Meridional Mode

工程力学 2025年第1期42卷 83-102页

作者：连鸣戴子琳程倩倩西安建筑科技大学土木工程学院西安710055 西安建筑科技大学结构工程与抗震教育部重点实验室西安710055 中国建筑西北设计研究院有限公司西安710018

为了提升传统钢框筒结构的延性和耗能能力，提出采用拼接板螺栓连接的可恢复功能剪切耗能型钢框筒结构(FTS-SRSL)，该结构结合了可更换剪切型耗能梁段和钢框筒结构具有良好的抗震性能。该文对一个2/3缩尺的单层单跨FTS-SRSL子结构试件... 详细信息

为了提升传统钢框筒结构的延性和耗能能力，提出采用拼接板螺栓连接的可恢复功能剪切耗能型钢框筒结构(FTS-SRSL)，该结构结合了可更换剪切型耗能梁段和钢框筒结构具有良好的抗震性能。该文对一个2/3缩尺的单层单跨FTS-SRSL子结构试件进行了往复加载试验，试验结果表明，FTS-SRSL子结构试件具有良好的抗震性能，结构损伤集中于耗能梁段，且耗能梁段可实现更换。在试验的基础上，以耗能梁段长度比、耗能梁段腹板加劲肋间距、螺栓直径、翼缘拼接板和腹板拼接板厚度为参数，利用ABAQUS建立了15个足尺的单层单跨FTS-SRSL有限元模型，探究各模型的抗震性能，包括承载力、刚度、耗能以及塑性变形能力。有限元分析结果表明：改变拼接板螺栓连接的剪切型耗能梁段长度比会显著影响结构的承载力、刚度及耗能，建议FTS-SRSL中的拼接板螺栓连接剪切型耗能梁段长度比取0.73~1.09;改变耗能梁段腹板加劲肋间距对结构的承载力、刚度和耗能影响较小，基于该文的分析结果，建议FTS-SRSL中的拼接板螺栓连接剪切型耗能梁段腹板加劲肋间距取e/4~e/3(e为耗能梁段长度)，且间距应满足我国抗规的规定;改变翼缘拼接板和腹板拼接板厚度对结构的承载力、刚度及耗能基本无影响;改变螺栓直径对结构承载力、刚度及耗能影响较小。

关键词：可更换耗能梁段拼接板螺栓连接钢框筒结构抗震性能参数分析

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Atmospheric and Oceanic Science Letters 2025年第1期18卷 6-11页

作者： Haoyu Zhou Pang-Chi Hsu Lin Chen yitian qian Key Laboratory of Meteorological Disaster Ministry of Education/Joint International Research Laboratory of Climate and Environmental Change/Collaborative Innovation Center on Forecast and Evaluation of Meteorological DisastersNanjing University of Information Science and TechnologyNanjingChina

During the boreal summer,intraseasonal oscillations exhibit significant interannual variations in intensity over two key regions:the central-western equatorial Pacific(5°S-5°N,150°E-150°W)and the subtropical Northwestern Pacific(10°-20°N,130°E-175°W).The former is well-documented and considered to be influenced by the ENSO,while the latter has received comparatively less attention and is likely influenced by the Pacific Meridional Mode(PMM),as suggested by partial correlation analysis *** elucidate the physical processes responsible for the enhanced(weakened)intraseasonal convection over the subtropical northwestern Pacific during warm(cold)PMM years,the authors employed a moisture budget *** findings reveal that during warm PMM years,there is an increase in summer-mean moisture over the subtropical northwestern *** increase interacts with intensified vertical motion perturbations in the region,leading to greater vertical moisture advection in the lower troposphere and consequently resulting in convective *** a process is pivotal in amplifying intraseasonal convection *** observational findings were further verified by model experiments forced by PMM-like sea surface temperature patterns.

关键词： Boreal summer intraseasonal oscillation Interannual variability Pacific Meridional Mode Moisture budget analysis

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Influence of inorganic salt on aerobic biodegradability of dyestuffs

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journal of Environmental Sciences 2000年第4期12卷 416-421页

作者： Zhan, X. Wang, j. Wen, X. Feng, y. qian, y. Key joint Lab. on Envl. Simulation Dept. of Envtl. Sciences and Eng. Tsinghua University Beijing 100084 China

In this paper, the influence of inorganic salt on aerobic biodegradability of dyestuffs was studied by means of semi-continuous activated sludge method. It was found that: biodegradability of dyestuffs would decrease with the increase of the concentration of NaCl; however, biodegradability in the condition of NaCl = 30 g/L was better than that in the condition of NaCl = 15 g/L; in the three NaCl conditions, biodegradability of tested dyestuffs followed the following order: NaCl = 0 g/L>NaCl = 30 g/L>NaCl = 15 g/L.

关键词： Biodegradation Positive ions Sludge disposal Sodium chloride Wastewater treatment

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PHOTOCATALyTIC PERFORMANCE OF PLASMA SPRAyED TiO_2-ZnFe_2O_4 COATINGS

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Acta Metallurgica Sinica(English Letters) 2005年第3期18卷 363-368页

作者： y.Zeng j.T.Liu W.j.qian j.H.Gao ShanghaiInstituteofCeramics TheChineseAcademyofSciencesShanghai200050China

A novel TiO2-ZnFe2O4 coating is prepared by plasma spraying. The effects of spra ying parameters and the composition of powders on the microstructure, surface mo rphology and photo-absorption of plasma sprayed coatings are studied. The photoc atalytic efficiency of the as-sprayed coatings is evaluated through the photo mi neralization of methylene blue. It was found that TiO2 coatings can decompose me thylene blue under the illumination of ultraviolet rays, and the degrading effic iency is improved with an increase in the content of FeTiO3 in the coatings. How ever, the presence of large amount of ZnFe2O4 compound will substantially lower the photocatalytic efficiency of the TiO2-ZnFe2O4 coatings for the unfavorable p hoto-excited electron-hole transfer process.

关键词： plasma spraying photocatalytic activity TiO2 ZnFe2O4

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