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Hard yet tough and self-lubricating(CuNiTiNbCr)C_(x) high-entropy nanocomposite films:Effects of carbon content on structure and properties

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journal of Materials Science & Technology 2024年第6期173卷 20-30页

作者： y.T.Li X.M.Chen X.K.zeng M.Liu X.jiang y.X.Leng Key Laboratory of Advanced Technologies of Materials Ministry of EducationSchool of Materials Science and EngineeringSouthwest Jiaotong UniversityChengdu 610031China Key Laboratory of Noise and Vibration Research Institute of AcousticsChinese Academy of SciencesBeijing 100190China State Key Laboratory of Acoustics Institute of AcousticsChinese Academy of SciencesBeijing 100190China School of Mechanical and Electrical Engineering Mianyang Teachers’CollegeMianyang 621000China

The single-phase high-entropy alloy film is difficult to meet severe friction conditions due to its low hardness and high friction ***-composite structure film is composed of at least two separated phases,showing the properties of strength and toughness integration and excellent wear *** design of nanocomposite structures can effectively improve the mechanical properties and tribological properties of high-entropy alloy *** this study,the(CuNiTiNbCr)C_(x) nanocomposite high-entropy films(HEFs)integrated with high hardness,high toughness,and self-lubrication were synthesized by the double-target co-sputtering *** effect of carbon content on microstructure,mechanical properties,and tribological properties of(CuNiTiNbCr)C_(x) films was *** the increase of carbon content in the HEFs,the carbon atoms preferentially react with Ti,Nb,and Cr to form a(TiNbCr)C ceramic-reinforced phase,and then the excess carbon atoms precipitate in the form of amorphous carbon(a-C)lubricating phase in the *** structure of the HEFs changes from an amorphous structure to a nanocomposite structure of amorphous(amorphous CuNiTiNbCr phase+a-C phase)/nanocrystalline(TiN-bCr)C *** the carbon content is about 21.2 at.%,the carbide phase in the film reaches saturation and the hardness and modulus of the films are highest,which are 18 GPa and 228 GPa,*** HEFs with a carbon content of 44.0 at.%show the best toughness and tribological properties with a friction coefficient of 0.16 and a wear rate of 2.4×10^(-6) mm^(3)/(N m),which is mainly attributed to the excellent resistance to fatigue crack growth and the interfacial lubricating layer formed in the friction *** nanocomposite(CuNiTiNbCr)C_(x) HEFs show very promising application prospect in the field of friction protection.

关键词： High-entropy films Nanocomposite Double-target co-sputtering Strengthening-toughening Tribological properties

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Preparation of Ga_2O_3 thin film solar-blind photodetectors based on mixed-phase structure by pulsed laser deposition

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Chinese Physics B 2019年第1期28卷 171-177页

作者： y M Lu C Li X H Chen S Han P j Cao F jia y X zeng X K Liu W y Xu W j Liu D L Zhu College of Materials Science and Engineering Shenzhen Key Laboratory of Special Functional MaterialsShenzhen Engineering Laboratory for Advanced Technology of CeramicsGuangdong Research Center for Interfacial Engineering of Functional MaterialsShenzhen UniversityShenzhen 518060China

Gallium oxide(Ga_2O_3) thin films were deposited on a-Al2O3(1120) substrates by pulsed laser deposition(PLD) with different oxygen pressures at 650?C. By reducing the oxygen pressure, mixed-phase Ga_2O_3 films with α and β phases can be obtained, and on the basis of this, mixed-phase Ga_2O_3 thin film solar-blind photodetectors(SBPDs) were *** the responsivities of the mixed-phase Ga_2O_3 SBPDs and the single β-Ga_2O_3 SBPDs at a bias voltage of 25 V,it is found that the former has a maximum responsivity of approximately 12 A/W, which is approximately two orders of magnitude larger than that of the latter. This result shows that the mixed-phase structure of Ga_2O_3 thin films can be used to prepare high-responsivity SBPDs. Moreover, the cause of this phenomenon was investigated, which will provide a feasible way to improve the responsivity of Ga_2O_3 thin film SBPDs.

关键词： Ga2O3 mixed-phase solar-blind photodetector pulsed laser deposition

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Research on optimal immunization strategies for hepatitis B in different endemic areas in China

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World journal of Gastroenterology 2000年第3期6卷 392-394页

作者： Li H Wang L Wang SS Gong j zeng Xj Li RC Nong y Huang yK Chen XR Huang ZN CAMS & PUMC Inst Basic Med Sci Dept Epidemiol Beijing 100005 Peoples R China

INTRODUCTION At present hepatitis B vaccine immunization is an unique effective measure for controlling hepatitis *** is important o determine optimal immunization

关键词： hepatitis B vaccine immunization strategy cost-benefit analysis china

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Effect of dissolved oxygen on electrochemical corrosion behavior of 2205 duplex stainless steel in hot concentrated seawater

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journal of Materials Science & Technology 2021年第7期66卷 177-185页

作者： Hongtao zeng yong yang Minhang zeng Moucheng Li Institute of Materials School of Materials Science and EngineeringShanghai UniversityShanghai 200072China

The corrosion behavior of 2205 duplex stainless steel was investigated in hot concentrated seawater with different dissolved oxygen(DO) concentration by electrochemical measurement techniques and surface analysis methods. DO obviously enhances the cathodic reaction process, the formation of passive film and polarization resistance. With increasing the DO concentration from 0.34 to 3.06 mg L^(-1), the relative contents of Fe_(2)O_(3) and Cr_(2)O_(3) and the Cr-enrichment gradually enlarge in the passive film. The higher DO concentrations result in lower defect densities and thicker of space charge layers in the passive films,whichmayeffectively inhibit the intrusion of aggressive chloride ions. The increment inDOconcentration clearly increases the pitting potential, but decreases the repassivation potential. It may weaken both the occurrence and repassviation tendencies of stable pitting corrosion.

关键词： Dissolved oxygen Pitting corrosion 2205 duplex stainless steel Hot concentrated seawater Passivation

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Comparative TEM investigation on the precipitation behaviors in Cu-15wt% Sn alloy

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Rare Metals 2013年第2期32卷 139-143页

作者： zeng-jie Wang Konno j. Toyohiko Chao-Li Ma School of Materials Science and Engineering Beijing University of Aeronautics and Astronautics Institute for Materials Research Tohoku University

The decomposition and precipitation behaviors of a quenched Cu-15wt%Sn alloy as a function of aging temperature were investigated using transmission electron microscopy （TEM）. Focused ion beam （FIB） was employed to assist TEM specimen preparation. At 300 ℃, the decomposition of the supersaturated phase occurred at grain boundaries, displaying a cellular morphology. The lamellae were found with and phases, rather than with the equilibrium e and phases. The and phases exhibit a welldefined orientation relationship （OR） as On the other hand, at 320 ℃, only incipient lamellar structures of several micron meters were observed, which were composed of the 6 and phases. At the same time, abundant intragranular precipitation of the e phase in the form of platelets was observed, and OR as （lil）j/ （001）, [110] j/[100] exists between e phase and the ct phase. These contrasting precipitation behaviors are discussed from the viewpoint of crystallographic coherency of these phases.

关键词： Cu-Sn alloy Precipitation behaviorsFocused ion beam (FIB) TEM Crystallography

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Comparative Study on Different Methods for Prediction of Thermal Insulation Performance of Thermal Barrier Coating Used on Turbine Blades

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journal of Thermal Science 2024年第1期33卷 172-189页

作者： ZHANG Zhixin zeng Wu ZHANG Xiaodong zeng yuntao Advanced Gas Turbine Laboratory Institute of Engineering ThermophysicsChinese Academy of SciencesBeijing 100190China Key Laboratory of Advanced Energy and Power Institute of Engineering ThermophysicsChinese Academy of SciencesBeijing 100190China Innovation Academy for Light-duty Gas Turbine Chinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China

As turbine inlet temperature gets higher and higher,thermal barrier coating(TBC) is more and more widely used in turbine *** turbine blades with TBC,it is of great significance to evaluate the temperature distribution of its substrate metal quickly and accurately,especially during the design *** different degrees of simplification such as whether to consider the change of the geometric size of the fluid domain by TBC and whether to consider the planar heat conduction in TBC,three different methods used in conjugate heat transfer(CHT) simulation to model the TBC of the turbine blades have been developed and widely used by ***,little research has been conducted to investigate the influence of the three methods on the temperature distribution of turbine *** fill this gap,three geometric models were *** are a solid conduction model with a substrate metal layer and a TBC layer,a transonic turbine vane with internal cooling and TBC,and a plate cylindrical film hole cooling model with *** methods were used in these geometric models and their differences were carefully analyzed and *** result shows that for the conduction model used in this paper,with the same TBC surface temperature distribution,the difference between the three methods is very small and can be *** a transonic turbine vane with internal cooling,regarding the local maximum temperature of the substrate-TBC interface,the largest difference between the method in which TBC is considered as a thermal resistance or a virtual layer of cells and the method in which three-dimensional heat conduction equation of TBC is solved occurs at the trailing *** difference near the leading edge is below *** employed to the film cooling model,the difference of the laterally averaged temperature of the substrate-TBC interface can be 8 K which is mainly due to the change of the length to diameter ratio of the film cooling hole by *** the substrate

关键词： turbine blade thermal barrier coating conjugate heat transfer film cooling hole

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沥青路面裂缝高聚物注浆效果试验评价研究

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山西建筑 2025年第2期51卷 129-132页

作者：祁敏曾辉江苏路通装配科技有限公司江苏宜兴214200 江苏众智交通创新产业研究院有限公司江苏南京211899

非开挖式注浆技术采用高聚物双组分材料注浆,能有效填充沥青路面裂缝处半刚性基层和底基层层间脱空,排出结构层水分,密封裂缝,达到补强路面结构层效果。为了评价注浆技术应用效果,通过施工过程注浆孔检测、注浆前后探地雷达图谱测试、... 详细信息

非开挖式注浆技术采用高聚物双组分材料注浆,能有效填充沥青路面裂缝处半刚性基层和底基层层间脱空,排出结构层水分,密封裂缝,达到补强路面结构层效果。为了评价注浆技术应用效果,通过施工过程注浆孔检测、注浆前后探地雷达图谱测试、弯沉测试以及取芯等方式来评判,结果显示注浆后裂缝处弯沉能降低20%,两侧弯沉差明显减小,三维探地雷达检测显示裂缝注浆后灰度图内部未出现异常信号,无振幅加强现象,证明裂缝处浆液被填充。

关键词：非开挖注浆高聚物半刚性基层三维探地雷达横向裂缝

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Revealing active species of CePO_(4)catalyst for selective catalytic reduction of NO_(x)with NH_(3)

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journal of Rare Earths 2022年第8期40卷 1232-1237页

作者： yiqing zeng Shule Zhang School of Chemical Engineering Nanjing University of Science and TechnologyNanjing 210094China

Revealing the active species of the catalyst is conducive to the design of more efficient ***,we tried to demonstrate the roles of amorphous and crystalline structures on CePO_(4)catalyst during selective catalytic reduction(SCR)of NO_(x)by NH_(3).Higher calcination temperature promotes the transfer of amorphous structure to crystalline structure on the surface of CePO_(4).Both amorphous and crystalline CePO_(4)species on CePO-X samples can provide acid sites for NH_(3)adsorption,but the former can provide more acid *** superior redox property of surface amorphous CePO_(4)species contributes to its high NH_(3)-SCR activity at low temperature,but it also leads to the decrease of high temperature(>350℃)NH_(3)-SCR activity due to the oxidation of NH_(3).In contrast,crystalline CePO_(4)species shows high activity only at high temperature because of its poor redox *** re,it can be inferred that amo rphous and crystalline structures on CePO_(4)catalyst can be the efficient active species of NH_(3)-SCR at low and high temperature,respectively.

关键词： CePO_(4)catalyst Active phase Calcination temperature NH_(3)-SCR Rare earths

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Systems Theory-Driven Framework for AI Integration into the Holistic Material Basis Research of Traditional Chinese Medicine

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Engineering 2024年第9期40卷 28-50页

作者： jingqi zeng Xiaobin jia School of Traditional Chinese Pharmacy China Pharmaceutical UniversityNanjing 211198China State Key Laboratory of Natural Medicines China Pharmaceutical UniversityNanjing 210009China

This paper introduces a systems theory-driven framework to integration artificial intelligence(AI)into traditional Chinese medicine(TCM)research,enhancing the understanding of TCM’s holistic material basis while adhering to evidence-based *** the System Function Decoding Model(SFDM),the research progresses through define,quantify,infer,and validate phases to systematically explore TCM’s material *** employs a dual analytical approach that combines top-down,systems theory-guided perspectives with bottom-up,elements-structure-function methodologies,provides comprehensive insights into TCM’s holistic material ***,the research examines AI’s role in quantitative assessment and predictive analysis of TCM’s material components,proposing two specific AIdriven technical *** interdisciplinary effort underscores AI’s potential to enhance our understanding of TCM’s holistic material basis and establishes a foundation for future research at the intersection of traditional wisdom and modern technology.

关键词： Artificial intelligence Systems theory Traditional Chinese medicine Material basis Bottom-up

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基于卡尔加里-剑桥指南的沙龙培训模式提升全科规培医师医患沟通技能的对照研究

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中国全科医学 2025年第1期28卷 71-76页

作者：彭涛邹川曾欣张焱沈静四川省成都市第五人民医院全科医学科 611130

背景医患沟通技能是全科医生的核心岗位胜任力之一,高水平的医患沟通能力是创建和谐医患关系的基石,有助于提高患者就医获得感和满意度。而我国全科医生沟通能力普遍偏低,有待探索出一种适应我国国情、满足我国全科医生沟通需求的医患... 详细信息

背景医患沟通技能是全科医生的核心岗位胜任力之一,高水平的医患沟通能力是创建和谐医患关系的基石,有助于提高患者就医获得感和满意度。而我国全科医生沟通能力普遍偏低,有待探索出一种适应我国国情、满足我国全科医生沟通需求的医患沟通培训模式来提高其医患沟通能力。目的探索基于卡尔加里-剑桥指南的沙龙培训模式在全科规培医师医患沟通技能培训中的应用效果,为构建适合我国国情的医患沟通培训体系提供参考依据。方法选取成都市第五人民医院2019—2020年度全科规培医师40名作为研究对象,按照随机数字表法分为沙龙组和对照组,每组20名,其中沙龙组使用基于卡尔加里-剑桥指南的沙龙培训模式进行医患沟通培训,对照组设置为空白对照,培训前、培训后1周分别对两组学员采用标准化病人(SP)模式进行接诊,使用医患沟通评价量表(SEGUE量表)进行现场观察评分,比较两组学员的医患沟通培训效果。结果最终纳入28名,其中沙龙组15名,对照组13名,培训后沙龙组规培医师SEGUE量表评分从(11.80±4.36)分提高至(18.07±4.11)分,对照组规培医师SEGUE量表评分从(12.15±4.63)分提高至(14.46±3.71)分。沙龙组培训后的SEGUE量表评分与培训前的比较,差异有统计学意义(t=3.250,P<0.001);对照组培训后的SEGUE量表评分与培训前比较,差异无统计学意义(t=2.582,P=0.624);培训后对SEGUE量表中的25个项目进行分析,沙龙组与对照组SEGUE量表评分比较,差异有统计学意义(P<0.05)。沙龙组以下5个项目结果优于对照组,准备阶段中的“建立个人信任关系”(93.3%比7.7%)、“保护患者的隐私/尊重患者选择权”(53.3%比15.4%);理解患者阶段中的“认同患者为疾病所付出的努力、改变及其遇到的困难”(33.3%比23.1%)、“表达关心,使患者感到温暖/树立信心”(100.0%比69.2%);结束问诊阶段中的“询问患者是否还有其他的问题需要探讨”(66.7%比23.1%)。结论基于卡尔加里-剑桥指南的沙龙培训模式对全科规培医师进行医患沟通技能培训可增强学员主动参加培训的兴趣和积极性,对于医患沟通能力的提升具有较好的培训效果,值得借鉴和推广。

关键词：全科医学全科医师规范化培训医患沟通沟通培训卡尔加里-剑桥指南

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