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Sulfur vacancies and heterogeneous interfaces promote high performance sodium storage of bimetallic chalcogenide hollow nanospheres

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Journal of Energy Chemistry 2024年第8期95卷 596-610,I0013页

作者： Shiyue cao Xiaoting Xu Qiming Liu Huijuan Zhu Ting Hu Key Laboratory of Artificial Micro-and Nano-structures of Ministry of Education School of Physics and TechnologyWuhan UniversityWuhan 430072HubeiChina

Transition metal sulfides have high theoretical capacities and are considered as potential anode materials for sodium-ion ***,due to low inherent conductivity and significant volume expansion,the electrochemical performance is greatly *** this study,a nickel/manganese sulfide material(Ni_(0.96)S_(x)/MnS_(y)-NC)with adjustable sulfur vacancies and heterogeneous hollow spheres was prepared using a simple *** introduction of a concentration-adjustable sulfur vacancy enables the generation of a heterogeneous interface between bimetallic sulfide and sulfur *** interface collectively creates an internal electric field,improving the mobility of electrons and ions,increasing the number of electrochemically active sites,and further optimizing the performance of Na~+*** direction of electron flow is confirmed by Density functional theory(DFT)*** hollow nano-spherical material provides a buffer for expansion,facilitating rapid transfer *** innovative discovery involves the interaction between the ether-based electrolyte and copper foil,leading to the formation of Cu_9S_5,which grafts the active material and copper current collector,reinforcing mechanical *** results in a new heterostructure of Cu_9S_5 with Ni_(0.96)S_(x)/MnS_(y),contributing to the stabilization of structural integrity for long-cycle ***,Ni_(0.96)S_(x)/MnS_(y)-NC exhibits excellent electrochemical properties following our modification *** stability performance,Ni0_(.96)S_(x)/MnS_(y)-NC demonstrates an average decay rate of 0.00944%after 10,000 cycles at an extremely high current density of 10000 mA g^(-1),A full cell with a high capacity of 304.2 mA h g^(-1)was also successfully assembled by using Na_(3)V_(2)(PO_(4))_(3)/C as the *** study explores a novel strategy for interface/vacancy co-modification in the fabrication of high-performance sodium-ion batteries electrode.

关键词： Sulfur vacancies Heterogeneous interface Interactions Sodium ion batteries

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Model-based offline reinforcement learning framework for optimizing tunnel boring machine operation

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Underground Space 2024年第6期19卷 47-71页

作者： Yupeng cao Wei Luo Yadong Xue Weiren Lin Feng Zhang Department of Urban Management Kyoto UniversityKyoto 615-8540Japan Department of Geotechnical Engineering College of Civil EngineeringTongji UniversityShanghai 200092China Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education Tongji UniversityShanghai 200092China

Research on automation and intelligent operation of tunnel boring machine(TBM)is receiving more and more attention,benefiting from the increasing construction ***,most studies on TBM operations optimization were trained by the labels of human drivers’decisions,which were subjective and *** a result,the control parameters suggested by these models could hardly surpass the performance of a human driver,even the possibility of subjective incorrect *** that the geomechanical feedback to TBM under drivers’actions is objective,in this paper,a transformer-based model called the geological response for tunnel boring machine(GRTBM),is proposed to learn the relationship between operation-adjust and TBM monitoring ***,with the model-based offline reinforcement learning,this paper provided a novel approach to optimizing the TBM excavation *** decision processes,recorded in the Yin-song TBM project for a waterway tunnel in Jilin Province of China,were used for the validation of the *** adopting an implicit perception of geological conditions in the GRTBM model,the suggested method achieved the desired state within a single action,greatly outperformed the practical adjustments where 500 s were taken,revealing the fact that the proposed model has the potential to surpass the capability of human beings.

关键词： TBM Reinforcement learning Transformer Data mining

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Hydrogen bond-bridged phosphorene flexible film for photodynamic inhibiting Staphylococcus aureus

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Nano Research 2024年第6期17卷 5461-5468页

作者： Ziyu Wei Wenting Li Zhifang Liu Yongfa Zhu Huaqiang cao Department of Chemistry Engineering Research Center of Advanced Rare Earth MaterialsTsinghua UniversityBeijing 100084China

Antibiotics are a widely used and effective treatment for bacterial ***,bacteria can gradually evolve during infection,leading to developing resistance to antibiotics,which renders previously effective treatments *** a useful and convenient manner to treat bacterial infections is a great ***,we report a flexible hydrogen-bond-bridged phosphorene film with photodynamic antibacterial properties and excellent mechanical properties,fabricated from electrochemical exfoliation of black phosphorus(BP).When illuminated under 700 nm light,the hydrogen bond-bridged phosphorene flexible film is capable of converting ground-state triplet oxygen(O_(2))into excited-state singlet oxygen(^(1)O_(2)),destroying the structure of the membrane of Staphylococcus aureus,and eventually leading to bacterial death,via breaking the C=C of unsaturated fatty acids within the bacterial cell membrane after the reaction between^(1)O_(2)and unsaturated fatty acids,thus realizing a highly efficient antibacterial approach,which is supported by gas chromatography-mass spectrometry(GC-MS)*** work establishes an effective phototherapy platform for treating bacterial traumatic infections.

关键词： hydrogen bond-bridged phosphorene flexible film photodynamic Staphylococcus aureus

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Ligand-controlled electrochemiluminescence generation from CdSe/CdS/ZnS core/shell/shell quantum dots

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Nano Research 2024年第8期17卷 7776-7785页

作者： Hui Sun Zhiyuan cao Haiyan Qin Xiaogang Peng Bin Su Key Laboratory of Excited-State Materials of Zhejiang Province Department of ChemistryZhejiang UniversityHangzhou 310058China

The CdSe/CdS/ZnS core/shell/shell quantum dots(QDs)with strong exciton confinement have manifested themselves as competitive light-emitting materials in electrochemiluminescence(ECL).However,cathodic ECL generation by these QDs requires the injection of electron and hole from solid electrode and electrogenerated radicals(for example SO_(4)•^(−)),which is inevitably influenced by not only the inorganic structure of QDs but also the organic ligands on the *** this work we aimed at studying the impact of surface organic ligands on ECL performance of CdSe/CdS/ZnS *** changing the surface ligand from oleate to acetate,we phenomenologically observed the positive shift of ECL onset potential by ca.200 mV and the increase of ECL intensity by~100 times,suggesting that a short ligand is more favorable for ECL *** further comprehend the ligand effect,we measured the charge injection kinetics using potential-modulated,time-resolved photoluminescence,and thinlayer spectroelectrochemistry *** electron and hole injection into QDs were found to be accelerated by 2–20 times if shortening the ligand from oleate to acetate,confirming the significant impact of surface ligands on ECL performance of *** study is expected to provide guidance on how to design surface functionalized QDs for specific applications such as ECL immunodiagnosis,photocatalysis,and photovoltaics.

关键词： electrochemiluminescence quantum dots spectroelectrochemistry surface ligands charge injection charge transfer

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Low-Temperature Reforming Products Coupling Spark Plug on Gasoline Compression Ignition and Combustion Characteristics under Low-Load Condition

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Journal of Thermal Science 2024年第06期33卷 2386-2398页

作者： LIU Long LI Mingkun cao Qun WANG Yang WANG Xichang College of Power and Energy Engineering Harbin Engineering University China Helicopter Research and Development Institute

Gasoline compression combustion engine has the advantages of low emission and high efficiency,which is very promising for research,but it is difficult to apply under low-load *** has the characteristics of low reactivity;in the case of low thermodynamic state in the cylinder,the fire delay period of the fuel is longer,and the combustion phase is relatively lagging,which will lead to the increase of combustion cycle fluctuations,and even difficult to ignite and other adverse combustion *** order to improve the combustion stability of Gasoline Compression Ignition（GCI） engine under low-load condition and expand the limit of low-load combustion boundary,gasoline was reformed without catalyst under the boundary condition of reforming temperature of 488 K and reforming equivalent ratio of 8,and the concentration of reformed product was measured by a gas detection ***,the coupling of the reformed product and spark plug with GCI engine under low-load condition was investigated to analyze the effect on engine combustion and *** results showed that the initial combustion timing of the low-load GCI engine was late,but the addition of reformed products could advance the combustion phase,shorten the combustion duration,reduce single-cycle NOxemission,and improve the small-load operation characteristics of GCI *** spark plug ignition on the basis of adding reformed products could further improve the problem of combustion stability under low-load GCI *** the optimization effect became more obvious as the ignition position of the spark plug moves ***,spark plug ignition would cause local high temperature areas,resulting in an increase in NOxemission.

关键词： combustion emission gasoline low-temperature reform spark plug

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Preparation and performance improvement of a dual-component microcapsule self-healing system for silicone rubber insulating material

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High Voltage 2024年第2期9卷 453-465页

作者： Mingzhe Li Bin cao Fanghui Yin Hongwei Mei Liming Wang Engineering Laboratory of Power Equipment Reliability in Complicated Coastal Environments Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhenChina

A key factor limiting the development of silicone rubber insulating materials is their short service life in harsh operating *** establishment of a self-healing system is desired to improve the long-term operational performance of silicone rubber and effectively extend its service *** this study,poly(urea-formaldehyde)microcapsules containing polydimethylsiloxane healing agents are prepared and a dual-component microcapsule self-healing system for silicone rubber material is established and *** addition,the key factors affecting the self-healing performance(such as microcapsule size,rupture rate,and microcapsule doping amount)are *** is found that when SYLGARDTM 184 is used as the healing agent and matrix,with a 4:6(A:B)doping ratio of dual-component microcapsules and 20 phr doping amount,the self-healing efficiency is approximately 51%.Furthermore,increasing the microcapsule rupture rate and the interface strength between the healing agent and the matrix can effectively improve the self-healing *** relationships between key factors and self-healing performance are theoretically *** on the relationships,the microcapsule self-healing system can be appropriately *** results of this paper can provide a reference for the development of long-life silicone rubber insulating materials.

关键词： service rubber performance

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Set Stabilization of Large-Scale Stochastic Boolean Networks:A Distributed Control Strategy

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IEEE/CAA Journal of Automatica Sinica 2024年第3期11卷 806-808页

作者： Lin Lin Jinde cao Jianquan Lu Leszek Rutkowski the Department of Mechanical Engineering the University of Hong KongHong Kong China the School of Mathematics Southeast UniversityNanjing 210096China IEEE the School of Mathematics and the Frontiers Science Center for Mobile Information Communication and Security Southeast UniversityNanjing 210096China the School of Mathematics the Southeast UniversityNanjing 210096 the School of Electronic Information and Electrical Engineering Chengdu UniversityChengdu 610106China the Systems Research Institute of the Polish Academy of Sciences Warsaw 01-447 the Institute of Computer Science AGH University of Science and TechnologyKraków 30-059 the Information Technology Institute University of Social SciencesŁódź90-113Poland

Dear Editor,This letter deals with the set stabilization of stochastic Boolean control networks(SBCNs)by the pinning control strategy,which is to realize the full control for systems by imposing control inputs on a fr... 详细信息

关键词： Boolean stabilization letter

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Investigation on ignition characteristics of charring conductive polymers stimulated by electric energy

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Chinese Journal of Aeronautics 2024年第10期37卷 68-82页

作者： Zhiyuan ZHANG Hanyu DENG Wenhe LIAO Yantao PU Ping cao School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing 210094China Anhui Hongxing Electrical Polytron Technologies Inc. Hefei 231135China

The arc ignition based on charring conductive polymers has advantages of simple structure,low ignition power consumption and restart capacity,which bringing it broadly application prospect in hybrid propulsion system of micro/nano *** order to optimize the performance of arc ignition system,it is essential to have a deeper understanding of the ignition processes and ignition characteristics of charring conductive *** this paper,the thermal decomposition,electrical conductivity and thermal conductivity characteristics of charring conductive polymers with different conductive additives and matrix materials were comprehensively *** experimental investigation was conducted to determine the ignition behaviors and characteristics of different charring conductive polymers in a visual ignition *** experiment result showed that the ignition delay and external energy required for ignition are negatively correlated with voltage and initial temperature of the ignition grain,but positively correlated with oxidizer flow *** with charring conductive polymers containing multi-walled carbon nanotube,the ignition delay of charring conductive polymers with carbon black is significantly higher and the pyrolysis time is relatively ***,the ignition and initial flame propagation of charring conductive polymers with carbon black is more violent and more inclined to carbon particle ***,the restart characteristic of different charring conductive polymers was *** ignition delay and external energy required for ignition of different charring conductive polymers all reduced with the increasing of the number of ***,the ignition characteristics would not change a lot after repeated ignition.

关键词： Micro/nano satellite hybrid rocket motors Arc ignition Charring conductive polymer Ignition process Ignition characteristic Restart characteristic

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Theoretical prediction of ground settlements due to shield tunneling in multi-layered soils considering process parameters

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Underground Space 2024年第3期16卷 29-43页

作者： Liqiang cao Xiangsheng Chen Dechun Lu Dingli Zhang Dong Su Institute of Geotechnical and Underground Engineering Beijing University of TechnologyBeijing 100124China Underground Polis Academy Shenzhen UniversityShenzhen 518060China Key Laboratory of Urban Underground Engineering of Ministry of Education Beijing Jiaotong UniversityBeijing 100044China Key Laboratory for Resilient Infrastructures of Coastal Cities(MOE) Shenzhen UniversityShenzhen 518060China

This paper conducts a theoretical analysis of ground settlements due to shield tunneling in multi-layered soils which are usually encountered in urban *** proposed theoretical solution which is based on the general form of the Mindlin’s solution and Loganathan-Poulos formula can comprehensively consider the in-process tunneling parameters including:unbalanced face pressure,shield-soil friction,unbalanced tail grouting pressure,unbalanced secondary grouting pressure,overloading during tunneling and the ground volume *** method is verified by comparing with the field data from the Qinghuayuan Tunnel Project in terms of the ground surface settlements along the longitudinal and transverse *** to the local settlement or heave caused by the certain tunneling parameters,the ground surface settlements calculated using current solution along the longitudinal direction presents an irregular S-shaped curve instead of the traditional S-shaped *** also find that the effect of the unbalanced secondary grouting pressure and the overloading during tunneling cannot be ignored.

关键词： Tunneling Shield Ground settlements Theoretical analysis Urban areas Multi-layered soils Qinghuayuan Tunnel

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Mechanism investigation of A-site doping on modulating electronic band structure and photocatalytic performance towards CO_(2) reduction of LaFeO_(3) perovskite

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Nano Research 2024年第5期17卷 3733-3744页

作者： Chi cao Jinshuo Li Yang Hu Lin Zhang Wensheng Yang State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of ChemistryJilin UniversityChangchun 130012China Engineering Research Center for Nanomaterials Henan UniversityKaifeng 475004China

Three kinds of metal atoms with different valence electronic configurations,Bi(6s^(2)6p^(3)),Y(4d^(1)5s^(2)),and Ce(4f^(1)5d^(1)6s^(2)),were selected to investigate the effect of A-site(La^(3+))doping on electronic band structure,photoelectric properties,and photocatalytic performance of LaFeO_(3) *** was identified that the Bi doped LaFeO_(3) presented significantly improved photocatalytic activity towards the reduction of CO_(2),while the Y or Ce doped LaFeO_(3) displayed decreased photocatalytic activity compared to the pristine LaFeO_(3).It was revealed that doping of all the three metal atoms resulted in narrowed band gap and thus extended light absorption of LaFeO_(3) by lowering its conduction band minimum(CBM).The recombination rate and mobility of the charge carriers were represented by the relative effective mass(D)between holes and electrons for pristine and A-site doped LaFeO_(3).The doping of Bi resulted in increased D value,attributed to the Bi 6s electron states at the valence band maximum(VBM),and thus promoted separation and transfer of the charge carriers and improved photocatalytic activity of LaFeO_(3).In contrast,the doping of Ce resulted in significantly decreased D value,induced by the highly localized Ce 4f hole states at the CBM,and thus higher recombination rate of the charge carriers and decreased photocatalytic activity of LaFeO_(3).Furthermore,the Y doped LaFeO_(3) with a slightly decreased D value presented slightly increased recombination rate of the charge carriers and thus decreased photocatalytic *** a work provides new insights into the A-site doping in LaFeO_(3) perovskite,which should be helpful for optimizing the electronic band structure and activity of perovskite-type photocatalysts at atomic level.

关键词： A-site doping electronic band structure charge carrier behavior photocatalytic CO_(2)reduction perovskite-type photocatalytsts

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