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Photoinduced Bending and Curling Motions in Molecular Microcrystals of Naphthyl Meldrum’s Acid Derivative Based on E-to-Z Photoisomerization

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Chemical Research in Chinese Universities 2024年第5期40卷 907-913页

作者： ZHANG Xiaowen xu tianyi ZHANG Chenchen TONG Fei Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering Feringa Nobel Prize Scientist Joint Research CenterFrontiers Science Center for Materiobiology and Dynamic ChemistrySchool of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai200237P.R.China

Dynamic photoresponsive molecular crystals are promising candidates for making intelligent devices and materials in the ***,we synthesized a new photoactive molecule(E)-2,2-dimethyl-5-[3-(naphthalen-1-yl)allylide]-1,3-dioxane-4,6-dione[(E)-DNADD]that undergoes an E-to-Z photoisomerization in both liquid solution and solids when exposed to visible light(405 nm).Compared to the bulk crystals,the photoresponsive behavior in microcrystals was profoundly *** crystalline(E)-DNADD microplate crystals exhibit robust motions,including bending,curling,and coiling under light *** photoproduct conversion of the photochemical reaction in the microplate is no more than 20%,while the large bending curvature of the coiled illuminated samples was estimated at approximately 150–300 mm−1,comparable to some photoactive *** results indicate that shrinking crystal dimensions can boost the photoresponses in molecular crystals and provide a facile strategy for developing dynamic molecular crystals at the microscopic scale.

关键词： Photochemistry Molecular crystal E-to-Z photoisomerization Photoinduced motion

Engineering Cu_(2)O/Cu/N-C interface to induce directional migration of charge for driving photocatalytic homo-coupling of terminal alkynes

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Nano Research 2024年第8期17卷 6895-6902页

作者： Xiaoqin Yan tianyi xu Wenwen Zhan Yang Yang Yang Yu Jianjian Yi Xiaoxiao He Lei Yang Jianwei Zhao Liming Sun Xiguang Han Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials Department of ChemistrySchool of Chemistry&Materials ScienceJiangsu Normal UniversityXuzhou 221116China State Key Laboratory of Precision Spectroscopy East China Normal UniversityShanghai 200241China College of Environmental Science and Engineering Yangzhou UniversityYangzhou 225009China Shenzhen HUASUAN Technology Co. LtdShenzhen 518055China

The efficient utilization of visible light catalysts for organic reactions necessitates not only the effective separation of photogenerated electrons and holes to participate in the reaction,but also their ability to form key intermediates with reactant *** present study successfully synthesized a crusiform-like mesoporous structure of nitrogen-doped carbon-coated Cu_(2)O/Cu(Cu_(2)O/Cu/N-C)with a Cu_(2)O/dual electron acceptor interface using etched HKUST-1 as the precursor.A series of theoretical and experimental studies have demonstrated that the Cu_(2)O/Cu/N-C interface in the photocatalytic homo-coupling of terminal alkynes not only effectively enhances the separation of photogenerated electron−hole pairs,but also facilitates the formation of the key intermediate[Cu_(2)O/Cu/N-C]-phenylacetylide and promotes the rearrangement of its internal *** a result,the homo-coupling reaction can be effectively *** primary reason for the functional role of Cu_(2)O/Cu/N-C interface lies in the downward bending of energy band from Cu_(2)O to N-doped C layers,induced by the different work functions of Cu_(2)O,Cu and N-doped C ***,Cu_(2)O/Cu/N-C photocatalysts demonstrate exceptional photocatalytic activity in the homo-coupling reaction of terminal alkynes under blue-light irradiation and air *** present study presents a novel research methodology for the development of highly efficient visible light catalysts to facilitate organic reactions in future applications.

关键词： photocatalysis homo-coupling of terminal alkynes directional migration of charges heterojunction interface Cu_(2)O carbon coated

Research on Visual Operation and Guide System of Railway Four⁃electric Engineering Construction

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International Journal of Plant Engineering and Management 2024年第1期29卷 47-54页

作者： PANG Zhining xu tianyi WU xusheng JIN Wenxin Design&Research Institute China Railway Electrification Bureau(Group)Co.Ltd.Beijing 100166China

The visualization operation of railway four-electric engineering construction is an important part in railway′s construction,which plays a critical role in improving operation efficiency and it is smoothly finished on railway four-electric majors′professional *** to the typical high-speed railway project construction′s technology,these four-electric professional construction′s technology scheme are made into construction method′s video,according to the technology plan′s characteristics of professional,visualization and information,under the premise of improving the efficiency about professional project management and construction of the railway four-electric project,the critical technology problems of railway four-electric project are *** the same time,it also improves efficiency of BIM model′s construction,the cooperation management′s efficiency of construction process,and the ability of integrating model information.

关键词： four electric platform BIM railway process method

Atomic Dispersed Hetero‑Pairs for Enhanced Electrocatalytic CO_(2)Reduction

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Nano-Micro Letters 2024年第1期16卷 55-67页

作者： Zhaoyong Jin Meiqi Yang Yilong Dong Xingcheng Ma Ying Wang Jiandong Wu Jinchang Fan Dewen Wang Rongshen Xi Xiao Zhao tianyi xu Jingxiang Zhao Lei Zhang David J.Singh Weitao Zheng Xiaoqiang Cui State Key Laboratory of Automotive Simulation and Control School of Materials Science and EngineeringKey Laboratory of Automobile Materials of MOEElectron Microscopy CenterJilin UniversityChangchun 130012People’s Republic of China Key Laboratory of Photonic and Electronic Bandgap Materials Ministry of Educationand College of Chemistry and Chemical EngineeringHarbin Normal UniversityHarbin 150025People’s Republic of China College of Chemistry Jilin UniversityChangchun 130012People’s Republic of China Department of Physics and Astronomy and Department of Chemistry University of MissouriColumbiaMO 65211USA

Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic *** example,increasing the binding of the*COOH to the active site will generally increase the*CO desorption *** this relationship may be expected to dramatically improve the intrinsic activity of CO_(2)RR,but remains an unsolved ***,we addressed this conundrum by constructing a unique atomic dispersed hetero-pair consisting of Mo-Fe di-atoms anchored on N-doped carbon *** system shows an unprecedented CO_(2)RR intrinsic activity with TOF of 3336 h−1,high selectivity toward CO production,Faradaic efficiency of 95.96%at−0.60 V and excellent *** calculations show that the Mo-Fe diatomic sites increased the*COOH intermediate adsorption energy by bridging adsorption of*COOH *** the same time,d-d orbital coupling in the Mo-Fe di-atom results in electron delocalization and facilitates desorption of*CO ***,the undesirable correlation between these steps is *** work provides a promising approach,specifically the use of di-atoms,for breaking unfavorable relationships based on understanding of the catalytic mechanisms at the atomic scale.

关键词： CO_(2)reduction reaction Atomic dispersed catalyst Hetero-diatomic pair Ad-desorption energy Linear scaling relation

Plant genomic resources at National Genomics Data Center:assisting in data-driven breeding applications

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aBIOTECH 2024年第1期5卷 94-106页

作者： Dongmei Tian tianyi xu Hailong Kang Hong Luo Yanqing Wang Meili Chen Rujiao Li Lina Ma Zhonghuang Wang Lili Hao Bixia Tang Dong Zou Jingfa Xiao Wenming Zhao Yiming Bao Zhang Zhang Shuhui Song National Genomics Data Center Beijing Institute of GenomicsChinese Academy of Sciences&China National Center for BioinformationBeijing 100101China CAS Key Laboratory of Genome Sciences and Information Beijing Institute of GenomicsChinese Academy of Sciences&China National Center for BioinformationBeijing 100101China University of Chinese Academy of Sciences Beijing 100049China

Genomic data serve as an invaluable resource for unraveling the intricacies of the higher plant systems,including the constituent elements within and among *** various efforts in genomic data archiving,integrative analysis and value-added curation,the National Genomics Data Center(NGDC),which is a part of the China National Center for Bioinformation(CNCB),has successfully established and currently maintains a vast amount of database *** dedicated initiative of the NGDC facilitates a data-rich ecosystem that greatly strengthens and supports genomic research ***,we present a comprehensive overview of central repositories dedicated to archiving,presenting,and sharing plant omics data,introduce knowledgebases focused on variants or gene-based functional insights,highlight species-specific multiple omics database resources,and briefly review the online application *** intend that this review can be used as a guide map for plant researchers wishing to select effective data resources from the NGDC for their specific areas of study.

关键词： Plant-omics data Data repositories Data integration Knowledgebase Plant genomics

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太湖流域超标洪水应急调度效益评估

人民长江 2024年第4期55卷 64-71页

作者：徐天奕何爽太湖流域管理局水利发展研究中心上海200434

太湖流域水利工程众多、调度复杂,科学评估水利工程洪水调度减灾效益对流域制定工程方案、预案具有重要意义。采用太湖流域洪涝淹没仿真模型及太湖流域洪灾损失评估模型,可模拟不同情景下的流域河网水位、水量及洪水淹没情况,并根据洪... 详细信息

太湖流域水利工程众多、调度复杂,科学评估水利工程洪水调度减灾效益对流域制定工程方案、预案具有重要意义。采用太湖流域洪涝淹没仿真模型及太湖流域洪灾损失评估模型,可模拟不同情景下的流域河网水位、水量及洪水淹没情况,并根据洪水淹没特征分布,评估不同水工程调度后的洪灾损失。以太湖流域发生2020年超标洪水为背景,分别模拟了采用常规调度方案和应急调度方案两种情景下太湖流域洪涝灾害情况,评估了采用超标洪水应急调度方案在2020年洪水防御中发挥的减灾效益。结果表明:采用超标洪水应急调度方案在发挥水利工程减灾效益方面作用明显,尤其是可提高太浦河、望虞河两条太湖主要泄洪河道的排水能力,可降低太湖水位0.31 m,缩短高水位持续时间1~22 d,减少淹没面积180.1 km^(2),减少流域直接经济损失约16.2亿元。研究成果可为太湖流域洪水调度方案、预案制定工作提供参考。

关键词：超标洪水洪水调度减灾效益水文水动力学模型太湖流域

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徐特立《小学各科教授法》中的美育观探析与启示

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湖南第一师范学院学报 2024年第2期24卷 44-50页

作者：许天译梁堂华长沙师范学院徐特立研究中心湖南长沙410100

徐特立编写的《小学各科教授法》是一部翔实、系统的分科教授法,在我国近代教育史上开了先河。在这部著作中,美育观随处可见,主要可归纳为:以美养德,陶冶情操;以美触感,发现美好;以美增趣,愉悦身心。徐特立的这些美育观和当下的新美育... 详细信息

徐特立编写的《小学各科教授法》是一部翔实、系统的分科教授法,在我国近代教育史上开了先河。在这部著作中,美育观随处可见,主要可归纳为:以美养德,陶冶情操;以美触感,发现美好;以美增趣,愉悦身心。徐特立的这些美育观和当下的新美育理念异曲同工、一脉相承:突出以美育人,陶冶品格情操;注重审美体验,激发学习兴趣;加强美育实践,倡导学科融合。这些美育观,在一百多年后的今天仍然焕发着勃勃生机。

关键词：徐特立《小学各科教授法》美育观

Variability of PM_(2.5) and O_(3) concentrations and their driving forces over Chinese megacities during 2018-2020

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Journal of Environmental Sciences 2023年第2期124卷 1-10页

作者： tianyi xu Chengxin Zhang Cheng Liu Qihou Hu School of Environmental Science and Optoelectronic Technology University of Science and Technology of ChinaHefei 230026China Department of Precision Machinery and Precision Instrumentation University of Science and Technology of ChinaHefei 230026China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Key Laboratory of Environmental Optics and Technology Anhui Institute of Optics and Fine MechanicsChinese Academy of SciencesHefei 230031China Key Laboratory of Precision Scientific Instrumentation of Anhui Higher Education Institutes University of Science and Technology of ChinaHefei 230026China

Recently,air pollution especially fine particulate matters(PM_(2.5))and ozone(O_(3))has become a severe issue in *** this study,we first characterized the temporal trends of PM_(2.5) and O_(3) for Beijing,Guangzhou,Shanghai,andWuhan respectively during *** annual mean PM2.5 has decreased by 7.82%-33.92%,while O_(3) concentration showed insignificant variations by-6.77%-4.65%during *** generalized additive models(GAMs)were implemented to quantify the contribution of individual meteorological factors and their gas precursors on PM_(2.5) and O_(3).On a short-term perspective,GAMs modeling shows that the daily variability of PM_(2.5) concentration is largely related to the variation of precursor gases(R=0.67-0.90),while meteorological conditions mainly affect the daily variability of O_(3) concentration(R=0.65-0.80)during *** impact of COVID-19 lockdown on PM_(2.5) and O_(3) concentrations were also quantified by using *** the 2020 lockdown,PM_(2.5) decreased significantly for these megacities,yet the ozone concentration showed an increasing trend compared to *** GAMs analysis indicated that the contribution of precursor gases to PM_(2.5) and O_(3) changes is 3-8 times higher than that of meteorological *** general,GAMsmodeling on air quality is helpful to the understanding and control of PM2.5 and O3 pollution in China.

关键词： Air pollution PM_(2.5)and O_(3)trends Meteorology COVID-19 lockdown

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结合密度图回归与检测的密集计数研究

计算机科学与探索 2024年第1期18卷 127-137页

作者：高洁赵心馨于健徐天一潘丽杨珺喻梅李雪威天津大学智能与计算学部天津300350 天津大学天津市认知计算与应用重点实验室天津300350 天津大学天津市先进网络技术与应用重点实验室天津300350 天津大学未来技术学院天津300350

针对基于检测以及基于密度图两种主流的密集计数方法中,基于检测的方法召回率较低、基于密度图的方法缺失目标物体位置信息的问题,将检测任务与回归任务相结合后提出一种基于密度图回归的检测计数方法,可以实现对密集场景中目标物体的... 详细信息

针对基于检测以及基于密度图两种主流的密集计数方法中,基于检测的方法召回率较低、基于密度图的方法缺失目标物体位置信息的问题,将检测任务与回归任务相结合后提出一种基于密度图回归的检测计数方法,可以实现对密集场景中目标物体的计数以及定位,对两种方法进行优势互补,在提高召回率的同时,实现标定所有目标物体的位置信息。为提取出更加丰富的特征信息以面对复杂的数据场景,网络提出特征金字塔优化模块,该模块纵向融合底层高分辨特征与顶层抽象语义特征,横向融合同尺寸的特征,丰富目标物体的语义表达;考虑到密集计数场景中目标物体所占像素比例较低的问题,提出一种针对小目标的注意力机制,通过对输入图像构建掩膜以增强网络对目标物体的注意力,从而提高网络的检测敏感性。实验结果表明,所提出方法在保持准确率基本不变的情况下,大幅度提高了召回率,同时可准确标定目标物体位置,有效提供输入目标图像的计数以及定位信息,在工业以及生态等各种领域具有广泛的应用前景。

关键词：密集计数目标检测深度学习密度图回归特征金字塔