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Deep insight of unique phase transition behaviors and mechanism in Zr_(2)Co-H isotope system with ultra-low equilibrium pressure

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Rare Metals 2024年第1期43卷 212-224页

作者： Yang liu Pan-Pan Zhou Xue-Zhang Xiao Jia-Cheng Qi Jia-peng Bi Tiao Ying xing-Wen Feng Yan Shi Wen-Hua Luo li-Xin Chen State Key Laboratory of Silicon Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027China Institute of Materials China Academy of Engineering PhysicsMianyang 621907China Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province Hangzhou 310013China

Efficient capture,safe storage and release of tritium from the international thermonuclear experimental reactor(ITER) reaction exhaust gas is a perplexing problem,and the development of an efficient tritium-getter material with ultra-low hydrogenation equilibrium pressure is considered as a reliable *** this work,Zr_(2)Co alloy was selected as a tritium-getter material and prepared through induction levitation *** performance test results show that Zr_(2)Co exhibits an ultra-low hydrogenation equilibrium pressure of 3.22 × 10^(-6) Pa at 25℃ and excellent hydriding kinetics under a low hydrogen pressure of 0.005 ***,unique phase transition behaviors were presented in Zr_(2)Co-H ***,Zr_(2)CoH_(5) formed by Zr_(2)Co hydrogenated at room temperature is initially decomposed into ZrH_(2) and ZrCoH_(3) at200 ℃.With the temperature increasing to 350 ℃,ZrCoH_(3)is dehydrogenated to ZrCo,and then ZrCo further reacts with ZrH_(2) at 650 ℃ to reform Zr_(2)Co and *** the staged phase transition pathways during dehydrogenation,the decomposition of Zr_(2)CoH_(5) occurs preferentially,which is well accordance with both the smallest reaction energy barrier and the maximum reaction spontaneity that are determined respectively from kinetics activation energy and thermodynamics Gibbs free ***,first principles calculation results indicate that the stronger binding of hydrogen in interstitial environments of ZrCoH_(3)and ZrH_(2) triggers the hydrogen-stabilized phase transformation of Zr_(2)CoH_(5).The unique phase transition mechanisms in Zr_(2)Co-H system can shed light on the further exploration and regulation of analogous staged phase transition of hydrogen storage materials.

关键词： Zr_(2)Co alloy Tritium-getter materials Ultralow equilibrium hydrogen pressure Phase transition mechanism

Drug delivery with Mn-doped MoO_(2) for photothermalenhanced chemotherapy in fighting cancers

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Rare Metals 2024年第5期43卷 2230-2240页

作者： Ping Zhao Hai-Fa Zheng Ju peng xing-Long li Fazal Raziq Xiao-Jun liu Hao-Quan Yu Jin-Lu Tang Yi-Fan Kang Wen-Huan Huang School of Chemistry and Chemical Engineering Guangdong Pharmaceutical UniversityGuangzhou 510006China KAUST Catalysis Center King Abdullah University of Science and Technology23955-6900 ThuwalKingdom of Saudi Arabia Key Laboratory of Chemical Additives for China National light Industry College of Chemistry and Chemical EngineeringShaanxi University of Science and TechnologyXi'an 710021China

Although chemotherapy has been intensively applied in cancer treatments,its inadequate therapeutic efficacy and severe side effects are still under constant *** used as anti-tumor drug delivery system(DDS)have attracted tremendous attentions owing to their various intriguing ***,Mn-doped MoO_(2)nanoparticles coated with ZrO_(2)and capped with Bi_(2)O_(3)have been designed as a DDS,namely *** possesses good magnetic properties,great photothermal conversion ability,sensitive tumor microenvironment(TME)responsiveness,and good biocompatibility in hemocompatibility in ***,MMZB has been utilized to load the chemotherapeutic agent daunomycin(DNM)(MMZB@DNM)for chemo-photothermal combined ***@DNM demonstrates a more impressive anti-cancer effect than the individual photothermal or chemotherapy both in vitro and in ***,the analysis of tumor specimen sections and serum levels after the treatment indicates negligible side effects for MMZB@DNM in *** contribution provides a valuable concept in designing therapeutic agents for achieving significantly enhanced tumor treatments,which benefits from the synergistic combination of chemotherapy and photothermal therapy in one single nanoagent.

关键词： Mn-doped MoO_(2) Bi_(2)O_(3) Nanocarrier Photothermal Chemotherapy

Syntheses and properties of associative acrylamide copolymers containing short hydrophobic chains used in a friction reducer for slick-water fracturing

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Petroleum Science 2024年第3期21卷 1889-1901页

作者： Ya-xing Dai Xian-li Zhang Si-Yuan liu Feng-Run-Ze Zhang Yi-Xi Zhang Yu-Tong Sang Jing-Xi Zheng Zhao-Sheng liu peng Zhang College of Chemistry and Chemical Engineering Chongqing University of Science and TechnologyChongqing401331China College of Ecology and Environment Chongqing Resources and Environmental Protection of UniversityChongqing401331China China China Property Project Department of Dezhou Mining Property Service CenterShengli Oilfield Company of SinopecDezhou253000ShandongChina

Two allyldimethylalkyl quaternary ammonium salt(AQAS)monomers,N,N-dimethylallylphenylpropylammonium bromide(AQAS1)and N,N-dimethylallylnonylammonium bromide(AQAS2),were synthesized and used to prepare modified polyacrylamide *** new drag reducers were synthesized from acrylamide(AM),sodium acrylate(Na AA)and a cationic modified monomer(AQAS1 or AQAS2)via aqueous solution polymerization,and the copolymers were named P(AM/Na AA/AQAS1)and P(AM/Na AA/AQAS2),*** structures of the drag reduction agents were confirmed by IR and1H NMR *** molecular weight(Mw)of P(AM/Na AA/AQAS1)was 1.79×10^(6)g/*** the copolymer concentration was 1000 mg/L and the flow rate was 45 L/min,in fresh water the highest drag reduction rate was 75.8%,in 10,000 mg/L Na Cl solution the drag reduction rate decreased to 72.9%.The molecular weight of P(AM/Na AA/AQAS2)was 3.17×10^(6)g/*** the copolymer concentration was500 mg/L and the flow rate was 45 L/min,the drag reduction rate reached 75.2%,and in 10,000 mg/L Na Cl solution the drag reduction rate was 73.3%,decreased by approximately 1.9%.The drag reduction rate for partially hydrolyzed polyacrylamide(HPAM)was also investigated,and the results showed that the drag reduction rates for 500 and 1000 mg/L HPAM solutions were merely 43.2%and 49.0%in brine,*** with HPAM,both of the above copolymers presented better drag reduction capacities.

关键词： Shale gas Slick water Drag reducer Modified monomer Copolymerization

Associative cultural landscape approach to interpreting traditional ecological wisdom:A case of Inuit habitat

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Frontiers of Architectural Research 2024年第1期13卷 79-96页

作者： peng Zhang Shuai li Department of Landscape Architecture College of Architecture and Urban PlanningTongji UniversityShanghai 200092China

Global climate change and the accelerated melting of glaciers have raised concerns about the ability to manage ice-snow ***,human ancestors have mastered the ecological wisdom of working with ice-snow environments,but the phenomenon has not yet been articulated in cultural landscape methodologies that emphasize“nature-culture relevance”.The challenging living environment often compels indigenous people to form a strong bond with their surroundings,leading to the creation of long-term ecological wisdom through synergistic relationships with the *** ecological environment is conceptualized as a cognitive space in the form of the landscape,with which the aboriginal community norms and individual spirits continually *** interactions generate numerous non-material cultural evidences,such as culture,art,religion,and other ideological aspects of the *** evidences symbolize the intellectual outcome of the relationship between humans and the landscape,and they create the“spiritual relevance”through personification and *** aim of the study is to explore the traditional ecological wisdom of the Inuit people who live in the harsh Arctic,and analyze the Inuit’s interaction with the landscape through the lens of“associative cultural landscape”,and decode the survival experience that the Inuit have accumulated through their long-term synergy with the Arctic *** findings focus on the synergy between the Inuit and the ice-snow landscape,examining the knowledge and ecological wisdom that the Inuit acquire from the ice-snow *** goal is to develop a perspective of the ecological environment from the viewpoint of aboriginal people and establish a methodology,model,and framework for“associative cultural landscape”that incorporates ethnic non-material cultural *** the results,a total of nine models for interpreting traditional Inuit ecological wisdom are generated based on the“diamond

关键词： Landscape architecture Associative cultural landscape Nature-culture relevance Cultural landscape Traditional ecological wisdom Non-material cultural evidence Methodology Habitat living environment Ice-snow landscape

Reaction pathways and selectivity in the chemo-catalytic conversion of cellulose and its derivatives to ethylene glycol:A review

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Chinese Journal of Chemical Engineering 2024年第2期66卷 310-331页

作者： Yao li Yuchun Zhang Zhiyu li Huiyan Zhang peng Fu College of Agricultural Engineering and Food Science Shandong University of TechnologyZibo 255000China Key Laboratory of Energy Thermal Conversion and Control Ministry of EducationSchool of Energy and EnvironmentSoutheast UniversityNanjing 210096China

Biomass-to-ethylene glycol is an effective means to achieve high-value utilisation of cellulose but is hindered by low conversion efficiency and poor catalyst activity and *** and cellobiose are derivatives of cellulose conversion to ethylene glycol,and it is found that studying the reaction process of both can help to understand the reaction mechanism of *** is desirable to develop a reusable,highly active catalyst to convert cellulose into ethylene *** ideal catalyst might have one or more active sites described the conversion steps ***,we discuss the catalyst development of celluloseto-ethylene glycol,including tungsten,tin,lanthanide,and other transition metal catalysts,and special attention is given to the reaction mechanism and kinetics for preparing ethylene glycol from cellulose,and the economic advantages of biomass-to-ethylene glycol are briefly *** insights given in this review will facilitate further development of efficient catalysts,for addressing the global energy crisis and climate change related to the use of fossil fuels.

关键词： Ethylene glycol Cellulose Catalyst Retro-aldol condensation Hydrolysis Kinetics

Investigation on taste characteristics and sensory perception of soft-boiled chicken during oral processing based on electronic tongue and electronic nose

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Food Science and Human Wellness 2024年第1期13卷 313-326页

作者： Na Xu Xianming Zeng peng Wang xing Chen xinglian Xu Minyi Han College of Food Science and Technology Nanjing Agricultural UniversityNanjing 210095China National Center of Meat Quality and Safety Control Nanjing Agricultural UniversityNanjing 210000China State Key Laboratory of Food Science and Technology Jiangnan UniversityWuxi 214122China Wens Foodstuff Co. Ltd.Yunfu 527400China

The sensory perception of food is a dynamic process,which is closely related to the release of flavor substances during oral ***’s not only affected by the food material,but also subjected to the individual oral *** explore the oral processing characteristics of soft-boiled chicken,the sensory properties,texture,particle size,viscosity,characteristic values of electronic nose and tongue of different chicken samples were *** correlation analysis showed that the physical characteristics especially the cohesiveness,springiness,resilience of the sample determined oral processing *** addition of chicken skin played a role in lubrication during oral *** particle size of the bolus was heightened at the early stage,and the fluidity was enhanced in the end,which reduced the chewing time to the swallowing point and raised the aromatic compounds signal of electronic *** the effect of chicken skin on chicken thigh with relatively high fat content,was opposite in electronic nose,which had a certain masking effect on the perception of umami and sweet *** conclusion,fat played a critical role in chicken oral processing and chicken thigh had obvious advantages in comprehensive evaluation of soft-boiled chicken,which was more popular among people.

关键词： Oral processing Chicken Electronic tongue Electronic nose

Sustainable Intensification and Large-scale Operation of Cultivated Land Use at the Farmers’ Scale:A Case Study of Shandong Province,China

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Chinese Geographical Science 2024年第1期34卷 149-167页

作者： li li LYU Xiao ZHANG Anlu NIU Shandong peng Wenlong School of Public Administration Huazhong Agricultural UniversityWuhan430070China Department of Geography University of ZurichZurich8057Switzerland School of Humanities and Law Northeastern UniversityShenyang110169China School of Geography and Tourism Qufu Normal UniversityRizhao276800China

Sustainable intensification of cultivated land use(SICLU) and large-scale operations(LSO) are widely acknowledged strategies for enhancing agricultural ***,the existing literature has faced challenges in precisely defining SICLU and constructing comprehensive indicators,which has hindered the exploration of factors influencing LSO within the SICLU *** address this gap,we integrated self-efficacy theory into the design of an index framework for evaluating *** subsequently employed econometric models to analyze the significant factors that impact *** findings reveal that SICLU can be divided into four key dimensions:intensive management,efficient output,resource conservation,and ecological environment ***,it is crucial to incorporate belief-based cognitive factors into the index system,as farmers’ understanding of fertilizer and pesticide application significantly influences their willingness to engage in ***,we identify grain market turnover as the most influential factor in promoting LSO,with single-factor contribution rates reaching 70.9% for cultivated land transfer willingness and 62.5% for the total planting ***,unlike irrigation and agricultural machinery inputs,increased labor inputs correspond to larger planting areas for *** trend may be attributed to reduced labor availability because of rural labor migration,whereas the reduction in irrigation and agricultural input is contingent on innovations in production practices and the transfer of cultivated land management ***,SICLU dynamically influences LSO,with each index related to SICLU having an optimal range that fosters *** insights offer valuable guidance for policymakers,emphasizing farmers as their central focus,with the adjustment of input and output factors as a means to achieve LSO as the ultimate *** conclusion,we propose research avenues for further enriching the SICLU framework to ensur

关键词： sustainable intensification of cultivated land use(SICLU) self-efficacy status quo bias input and output Boosted Regression Tree willingness to transfer cultivated land cultivated land planting areas Shandong,China

OsFK1 encodes C-14 sterol reductase,which is involved in sterol biosynthesis and affects premature aging of leaves in rice

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The Crop Journal 2024年第4期12卷 1010-1021页

作者： Ping li Xia Zhang Wuzhong Yin Yang Shui Jie Zhang Nana Xu Dasong Bai Qingxiong Huang Yuanyuan li Pan Qi xing li Qianlong li Shihong Yang Guotao Yang Hong Chen peng Qin Yungao Hu Youlin peng Rice Research Institute School of Life Science and EngineeringSouthwest University of Science and TechnologyMianyang 621010SichuanChina Hainan Yazhou Bay Seed Laboratory Sanya 572025HainanChina Rice Research Institute State Key Laboratory of Crop Gene Exploration and Utilization in Southwest ChinaSichuan Agricultural UniversityChengdu 610061SichuanChina Yazhouwan National Laboratory Sanya 572704HainanChina

The enzyme C-14 sterol reductase is involved in biosynthesis of brassinosteroids(BR)and sterols,as well as plant ***1,a member of the sterol biosynthesis pathway located in the endoplasmic reticulum(ER),encodes C-14 sterol ***,there is little research on the function of C-14 sterol reductase in *** with the wild type,an osfk1 mutant showed dwarf phenotype and premature aging in the second leaf during the trefoil stage,and abnormal development of leaf veins during the tillering *** osfk1 mutant showed signs of aberrant PCD,as evidenced by TUNEL *** suggested that high ROS buildup caused DNA damage and ROS-mediated cell death in the *** osfk1 mutant also showed decreased chlorophyll content and aberrant chloroplast *** of the osfk1 mutant allele revealed a non-synonymous G to A mutation in the final intron,leading to early ***,we identified the OsFK1 allele,cloned it by Mutmap sequencing,and verified it by ***-MS/MS assays demonstrated that the osfk1 mutation caused lower phytosterol *** findings showed that the OsFK1 allele encoding C-14 sterol reductase is involved in phytosterol biosynthesis and mediates normal development of rice plants.

关键词： Leaf development ROS Phytosterol biosynthesis Rice

Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance

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Chinese Chemical Letters 2024年第8期35卷 433-436页

作者： peng Zhou Ziang Jiang Yang li peng Xiao Feixiang Wu Powder Metallurgy Research Institute School of Metallurgy and EnvironmentCentral South UniversityChangsha 410083China

Sulphur(S)-template method based on conventional slurry-casting method has been developed to pro-duce porous silicon(Si)*** facile fabrication technology is suitable for current production line and expected to be widely applied to various electrode materials under large volume change during ***,S particles as template agent are mixed with active material Si,carbon conductor and binder forming uniform *** casting and drying,the electrodes are immersed in carbon disul-fide solution to remove S particles rapidly,generating pores in-situ at the original position of S *** analysis shows that the pores inside electrodes are able to shorten lithium ion diffusion paths,reduce normal expansion rate and decrease formation of cracks in the Si electrode(2 mg_(Si)/cm^(2)),demonstrating a reversible capacity of 951 mAh/g at 0.5 A/g after 100 cycles(with a capacity retention of 99.5%)and a capacity of-826 mAh/g at 2 A/g.

关键词： Sulphur-template Porous electrodes Silicon anodes Low volume expansion lithium-ion batteries