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Enhancing electrochemical performances of small quinone toward lithium and sodium energy storage

Rare Metals 2022年第2期41卷 425-437页

作者： li-Min Zhu Guo-Chun Ding Qing Han Yong-Xia Miao xin li xin-li yang Lei Chen Gong-Ke Wang ling-ling Xie Xiao-Yu Cao School of Chemistry and Chemical Engineering Henan University of TechnologyZhengzhou 450001China Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou City Henan University of TechnologyZhengzhou 450001China College of Chemical and Printing-Dyeing Engineering Henan University of EngineeringZhengzhou 450007China School of Materials Science and Engineering Henan Normal UniversityXinxiang 453007China School of Environmental Engineering Henan University of TechnologyZhengzhou 450001China

Further application of organic quinone cathodes is restricted because they are inherent in poor conductivity and tend to dissolve in aprotic *** can work on the strong solubility of ***,the ortho-disodium salt of tetrahydroxyquinone(o-Na_(2)THBQ)was selected to promote the electrochemical properties of tetrahydroxyquinone(THBQ).Reduced dissolution of o-Na_(2)THBQ in electrolyte after salinization(replacement of two H with two Na)contributed to enhanced electrochemical *** sodium-ion batteries(SIBs)in ester-based electrolyte,o-Na2THBQ cathodes at 50 mA·g^(-1)exhibited a reversible discharge capacity of 107 mAh·g^(-1)after 200 ***,in ether-based electrolyte,reversible discharge capacities of 200.4,102.2,99.5 and 88 mAh·g^(-1)were obtained at 800,1600,3200 and 4800 mA·g^(-1)after 1000,2000,5000 and 8000 cycles,*** ultraviolet absorption spectra and ex situ dissolution experiments of THBQ and o-Na_(2)THBQ showed that o-Na_(2)THBQ hardly dissolved in ether-based *** lithium-ion batteries(liBs),graphene was selected to further enhance the conductivity of *** 50 mA·g^(-1),o-Na_(2)THBQ and o-Na_(2)THBQ/Gr cathodes exhibited reversible discharge capacities of 124 and 131.5 mAh·g^(-1)after 200 cycles in ester-based electrolyte,*** 50 mA·g^(-1),PTPAn/o-Na_(2)THBQ electrodes in an all-organic Na/li-ion battery showed reversible charge/discharge capacities of 51/50.3 and 33.8/33.1 mAh·g^(-1)after 200 cycles.

关键词： Na/li-ion batteries All-organic batteries Cathodes Organic materials Electrochemical performance

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NaV3O8/poly(3,4-ethylenedioxythiophene) composites as high-rate and long-lifespan cathode materials for reversible sodium storage

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Rare Metals 2020年第8期39卷 865-873页

作者： Guo-Chun Ding li-Min Zhu Qi yang ling-ling Xie Xiao-Yu Cao Yu-ling Wang Jian-Ping liu xin-li yang School of Chemistry and Chemical Engineering Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou CityHenan University of TechnologyZhengzhou 450001China School of Environmental Engineering Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou CityHenan University of TechnologyZhengzhou 450001China Department of Molecular Sciences Australian Research Council Centre of Excellence for Nanoscale BioPhotonicsFaculty of Science and EngineeringMacquarie UniversitySydneyNSW 2109Australia

Sodium-ion batteries have received a surge of interests for the alternatives to lithium-ion batteries due to their abundant reserves and low *** quest of reliable and high-performance cathode materials is crucial to future Na storage ***,poly(3,4-ethylenedioxythiophene)(PEDOT)was successfully introduced to NaV3O8 via in situ oxidation polymerization,which can effectively enhance electron conductivity and ionic diffusion of NaV3O8 *** a result,these NaV3O8@-PEDOT composites exhibit a significantly improved electrochemical performance including cycle stability and rate *** particular,NaV3O8@20 wt%PEDOT composite demonstrates better dispersibility and lower charge transfer resistance compared with bare NaV3O8,which delivers the first discharge capacity of 142 mAh-g-1and holds about 128.7 mAh·g-1 after 300 cycles at a current density of 120 mA·*** at a high current density of 300 mA·g-1,a high reversible capacity of 99.6 mAh·g-1 is *** these consequences suggest that NaV3O8@20 wt%PEDOT composite may be a promising candidate to serve as a high-rate and long-lifespan cathode material for sodium-ion batteries.

关键词： Sodium-ion batteries NaV3O8@PEDOT cathode composites In situ oxidation polymerization High-rate Long-lifespan

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X-ray Crystal Structure and Characterization of Tetra-vanadyl Capped Highly Reduced Polyoxometalate Anion [PMo_5~ⅥMo_7~ⅤO_(40)(V~ⅣO)_4]^(2-)

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Chemical Research in Chinese Universities 2006年第1期22卷 17-20页

作者： CHANG Song QIN Chao WANG xin-long li yang-guang WANG En-bo Institute of Polyoxometalate Chemistry Faculty of Chemistry Northeast Normal University Changchun 130024 P. R. China

A novel polyoxometalate [H3O][PMo5^ⅥMo7^ⅤO40 （V^ⅣO）4]·6Py （Py = pyridine） was synthesized and characterized by IR spectrometry, TG and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic space group（C2/m） with α=1.3680（3） nm, b=2.1740（4） nm, c=1.1630（2） nm, β= 118.62（3）°, V= 3. 0362 （10） nm^3, Z = 2, and Rt （wR2） = 0. 0772 （0. 2312）. The compound contains a highly reduced vanadylpoly-molybdophosphate polyoxometalate anion with a four-capped structure. The four {VO} units cap four opposite pits of the pseudo-Keggin core {PMo12O40}.

关键词： Highly reduced polyoxometalate anion Hydrothermal synthesis Four-capped Pseudo-Keggin core

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Primary sigmoid squamous cell carcinoma with liver metastasis:A case report

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World Journal of Clinical Cases 2022年第14期10卷 4608-4616页

作者： xin-yang li Gen Teng xing Zhao Cui-Min Zhu Department of Oncology The Affiliated Hospital of Chengde Medical UniversityChengde 067000Hebei ProvinceChina Department of Pathology The Affiliated Hospital of Chengde Medical UniversityChengde 067000Hebei ProvinceChina

BACKGROUND The pathological type of simple squamous carcinoma in colorectal malignancies is *** squamous cell carcinoma of the colorectum occurs most frequently in the *** clinicopathological features and biological behaviors of squamous colorectal carcinoma are unclear,and its prognosis may be worse than that of simple *** on squamous colorectal cancer are currently limited to case reports,and there is no standard treatment ***,more case reports are required to fully understand squamous colorectal *** SUMMARY We reported the case of a 56-year-old woman who complained of constipation for 2 *** revealed a sigmoid colon tumor,and the pathological result of colonoscopy was squamous *** completing the relevant assessment,the patient was clinically diagnosed with cT4aN0M0,stage IIB,and surgery was *** on postoperative pathological results,the patient was diagnosed with pT4bN0M0,stage *** cycles of adjuvant chemotherapy were administered after *** metastasis and abdominal wall mass were found more than 1 mo after the end of the last chemotherapy *** local treatment was not performed because the liver had multiple metastases,but I^(125) particle implantation of the abdominal wall mass was *** cycles of first-line chemotherapy were administered after the *** patient underwent 14 mo of treatment and eventually died from the *** Squamous carcinoma of sigmoid colon is a rare tumor with unclear *** clinicopathological diagnosis should be paid close attention.

关键词： Colon malignancies Sigmoid colon Squamous carcinoma liver metastases Case report

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Solvent effects on Pt-Ru/C catalyst for methanol electro-oxidation

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Journal of Natural Gas Chemistry 2009年第3期18卷 341-345页

作者： Jinwei Chen Chunping Jiang Hui Lu Lan Feng xin yang liangqiong li Ruilin Wang College of Materials Science and Engineering Sichuan University Chengdu 610065 Sichuan China

Alloying degree, particle size and the level of dispersion are the key structural parameters of Pt-Ru/C catalyst in fuel cells. Solvent（s） used in the preparation process can affect the particle size and alloying degree of the object substance, which lead to a great positive impact on its properties. In this work, three types of solvents and their mixtures were used in preparation of the Pt-Ru/C catalysts by chemical reduction of metal precursors with sodium borohydride at room temperature. The structure of the catalysts was characterized by X-ray diffraction （XRD） and Transmission electron microscopy （TEM）. The catalytic activity and stability for methanol electro-oxidation were studied by Cyclic Voltammetry （CV） and Chronoamperometry （CA）. Pt-Ru/C catalyst prepared in H2O or binary solvents of H2O and isopropanol had large particle size and low alloying degree leading to low catalytic activity and less stability in methanol electro-oxidation. When tetrahydrofuran was added to the above solvent systems, Pt-Ru/C catalyst prepared had smaller particle size and higher alloying degree which resulted in better catalytic activity, lower onset and peak potentials, compared with the above catalysts. Moreover, the catalyst prepared in ternary solvents of isopropanol, water and tetrahydrofuran had the smallest particle size, and the high alloying degree and the dispersion kept unchanged. Therefore, this kind of catalyst showed the highest catalytic activity and good stability for methanol electro-oxidation.

关键词： solvent effect fuel cell methanol electro-oxidation Pt-Ru/C catalyst tetrahydrofuran

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A Rendezvous Mission to the Second Earth Trojan Asteroid 2020 XL_5 with Low-Thrust Multi-Gravity Assist Techniques

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Research in Astronomy and Astrophysics 2024年第1期24卷 245-264页

作者： Shi-Hai yang Bo Xu xin li School of Aeronautics and Astronautics Sun Yat-sen UniversityShenzhen 518107China

As the second of Earth's Trojan asteroids, 2020 XL_(5) is worthy of rendezvous and even sample return missions in many aspects. In this paper, a rendezvous mission to Earth's second Trojan asteroid 2020 XL_(5) is ***, due to its high inclination and large eccentricity, direct impulsive transfer requires large amounts of fuel consumption. To address this challenge, we explore the benefits of electric propulsion and multi-gravity assist techniques for interplanetary missions. These two techniques are integrated in this mission design. The design of a low-thrust gravity-assist(LTGA) trajectory in multi-body dynamics is thoroughly investigated,which is a complex process. A comprehensive framework including three steps is presented here for optimization of LTGA trajectories in multi-body dynamics. The rendezvous mission to 2020 XL_(5) is designed with this three-step approach. The most effective transfer sequence among the outcomes involves Earth–Venus–Earth–Venus-2020 XL_(5). Numerical results indicate that the combination of electric propulsion and multi-gravity assists can greatly reduce the fuel consumption, with fuel consumption of 9.03%, making it a highly favorable choice for this rendezvous mission.

关键词： minor planets asteroids:general celestial mechanics Planetary Systems

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Generalized Embedding Machines for Recommender Systems

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Machine Intelligence Research 2024年第3期21卷 571-584页

作者： Enneng yang xin xin li Shen Yudong Luo Guibing Guo Software College Northeastern UniversityShenyang110000China School of Computer Science and Technology Shandong UniversityQingdao266000China JD Explore Academy JD Explore AcademyBeijing100000China

Factorization machine (FM) is an effective model for feature-based recommendation that utilizes inner products to capture second-order feature interactions. However, one of the major drawbacks of FM is that it cannot capture complex high-order interaction signals. A common solution is to change the interaction function, such as stacking deep neural networks on the top level of FM. In this work, we propose an alternative approach to model high-order interaction signals at the embedding level, namely generalized embedding machine (GEM). The embedding used in GEM encodes not only the information from the feature itself but also the information from other correlated features. Under such a situation, the embedding becomes high-order. Then we can incorporate GEM with FM and even its advanced variants to perform feature interactions. More specifically, in this paper, we utilize graph convolution networks (GCN) to generate high-order embeddings. We integrate GEM with several FM-based models and conduct extensive experiments on two real-world datasets. The results demonstrate significant improvement of GEM over the corresponding baselines.

关键词： Feature interactions high-order interaction factorization machine(FM) recommender system graph neural network(GNN)

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High-temperature nodal ring semimetal in two-dimensional honeycomb-kagome Mn_(2)N_(3) lattice

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Chinese Physics B 2022年第12期31卷 477-483页

作者： xin-Ke liu xin-yang li Miao-Juan Ren Pei-Ji Wang Chang-Wen Zhang School of Physics and Technology University of JinanJinan 250022China

The search for two-dimensional(2D)nodal ring semimetallic materials is a current research hotspot in spintronics,and designing a 2D nodal ring(NR)material with high Curie temperature(TC)and strong robustness to spin-orbit coupling(SOC)is an even greater ***,based on the first-principles calculations and symmetry analysis,we predict that 2D Mn_(2)N_(3)is a nodal ring semimetal(NRSM)with three energy bands near the Fermi energy level consisting of electrons in the same spin *** electron-like energy band and two hole-like energy bands near the Fermi plane cross to form two NRs centered at the pointΓ.Symmetry analysis shows that the spin-polarized NR semimetal is robust to SOC due to the conservation of horizontal mirror ***-Carlo simulations further demonstrate that the TCof the 2D Mn_(2)N_(3)reaches 530 K,well above the room ***,the 2D Mn_(2)N_(3)remains an NRSM on h-BN *** results not only reveal a general framework for designing 2D NR materials,but also promote further research in the direction of multifunctional quantum devices for spintronics.

关键词： first-principles calculation semi-metal nodal ring Curie temperature

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Eliminating H_(2)O/HF and regulating interphase with bifunctional tolylene-2,4-diisocyanate(TDI)additive for long life li-ion battery

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Journal of Energy Chemistry 2024年第8期95卷 519-528,I0011页

作者： Xueyi Zeng Xiang Gao Peiqi Zhou Haijia li xin He Weizhen Fan Chaojun Fan Tianxiang yang Zhen Ma Xiaoyang Zhao Junmin Nan School of Chemistry South China Normal UniversityGuangzhou 510006GuangdongChina Guangzhou Tinci Materials Technology Co.Ltd. Guangzhou 510760GuangdongChina School of Environmental Engineering and Chemistry Luoyang Institute of Science and TechnologyLuoyang 471023HenanChina School of Geomatic and Environmental Engineering Henan Polytechnic InstituteNanyang 473000HenanChina

lithium-ion batteries(liBs)featuring a Ni-rich cathode exhibit increased specific capacity,but the establishment of a stable interphase through the implementation of a functional electrolyte strategy remains *** when the battery is operated under high temperature,the trace water present in the electrolyte will accelerate the hydrolysis of the electrolyte and the resulting HF will further erode the *** order to enhance the long-term cycling performance of graphite/liNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)liBs,herein,Tolylene-2,4-diisocyanate(TDI)additive containing lone-pair electrons is employed to formulate a novel bifunctional electrolyte aimed at eliminating H_(2)O/HF generated at elevated *** 1000 cycles at 25℃,the battery incorporating the TDI-containing electrolyte exhibits an impressive capacity retention of 94%at 1 *** contrast,the battery utilizing the blank electrolyte has a lower capacity retention of only 78%.Furthermore,after undergoing 550 cycles at 1 C under45℃,the inclusion of TDI results in a notable enhancement of capacity,increasing it from 68%to 80%.This indicates TDI has a favorable influence on the cycling performance of liBs,especially at elevated *** analysis of the film formation mechanism suggests that the lone pair of electrons of the isocyanate group in TDI play a crucial role in inhibiting the generation of H_(2)O and HF,which leads to the formation of a thin and dense *** existence of this interphase is thought to substantially enhance the cycling performance of the *** work not only improves the performance of graphite/NCM811 batteries at room temperature and high temperature by eliminating H_(2)O/HF but also presents a novel strategy for advancing functional electrolyte development.

关键词： Graphite/liNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)battery Tolylene-2 4-diisocyanate Long-cycling performance H_(2)O/HF eliminated additive

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li-ion Battery Failure Warning Methods for Energy-storage Systems

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Chinese Journal of Electrical Engineering 2024年第1期10卷 86-100页

作者： Peihao Wu Nawei Lyu Yuhang Song xin Jiang yang Jin School of Electrical and Information Engineering Zhengzhou UniversityZhengzhou 450001China

Energy-storage technologies based on lithium-ion batteries are advancing ***,the occurrence of thermal runaway in batteries under extreme operating conditions poses serious safety concerns and potentially leads to severe *** address the detection and early warning of battery thermal runaway faults,this study conducted a comprehensive review of recent advances in lithium battery fault monitoring and early warning in energy-storage systems from various physical *** focus was electrical,thermal,acoustic,and mechanical aspects,which provide effective insights for energy-storage system safety enhancement.

关键词： lithium-ion batteries energy-storage systems thermal runaway characteristic signals fault warning

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