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Journal of Iron and Steel Research International 2016年第5期23卷 434-441页

作者： Gui-ming YANG xiao-hui FAN Xu-ling CHEN xiao-xian huang Zong-ping LI School of Minerals Processing and Bioengineering Central South University

Grate-kiln-cooler has become a major process of producing iron ore pellets in China. Due to the diversity of the raw materials used and the multi-device multi-variable characteristics,this process still encounters with control problem. An attempt was proposed to deal with this issue. The three-device-integrated feature of the process was firstly analyzed to obtain control strategy,and then an intelligent control system using a combination of expert system approach and Takagi-Sugeno（ T-S） fuzzy model was developed. Expert system approach was used to diagnose and remedy the abnormal conditions,while T-S fuzzy model was used to stabilize the thermal state. In the construction of T-S fuzzy rules,antecedents were identified by fuzzy c-mean clustering algorithm incorporated with subtractive clustering algorithm,and consequent parameters were identified by recursive least square algorithm. The control system was applied in a Chinese pelletizing plant and the application results demonstrated its effectiveness of stabilizing the thermal states within three devices.

关键词： intelligent control grate-kiln-cooler expert system fuzzy model iron ore pellet

Optimization of Cooling Process of Iron Ore Pellets Based on Mathematical Model and Data Mining

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Journal of Iron and Steel Research International 2015年第11期22卷 1002-1008页

作者： Gui-ming YANG xiao-hui FAN Xu-ling CHEN xiao-xian huang Xi LI School of Minerals Processing and Bioengineering Central South University

Cooling process of iron ore pellets in a circular cooler has great impacts on the pellet quality and systematic energy exploitation. However, multi-variables and non-visualization of this gray system is unfavorable to efficient production. Thus, the cooling process of iron ore pellets was optimized using mathematical model and data mining techniques. A mathematical model was established and validated by steady-state production data, and the results show that the calculated values coincide very well with the measured values. Based on the proposed model, effects of important process parameters on gas-pellet temperature profiles within the circular cooler were analyzed to better understand the entire cooling process. Two data mining techniques—Association Rules Induction and Clustering were also applied on the steady-state production data to obtain expertise operating rules and optimized targets. Finally, an optimized control strategy for the circular cooler was proposed and an operation guidance system was developed. The system could realize the visualization of thermal process at steady state and provide operation guidance to optimize the circular cooler.

关键词： iron ore pellet circular cooler model data mining optimization

Prediction of suitable water content in granulation of sintering mixture based on Litster's model

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Journal of Iron and Steel Research International 2024年第3期31卷 552-560页

作者： Fang-lei Dai xiao-hui Fan xiao-xian huang Xu-ling Chen Min Gan Zhi-yun Ji Zeng-qing Sun School of Minerals Processing and Bioengineering Central South UniversityChangsha 410083HunanChina

Suitable water content plays a decisive role in the granulation of sintering ***,a method was proposed to predict the suitable water content for effective granulation on the basis of Litster's granulation *** granulation effectiveness of a sintering mixture was predicted by the model,with the allowance error of±10%.The effects of the water absorption properties,particle size composition and content of adhesive particles on the suitable water content were *** results showed that the allowable error of prediction was within±0.5%compared to the experimentally determined suitable water *** an increase in adhesive powder content of mixtures with higher water absorption,the suitable water content increased to achieve similar granulation ***,as the amount of concentrates increased,the suitable water content first increased and then remained *** influence of the water absorption characteristics of the adhesive particles on the suitable water content was less than that of their particle size composition in the mixture.

关键词： Adhesive particle Sintering mixture Granulation effectiveness Suitable water content

Emission characteristics and control technology of heavy metals during collaborative treatment of municipal solid waste incineration fly ash in iron ore sintering process

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Journal of Iron and Steel Research International 2024年第11期31卷 2655-2663页

作者： xiao-hui Fan Zhi-an Zhou Bin-bin huang Zhi-yun Ji Min Gan Zeng-qing Sun Xu-ling Chen xiao-xian huang Guo-jing Wang School of Minerals Processing and Bioengineering Central South UniversityChangsha410083HunanChina Hubei Provincial Key Laboratory of Regional Development and Environmental Response Department of Environmental EngineeringHubei UniversityWuhan430062HubeiChina

The municipal solid waste incineration fly ash (MSWI-FA) contains a large amount of heavy metals, and the process of iron ore sintering and treating fly ash needs to pay attention to the migration characteristics of heavy metals. The impact of the application of MSWI-FA in the sintering process on the emission law of heavy metals in the collaborative treatment process was studied, and corresponding control technologies were proposed. The results showed that the direct addition of water washing fly ash (WM-FA) powder resulted in varying degrees of increase in heavy metal elements in the sinter. As the amount of WM-FA added increases, the content of heavy metal elements correspondingly increases, and an appropriate amount of WM-FA added is 0.5%–1.0%. The migration mechanism of heavy metals during the sintering treatment of WM-FA was clarified. Heavy metals are mainly removed through direct and indirect chlorination reactions, and Cu and Cr can react with SiO_(2) and Fe_(2)O_(3) in the sintered material to solidify in the sinter. Corresponding control techniques have been proposed to reduce the heavy metal elements in WM-FA through the pre-treatment of WM-FA. When the WM-FA was fed in the middle and lower layers of the sintered material, the high temperature of the lower layer was utilized to promote the removal of heavy metals. The Ni element content has decreased from 130 to 90 mg kg^(−1), and the Cd removal rate has increased by 23%. The removal rates of Cd and Cr elements increase by 2.4 and 5.5 times, respectively. There is no significant change in sintering indexes.

关键词： Control technique Emission characteristics Heavy metal Iron ore sintering Municipal solid waste incineration fly ash

Migration behavior of solid fuel particles during granulation process and its influence on combustion property

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Journal of Iron and Steel Research International 2023年第11期30卷 2153-2162页

作者： Zhi-yun Ji Yi-fan Wang xiao-hui Fan Gai-ge Zhao Min Gan Le-yun Tang Yong Tu xiao-long Wang Hao-xiang Zheng Xu-ling Chen xiao-xian huang Zeng-qing Sun School of Minerals Processing and Bioengineering Central South UniversityChangsha410083HunanChina Hunan Valin xiangtan Iron and Steel Co. Ltd.Xiangtan411101HunanChina

Iron ore sintering process is the main CO_(2) emission source throughout the integrate steelworks,which primarily comes from the combustion of solid *** the combustion efficiency and reducing the solid fuel consumption are important ways to reduce the CO_(2) emission in the sintering *** the efficient combustion of fuel,the migration behavior and combustion characteristics of solid fuel in the granulation process were *** results indicated that during the granulation process,fuel particles with size less than 0.5 mm mainly migrated into the granules with grain size of 1-3,3-5 and 5-8 mm;fuel particles with size of 0.5^(-1)mm mainly migrated into granules of 1-3 mm;fuel particles with size of 1-3,3-5 and 5-8 mm mainly entered the granules with the same grain *** the increase in fuel particles grain size from-0.5 to+8 mm,the combustion efficiency exhibited a firstly-increasing and then decreasing tendency,while the NO_(x) exhibited a decreasing *** reason can be described that finer fuel particles(-1 mm)easily distributed in the outer layer of the granules,which combusted fiercely due to its larger specific surface area,leading to the development of incomplete combustion and the conversion of fuel nitrogen;the combustion efficiency of larger fuel particles was restricted by the inner diffusion of O_(2),which then contributed to the reduction of NO_(x) under the inadequate combustion atmosphere.

关键词： Iron ore sintering Granulation Solid fuel distribution Pollutant emission Combustion efficiency

Influence of oxygen-rich hot air composite gas medium on sintering performance and function mechanism

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Journal of Iron and Steel Research International 2024年第5期31卷 1071-1081页

作者： Min Gan Hao-xiang Zheng xiao-hui Fan Zhi-yun Ji Qiang Li Ming Wu Yi-fan Wang xiao-long Wang Yu-feng Wu Xu-ling Chen Zeng-qing Sun xiao-xian huang School of Minerals Processing and Bioengineering Central South UniversityChangsha410083HunanChina Shanxi Taigang Stainless Steel Co. Ltd.Taiyuan030003ShanxiChina

Hot air sintering technology is used to improve the quality and production efficiency of sintered ***,the current thick layer condition highlights the disadvantage of the low oxygen potential of the hot air sintering ***,it is considered to use oxygen enrichment sintering to improve the environment of hot air *** sintering,hot air sintering,and oxygen-rich hot air sintering were compared through sintering cup experiments,and the influence of hot air and oxygen-rich hot air on sintering indexes was *** air reduced the vertical sintering velocity,while improved the yield and tumbler ***-rich hot air sintering contributed to improving the vertical sintering velocity while ensuring the quality of sintered ore,thus comprehensively improving production *** the action of hot air,the highest temperature of the sintering layer increased and the high-temperature holding time was *** oxygen enrichment,the combustion efficiency of fuels in the upper layer of materials was promoted,which optimized heat distribution in the middle and lower layers of materials and increased the content of calcium ferrite in the sintered ore,thus strengthening the sintering process.

关键词： Iron ore sintering Hot air sintering Oxygen enrichment Function mechanism

Enhanced post-combustion CO2 capture and direct air capture by plasma surface functionalization of graphene adsorbent

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Journal of Energy Chemistry 2025年第1期100卷 653-664页

作者： Rahul Navik Eryu Wang xiao Ding huang Yunyi Yiyu Liu Jia Li Guangdong-Hong Kong Joint Laboratory for Carbon Neutrality Jiangmen Laboratory of Carbon and Science and Technology Guangzhou HKUST Fok Ying Tung Research Institute The Hong Kong University of Science and Technology (Guangzhou) Carbon Neutrality and Climate Change Thrust Society Hub The Hong Kong University of Science and Technology (Guangzhou) Stoddart Institute of Molecular Science Department of Chemistry Zhejiang University

Graphene has enormous potential to capture CO2due to its unique properties and ***,graphene-based adsorbents have drawbacks of lower CO2adsorption capacity and poor *** work demonstrates a one-step rapid and sustainable N2/H2plasma treatment process to prepare graphene-based sorbent material with enhanced CO2adsorption *** treatment directly enriches amine species,increases surface area,and improves textural *** CO2adsorption capacity increases from 1.6 to 3.3 mmol/g for capturing flue gas,and from 0.14 to 1.3 mmol/g for direct air capture （DAC）.Importantly,the electrothermal property of the plasma-modified aerogels has been significantly improved,resulting in faster heating rates and significantly reducing energy consumption compared to conventional external heating for regeneration of *** aerogels display improved selectivity of 42 and 87 after plasma modification for 5 and 10 min,*** plasma-treated aerogels display minimal loss between 17%and 19% in capacity after 40 adsorption/desorption cycles,rendering excellent *** N2/H2plasma treatment of adsorbent materials would lower energy expenses and prevent negative effects on the global economy caused by climate change.

关键词： Carbon neutrality CO 2 capture Climate change Plasma treatment Graphene aerogel

目标市场负向需求冲击影响企业跨国并购的机理与实证

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经济理论与经济管理 2017年第3期37卷 85-100页

作者：徐晓慧黄先海李杰浙江大学宁波理工学院商学院浙江大学经济学院暨南大学产业组织与规制研究所

本文对目标市场负向需求冲击对中国企业跨国并购的影响进行了理论和实证分析。研究发现:第一,目标市场负向需求冲击与跨国并购发生的概率呈正相关关系;第二,目标企业的选择要么是生产成本最高的企业,要么是生产成本最低的企业。最后,本... 详细信息

本文对目标市场负向需求冲击对中国企业跨国并购的影响进行了理论和实证分析。研究发现:第一,目标市场负向需求冲击与跨国并购发生的概率呈正相关关系;第二,目标企业的选择要么是生产成本最高的企业,要么是生产成本最低的企业。最后,本文依据核心结论提出政策建议。

关键词：跨国并购市场负向需求冲击潜在Ordered Probit模型

江苏沿海地区耕地利用转型及其生态系统服务价值变化响应

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自然资源学报 2017年第6期32卷 961-976页

作者：史洋洋吕晓黄贤金于淼曲阜师范大学地理与旅游学院山东日照276826 国土资源部海岸带开发与保护重点实验室南京210024 南京大学地理与海洋科学学院南京210023

论文以江苏沿海地区1990、2000和2010年3期土地利用空间数据为基础,在GIS、地学信息图谱理论和Costanza等生态系统服务价值测算方法的支持下合成时间序列表征下的耕地利用转型图谱、耕地利用转型模式图谱和生态系统服务价值图谱,据此揭... 详细信息

论文以江苏沿海地区1990、2000和2010年3期土地利用空间数据为基础,在GIS、地学信息图谱理论和Costanza等生态系统服务价值测算方法的支持下合成时间序列表征下的耕地利用转型图谱、耕地利用转型模式图谱和生态系统服务价值图谱,据此揭示江苏沿海地区耕地转型时空变化特征及其生态系统服务价值变化响应规律。结果表明:1)1990—2000年阶段耕地以建设用地、水域和林地占用为主,补充耕地来源除建设用地、水域和林地外,还包括了草地,耕地占用大于补充。空间差异以"耕地→建设用地"、"草地→耕地"最为明显,空间分离度低。2)2000—2010年阶段耕地占用的去向增加了未利用地,草地仍是主要的耕地补充来源。空间上以"耕地→建设用地"和"耕地→水域"图谱变化最为显著,空间分离度变大。3)1990—2010年耕地利用转型模式以后期变化最为显著。4)近20 a间,江苏沿海生态系统服务总价值由170.85×108元提升为182.23×108元,水域是提高生态系统服务价值最主要的贡献类型。耕地利用转型导致耕地的生态系统服务价值降低,"耕地→建设用地"是最主要的生态减值图谱类型。

关键词：耕地利用转型生态系统服务价值地学信息图谱江苏沿海地区

Synergistically enhanced ORR and HER performance on Co-N-C coupled in-situ generated PtCo intermetallic

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Journal of Energy Chemistry 2025年第1期100卷 721-729页

作者： Guanyu Luo Min Song Lulu An xiao huang Qian Zhang Chenhao Zhang Tao Shen Shuang Wang Deli Wang Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology) Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology

Integrating multi-scale sites in a composite catalyst is vital to realize efficient ***,a synergistic composite catalyst consisting of Co atomic sites and in-situ generated PtCo intermetallic compounds （IMCs）(o-PtCo@CoNC) is proposed through Co pre-anchoring and subsequent impregnation-reduction *** loading of Co atoms provides a chance for in-situ generating PtCo ordered intermetallic *** remaining Co single atoms and PtCo IMCs construct synergistic electrocatalytic *** from the ordered structure,synergistic effect of Pt Co IMCs and Co single atoms,o-PtCo@CoNC exhibits excellent electrocatalytic performance for oxygen reduction reaction （ORR） and hydrogen evolution reaction （HER） with mass activity of 1.21 A mgPt-1（at 0.9 V） and5.70 A mgPt-1（at an overpotential of 100 mV）,***,o-PtCo@CoNC delivers negligible loss of half-wave potential and overpotential during long-term stability test in acid solutions,with 13 mV decay after 50,000 potential cycles for ORR and a 2.7 mV decay after 20,000 potential cycles for *** integration strategy of single-atomic sites coupled IMCs paves the way for enhancing the activity and durability of Pt-based electrocatalysts.

关键词： Electrolytic reduction