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Frontiers in Energy 2024年第3期18卷 291-307页

作者： Hongxia LI Khaja WAHAB AHMED Mohamed A.ABDELSALAM Michael FOWLER xiao-yu WU Technology Innovation Institute Masdar CityAbu Dhabi 9639United Arab Emirates Department of Chemical Engineering University of WaterlooWaterlooON N2L 3G1Canada Department of Mechanical and Nuclear Engineering Khalifa University of Science and TechnologyAbu Dhabi 127788United Arab Emirates Department of Mechanical and Mechatronics Engineering University of WaterlooWaterlooON N2L 3G1Canada

Solar-driven hydrogen production from seawater attracts great interest for its emerging role in decarbonizing global energy consumption. Given the complexity of natural seawater content, photocatalytic vapor splitting offers a low-cost and safe solution, but with a very low solar-to-hydrogen conversion efficiency. With a focus on cutting-edge photothermal–photocatalytic device design and system integration, the recent research advances on vapor splitting from seawater, as well as industrial implementations in the past decades were reviewed. In addition, the design strategies of the key processes were reviewed, including vapor temperature and pressure control during solar thermal vapor generation from seawater, capillary-fed vaporization with salt repellent, and direct photocatalytic vapor splitting for hydrogen production. Moreover, the existing laboratory-scale and industrial-scale systems, and the integration principles and remaining challenges in the future seawater-to-hydrogen technology were discussed.

关键词： seawater hydrogen photocatalytic vapor splitting solar-driven

Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline

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Chinese Chemical Letters 2024年第4期35卷 99-105页

作者： Tao yu Vadim A.Soloshonok Zhekai xiao Hong Liu Jiang Wang State Key Laboratory of Drug Research Shanghai Institute of Materia MedicaChinese Academy of SciencesShanghai 201203China School of Pharmacy University of Chinese Academy of SciencesBeijing 100049China Department of Organic Chemistry Ⅰ Faculty of ChemistryUniversity of the Basque Country UPV/EHUSan Sebastian 20018Spain IKERBASQUE Basque Foundation for ScienceBilbao 48013Spain School of Pharmaceutical Science and Technology Hangzhou Institute for Advanced StudyUCASHangzhou 310024China Lingang Laboratory Shanghai 200031China

Schiff base metal complexes are of great importance in pharmaceutical science owing to their unique chemical properties, which enable them to exhibit diverse biological activities such as anti-bacterial,anti-oxidant, anti-inflammatory, and anti-tumor properties. Furthermore, Schiff base metal complexes can serve as reagents and catalysts in chemical reactions. This review aims to provide an overview of our recently published studies on Cu(Ⅱ) and Pd(Ⅱ) complexes derived from proline Schiff base ligands. We also discuss the potential applications of these metal complexes in the fields of antibacterial and chiral resolution.

关键词： Schiff bases Biological activity Tailor-made amino acids Asymmetric synthesis Chiral tridentate ligands Square-planar Cu(Ⅱ)-complexes Square-planar Pd(Ⅱ)-complexes

Acoustic characterization of hydrate formation and decomposition in clay-bearing sediments

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Petroleum Science 2024年第4期21卷 2830-2838页

作者： Yi-Jian Zhu xiao-Mei Yang Xing Huang Hao Li xiao-Hui Wang Yi-Fei Sun Peng xiao Chang-yu Sun Guang-Jin Chen State Key Laboratory of Heavy Oil Processing College of Chemical Engineering and Environment China University of Petroleum

Understanding the acoustic characteristics of hydrates in various sediments is crucial for hydrate resource detection and safe and efficient exploitation, as hydrate occurrence patterns vary greatly in different sediments. In this work, sediments with different bentonite contents, water saturations, and types were prepared to investigate the characteristics of P-wave velocity(reflecting the magnitude of hydrate saturation in the sediment) and amplitude(reflecting the degree of hydrate-sediment cementation) during hydrate formation and depressurization. During hydrate formation, the P-wave velocity and amplitude have similar trends. As clay content increases, the P-wave velocity increase rates quickened. On the other hand, the increased rate of P-wave velocity slows down with the increase of water saturation in the clay-bearing sediments. Comparing various types of sediment shows that the water absorption and swelling of bentonite reduce the pore space, speeding up the cementation of the hydrate with the sediment and increasing P-wave velocity at a faster rate. Correspondence between P-wave velocity and hydrate saturation is strongly related to sediment type, clay content, and water *** rapidly decreasing amplitude in the early stage of hydrate depressurization indicates that hydrate in clay-bearing sediments is weakly cemented to the sediments, which is prone to stratigraphic *** findings of this study offer guidance for hydrate resource assessments in clay-bearing sediments as well as geologic risk estimations during hydrate mining.

关键词： Gas hydrate Bentonite Illite P-wave velocity Amplitude

Simplified p-i-n Perovskite Solar Cells with a Multifunctional Polyfullerene Electron Transporter

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Chinese Journal of Polymer Science 2024年第8期42卷 1060-1066页

作者： Fei-Fei Wang Tian-xiao Liu Ze-Wei Cui Ling-yuan Wang yun-Jie Dou xiao-yu Shi Si-Wei Luo xiao-Dong Hu Zhi-Jun Ren Yang-Yang Liu yu Zhao Shang-Shang Chen State Key Laboratory of Coordination Chemistry MOE Key Laboratory of High Performance Polymer Materials&TechnologySchool of Chemistry and Chemical EngineeringNanjing UniversityNanjing 21003China

In prevailing p-i-n perovskite solar cells(PSCs),solution-processible fullerene molecules are widely used as electron-transporting layers(ETLs)but they typically suffer from poor uniformity and undesirable stability ***,a separate bathocuproine(BCP)layer is needed to block hole tran sfer,increasing fabrication complexity and ***,we address these limitations by develo ping a novel polymeric ETL(named PF BCP)synthesized by polymerizing C_(60)with *** innovative material achieves both efficient electron transport and hole blocking,while its excellent uniformity minimizes interface recombination and enhances ***,our blade-coated PSCs utilizing PFBCP achieve a high power conversion efficiency exceeding 22%and retain 91%of initial efficiency after 1200 h of light *** development not only paves the way for commercially viable PSCs but also opens avenues for future ETL design to realize even more efficient and stable PSCs.

关键词： Polyfullerene Perovskite solar cells Electron transporter Stability

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基于阵列基线旋转的多目标DOA估计算法

系统工程与电子技术 2014年第5期36卷 809-815页

作者：司伟建吴娜蓝晓宇邹岩哈尔滨工程大学信息与通信工程学院中国人民解放军91404部队

传统均匀圆阵波达方向(direction of arrival,DOA)估计算法要求天线数目多于目标数量,易受阵列的通道不一致性影响。针对此问题,引入阵列基线旋转这一思想对多目标进行测向。通过旋转两天线阵列基线,并以固定的时间延迟对阵元的接收数... 详细信息

传统均匀圆阵波达方向(direction of arrival,DOA)估计算法要求天线数目多于目标数量,易受阵列的通道不一致性影响。针对此问题,引入阵列基线旋转这一思想对多目标进行测向。通过旋转两天线阵列基线,并以固定的时间延迟对阵元的接收数据进行采样,相当于利用有限的两个阵元对目标进行多位置观测,增加了阵元的利用率,提高了DOA估计的测向精度。计算机仿真实验表明,该算法采用两阵元就可以实现多目标测向,其测向性能与基于均匀5元圆阵的传统多重信号分类算法相当,具有对多通道间相位不一致鲁棒性强的优点。

关键词：波达方向估计空间谱估计多重信号分类阵列旋转

Research and development of a 0.5-m-long helical superconducting undulator prototype

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NUCLEAR SCIENCE AND TECHNIQUES 2024年第10期35卷 1-10页

作者： Yang, Xiang-Chen yu, xiao-Wu Wei, Jun-Hao Zhang, Xiang-Zhen Chen, Zi-Lin Bian, xiao-Juan Li, He-Ting Feng, Guang-Yao Li, yu-Hui Univ Sci & Technol China Natl Synchrotron Radiat Lab Hefei 230029 Peoples R China Chinese Acad Sci Inst High Energy Phys Beijing 100049 Peoples R China Chinese Acad Sci Inst High Energy Phys China Spallat Neutron Source Dongguan 523000 Peoples R China Chinese Acad Sci Inst Plasma Phys ASIPP Hefei 230031 Peoples R China

The helical undulator is in high demand in synchrotron radiation facilities for circular polarization generation. Owing to the higher field strength provided by the superconducting undulator compared to the conventional permanent-magnet undulator, greater research efforts should be directed toward this area. The helical superconducting undulator holds great potential in synchrotron radiation facilities, especially in low-energy storage rings that seek circularly polarized radiation with the highest possible radiation flux. Following the successful development of planar superconducting undulators, the Institute of High Energy Physics conducted research and development for the helical superconducting undulator. A 0.5-m-long Delta-type superconducting undulator prototype was developed and tested. Detailed information on the design, fabrication, and cryogenic testing of the prototype is presented and discussed.

关键词： Helical Superconducting undulator Delta DESIGN

Robust Estimation of Average Treatment Effects with Observational Studies

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Wuhan University Journal of Natural Sciences 2024年第2期29卷 117-124页

作者： xiao Li yu Peichao Department of Physical Education Guilin University of Aerospace TechnologyGuilin 541004GuangxiChina School of Statistics and Mathematics Zhongnan University of Economics and LawWuhan 430073HubeiChina

Estimating treatment effects has always been one of the hot issues in empirical *** brings great challenges to estimating treatment effects because heterogeneity exists in the distribution of covariates between treated and controlled *** score methods have been widely used to adjust for heterogeneity in observational ***,the propensity score is usually unknown and needs to be *** this article,we propose a generalized single-index model to estimate the propensity score and use the propensity score residuals to reduce the estimation *** finite-sample performance of the proposed method is evaluated through simulation *** use the proposed method to evaluate the policy of"Sunshine Running"and find that the physical test scores of college students par-ticipating in the"Sunshine Running"can be improved by 3.72 points.

关键词： treatment effect propensity score generalized single-index model partial linear model

Developing and validating a predictive model of delivering large-forgestational-age infants among women with gestational diabetes mellitus

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World Journal of Diabetes 2024年第6期15卷 1242-1253页

作者： Yi-Tian Zhu lan-lan Xiang Ya-Jun Chen Tian-Ying Zhong Jun-Jun Wang yu Zeng Department of Clinical Laboratory Jinling Clinical Medical College of Nanjing Medical UniversityNanjing 210002Jiangsu ProvinceChina Department of Clinical Laboratory Women’s Hospital of Nanjing Medical UniversityNanjing Women and Children’s Healthcare HospitalNanjing 210003Jiangsu ProvinceChina

BACKGROUND The birth of large-for-gestational-age(LGA)infants is associated with many shortterm adverse pregnancy *** has been observed that the proportion of LGA infants born to pregnant women with gestational diabetes mellitus(GDM)is significantly higher than that born to healthy pregnant ***,traditional methods for the diagnosis of LGA have ***,this study aims to establish a predictive model that can effectively identify women with GDM who are at risk of delivering LGA *** To develop and validate a nomogram prediction model of delivering LGA infants among pregnant women with GDM,and provide strategies for the effective prevention and timely intervention of *** The multivariable prediction model was developed by carrying out the following ***,the variables that were associated with LGA risk in pregnant women with GDM were screened by univariate analyses,for which the P value waslanine transaminase-aspartate aminotransferase ratio and weight at 24 gestational *** nomogram’s prediction ability was supported by the area under the curve(0.703,0.709,and 0.699 f

关键词： Large-for-gestational-age Gestational diabetes mellitus Predictive model Nomogram Triglyceride-glucose index

Lactonization of dyes promoted by a coordination cage facilitates cavity-induced chromism as ion mobile detector

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Science China Chemistry 2024年第5期67卷 1554-1560页

作者： Liangliang Zhang yu Liang Zhifeng xiao yuxuan Meng Jinyi Huang Xi Lin Ji Li Hong-Cai Zhou yu Fang Strait Institute of Flexible Electronics(SIFE Future Technologies)Fujian Normal University and Strait Laboratory of Flexible Electronics(SLoFE)Fuzhou 350017China State Key Laboratory of Chemo/Bio-Sensing and Chemometrics College of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082China Department of Chemistry Texas A&M UniversityCollege StationTexas 77842-3012USA State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Frontiers Science Center for Flexible Electronics(FSCFE) MIIT Key Laboratory of Flexible Electronics(KLoFE)Northwestern Polytechnical UniversityXi’an 710072China

Dye molecules often change colors(so-called “chromism”) according to the environment variation. However, they are rarely induced by a catalytic amount of cavity. Through encapsulation in the cavity of a porous coordination cage(PCC-2), Rhodamine B(1) is transformed from red quinonoid form(1q) into colorless lactone form(1l) in aprotic polar solutions. The μ4-OH groups in the cavity of PCC-2 are shown to stabilize the uncommon zwitterion intermediate(1z), followed by converting to 1l, thus accelerating the equilibrium. The chromism is catalyzed by 0.25 mol% of PCC-2, and the reaction rate is improved by 80,400times. 1@PCC-2 can be further fabricated to a sol-gel that exhibits ion recognition properties. The resulting encapsulation and stabilization of an unconventional intermediate by a catalytic amount of the coordination cage provides fundamental insights into molecular isomerization and has potential use in chemical sensing.

关键词： porous coordination cage Zwitterion intermediate cavity Rhodamine B chromism

Lightweight,Strong and High Heat-Resistant Poly(lactide acid)Foams via Microcellular Injection Molding with Self-Assembly Nucleating Agent

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Chinese Journal of Polymer Science 2024年第6期42卷 739-750页

作者： xiao-Hu Bing Wen-yu Ma Ming-Hui Wu Peng Gao xiao Zhou Hai-Bin Luo Long Wang Wen-Ge Zheng School of materials Science and Engineering Shanghai UniversityShanghai200444China Ningbo Key Lab of Polymer Materials Ningbo Institute of Material Technology and EngineeringChinese Academy of SciencesNingbo315201China University of Chinese Academy of Sciences Beijing100049China

Poly(lactide acid)(PLA)foams have shown considerable promise as eco-friendly alternatives to nondegradable plastic foams,such as polystyrene(PS)***,PLA foam typically suffers from low heat-resistance and poor cellular structure stemming from its inherent slow crystallization rate and low melt *** this study,a high-performance PLA foam with well-defined cell morphology,exceptional strength and enhanced heat-resistance was successfully fabricated via a core-back microcellular injection molding(MIM)*** scanning calorimetry(DSC)results revealed that the added hydrazine-based nucleating agent(HNA)significantly increased the crystallization temperature and accelerated the crystallization process of ***,the addition of a 1.5 wt%of HNA led to a significant reduction in PLA’s cell size,from 43.5µm to 2.87µm,and a remarkable increase in cell density,from 1.08×10^(7)cells/cm^(3)to 2.15×10^(10)cells/cm^(3).This enhancement resulted in a final crystallinity of approximately 55.7%for the PLA blend foam,a marked improvement compared to the pure PLA ***,at 1.5 wt%HNA concentration,the tensile strength and tensile toughness of PLA blend foams demonstrated remarkable improvements of 136%and 463%,***,the Vicat softening temperature of PLA blend foam increased significantly to 134.8°C,whereas the pure PLA foam exhibited only about 59.7℃.These findings underscore the potential for the preparation of lightweight injection-molded PLA foam with enhanced toughness and heat-resistance,which offers a viable approach for the production of high-performance PLA foams suitable for large-scale applications.

关键词： Poly(lactide acid) Nucleating agent Microcellular injection molding Heat-resistance Toughness