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Dual-Donor-Induced Crystallinity Modulation Enables 19.23% Efficiency Organic Solar Cells

NANO-MICRO LETTERS 2025年第1期17卷 1-13页

作者： Liang, Anhai Sun, Yuqing Chung, Sein Shin, Jiyeong Sun, Kangbo Zhu, Chaofeng zhao, Jingjing zhao, Zhenmin Zhong, Yufei Zhang, Guangye Cho, Kilwon Kan, Zhipeng Guangxi Univ Inst Sci & Technol Carbon Peak & Neutral Ctr Nanoenergy Res Sch Phys Sci & Technol Nanning 530004 Peoples R China Pohang Univ Sci & Technol Dept Chem Engn Pohang 37673 South Korea Shenzhen Technol Univ Coll New Mat & New Energies Shenzhen 518118 Peoples R China NingboTech Univ Zhejiang Engn Res Ctr Fabricat & Applicat Adv Phot Sch Mat Sci & Engn Ningbo 315100 Peoples R China State Key Lab Featured Met Mat & Life Cycle Safety Nanning 530004 Peoples R China

By modulating the crystalline properties of the active layer with dual donors, the efficiency of organic solar cells reaches 19.23%.The introduction of PTzBI-dF suppresses the accumulation of traps and charge recombination, allowing ternary devices to maintain 82% of their initial power conversion efficiency (PCE) after illumination for 800 *** dual-donor strategy for modulating the crystallinity of the active layer is applicable to a variety of Y6 derivatives, and the increase in PCE exceeds 1%. Trap-assisted charge recombination is one of the primary limitations of restricting the performance of organic solar cells. However, effectively reducing the presence of traps in the photoactive layer remains challenging. Herein, wide bandgap polymer donor PTzBI-dF is demonstrated as an effective modulator for enhancing the crystallinity of the bulk heterojunction active layers composed of D18 derivatives blended with Y6, leading to dense and ordered molecular packings, and thus, improves photoluminescence quenching properties. As a result, the photovoltaic devices exhibit reduced trap-assisted charge recombination losses, achieving an optimized power conversion efficiency of over 19%. Besides the efficiency enhancement, the devices comprised of PTzBI-dF as a third component simultaneously attain decreased current leakage, improved charge carrier mobilities, and suppressed bimolecular charge recombination, leading to reduced energy losses. The advanced crystalline structures induced by PTzBI-dF and its characteristics, such as well-aligned energy level, and complementary absorption spectra, are ascribed to the promising performance improvements. Our findings suggest that donor phase engineering is a feasible approach to tuning the molecular packings in the active layer, providing guidelines for designing effective morphology modulators for high-performance organic solar cells.

关键词： Trap-assisted charge recombination Photoluminescence Miscibility Current leakage Power conversion efficiency

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Revolutionizing photothermal CO_(2)hydrogenation with ceria-based catalysts

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Nano Research 2025年第1期18卷 30-49页

作者： zhaorui Zhang xiao Han Junhong Zhang Yunyun Dong Jinsheng zhao Qian Xu ingqiang Zhang School of Chemistry and Chemical Engineering Liaocheng UniversityLiaocheng 252059China Institute for Catalysis Hokkaido UniversityN-21W-10Sapporo 001-0021Japan National Synchrotron Radiation Laboratory University of Science and Technology of ChinaHefei 230029China

In the context of achieving carbon neutrality,CO_(2)catalytic conversion technologies are effective in reducing atmospheric CO_(2)concentrations while simultaneously producing renewable *** approach is seen as a viable method for constructing a new carbon cycle,thereby effectively addressing the issue of global *** CO_(2)conversion has recently emerged as a promising research focus due to its high energy utilization efficiency,superior CO_(2)conversion,excellent product selectivity,mild operating conditions,low energy consumption and minimal operating *** oxide(CeO_(2))has been widely used in photothermal catalysis due to its unique chemical properties,particularly when used as a support material with supported metals,creating distinctive interfacial sites for catalytic *** an emerging star support in photothermal CO_(2)conversion,its contributions are equally significant and should not be ***,to our knowledge,there has been no comprehensive review of CeO_(2)applications in catalytic hydrogenation of CO_(2).In this paper,we summarize and discuss CeO_(2)-based materials for photothermal CO_(2)conversion to value-added *** research particularly focuses on the synthesis methods of CeO_(2)-supported catalysts,the history of CeO_(2)in photothermal catalysis,types of photothermal catalytic reactors,unique characterization methods for the photothermal catalysts and the photothermal CO_(2)hydrogenation reactions by CeO_(2)-based *** related to further challenges and future directions for photothermal CO_(2)hydrogenation are also provided.

关键词： CO_(2)neutrality hydrogenation photothermal catalysis ceria C1 chemistry

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Comparative Proteomic Analysis Shows an Elevation of Mdh1 Associated with Hepatotoxicity Induced by Copper Nanoparticle in Rats

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Journal of Integrative Agriculture 2014年第5期13卷 1073-1081页

作者： DONG Shu-wei GAO zhao-hui SHEN xiao-yun xue Hui-wen LI Xia Key Laboratory of Veterinary Pharmaceutical Development Ministry of Agriculture/Key Laboratory of New Animal Drug ProjectGansu Province/Lanzhou Institute of Husbandry and Pharmaceutical Sciences Chinese Academy of Agricultural Sciences College of Veterinary Medicine Gansu Agricultural University Bijie College

Copper nanoparticle is a new material widely used in biological medicine, animal husbandry and industrial areas, but its potential toxicity to human health and environment remains unclear. In order to study the hepatotoxic mechanisms of nanoparticles copper, two-dimensional gel electrophoresis （2-DE） and matrix-assisted laser desorption/ionization time of flight mass spectrometry （MALDI/TOF MS） of proteomics technology were used to isolate and identify the differentially expressed proteins from liver, which associated with hepatotoxicity induced by copper nanoparticle in rats. In this study, we have screened 15 kinds of proteins related with hepatotoxicity, of which spot8212 was identified as Malate dehydrogenase （Mdhl）. The mRNA expression trend of Mdhl was consistent with the result of 2-DE by RT-PCR validation. Bioinformatics analysis showed that Mdhl was stable and no signal peptides, subcellular location was in endoplasmic reticulum; it contained many functional sites such as malate dehydrogenase activity signal sites 155LTRLDHNRAKSQI167; a helixes and random coils were the two main elements. Homologous analysis demonstrated high homologous of Mdhl in rats with mouse and human, and the phylogenetic tree of Mdhl was constructed. The result indicated that copper nanoparticle could regulate up the Mdhl protein expression so as to compensate the energy deficit. Energy metabolic disturbance may be a pathway for copper nanoparticle particles to exert the hepatotoxic effects in rats.

关键词： copper nanoparticle hepatotoxicity proteomics malate dehydrogenase bioinformatics rat

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The 2012 Flash Drought Threatened US Midwest Agroecosystems

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Chinese Geographical Science 2019年第5期29卷 768-783页

作者： JIN Cui LUO xue xiao Xiangming DONG Jinwei LI xueming YANG Jun zhao Deyu College of Urban and Environment Liaoning Normal UniversityDalian116029China Department of Microbiology and PlantBiology Center for Spatial AnalysisUniversity of OklahomaNormanOK73019USA Ministry of Education Key Laboratory ofBiodiversity Science and Ecological Engineering Institute of Biodiversity ScienceFudan UniversityShanghai200433China KeyLaboratory of Land Surface Pattern and Simulation Institute of Geographic Sciences and Natural Resources ResearchChinese Academyof SciencesBeijing100101China

In the summer of 2012, the US Midwest, the most productive agricultural region in the world, experienced the most intense and widespread drought on record for the past hundred years. The 2012 drought, characterized as ‘flash drought’, developed in May with a rapid intensification afterwards, and peaked in mid-July. ~76% of crop region and 60% of grassland and pasture regions have been under moderate to severe dry conditions. This study used multiple lines of evidences, i.e., in-situ AmeriFlux measurements, spatial satellite observations, and scaled ecosystem modeling, to provide independent and complementary analysis on the impact of 2012 flash drought on the US Midwest vegetation greenness and photosynthesis carbon uptake. Three datasets consistently showed that 1) phenological activities of all biomes advanced 1–2 weeks earlier in 2012 compared to the other years of 2010–2014;2) the drought had a more severe impact on agroecosystems(crop and grassland) than on forests;3) the growth of crop and grassland was suppressed from June with significant reduction of vegetation index, sun-induced fluorescence(SIF) and gross primary production(GPP), and did not recover until the end of growing season. The modeling results showed that regional total GPP in 2012 was the lowest(1.76 Pg C/yr) during 2010–2014, and decreased by 63 Tg C compared with the other-year mean. Agroecosystems, accounting for 84% of regional GPP assimilation, were the most impacted by 2012 drought with total GPP reduction of 9%, 7%, 6%, and 29% for maize, soybean, cropland, and grassland, respectively. The frequency and severity of droughts have been predicted to increase in future. The results imply the importance to investigate the influences of flash droughts on vegetation productivity and terrestrial carbon cycling.

关键词： food security terrestrial carbon cycling eddy covariance Vegetation Photosynthesis Model sun-induced fluorescence(SIF)

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Multifractal estimation of NMR T_(2) cut-off value in low-permeability rocks considering spectrum kurtosis: SMOTE-based oversampling integrated with machine learning

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Petroleum Science 2023年第6期20卷 3411-3427页

作者： xiao-Jun Chen Rui-xue Zhang xiao-Bo zhao Jun-Wei Yang Zhang-Jian Lan Cheng-Fei Luo Jian-Chao Cai MOE Key Laboratory of Tectonics and Petroleum Resources Wuhan430074HubeiChina Department of Chemical Engineering and Analytical Science The University of ManchesterManchesterM139PLUK Jianghan Oilfied SINOPECQianjiang430063HubeiChina Hainan Branch of CNOOC Ltd Haikou570311HainanChina CNOOC EnerTech-Drilling&Production Co.CNOOC Central Laboratory(Zhanjiang) Zhanjiang524057GuangdongChina National Key Laboratory of Petroleum Resources and Engineering China University of PetroleumBeijing102249China

The transverse relaxation time (T_(2)) cut-off value plays a crucial role in nuclear magnetic resonance for identifying movable and immovable boundaries, evaluating permeability, and determining fluid saturation in petrophysical characterization of petroleum reservoirs. This study focuses on the systematic analysis of T_(2) spectra and T_(2) cut-off values in low-permeability reservoir rocks. Analysis of 36 low-permeability cores revealed a wide distribution of T_(2) cut-off values, ranging from 7 to 50 ms. Additionally, the T_(2) spectra exhibited multimodal characteristics, predominantly displaying unimodal and bimodal morphologies, with a few trimodal morphologies, which are inherently influenced by different pore types. Fractal characteristics of pore structure in fully water-saturated cores were captured through the T_(2) spectra, which were calculated using generalized fractal and multifractal theories. To augment the limited dataset of 36 cores, the synthetic minority oversampling technique was employed. Models for evaluating the T_(2) cut-off value were separately developed based on the classified T_(2) spectra, considering the number of peaks, and utilizing generalized fractal dimensions at the weight 0. The primary objective of this work is to gain insights into the relationship between the kurtosis of the T_(2) spectrum and pore types, as well as to predict the T_(2) cut-off value of low-permeability rocks using machine learning and data augmentation techniques.

关键词： Nuclear magnetic resonance Low-permeability porous media T_(2)cut-off value Fractal and multifractal Data augmentation Machine learning

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Steam explosion of crop straws improves the characteristics of biochar as a soil amendment

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Journal of Integrative Agriculture 2019年第7期18卷 1486-1495页

作者： CHEN xue-jiao LIN Qi-mei Muhammad Rizwan zhao xiao-rong LI Gui-tong College of Resources and Environmental Sciences China Agricultural UniversityBeijing 100193P.R.China Key Laboratory of Arable Land Conservation (North China) Ministry of Agriculture/Key Laboratory of Plant-Soil InteractionsMinistry of EducationBeijing 100193P.R.China

Five crop straws (wheat, rice, maize, oil-rape, and cotton) were first steam-exploded for 2 min at 210℃, 2.5 MPa and then pyrolyzed at 500℃ for 2 h. Steam explosion (SE) induced 47–95% and 5–16% reduction of hemicellulose and cellulose, respectively, in the crop straws. The biochars derived from SE-treated feedstocks had a lower specific surface area (SSA) and pore volume, compared to those from pristine feedstocks, with one exception that SE enhanced SSA of oil-rape straw biochar by approximately 16 times. After SE, biochars had significant higher anion exchange capacity (AEC) (6.88–11.44 cmol kg–1) and point of zero net charges (PZNC) (pH 3.61–5.32) values. It can thus be speculated that these biochars may have higher potential for anions adsorption. In addition, oil-rape straw might be suitable to SE pretreatment for preparing biochar as a soil amendment and sorbent as well. Further work is required for testing its application in soil.

关键词： crop straws steam explosion biochar characterization

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Ion-Pairing Chirality Transfer in Atropisomeric Biaryl-Centered Gold Clusters

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CCS Chemistry 2021年第1期3卷 555-565页

作者： Kui xiao Yang xue Biao Yang Liang zhao Key Laboratory of Bioorganic Phosphorus Chemistry&Chemical Biology(Ministry of Education) Department of ChemistryTsinghua UniversityBeijing 100084

The stereocontrol of chiral metal clusters and nanoclusters has become a focus of interest in metal cluster chemistry due to their promising applications in asymmetric *** being a general chirality transfer strategy,the ion-pairing process is still ambiguous in the course of bestowing chirality to metal *** we construct a biaryl-centered axially chiral gold-cluster system to study an outside-in ion-pairing chirality transfer *** hexanuclear gold(I)clusters,centered by two types of biaryl ligands[(2-indolyl)aniline(L^(1))and biindole(L^(2))],were synthesized via in situ cyclization *** the crystalline state,the biaryl centers showed axial chirality in which the gold atoms were in an asymmetric *** solution,the chiral phosphates induced an outside-in chirality transfer by significant interactions with the periphery of the biaryl-centered gold ***,the chiral resolution of hexa-aurated biindoliums was accomplished via an efficient outside-in chirality transfer process relying on strong aurophilic interaction and extra peripheral *** study not only deepens the understanding of the outside-in ion-pairing chirality transfer process but also provides a new approach for fabricating desired chiral metal clusters by a combination of organometallic transformation and chirality transfer.

关键词： axial chirality biaryl ligand chirality transfer gold cluster ion-pairing

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Defect Engineering:Can it Mitigate Strong Coulomb Effect of Mg^(2+)in Cathode Materials for Rechargeable Magnesium Batteries?

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Nano-Micro Letters 2025年第1期17卷 135-159页

作者： Zhengqing Fan Ruimin Li Xin Zhang Wanyu zhao Zhenghui Pan xiaowei Yang School of Chemistry and Chemical Engineering Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China School of Chemistry and Chemical Engineering Taiyuan University of TechnologyTaiyuan 030024People’s Republic of China School of Materials Science and Engineering Tongji UniversityShanghai 201804People’s Republic of China

Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage ***,the sluggish diffusion kinetics of bivalent Mg^(2+)in the host material,related to the strong Coulomb effect between Mg^(2+)and host anion lattices,hinders their further development toward practical *** engineering,regarded as an effective strategy to break through the slow migration puzzle,has been validated in various cathode materials for *** this review,we first thoroughly understand the intrinsic mechanism of Mg^(2+)diffusion in cathode materials,from which the key factors affecting ion diffusion are further ***,the positive effects of purposely introduced defects,including vacancy and doping,and the corresponding strategies for introducing various defects are *** applications of defect engineering in cathode materials for RMBs with advanced electrochemical properties are also ***,the existing challenges and future perspectives of defect engineering in cathode materials for the overall high-performance RMBs are described.

关键词： Rechargeable magnesium battery Sluggish diffusion kinetic Defect engineering Cathode materials Ion migration

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Cob color, an indicator of grain dehydration and agronomic traits in maize hybrids

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The Crop Journal 2022年第2期10卷 582-586页

作者： xiao-Gui Liang Zhen Gao Si Shen xue zhao Li Zhang Shun-Li Zhou Key Laboratory of Crop Physiology Ecology and Genetic BreedingMinistry of Education/Jiangxi ProvinceJiangxi Agricultural UniversityNanchang 330045JiangxiChina College of Agronomy and Biotechnology China Agricultural UniversityBeijing 100193China Scientific Observation and Experimental Station of Crop High-Efficiency Use of Water in Wuqiao Ministry of Agriculture and Rural AffairsWuqiao 061802HebeiChina Innovation Center of Agricultural Technology for Lowland Plain of Hebei Wuqiao 061802HebeiChina

Screening for agronomic traits associated with grain moisture is important for mechanical grainharvesting of maize. Cob color as a visual indicator has received limited attention, though it has been subjected to artificial selection, and may have some association with threshability. To investigate the relationships between cob color and grain moisture and other agronomic traits, field experiments were conducted during 2016–2017 using 23 commercial hybrids with red or white cobs. Kernels of red-cob hybrids dehydrated faster, showing lower moisture content at harvest than white-cob hybrids. A cob color index(CCI) was established as a quantitative measure of cob color in the hybrid panel. Ranging from0(whitest) to 17.98(reddest), CCI correlated well with grain dehydration and other agronomic traits associated with growth ontogeny, plant morphology, and plant N content. Strong selection of red cob for recently released hybrids suitable for mechanical grain-harvesting indirectly validated the observed link between cob color and grain dehydration. We propose that cob color and CCI could be used in future selection of maize cultivars bred for mechanical grain-harvesting.

关键词： Maize hybrids Cob color Grain dehydration Agronomic traits Artificial selection

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Preparation of FeCoNi medium entropy alloy from Fe^(3+)-Co^(2+)-Ni^(2+)solution system

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 92-101页

作者： Zongyou Cheng Qing zhao Mengjie Tao Jijun Du Xingxi Huang Chengjun Liu Key Laboratory for Ecological Metallurgy of Multimetallic Mineral(Ministry of Education) Northeastern UniversityShenyang 110819China School of Metallurgy Northeastern UniversityShenyang 110819China Engineering Research Center of Frontier Technologies for Low-carbon Steelmaking(Ministry of Education) Shenyang 110819China

In recent years,medium entropy alloys have become a research hotspot due to their excellent physical and chemical *** controlling reasonable elemental composition and processing parameters,the medium entropy alloys can exhibit similar properties to high entropy alloys and have lower *** this paper,a FeCoNi medium entropy alloy precursor was prepared via sol-gel and coprecipitation methods,respectively,and FeCoNi medium entropy alloys were prepared by carbothermal and hydrogen *** phases and magnetic properties of FeCoNi medium entropy alloy were *** showed that FeCoNi medium entropy alloy was produced by carbothermal and hydrogen reduction at 1500℃.Some carbon was detected in the FeCoNi medium entropy alloy prepared by carbothermal *** alloy prepared by hydrogen reduction was uniform and showed a relatively high ***,the hydrogen reduction product exhibited better saturation magnetization and lower coercivity.

关键词： medium entropy alloy sol-gel co-precipitation carbothermal hydrogen reduction

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