检索结果-南通市图书馆

Synergistically enhanced ORR and HER performance on Co-N-C coupled in-situ generated PtCo intermetallic

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第1期100卷 721-729页

作者： Guanyu luo Min Song Lulu An xiao Huang Qian Zhang Chenhao Zhang Tao Shen Shuang Wang Deli Wang Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology) Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology

Integrating multi-scale sites in a composite catalyst is vital to realize efficient ***,a synergistic composite catalyst consisting of Co atomic sites and in-situ generated PtCo intermetallic compounds （IMCs）(o-PtCo@CoNC) is proposed through Co pre-anchoring and subsequent impregnation-reduction *** loading of Co atoms provides a chance for in-situ generating PtCo ordered intermetallic *** remaining Co single atoms and PtCo IMCs construct synergistic electrocatalytic *** from the ordered structure,synergistic effect of Pt Co IMCs and Co single atoms,o-PtCo@CoNC exhibits excellent electrocatalytic performance for oxygen reduction reaction （ORR） and hydrogen evolution reaction （HER） with mass activity of 1.21 A mgPt-1（at 0.9 V） and5.70 A mgPt-1（at an overpotential of 100 mV）,***,o-PtCo@CoNC delivers negligible loss of half-wave potential and overpotential during long-term stability test in acid solutions,with 13 mV decay after 50,000 potential cycles for ORR and a 2.7 mV decay after 20,000 potential cycles for *** integration strategy of single-atomic sites coupled IMCs paves the way for enhancing the activity and durability of Pt-based electrocatalysts.

关键词： Electrolytic reduction

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

食管高密度异物(鱼刺)的CT诊断

实用放射学杂志 2007年第7期23卷 914-915页

作者：何小川罗新谭长连湖南省华容县人民医院CT室中南大学湘雅二医院放射科湖南岳阳414200

目的探讨CT在食管异物诊断中的应用价值方法食管异物10例(均为鱼刺),均行常规CT平扫,必要时加CT薄层扫描,再将CT征象与手术及内镜结果比较结果10例食管异物(鱼刺)均为CT所显示,呈大小、形态不一的稍高或高密度影,其中合并食管出血2例,... 详细信息

目的探讨CT在食管异物诊断中的应用价值方法食管异物10例(均为鱼刺),均行常规CT平扫,必要时加CT薄层扫描,再将CT征象与手术及内镜结果比较结果10例食管异物(鱼刺)均为CT所显示,呈大小、形态不一的稍高或高密度影,其中合并食管出血2例,黏膜下血肿1例,脓肿3例及脓胸1例结论常规CT扫描及薄层扫描在食管异物检查中具有重要意义

关键词：食管异物体层摄影术,X线计算机

Social function scores and influencing factors in patients with residual depressive symptoms

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

World Journal of Psychiatry 2025年第1期15卷 117-127页

作者： Zong-Ling Liao xiao-Li Pu Zhi-Yi Zheng Jie luo Department 1 of Psychiatry Gele Mountain Hospital of Chongqing Mental Health CenterChongqing 400030China Department of Psychology Chongqing Jiangjin District Psychiatric HospitalChongqing 402260China Department of Psychiatry Chongqing Third Social Welfare InstituteChongqing 400036China Women and Children’s Mental Health Center Affiliated Hospital of Chongqing Population and Family Planning Research InstituteChongqing 400020China

BACKGROUND At present,the influencing factors of social function in patients with residual depressive symptoms are still *** depressive symptoms are highly harmful,leading to low mood in patients,affecting work and interpersonal communication,increasing the risk of recurrence,and adding to the burden on *** the influencing factors of their social function is of great *** To explore the social function score and its influencing factors in patients with residual depressive *** This observational study surveyed patients with residual depressive symptoms(case group)and healthy patients undergoing physical examinations(control group).Participants were admitted between January 2022 and December *** functioning was assessed using the Sheehan Disability Scale(SDS),and scores were compared between *** influencing SDS scores in patients with residual depressive symptoms were analyzed by applying multiple linear regression while using the receiver operating characteristic curve,and these RESULTS The SDS scores of the 158 patients with depressive symptoms were 11.48±*** with the control group,the SDS scores and all items in the case group were *** scores were higher in patients with relapse,discon-tinuous medication,drug therapy alone,severe somatic symptoms,obvious residual symptoms,and anxiety scores≥*** history,medication compliance,therapy method,and residual symptoms correlated positively with SDS scores(r=0.354,0.414,0.602,and 0.456,respectively).Independent influencing factors included disease history,medication compliance,therapy method,somatic symptoms,residual symptoms,and anxiety scores(P<0.05).The areas under the curve for predicting social functional impairment using these factors were 0.713,0.559,0.684,0.729,0.668,and 0.628,respectively,with sensitivities of 79.2%,61.8%,76.8%,81.7%,63.6%,and 65.5%and specificities of 83.3%,87.5%,82.6%,83.3%,86.7%,and 92.1%,respectively.C

关键词： Depressive Residual symptoms Social function Influence factors

基于Webots仿真软件的仿生六足机器人机构设计与步态规划

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

系统仿真学报 2009年第11期21卷 3241-3245,3267页

作者：赵小川罗庆生韩宝玲北京理工大学机电学院学院北京100081 北京理工大学机械与车辆工程学院北京100081

仿真技术在机器人机构设计与运动分析的研究与应用中发挥着重要的作用,可提升机器人机构设计的质量和改善机器人的运动性能。在六足纲昆虫观测实验的基础上,模仿六足纲昆虫的躯体形态和结构特征,以蚂蚁爬行的三角步态为摹本,对仿生六足... 详细信息

仿真技术在机器人机构设计与运动分析的研究与应用中发挥着重要的作用,可提升机器人机构设计的质量和改善机器人的运动性能。在六足纲昆虫观测实验的基础上,模仿六足纲昆虫的躯体形态和结构特征,以蚂蚁爬行的三角步态为摹本,对仿生六足机器人进行了机构设计与步态规划,并在Webots移动机器人仿真软件的环境下完成了仿生六足机器人的实体造型,编制了相应的运动控制程序,且通过仿真实验验证了仿生六足机器人机构的合理性和运动的灵活性。

关键词：仿生六足机器人机构设计步态规划 Webots机器人仿真软件昆虫观测实验仿真

Construction of daily precipitation series and the observational characteristics of extreme precipitation in Tianjin,China during 1888-2022

在线全文

学校读者我要写书评

暂无评论

Advances in Climate Change Research 2024年第1期15卷 52-61页

作者： Peng SI Qing-Xiang LI xiao-Yang CHEN Min WANG chuan-Jun luo Tianjin Meteorological Information Center Tianjin Meteorological BureauTianjin 300074China Research Centerfor Ecology and Environment of Central Asia Chinese Academy of SciencesWulumuqi 830011China School of Atmospheric Sciences Sun Yat-sen UniversityZhuhai 528478China Key Laboratory of Tropical Amosphere-Ocean System Ministry of EducationZhuhai 528478China Shaoguan Meteorological Service Shaoguan 512028China

Given the difficulties in rescuing and ensuring the quality of long-term climate data,current studies on century-scale climate change are usually limited to annual and monthly data,resulting in the poor detection of extreme climate events and their changes before *** this study,we reconstructed a daily precipitation series for Tianjin from 15 September 1887 to 31 December 2022 on the basis of the most comprehensive daily precipitation records collected from the Tianjin Meteorological Archive,China,and in reference to the precipitation analysis results based on the datasets developed by the Climatic Research Unit Time-Series version 4.06,Global Precipitation Climatology Centre and University of Delaware along with the application of various homogenisation methods for climate *** approach provides a complete and reliable century-long daily precipitation series for the study of regional or local extreme weather and climate *** reconstructed daily dataset reveals that the annual precipitation amount and R95 intensity in Tianjin during 1888-2022 lack significant trends and have values of 0.74±6.99 and-1.84±3.22 mm per decade,*** the annual and seasonal scales,the precipitation amount and R95 intensity,particularly those in autumn,have increased since the latter half of the 20th century relative to those in ***,the increase in precipitation amount and R95 intensity is relatively limited compared with that in atmospheric water vapour content due to surface warming,indicating the highly sensitive response of extreme precipitation events to *** addition,the estimates for the return periods of 5,10,20,50 and 100 years covering 1888-2022,1888-1950 and 1951-2022 depict that the intensity of heavy rain and above magnitude was highest in 1888-1950 and decreased in 1951-2022.

关键词： Over a century-long timescale Daily precipitation series Extreme precipitation Return period

A new Complex from TMPDB and SSDMA:Preparation,Characterization and Photopolymerization

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chemical Research in Chinese Universities 2003年第4期19卷 518-520页

作者： LU Cong-hua ZHENG xiao-liang luo chuan-qiou CAO Wei-xiao College of Chemistry and Molecular Engineering Peking UniversityBeijing 100871P.R.China

The study of chemical reactions in ordered solid state has been an active field of research for the chemists. It may be that the reactions in solid state have advantages over those in solutions or in gas state. For instance, the reactions giving the mixtures of the products in solutions may give a single product if they are carried out in solid state. In some cases, the reactions failing at all in solutions can be realized in solid state due to the minimum movement required for reacting atoms and molecules. Polymerizations carried out in solid state can be used to produce highly stereo-regular polymers with high molecular weights, which is called as "crystal engineering". Of course, it is necessary that the monomer crystals should be of special structures in geometry, ordered arrangements and appropriate distances between the reactive groups.

关键词： Complex Lamellar structure Photopolymerization

Recent progress in synthesis of composite powders and their applications in low-carbon refractories

在线全文

学校读者我要写书评

暂无评论

Journal of Iron and Steel Research International 2022年第7期29卷 1041-1051页

作者： Ji-yuan luo Xin-ming Ren xiao-chuan Chong Dong-hai Ding Bei-yue Ma Guo-qing xiao Jing-kun Yu College of Materials Science and Engineering Xi’an University of Architecture and TechnologyXi’an 710055ShaanxiChina School of Metallurgy Northeastern UniversityShenyang 110819LiaoningChina

The development of low-carbon refractories is of great significance,but it is limited by the deteriorated properties that resulted from the decreased graphite *** composite powders has proved to be effective in improving the properties of low-carbon *** recent progress in the synthesis of composite powders including modified graphite,nanocarbon-containing composite powders,oxide/non-oxide and non-oxide composite powders and their applications in low-carbon refractories were reviewed,and the future development of composite powder technology was prospected.

关键词： Composite powder Modified graphite Nanocarbon-containing composite powder Oxide/non-oxide Non-oxide Low-carbon refractory

Effect of Crystallization and Entropy Contribution Upon the Mechanical Response of Polymer Nano-fibers:A Steered Molecular Dynamics Study

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2023年第3期41卷 465-474,I0011页

作者： Rui Ma Dan Xu chuan-Fu luo Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters College of Physical Science and TechnologyYili Normal UniversityYining 835000China State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China University of Science and Technology of China School of Applied Chemistry and EngineeringHefei 230026China

The mechanical response of polyethylene nano-fibers with the same chain length but different chain numbers are studied by using steered molecular dynamics *** shrinking or stretching forces acted on the chain ends are investigated according to the chain-end distance and temperature under isothermal or continuous warming-cooling conditions,*** inflection point is found in the ForceDistance response when temperature is below 500 *** inflection point is related to the balance between entropy force and inter-monomer interaction and it reflects the strong effect of crystallization on the mechanical response of the *** force at inflection point is also affected by the buckling effect due to increased stiffness when crystallization *** two stages found in the Force-Temperature response and the difference between the shrinking and stretching forces indicate the hysteresis of crystallization and *** forces at different shrinking and stretching rates reveal the entropy contribution upon the mechanical response,indicated by the Ramachandran plot of *** chain-conformation entropy is majorly contributed by dihedrals and is quantified by the information entropy of dihedrals,which has a highly similarity to the mechanical Force-Temperature *** enlarged forces in multiple chains over a single chain are attributed to the enhanced dihedral-conformation *** study provides a new insight to the dynamically mechanical response of polymer nano-fibers according to the effect of crystallization and entropy contribution.

关键词： Polymer fibers Crystallization Entropy contribution Mechanical response

Reconstruction of the Sturm-Liouville operator with discontinuities from a particular set of eigenvalues

在线全文

学校读者我要写书评

暂无评论

Applied Mathematics(A Journal of Chinese Universities) 2018年第2期33卷 225-233页

作者： XU xiao-chuan YANG chuan-fu Department of Applied Mathematics School of Science Nanjing University of Science and Technology

Sturm-Liouville operators on a finite interval with discontinuities are considered. We give a uniqueness theorem for determining the potential and the parameters in boundary and under discontinuous conditions from a particular set of eigenvalues, and provide corresponding reconstruction algorithm, which can be applicable to McLaughlin-Rundell＇s uniqueness theorem （see J. Math. Phys. 28, 1987）.

关键词： Sturm-Liouville operator discontinuous condition inverse spectral problem reconstruction al-gorithm