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Fluoro-functionalized plant biomass adsorbent:Preparation and application in extraction of trace perfluorinated compounds from environmental water samples

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Journal of Environmental Sciences 2024年第3期137卷 703-715页

作者： Xi Tan Yan Shi Chun-Feng Ma Quan Chi Yu-Hang Yang wen-xiang zhang Hua-Ming Xiao Xian Wang Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission School of Chemistry and Materials ScienceSouth-Central Minzu UniversityWuhan 430074China School of Pharmaceutical Sciences South-Central Minzu UniversityWuhan 430074China Key Laboratory of Oilseeds Processing of Ministry of Agriculture Hubei Key Laboratory of Lipid Chemistry and NutritionOil Crops Research Institute of the Chinese Academy of Agricultural SciencesWuhan 430062China

Perfuorinated compounds(PFCs)are toxic and widely present in the environment,and therefore effective adsorbents are required to remove PFCs from environmental *** the present study,a new type of fuorinated biomass materials was synthesized via an ingenious fuorosilanization *** adsorbents were applied for the adsorption of 13typical PFCs,including perfuorocarboxylic acids(PFCAs)and perfuorosulfonic acids(PFSAs).By comparing their adsorption performance,Fluorinated cedar slag(FCS)was discovered to have the best absorption efficiency and enabled highly efficient enrichment of *** adsorption recovery of FCS with the investigated PFCs is greater than 90%under the optimal adsorption *** to the high affinity of F-F sorbent-sorbate interaction,FCS had good adsorption capacities of PFCs from aqueous solution,with the maximum adsorption capacity of 15.80 mg/g for PFOS and 10.71 mg/g for PFOA,***,the adsorption time could be achieved in a short time(8 min).Using the FCS absorbent,an innovative FCS-solid phase extraction assisted with high performance liquid chromatography-electrospray-tandem mass spectrometry(FCS-SPE-HPLC-ESI-MS/MS)method was first developed to sensitively detect PFCs in the environmental water *** intra-day and inter-day recovery rates of the 13 compounds ranged from 90.7%-104.3%,with the RSD of 2.1%-4.7%(intra-day)and 2.5%-8.5%(inter-day),*** research demonstrates the potential of the newly fuoro-functionalized plant biomass to adsorb PFCs from environmental water,with the advantages of high adsorption efficiencies,high antiinterference,easy operation and low economic cost.

关键词： Fluoro-functionalized biomass Perfuorinated compounds(PFCs) Adsorption efficiency Mass spectrometry(MS) Fluorinated cedar slag(FCS)

Practical construction of globally injective parameterizations with positional constraints

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Computational Visual Media 2023年第2期9卷 265-277页

作者： Qi Wang wen-xiang zhang Yuan-Yuan Cheng Ligang Liu Xiao-Ming Fu School of Mathematical Sciences University of Science and Technology of ChinaHefei 230026China

We propose a novel method to compute globally injective parameterizations with arbitrary positional constraints on disk topology *** to this method is the use of a scaffold mesh that reduces the globally injective constraint to a locally flipfree ***,given an initial parameterized mesh containing flipped triangles and satisfying the positional constraints,we only need to remove the flips of a overall mesh consisting of the parameterized mesh and the scaffold mesh while always meeting positional *** successfully apply this idea,we develop two key ***,an initialization method is used to generate a valid scaffold mesh and mitigate difficulties in eliminating ***,edgebased remeshing is used to optimize the regularity of the scaffold mesh containing flips,thereby improving practical *** to state-of-the-art methods,our method is much more *** demonstrate the capability and feasibility of our method on a large number of complex meshes.

关键词： globally injective parameterization constrained parameterization bijection flip-free scaffold mesh

Recent Advances in Rare-Earth Polypnictides

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Chinese Journal of Chemistry 2020年第3期38卷 295-304页

作者： Lei Qiao Chao zhang xiang wen zhang Zi-Chuan Wang Haolin Yin Zhong Ming Sun School of Materials Science and Engineering Tianjin Key Laboratory for Rare Earth Materials and ApplicationsState Key Laboratory of Element-Organic ChemistryNankai UniversityTianjin 300350China Division of Chemistry and Chemical Engineering California Institute of TechnologyPasadenaCA 91125United Stotes

The polypnictide complexes of rare earth cations have drawn the attention of the scientific community for their uncommon bonding modes and potential ***,we present a systematic and comprehensive summary on recent advances in the field of rare earth polypnictides,focusing on their synthesis,structures,and *** structural stbilizing effects imposed by the electropositive rare earth cations as well as the reducing capability of rare earth precursors in the synthesis of these polypnictide complexes are described in this *** also disscuss in detail the bonding interactions and coordination modes between rare earth cations and polypnictide clusters as well as the similarities and the peculiarity of some structures.

关键词： rare bonding complexes

Research on downward crack closing of clay aquiclude in shallow coal seam safety mining

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Journal of Coal Science & Engineering(China) 2011年第3期17卷 349-354页

作者： HUANG Qing-xiang zhang wen-zhong School of Energy Engineering Key Laboratory of Western Mine Exploitation and Hazard Prevention of Ministry of Education Xi＇an University of Science and Technology Xi＇an 710054 China

The water resisting property of aquiclude is the key factor of water conservation and safety mining, and the mining induced cracks in aquiclude is major factor of water resisting property. The aquiclude is composed by loess layer and red clay layer in Yushuwan Coal Mine, and the water reaction property of clay and loess of aquiclude was tested by soil mechanics method. The permeability coefficient of the loess is 0.856 m/d and the clay is 0.434 m/d. The dilatability coefficient of the loess is 16.1% and the clay is 14.6%. Through physical solid-liquid simulation with whole stress-stain similarity, the distribution of ＂downward crack zone＂ and ＂upward crack zone＂ was found to be the major factor of aquiclude stability. The downward crack closing length is about 30% of the downward crack length. The expanding of clay and loess with water are principal factors of downward crack closing. At last, the mechanical model of downward crack closing was constructed, and the criterion of crack closing was put forward at all. This work will provides the theoretical base for aquiclude stability research and safety mining in shallow seam.

关键词： shallow coal seam simulation clay aquiclude downward crack crack closing

Novel endo-to exo-isomerization of dicyclopentadiene

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Chinese Chemical Letters 2007年第6期18卷 673-676页

作者： xiang wen zhang[a] Kai Jiang[a] Qiang Jiang[a] Ji Jun Zou[a]&Email:jj_zouchem@*** Li Wang[a] Zhen Tao Mi[a] [a]Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China

Endo-dicyclopentadiene was isomerized to exo-isomer by thermal treatment at evaluated temperature and pressure. The reaction temperature and pressure are key factors for this novel isomerization. This result may have ... 详细信息

关键词： Endo-dicyclopentadiene Exo-dicyclopentadiene Isomerization

pH Induced Self-assembly of AIE Fluorescent Probe for Tumor Imaging

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Chinese Journal of Polymer Science 2024年第1期42卷 7-13,I0005页

作者： Jing-Yuan xiang wen-Long zhang He-Ting Li Ya-Ning He Department of Chemical Engineering Key Laboratory of Advanced Materials(MOE)Tsinghua UniversityBejing 100084China

This work reported an AIE fluorescent probe for tumor imaging based on the p H induced self-assembly strategy. The fluorescent probe was composed of an acid-responsive soluble copolymer PEG-b-PAMA-DMMA with a maleic acid amide group and an anionic soluble aggregation-induced emission fluorogen(AIEgen) TPE-2SO_(3)^(-). The polymer could be transformed into a protonated amine-containing polymer after the hydrolysis of maleic acid amide in acidic tumor microenvironment, which would be further self-assembled with TPE-2SO_(3)^(-)to form aggregated nanoparticles. The transition of TPE-2SO_(3)^(-)from dispersed state to aggregated state led to an obvious increase in fluorescence intensity due to its AIE characteristics.

关键词： p H-responsive Self-assembly Fluorescent probe AIE Tumor imaging

Dual-ion carrier storage through Mg^(2+) addition for high-energy and long-life zinc-ion hybrid capacitor

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International Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 179-185页

作者： Junjie zhang xiang Wu School of Materials Science and Engineering Shenyang University of TechnologyShenyang 110870China

Cation additives can efficiently enhance the total electrochemical capabilities of zinc-ion hybrid capacitors (ZHCs).However their energy storage mechanisms in zinc-based systems are still under ***,we modulate the electrolyte and achieve dual-ion storage by adding magnesium *** we assemble several Zn//activated carbon devices with different electrolyte concentrations and investigate their electrochemical reaction dynamic *** zinc-ion capacitor with Mg^(2+)mixed solution delivers 82 mAh·g^(-1)capacity at 1 A·g^(-1) and maintains 91%of the original capacitance after 10000 *** is superior to the other assembled zinc-ion devices in single-component *** finding demonstrates that the double-ion storage mechanism enables the superior rate performance and long cycle lifetime of ZHCs.

关键词： zinc-ion hybrid capacitor MgSO_(4) electrolyte rate performance storage mechanism

Multidimensional hollow SiO_(2)/C nanofibers modified by magnetic nanocrystals for electromagnetic energy conversion and lithium battery storage

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Nano Research 2024年第8期17卷 7301-7314页

作者： Chen Han Qi Zheng Juncheng Jin Jiajia zhang wen-Qiang Cao Kun xiang Min zhang Mao-Sheng Cao Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology College of Materials and Chemical EngineeringWest Anhui UniversityLu’an 237012China School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Department of Physics Beijing Technology and Business UniversityBeijing 100048China

Multifunctional materials are powerful tools to support the advancement of energy conversion *** with prominent electromagnetic and electrochemical properties can realize the conversion of electromagnetic energy and solve the subsequent storage ***,an electrospinning-thermal reduction method is employed to construct ultrafine nickel nanoparticle modified porous SiO_(2)/C(Ni-SiO_(2)/C)hollow nanofibers as promising materials for applications in both electromagnetic wave absorption(EMA)and lithium-ion ***,when used as an EMA material,the reflection loss(RL)of Ni-SiO_(2)/C can reach−47.8 dB at 15.8 GHz with a matching thickness of 2.2 *** excellent microwave absorption performance can be attributed to the enhanced conduction loss,polarization relaxation,synergistic magnetic loss,and preferred impedance matching,which result from multi-component magnetic/dielectric synergy and the unique interconnected multidimensional hollow ***,the electronic conductivity and electrochemical activity of the samples are significantly enhanced due to the uniform distribution of ultrafine Ni nanoparticles in the amorphous SiO_(2)/C ***,the hierarchical hollow porous structure provides sufficient free space for volume change during lithiation/delithiation ***,the Ni-SiO_(2)/C nanocomposite exhibits a high reversible capacity of 917.6 mAh·g^(−1)at 0.1 A·g^(−1).At a high current density of 2 A·g^(−1),a capacity of 563.9 mAh·g^(−1)can be maintained after 300 *** energy conversion-storage device is designed to store waste electromagnetic energy in the form of useful electrical *** work inspires the development of high-performance bifunctional materials.

关键词： Ni-SiO_(2)/C nanofiber electromagnetic absorption lithium-ion storage electrospinning multidimensional structure

Contact Stress Reliability Analysis Model for Cylindrical Gear with Circular Arc Tooth Trace Based on an Improved Metamodel

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Computer Modeling in Engineering & Sciences 2024年第7期140卷 593-619页

作者： Qi zhang Zhixin Chen Yang Wu Guoqi xiang Guang wen Xuegang zhang Yongchun Xie Guangchun Yang School of Intelligent Manufacturing&Automobile Chengdu Industrial Vocational Technical CollegeChengdu610218China School of Intelligent Manufacturing Panzhihua UniversityPanzhihua617000China School of Electrical Engineering Chengdu Industry and Trade CollegeChengdu601165China School of Mechanical Engineering Sichuan UniversityChengdu601165China Chengdu Technological University Chengdu611730China

Although there is currently no unified standard theoretical formula for calculating the contact stress of cylindrical gears with a circular arc tooth trace(referred to as CATT gear),a mathematical model for determining the contact stress of CATT gear is essential for studying how parameters affect its contact stress and building the contact stress limit state equation for contact stress reliability *** this study,a mathematical relationship between design parameters and contact stress is formulated using the *** enhance the model’s accuracy,we propose a new hybrid algorithm that merges the genetic algorithm with the Quantum Particle Swarm optimization algorithm,leveraging the strengths of ***,the“parental inheritance+self-learning”optimization model is used to fine-tune the KrigingMetamodel’s *** this,amathematicalmodel for calculating the contact stress of Variable Hyperbolic Circular-Arc-Tooth-Trace(VH-CATT)gears using the optimized Kriging model was *** then examined how different gear parameters affect the VH-CATT gears’contact *** simulation results show:(1)Improvements in R2,RMSE,and RMAE.R2 rose from0.9852 to 0.9974(a 1.22%increase),nearing 1,suggesting the optimized Kriging Metamodel’s global error is ***,RMSE dropped from3.9210 to 1.6492,a decline of 57.94%.The global error of the GA-IQPSO-Kriging algorithm was also reduced,with RMAE decreasing by 58.69%from 0.1823 to 0.0753,showing the algorithm’s enhanced *** a comparison of ten experimental groups selected randomly,the GA-IQPSO-Kriging and FEM-based contact analysis methods were used to measure contact *** revealed a maximum error of 12.11667 MPA,which represents 2.85%of the real value.(2)Several factors,including the pressure angle,tooth width,modulus,and tooth line radius,are inversely related to contact *** descending order of their impact on the contact stress is:tooth line radius>modulus

关键词： CATT gear contact stress finite element method metamodel hybrid algorithm influencing factors