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Highly efficient catalyst for 1,1,2-trichloroethane dehydrochlorination via BN_(3) frustrated Lewis acid-base pairs

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Nano Research 2024年第6期17卷 4773-4781页

作者： Yuxue Yue Fangmin Zuo Bolin Wang Xiaoling xian Jun Tang Haifeng zhang Zilong zhang Qingping Ke Wei Chen School of Chemical Engineering Northeast Electric Power UniversityJilin 132012China Industrial Catalysis Institute of Zhejiang University of Technology Hangzhou 310014China Key Laboratory of Carbon Materials of Zhejiang Province College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China College of Chemistry and Chemical Engineering Anhui University of TechnologyMaanshan 243002China

In this study,a novel non-metallic carbon-based catalyst co-doped with boron and nitrogen(B,N)was successfully *** precisely controlling the carbonization temperature of a binary mixed ionic liquid,we selectively modified the doping site structure,ultimately constructing a B,N co-doped frustrated Lewis acid-base pair *** catalyst exhibited remarkable catalytic activity,selectivity,and stability in the dehydrochlorination reaction of 1,1,2-trichloroethane(TCE).Detailed characterization and theoretical calculations revealed that the primary active center of this catalyst was the BN_(3)*** to conventional graphitic N structures,the BN_(3)structure had a higher p-band center,ensuring superior adsorption and activation capabilities for TCE during the *** the BN_(3)site,three negatively charged nitrogen atoms acted as Lewis bases,while positively charged boron atoms acted as Lewis *** synergistic interaction facilitated the specific dissociation of chlorine and hydrogen atoms from TCE,significantly enhancing the 1,1-dichloroethene *** this research,we not only explored the active site structure and catalytic mechanism of B,N co-doped catalysts in depth but also provided an efficient,selective,and stable catalyst for the dehydrochlorination of TCE,contributing significantly to the development of non-metallic catalysts.

关键词： B N co-doped sites dehydrochlorination frustrated Lewis acid-base pairs catalytic mechanism

Manipulation of magnetocaloric and elastocaloric effects in Ni-Mn-In alloys by lattice volume and magnetic variation:Effect of Co and Fe co-doping

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Journal of Materials Science & Technology 2024年第5期172卷 156-165页

作者： Xinzeng Liang Chi zhang Jing Bai Jianglong Gu Yudong zhang Claude Esling xiang Zhao Liang Zuo School of Materials Science and Engineering Shenyang University of TechnologyShenyang 110870China Key Laboratory for Anisotropy and Texture of Materials Northeastern UniversityShenyang 110819China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004China State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao 066004China Laboratoire d’Étude des Microstructures et de Mécanique des Matériaux LEM3 CNRSUMR 7239University of Lorraine57045 MetzFrance

The effects of Co and Fe co-doping Ni-Mn-In alloy on the phase stability,lattice parameters,mag-netic properties,and electronic structures are systematically investigated by using the first-principles *** indicate that Fe atoms replace the excess Mn2 atoms by direct and indirect coex-istence(Fe→Mn 2 and Fe→In→Mn2);Co substitutes the Ni atoms by direct substitution(Co→Ni)for the Ni-Mn-In *** austenites all exhibit the ferromagnetic(FM)state for the studied *** NM martensites are in the ferrimagnetic(FIM-1)state for the Ni_(2)Mn_(1.5)In_(0.5),Ni_(2)Mn_(1.25)In_(0.5)Fe 0.25,Ni_(1.75)Mn_(1.5)In_(0.5)Co_(0.25),and Ni_(1.75)Mn_(1.25)In_(0.5)Co_(0.25)Fe 0.25 alloys,while the other compositions are in the FM *** phase stability of austenite and martensite decreases with increasing Co and Fe co-doping.A magnetic-structural coupling transition occurs at x<0.25 and y<*** Ni_(1.91)Mn_(1.5)In_(0.5)Co_(0.08)and Ni_(1.91)Mn_(1.42)In_(0.5)Co_(0.08)Fe_(0.08)alloys exhibit an A→6M→NM transformation,accompanied by a magnetic *** Co and Fe are co-doped,the hybridization strength between Co and Fe is greater than that between Co/Fe and *** enhancement of magnetocaloric and elastocaloric effects is favored by larger magnetization difference(△M)and lattice volume change(△V/V_(0)).Based on the calculated phase stability,magneto-structure coupling,△V/V 0 and c/a ratio,one can predict that the Ni_(2)-x Mn_(1.5)-y In_(0.5)Co x Fe y alloy with Co content 0≤x≤0.25 and Fe content 0≤y≤0.05 is predicted to have good magneto-controlled functional behavior.

关键词： Ni-Mn-In-Co-Fe Phase stability Magnetocaloric effect Elastocaloric effect

Energy Absorption by 3D-Printed Mesh Structures with a Negative Poisson’s Ratio

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Acta Metallurgica Sinica(English Letters) 2024年第1期37卷 205-212页

作者： Wenyu Li Weiming Yang Mingze Li xiang zhang Ping zhang Yucheng Zhao Peijian Chen Haishun Liu School of Mechanics and Civil Engineering China University of Mining and TechnologyXuzhou221116China School of Materials Sciences and Physics China University of Mining and TechnologyXuzhou221116China

A negative Poisson's ratio(NPR)structure represents optimal impact-resistance with applications in various fields,including the crash box in vehicles,which absorbs impact kinetic *** crash box is designed to deform in response to impact,increasing local structural density,which enhances impact resistance *** studies have only focused on the NPR effect in the plane dimension at low-speed *** studies have considered high-speed impact loads on three-dimensional NPR *** have developed two types of AlSi10Mg alloy energy-absorbing structures with NPR using three-dimensional printing technology,and have compared our systems with a conventional hexagonal mesh *** testing involved split-Hopkinson pressure bar measurements,which showed good agreement with dynamic numerical *** subjected to an impact load,the NPR structure exhibited better impact resistance and energy absorption compared with the positive Poisson's ratio *** proposed dual-layer hexagonal structure ensures an NPR effect while exhibiting higher strength and improved stability relative to the conventional concave hexagon structure.

关键词： Negative Poisson’s ratio Energy absorption 3D printing Split-Hopkinson pressure bar Numerical simulation

Real-time,single-particle chemical composition,volatility and mixing state measurements of urban aerosol particles in southwest China

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Journal of Environmental Sciences 2024年第2期136卷 361-371页

作者： Luyao Chen Junke zhang Jiaqi Li Xiaojuan Huang Yuzheng xiang Jing Chen Tingru Pan Wei zhang Faculty of Geosciences and Environmental Engineering Southwest Jiaotong UniversityChengdu 611756China School of Atmospheric Sciences Chengdu University of Information TechnologyChengdu 610225China Sichuan Environmental Monitoring Center Chengdu 610074China

To investigate the volatility of atmospheric particulates and the evolution of other particulate properties(chemical composition,particle size distribution and mixing state)with temperature,a thermodenuder coupled with a single particle aerosol mass spectrometer was used to conduct continuous observations of atmospheric fine particles in Chengdu,southwest *** of their complex sources and secondary reaction processes,the average mass spectra of single particles contained a variety of chemical components(including organic,inorganic and metal species).When the temperature rose from room temperature to280℃,the relative areas of volatile and semi-volatile components decreased,while the relative areas of less or non-volatile components ***(>80%)nitrate and sulfate existed in the form of NH_(4)NO_(3)and(NH_(4))_(2)SO_(4),and their volatilization temperatures were50–100℃and 150–280℃,*** contribution of biomass burning(BB)and vehicle emission(VE)particles increased significantly at 280℃,which emphasized the important role of regional biomass burning and local motor vehicle emissions to the core of *** the increase in temperature,the particle size of the particles coated with volatile or semi-volatile components was reduced,and their mixing with secondary inorganic components was significantly *** formation of K-nitrate(KNO_(3))and K-sulfate(KSO_(4))particles was dominated by liquid-phase processes and photochemical reactions,*** KNO_(3)and BB particles is the key to improving *** new results are helpful towards better understanding the initial sources,pollution formation mechanisms and climatic effects of fine particulate matter in this megacity in southwest China.

关键词： Atmospheric fine particles TD-SPAMS Chemical composition Volatility Mixing state

Lagrangian coherent structure analysis on transport of Acetes chinensis along coast of Lianyungang,China

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Journal of Oceanology and Limnology 2024年第1期42卷 345-359页

作者： Kexin WANG Xueqing zhang Qi LOU Xusheng xiang Ying XIONG College of Environmental Science and Engineering Ocean University of ChinaQingdao 266100China Key Laboratory of Marine Environment and Ecology Ministry of Education of ChinaOcean University of ChinaQingdao 266100China Jiangsu Marine Fisheries Research Institute Nantong 226007China

Spatial heterogeneity or“patchiness”of plankton distributions in the ocean has always been an attractive and challenging scientific issue to *** focused on the accumulation and dynamic mechanism of the Acetes chinensis in the Lianyungang nearshore licensed fishing *** Lagrangian frame approaches including the Lagrangian coherent structures theory,Lagrangian residual current,and Lagrangian particle-tracking model were applied to find the transport pathways and aggregation characteristics of Acetes *** exist some material transport pathways for Acetes chinensis passing through the licensed fishing area,and Acetes chinensis is easy to accumulate in the licensed fishing *** main mechanism forming this distribution pattern is the local circulation induced by the nonlinear interaction of topography and tidal *** the Lagrangian coherent structure analysis and the particle trajectory tracking indicate that Acetes chinensis in the licensed fishing area come from the nearshore *** work contributed to the adjustment of licensed fishing area and the efficient utilization of fishery resources.

关键词： plankton accumulation hydrodynamic model Lagrangian particle-tracking model Lagrangian analysis

Structural Stability of Natural Magnesiochromite at High-Temperature-Pressure Conditions

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Journal of Earth Science 2024年第4期35卷 1196-1203页

作者： Shuyu Jin xiang Wu Yungui Liu Yanfei zhang Chao Wang State Key Laboratory of Geological Processes and Mineral Resources China University of GeosciencesWuhan430074China College of Gems and Materials Hebei GEO UniversityShijiazhuang050031China

The podiform chromitites in the Luobusha ophiolite have been thought to experience a very deep formation,but the maximum depth is still an open ***,we have investigated the structural stability of natural magnesiochromite using the synchrotron-based powder X-ray diffraction and diamond anvil cells up to 48.6 GPa and 2450 *** results have shown that spinel-type magnesiochromite first decomposes into corundum-type‘Cr_(2)O_(3)’+B1-type‘MgO’at 11–14 GPa and 1250–1450 K,then modified ludwigite(mLd)-type‘Mg_(2)Cr_(2)O_(5)’+corundum-type‘Cr_(2)O_(3)’at 14.3–20.5 GPa and 1300–2000 K,and finally CaTi_(2)O_(4)-type phase at 24.5 *** the quenching procession from high-temperature-pressure conditions,the mLd-type phase appeared again and was kept at ambient *** also obtained the isothermal equation states of spinel-type and CaTi_(2)O_(4)-type phases,revealing the composition effect on their *** on the updated results,we propose chromitites could not experience pressure exceeding∼14.3 GPa(approximate maximum depth∼400 km)in the subduction-recycling genesis model.

关键词： chromite high-temperature and high-pressure phase transitions equation of state chromitites genesis

Temperature prediction model in multiphase flow considering phase transition in the drilling operations

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Petroleum Science 2024年第3期21卷 1969-1979页

作者： Yang zhang Yong-An Li xiang-Wei Kong Hao Liu Teng-Fei Sun College of Mechanical and Electrical Engineering Beijing University of Chemical TechnologyBeijing 100027China School of Petroleum Engineering Yangtze UniversityWuhan430000HubeiChina

The study considers gas compression properties,gas slippage,back pressure(BP),phase transition(PT),well depth,and differences in gas-liquid physical properties.A new temperature model for multiphase flow is proposed by considering phase transition in the drilling *** mathematical model of multiphase flow is solved using the finite difference method with annulus mesh division for grid nodes,and a module for multiphase flow calculation and analysis is *** results indicate that the temperature varies along the annulus with the variation of gas influx at the bottom of the *** the process of controlled pressure drilling,as gas slips along the annulus to the wellhead,its volume continuously expands,leading to an increase in the gas content within the annulus,and consequently,an increase in the pressure drop caused by gas *** temperature increases with the increase in BP and decreases in gas influx rate and wellbore *** gas influx,the thermal conductivity coefficient for the gas-drilling mud two phases is significantly weakened,resulting in a considerable change in temperature along the *** the context of MPD,the method of slightly changing the temperature along the annulus by controlling the back pressure is feasible.

关键词： Managed pressure drilling Phase transition Temperature Gas-drilling mud two phase

Cobalt doping amount determines dominant reactive species in peroxymonosulfate activation via porous carbon catalysts co-doped by cobalt and nitrogen

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Journal of Environmental Sciences 2024年第4期138卷 212-226页

作者： xiang Li Limeng Wu Aiqin zhang Shaohua Wu Yan Lin Chunping Yang Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Nanchang Hangkong UniversityNanchang 330063China Academy of Environmental and Resource Sciences School of Environmental Science and EngineeringGuangdong University of Petrochemical TechnologyMaoming 525000China College of Environmental Science and Engineering Hunan University and Key Laboratory of Environmental Biology and Pollution Control(Hunan University)Ministry of EducationChangsha 410082China

Switching the reaction routes in peroxymonosulfate(PMS)-based advanced oxidation processes have attracted much attention but remain ***,a series of Co-N/C catalysts with different compositions and structures were prepared by using bimetallic zeolitic imidazolate frameworks based on ZIF-8 and ZIF-67(x Zn/Co-ZIFs).Results show that Co doping amount could mediate the transformation of the activation pathway of PMS over CoN/*** Co doping amount was less than 10%,the constructed x Co-N/C/PMS system(x≤10%)was singlet oxygen-dominated reaction;however further increasing Co doping amount would lead to the generation and coexistence of sulfate radicals and high-valent cobalt,besides singlet ***,the nitrogen-coordinated Co(Co-NX)sites could serve as main catalytically active sites to generate singlet *** excess Co doping amount caused the formation of Co nanoparticles from which leached Co ions were responsible for the generation of sulfate radicals and high-valent *** to undoped N/C,Co doping could significantly enhance the catalytic *** 0.5%Co-N/C could achieve the optimum degradation(0.488 min^(-1))and mineralization abilities(78.4%)of sulfamethoxazole among the investigated Co-N/C catalysts,which was superior to most of previously reported *** addition,the application prospects of the two systems in different environmental scenarios(pH,inorganic anions and natural organic matter)were assessed and showed different degradation *** study provides a strategy to regulate the reactive species in PMS-based advanced oxidation process.

关键词： Peroxymonosulfate Sulfate radical Singlet oxygen Cobalt Zeolitic imidazolate framework Advanced oxidation process

Characteristic Study of Self-Powered Sensors Based on Native Protein Composite Film

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Energy & Environmental Materials 2024年第1期7卷 222-228页

作者： Jiehui Xue Huijing xiang Yanrong zhang Jun Yang Xia Cao Zhonglin Wang Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 101400China School of Resources Environment and MaterialsSchool of PhysicsScience and TechnologyCenter on Nanoenergy ResearchGuangxi UniversityNanning 530004China Center for Green Innovation School of Mathematics and PhysicsUniversity of Science and Technology BeijingBeijing 100083China Research Centre of Information Technology Shenzhen Institute of Information TechnologyShenzhen 518172China School of Chemistry and Biological Engineering University of Science and Technology BeijingBeijing 100083China School of Materials Science and Engineering Georgia Institute of TechnologyAtlanta GA 30332-0245USA

Flexible electronic sensors composed of flexible film and conductive materials play an increasingly important role in wearable and internet information *** has received more and more attention and made some progress over the ***,it is still a great challenge to prepare biocompatible and highly transparent conductive *** white is a pure natural protein-rich *** cellulose has a good compatibility and high transparency,which is an ideal material for flexible ***,we overcome the problem of poor mechanical flexibility and electrical conductivity of protein,and develop a high transparency and good flexibility hydroxypropylmethyl cellulose/egg white protein composite membrane-based triboelectric nanogenerator('X'-TENG).The experimental results show that the flexible pressure sensor based on'X'-TENG has a high sensitivity,fast response speed,and low detection *** can even be used as a touch/pressure sensing artificial electronic *** can also be made into an intelligent waffle keyboard for recording and tracking users of the *** strategy may provide a new way to easily build flexible electronic sensors and move toward practical applications.

关键词： flexible sensors intelligent sensing natural protein-rich material triboelectric nanogenerators