检索结果-南通市图书馆

An integrated strategy towards the facile synthesis of core-shell SiC-derived carbon@N-doped carbon for high-performance supercapacitors

引用

Journal of Energy Chemistry 2021年第5期30卷 512-521页

作者： Zhongya Pang Guangshi Li Xingli Zou Chenteng Sun Conghui Hu Wei Tang Li Ji Hsien-Yi Hsu Qian Xu xionggang Lu State Key Laboratory of Advanced Special Steel&Shanghai Key Laboratory of Advanced Ferrometallurgy&School of Materials Science and Engineering Shanghai UniversityShanghai 200444China State Key Laboratory of ASIC and System School of MicroelectronicsFudan UniversityShanghai 200433China School of Energy and Environment&Department of Materials Science and Engineering City University of Hong KongKowloon Tong 999077Hong KongChina Shenzhen Research Institute of City University of Hong Kong Shenzhen 518057GuangdongChina

Porous active core-shell carbon material with excellent synergistic effect has been regarded as a prospective material for ***,we report an integrated method for the facile synthesis of carbide-derived carbon(CDC)encapsulated with porous N-doped carbon(CDC@NC)towards highperformance ***(PDA)as nitrogen and carbon sources was simply coated on SiC nanospheres to form SiC@PDA,which was then directly transformed into CDC@NC via a onestep molten salt electro-etching/in-situ doping *** synthesized CDC@NC with hierarchically porous structure has a high specific surface area of 1191 m^(2) g^(-1).The CDC core and NC shell are typical amorphous carbon and more ordered N-doped carbon,*** from its unique dual porous structures,the CDC@NC demonstrates high specific capacitances of 255 and 193 F g^(-1) at 0.5 and20 A g^(-1),*** reaction mechanism of the electro-etching/in-situ doping process has also been investigated through experimental characterizations and theoretical density functional theory *** is suggested that the molten salt electro-etching/in-situ doping strategy is promising for the synthesis of active core-shell porous carbon materials with synergistic properties for supercapacitors without the need for additional doping/activation processes.

关键词： Molten salt Electrochemical etching Core-shell structure Porous carbon In-situ nitrogen doping Supercapacitors

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Hydrogen production from coke oven gas over LiNi/γ-Al_2O_3 catalyst modified by rare earth metal oxide in a membrane reactor

引用

Journal of Natural Gas Chemistry 2009年第4期18卷 407-414页

作者： Zhibin Yang Yunyan Zhang Weizhong Ding Yuwen Zhang Peijun Shen Yuding Zhou Yong Liu Shaoqing Huang xionggang Lu Shanghai Key Laboratory of Modern Metallurgy and Materials Processing Shanghai University Shanghai 200072 China

The performance of LiNi/γ-Al2O3 catalysts modified by rare earth metal oxide （La2O3 or CeO2） packed on BCFNO membrane reactor was discussed for the partial oxidation of methane （POM） in coke oven gas （COG） at 875 ℃. The NiO/γ-Al2O3 catalysts with different amounts of La2O3 and CeO2 were prepared with the same preparation method and under the same condition in order to compare the reaction performance （oxygen permeation, CH4 conversion, H2 and CO selectivity） on the membrane reactor. The results show that the oxygen permeation flux increased significantly with LiNiREOx/γ-Al2O3 （RE = La or Ce） catalysts by adding the element of rare earth especially the Ce during the POM in COG. Such as, the Li15wt%CeO29wt%NiO/γ-Al2O3 catalyst with an oxygen permeation flux of 24.71 ml·cm^-2·min^-1 and a high CH4 conversion was obtained in 875 ℃. The resulted high oxygen permeation flux may be due to the added Ce that inhibited the strong interaction between Ni and Al2O3 to form the NiAl2O4 phase. In addition, the introduction of Ce leads up to an important property of storing and releasing oxygen.

关键词： rare earth metal oxide oxygen permeation membrane reactor

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Influence of Conductivity of Slag on Decarburization Reaction

引用

International Journal of Minerals,Metallurgy and Materials 1998年第1期12卷 20-22页

作者： xionggang Lu Fushen Li Lifen Li Kouchih Chou (Laboratory on Solid Electrolytes and Metallurgical Testing Techniques, University of Science and Technology Beijing, Beijin 100083, China) Laboratory on Solid Electrolytes and Metallurgical Testing Techniques University of Science and Technology Beijing Beijing 100083 China

By altering the electrochemical properties of slag, the decarburization reaction of Fe3+-based slag withFe-C droplet was studied. The results showed that a lot of free electrons and holes exist in the slag containing transition metal oxides (such as TiO2 and Fe2O3). So electronic conduction in the slag increases. Finally, it led to the increment of the decarburization reaction rate between slag and Fe-C droplet, and mass fraction of carbon remaining indroplet decreases to a lower level.

关键词： smelt slag electronic conductivity decarburization reaction

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Oxygen permeability and CO_2-tolerance of Ce_(0.8)Gd_(0.2)O_(2-δ)-Ln BaCo_2O_(5+δ) dual-phase membranes

引用

Journal of Energy Chemistry 2015年第1期24卷 15-22页

作者： Longfei Luo Hongwei Cheng Guangshi Li xionggang Lu Bo Jiang Shanghai Key Laboratory of Modern Metallurgy and Materials Processing Shanghai University

A series of oxygen permeable dual-phase composite oxides 60 wt% Ce0.8Gd0.2O2-δ-40 wt% LnBaCo2O5＋δ （CGO-LBCO, Ln = La, Pr, Nd, Sin, Gd and Y） were synthesized through a sol-gel route and effects of the Ln3＋ cations on their phase structure, oxygen permeability and chemical stability against CO2 were investigated systemically by XRD, SEM, TG-DSC and oxygen permeation experiments. XRD patterns reveal that the larger Ln3＋ cations （La3＋, Pr3＋ and Nd3＋） successfully stabilized the double-layered perovskite structure of sintered LBCO, while the smaller ones （Sm3＋, Gd3＋, and Y3＋） resulted in the partial decomposition of LBCO with some impurities formed. CGO-PBCO yields the highest oxygen permeation flux, reaching 2.8× 10^-7 ***-2 at 925 ℃ with 1 mm thickness under air/He gradient. The TG-DSC profiles in 20 mol% CO2/N2 and oxygen permeability experiments with CO2 as sweep gas show that CGO-YBCO demonstrates the best chemical stability against CO2, possibly due to its minimum basicity. The stable oxygen permeation flux of CGO-YBCO under CO2 atmosphere reveals its potential application in the oxy-fuel combustion route for CO2 capture.

关键词： oxygen permeability dual-phase membrane fluorite double-layered perovskite chemical stability C02 capture

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Influence of rare earth promoters on the performance of Ni/Mg(Al)O catalysts for hydrogenation and steam reforming of toluene

引用

Rare Metals 2009年第6期28卷 582-589页

作者： ZHANG Yuwen CHENG Hongwei LU xionggang DING Weizhong ZHOU Guozhi Shanghai Key Laboratory of Modem Metallurgy and Materials Processing School of Materials Science and Engineering Shanghai University Shanghai 200072 China School of Metallurgical and Ecological Engineering University of Science and Technology Beijing Beijing 100083 China

CeO2-, La2O3-, and ZrO2-promoted Ni/Mg（Al）O catalysts synthesized by hydrotalcite-type precursors have been investigated with respect to catalytic activity and carbon formation in the hydrogenation and steam reforming of toluene as a model tar compound. X-ray diffraction （XRD）, Brunauer-Emmett-Teller （BET） specific surface area and Hz-temperature programmed reduction （TPR） were used to observe the characteristics of the prepared catalysts. The carbon formation and its amount on the used catalysts were examined by transmission electron microscope （TEM）, scanning electron microscope （SEM） and thermogravimetric （TG）. The trend of catalytic activity as derived from the experimental results followed the order： Ni-Ce〉Ni-La〉Ni-Zr〉Ni. The catalyst modified with CeO2 exhibited the highest catalytic performance and had good carbon resistance in the hydrogenation and steam reforming of toluene. A toluene conversion of 96.8%, a CH4 yield of 45.2% and a CO yield of 50.4% have been achieved. The addition of promoters led to better dispersion of nickel species and higher interaction nickel-support, which were favorable for increasing the catalytic activity and effectively preventing carbon formation.

关键词： hydrogen production hydrogenation rare earth hydrotalcite

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Oxygen permeation and phase structure properties of partially A-site substituted BaCo_(0.7)Fe_(0.225)Ta_(0.075)O_(3-δ) perovskites

引用

Journal of Energy Chemistry 2014年第2期23卷 164-170页

作者： Bo Jiang Hongwei Cheng Longfei Luo xionggang Lu Naijun Zhang Jizhong Liu Shanghai Key Laboratory of Modern Metallurgy and Materials Processing Shanghai University

***0.225Ta0.07503-δ （BRCFT, R = Ca, La or Sr） membranes were synthesized by a solid-state reaction. Metal cation Ca2＋, La3＋ or Sr2＋ doping on A-site partially substituted Ba2＋ in ***0.225Ta0.07503-δ oxides, and its subsequent effects on phase structure stability, oxygen permeability and oxygen desorption were systematically investigated by XRD, TG-DSC, Hz-TPR, O2-TPD techniques and oxygen permeation experiments. The partial substitution with Ca2＋, La3＋ or Sr2＋, whose ionic radii are smaller than that of Ba2＋, succeeded in stabilizing the cubic perovskite structure without formation of impurity phases, as revealed by XRD analysis. Oxygen-involving experi- ments showed that BRCFT with A-site fully occupied by Ba2＋ exhibited good oxygen permeation flux under He flow, reaching about 2.3 ***-l .cm-2 at 900 with I mm thickness. Of all the membranes, BLCFT membrane showed better chemical stability in CO2, owing to the reduction in alkalinity of the mixed conductor oxide by La doping. In addition, we also found the stability of the perovskite structure under reducing atmospheres was strengthened by increasing the size of A-site cation （Ba2＋〉La3＋〉SrZ＋〉Ca2＋）.

关键词： perovskite phase stability oxygen permeation A-site substituted

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Electrochemical Characteristic of Decarburization Reaction

引用

International Journal of Minerals,Metallurgy and Materials 1999年第1期13卷 27-30页

作者： xionggang Lu Fushen Li Lifen Li Kouchih Chou (Applied Science School, University of Science and Technology Beijing, Beijing 100083, China)(Material Science and Engineering School, Shanghai University, Shanghai 200072, China) Applied Science School University of Science and Technology Beijing Beijing 100083 China Material Science and Engineering School Shanghai University Shanghai 200072 China

The electrochemical mechanism of the reaction between Fe-C melts and CaO-SiO2-Al2O3-FeOx slag systems has been carried out. The experimental results suggest that the final content of carbon in melt increases as the partial oxygen pressure of gas decreases no matter whether there is electronic conductor or not. However, the final content of carbon in the system with electronic conductor is much lower than that without electronic conductor. It can be deduced that the transfer ability of oxygen in slag is dominated by electrons. When an electronic conductor exists, an easy pathway for the electrons is provided and the oxygen transfer rate is accelerated.

关键词： melt-slag reaction decarburization electrochemistry electronic conductor

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Electrolysis of Converter Matte in Molten CaCl<sub>2</sub>-NaCl

引用

Journal of Materials Science and Chemical Engineering 2018年第2期6卷 1-11页

作者： Dan Wang Changyuan Lu Xingli Zou Kai Zheng Zhongfu Zhou xionggang Lu State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy School of Materials Science and Engineering Shanghai University Shanghai China Department of Physics Aberystwyth University Aberystwyth UK

The electrolytic production of nickel-copper alloy by electrochemical reduction of converter matte in molten salt has been investigated. The sintered solid porous pellets of Ni3S2, Cu2S and converter matte were electrolyzed at a voltage of 3.0 V in molten CaCl2-NaCl under the protection of argon gas at 700℃, respectively. The electro-reduction processes were investigated and the products were characterized. The results show that the molten salt electro-reduction process can be used to produce nickel, copper and nickel-copper alloy directly from Ni3S2, Cu2S and converter matte precursors in molten CaCl2-NaCl, respectively. CaS would be formed as the intermediate compound during the electro-reduction process, and then the formed CaS can be gradually decomposed and removed with the increase of the electrolysis time. The experimental results show that the molten salt electro-reduction process has the potential to be used for the reduction of sulfide minerals in molten CaCl2-NaCl.

关键词： Converter Matte Electro-Reduction Nickel-Copper Alloy Molten CaCl2-NaCl Solid-State Electrochemistry

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Wafer-Scale Synthesis of WS_(2)Films with In Situ Controllable p-Type Doping by Atomic Layer Deposition

引用

Research 2021年第1期2021卷 1424-1432页

作者： Hanjie Yang Yang Wang Xingli Zou Rongxu Bai Zecheng Wu Sheng Han Tao Chen Shen Hu Hao Zhu Lin Chen David W.Zhang Jack C.Lee xionggang Lu Peng Zhou Qingqing Sun Edward T.Yu Deji Akinwande Li Ji State Key Laboratory of ASIC and System School of MicroelectronicsFudan UniversityShanghai 200433China State Key Laboratory of Advanced Special Steel School of Materials Science and EngineeringShanghai UniversityShanghai 200444China Microelectronics Research Center Department of Electrical and Computer EngineeringThe University of Texas at AustinAustin78758 TexasUSA

Wafer-scale synthesis of p-type TMD films is critical for its commercialization in next-generation electro/*** this work,wafer-scale intrinsic n-type WS_(2)films and in situ Nb-doped p-type WS_(2)films were synthesized through atomic layer deposition(ALD)on 8-inchα-Al_(2)O_(3)/Si wafers,2-inch sapphire,and 1 cm^(2)GaN substrate *** Nb doping concentration was precisely controlled by altering cycle number of Nb precursor and activated by ***_(2)n-FETs and Nb-doped p-FETs with different Nb concentrations have been fabricated using CMOS-compatible processes.X-ray photoelectron spectroscopy,Raman spectroscopy,and Hall measurements confirmed the effective substitutional doping with *** on/off ratio and electron mobility of WS_(2)n-FET are as high as 105 and 6.85 cm^(2)V^(-1)s^(-1),*** WS_(2)p-FET with 15-cycle Nb doping,the on/off ratio and hole mobility are 10 and 0.016 cm^(2)V^(-1)s^(-1),*** p-n structure based on n-and p-type WS_(2)films was proved with a 10^(4)rectifying *** realization of controllable in situ Nb-doped WS_(2)films paved a way for fabricating wafer-scale complementary WS_(2)FETs.

关键词： sapphire doping realization

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Hybrid Procedure for Thoracic Aortic Disease

引用

Journal of Huazhong University of Science and Technology(Medical Sciences) 2010年第5期30卷 666-668页

作者：孙图成王刚张凯伦梁惠民蒋雄刚 Department of Cardiovascular Surgery Union HospitalTongji Medical CollegeHuazhong University of Science and Technology

Form 2008 to 2009, four patients with complex thoracic aortic disease, including aortic aneurysms and dissections, were successfully treated in our department with a new treatment approach:hybrid *** open surgery and endovascular repair were performed in these patients without deep hypothermia or circulatory *** to those who underwent traditional open surgery in the same period, time of mechanical ventilation and ICU stay was decreased in these four *** of them were discharged soon after operation without postoperative complications or *** result suggests that this new approach could be an option for thoracic aortic disease, but long-term and large-population studies are still required to demonstrate the safety and validity.

关键词： hybrid procedure thoracic aortic disease case report

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：