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Regulating surface base of LiCoO_(2) to inhibit side reactions between LiCoO_(2) and sulfide electrolyte

Rare Metals 2023年第12期42卷 4128-4141页

作者： Kai Yang Rong-Zheng Tian Zhen-Yu Wang Hong-Zhou Zhang Yue Ma xi-xi shi Da-Wei Song Lian-Qi Zhang Ling-Yun Zhu School of Materials Science and Engineering Tianjin University of TechnologyTianjin 300384China Guilin Electrical Equipment Scientifie Research Institute Co.Lud Guilin 541004China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China School of Materials Science and Engineering Anhui UniversityHefei 230601China

The interface instability between layered oxide cathode and sulfide electrolyte is a key point affecting the perform ance of sulfide-based all-solid-state lithium batteries.Coating with fast-ionic conductor and constructing core-shell structure can effectively alleviate the interfacial side reactions and improve the interfacial stability between layered oxide and sulfide electrolyte.However,what have been neglected is the surface base(including Li_(2)CO_(3) and LiOH)of layered oxide can also affect the interfacial stability.To clarify this point clearly and improve the interfacial stability,the surface base of LiCoO_(2)(LCO)is regulated and investigated in this work.First,LCO with surface base Li_(2)CO_(3)(LCO@Li_(2)CO_(3))is prepared by the reaction of Co_(3)O_4 and excess Li_(2)CO_(3).Then,the bare LCO is obtained after LCO@Li_(2)CO_(3) is washed with deionized water and calcined again.Besides,LCO with surface base Li_(2)O(LCO@Li_(2)O)is also prepared with the bare LCO and LiOH.As a result,the electrochemical performances of LCO@Li_(2)O are significantly improved and much higher than those of LCO@Li_(2)CO_(3) and the bare LCO electrodes.In particular,LCO@Li_(2)O-2 cathode display the most outstanding electrochemical performances(discharge capacity138.4 mAh·g^(-1)at 0.2C,105 mAh·g^(-1)at 2C and a capacity retention of 95.4%after 150 cycles at 0.5C).The high discharge capacity and excellent cycle stability of LCO@Li_(2)O electrode confirm the effectiveness of regulating the surface base of layered oxide from Li_(2)CO_(3) to Li_(2)O.The surface base regulating is expected to be a simple but effective strategy to construct the stable interface between the cathode and the sulfide electrolyte of the all-solid-state lithium batteries.

关键词： All-solid-state lithium battery Sulfide electrolyte LiCoO_(2) Surface base Interfacial stability

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Electrochemical performance of LiNi_(0.5)Mn_(0.5)O_2 with different synthesis methods

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Rare Metals 2015年第8期34卷 580-585页

作者： Hong Li Qiang Xu xi-xi shi Da-Wei Song Lian-Qi Zhang Department of Applied Chemistry School of Chemical and Engineering Tianjin University School of Materials Science and Engineering Tianjin University of Technology

Li Ni0.5Mn0.5O2 as a cathode material for Li-ion battery was prepared by the metal acetate decomposition method, sol–gel method, and carbonate co-precipitation method, respectively. The influences of synthesis methods on the physical and electrochemical behaviors of Li Ni0.5Mn0.5O2 were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM) and electrochemical tests. XRD patterns show that both the sol–gel and carbonate co-precipitation methods can form single phase of layered structure, while a trace of Ni O impurity is observed via the metal acetate decomposition method. SEM results show the as-prepared carbonate particle has a spherical morphology with an average diameter of 10 lm, consisted of primary nano-sized particles with particle diameter of200 nm. The sample prepared by the carbonate co-precipitation method exhibits the highest discharge specific capacity and the best cycling stability, which results from the steady homogeneity of precursor constant by the fixation of CO2-3group. It can deliver an initial discharge specific capacity of 186.3 m Ahág-1, and retain 170 m Ahág-1after100 cycles at a current rate of 20 m Aág-1in the voltage range of 2.5–4.7 V at 25 °C. Moreover, even at the high temperature of 55 °C, it still delivers a reversible specific capacity of 222.6 m Ahág-1with little capacity loss after 30 cycles.

关键词： Sol–gel Carbonate co-precipitation LiNi0.5Mn0.5O2

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Structural Characteristics and Influencing Factors of Carbon Emission Spatial Association Network:A Case Study of Yangtze River Delta City Cluster,China

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Chinese Geographical Science 2024年第4期34卷 689-705页

作者： BI xi SUN Renjin HU Dongou shi Hongling ZHANG Han School of Economics and Management China University of Petroleum(Beijing)Beijing 102249China China Petroleum Planning&Engineering Institute Beijing 100083China

City cluster is an effective platform for encouraging regionally coordinated development.Coordinated reduction of carbon emissions within city cluster via the spatial association network between cities can help coordinate the regional carbon emission management,realize sustainable development,and assist China in achieving the carbon peaking and carbon neutrality goals.This paper applies the improved gravity model and social network analysis(SNA)to the study of spatial correlation of carbon emissions in city clusters and analyzes the structural characteristics of the spatial correlation network of carbon emissions in the Yangtze River Delta(YRD)city cluster in China and its influencing factors.The results demonstrate that:1)the spatial association of carbon emissions in the YRD city cluster exhibits a typical and complex multi-threaded network structure.The network association number and density show an upward trend,indicating closer spatial association between cities,but their values remain generally low.Meanwhile,the network hierarchy and network efficiency show a downward trend but remain high.2)The spatial association network of carbon emissions in the YRD city cluster shows an obvious‘core-edge’distribution pattern.The network is centered around Shanghai,Suzhou and Wuxi,all of which play the role of‘bridges’,while cities such as Zhoushan,Ma'anshan,Tongling and other cities characterized by the remote location,single transportation mode or lower economic level are positioned at the edge of the network.3)Geographic proximity,varying levels of economic development,different industrial structures,degrees of urbanization,levels of technological innovation,energy intensities and environmental regulation are important influencing factors on the spatial association of within the YRD city cluster.Finally,policy implications are provided from four aspects:government macro-control and market mechanism guidance,structural characteristics of the‘core-edge’network,reconfiguration and optimization of the spatial layout of t

关键词： carbon emission spatial association network social network analysis(SNA) quadratic assignment procedure(QAP)model Yangtze River Delta city cluster China

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Nanofluidic memristor based on the elastic deformation of nanopores with nanoparticle adsorption

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National Science Review 2024年第4期11卷 46-54页

作者： xi Zhou Yuanyuan Zong Yongchang Wang Miao Sun Deli shi Wei Wang Guanghua Du Yanbo xie Department of Chemistry and Chemical Engineering Northwestern Polytechnical University School of Physical Science and Technology Northwestern Polytechnical University School of Aeronautics and Institute of Extreme Mechanics Northwestern Polytechnical University Institute of Modern Physics Chinese Academy of Sciences

The memristor is the building block of neuromorphic computing. We report a new type of nanofluidic memristor based on the principle of elastic strain on polymer nanopores. With nanoparticles absorbed at the wall of a single conical polymer nanopore, we find a pinched hysteresis of the current within a scanning frequency range of 0.01–0.1 Hz, switching to a diode below 0.01 Hz and a resistor above 0.1 Hz. We attribute the current hysteresis to the elastic strain at the tip side of the nanopore, caused by electrical force on the particles adsorbed at the inner wall surface. Our simulation and analytical equations match well with experimental results, with a phase diagram for predicting the system transitions. We demonstrate the plasticity of our nanofluidic memristor to be similar to a biological synapse. Our findings pave a new way for ionic neuromorphic computing using nanofluidic memristors.

关键词： nanofluidics memristor neurocomputing elastic deformation

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Six million Q factor micro fused silica shell resonator with teeth-like tines released by femtosecond laser-assisted chemical etching

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Science China(Technological Sciences) 2024年第6期67卷 1923-1932页

作者： ZHAO Tao shi Yan LU Kun xi xiang WU XueZhong xiAO DingBang College of Intelligence Science and Engineering National University of Defense TechnologyChangsha410073China

The quality factor(Q factor)is a crucial performance parameter for resonators.In this paper,a novel release method for highquality micro fused silica shell resonators with teeth-like tines with good surface morphology is proposed.This method is based on femtosecond laser-assisted chemical etching.First,the optimal energy range of femtosecond laser modification is obtained through mechanism analysis.Second,the optimal parameters for a straight line and arc pattern are determined by optimizing the average output power,processing speed,and processing spacing.The results demonstrate why edge breakage in rounded corners is easy under different parameters.Finally,according to these conclusions,the processing is performed on a micro fused silica shell resonator with a Q factor exceeding 6 million.In addition,subsurface damage is rare throughout the fabrication process,and the surface roughness of the released cross section reaches the nanometer level.The improved Q factor helps suppress mechanical thermal noise and reduce zero bias and zero bias drift,constituting the primary method for enhancing the performance of the resonant gyroscope.

关键词： micro hemispherical resonator fused silica laser-assisted chemical etching quality factor

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Heterostructure of 2D MoSe_(2) nanosheets vertically grown on bowllike carbon for high-performance sodium storage

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Nano Research 2024年第5期17卷 4023-4030页

作者： Nianxiang shi Guangzeng Liu Baojuan xi Xuguang An Changhui Sun Shenglin xiong School of Chemistry and Chemistry Engineering Qilu Normal UniversityJinan 250200China School of Chemistry and Chemical Engineering Shandong UniversityJinan 250100China School of Mechanical Engineering Chengdu UniversityChengdu 610106China

Transition metal dichalcogenides are attractive anode materials for sodium ion batteries(SIBs)due to their high theoretical capacity and large interlayer spacing.However,its practical application is hampered by the sluggish kinetics of Na^(+)insertion and structure collapse caused by Na^(+)insertion/deinsertion.Herein,the heterostructures of MoSe_(2) nanosheets vertically growing on bowl-like carbon(MoSe_(2)@C)are designed and prepared by a template method coupled with selenization treatment to boost storage sodium performance.The hollow and collapse could provide enough storage space for Na^(+)and alleviate the volume expansion during the charge/discharge processes.MoSe_(2) nanosheets vertically grown on carbon could expose more active sites for adsorbing Na^(+)to enhance the utilization rate of electrode materials.Moreover,building heterostructures by combining different phase components could facilitate Na^(+)diffusion and advance reaction kinetics.Benefiting from these merits,the bowl-like MoSe_(2)@C shows outstanding reversible capacity(356.8 mAh·g^(-1) after 1500 cycles at 1 A·g^(-1))and remarkable rate performance(249.9 mAh·g^(-1)10 A·g^(-1)).

关键词： MoSe_(2)nanosheets bowl-like carbon heterostructure sodium ion batteries

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Insights into plant salt stress signaling and tolerance

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Journal of Genetics and Genomics 2024年第1期51卷 16-34页

作者： Huapeng Zhou Haifan shi Yongqing Yang xixian Feng xi Chen Fei xiao Honghui Lin Yan Guo Key Laboratory of Bio-Resource and Eco-Environment of Ministry of Education College of Life SciencesSichuan UniversityChengduSichuan 610064China State Key Laboratory of Plant Environmental Resilience China Agricultural UniversityBeijing 100193China College of Grassland Science Nanjing Agricultural UniversityNanjingJiangsu 210095China xinjiang Key Laboratory of Biological Resources and Genetic Engineering College of Life Science and TechnologyXinjiang UniversityUrumqiXinjiang 830046China

Soil salinization is an essential environmental stressor,threatening agricultural yield and ecological security worldwide.Saline soils accumulate excessive soluble salts which are detrimental to most plants by limiting plant growth and productivity.It is of great necessity for plants to efficiently deal with the adverse effects caused by salt stress for survival and successful reproduction.Multiple determinants of salt tolerance have been identified in plants,and the cellular and physiological mechanisms of plant salt response and adaption have been intensely characterized.Plants respond to salt stress signals and rapidly initiate signaling pathways to re-establish cellular homeostasis with adjusted growth and cellular metabolism.This review summarizes the advances in salt stress perception,signaling,and response in plants.A better under-standing of plant salt resistance will contribute to improving crop performance under saline conditions using multiple engineering approaches.The rhizosphere microbiome-mediated plant salt tolerance as well as chemical priming for enhanced plant salt resistance are also discussed in this review.

关键词： Salt stress Salt perception Salt response and signaling Plant salt tolerance Chemical priming Rhizosphere microbiome

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A method for support stiffness failure identification in a steel spring floating slab track of urban railway: a case study in China

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2024年第3期25卷 206-222页

作者： Junyuan ZHENG Caiyou ZHAO Duojia shi Ping WANG Jian WANG Bolong JIANG xi SHENG Key Laboratoryof High-speed Railway Engineering Ministry of EducationSouthwest Jiaotong UniversityChengdu 60031China School of Civil Engineering Southwest Jiaotong UniversityChengdu 610031China 01 DYNA(Qingdao)Test&Data Co. Ltd.Qingdao 266000China Rail Transit Digital Construction and Measurement Technology National Engineering Research Center China Railway Design CorporationTianjin300308China Institute of Urban Smart Transportation&Safety Maintenance Shenzhen UniversityShenzhen 518060China

The extensive use of steel spring floating slab tracks has effectively addressed the challenge of alleviating the environmental vibrations induced by urban rail transit systems.However,under the combined action of train dynamic loads and complex environmental factors,problems,such as the fracture of steel spring vibration isolators and suspension vibrations induced by the uneven settlement of the base,often occur.The failure of isolator support stiffness is often hidden in its early stages and is challenging to identify by conventional detection methods.At the same time,it will aggravate the wheel-rail interaction,accelerate the deterioration of track structure,and even affect the driving safety.This study first establishes a detailed coupled train-floating slab track-foundation analytical model.Then the influence of the vibration isolator support stiffness failure on the dynamic indices of the floating slab track system response is analyzed.A set of defect identification methods that can detect the number of failed steel springs,severity of damage,and their location is proposed.Finally,an intelligent monitoring system for support stiffness of floating slab track is built by combining the density-based spatial clustering of applications with noise algorithm and statistical data analysis and is applied to a rail line in southern China.During a three-year monitoring campaign,a suspension failure and a fracture of a steel spring were each successfully detected and detailed failure information was obtained.Field investigation results were consistent with the damage identification results.After repair,the track structure dynamic response returned to the average pre-damage level and further deterioration had been arrested.The proposed damage identification methods and monitoring system provide an approach for intelligent identification of track structure support stiffness failures.

关键词： Floating slab track Support stiffness Detailed analytical model Failure identification Monitoring system

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Static recrystallization behaviors and mechanisms of 7Mo super-austenitic stainless steel with undissolved sigma precipitates during double-stage hot deformation

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Journal of Iron and Steel Research(International) 2024年第2期31卷 475-487页

作者： shi-guang Xu Jin-shan He Run-ze Zhang Fu-cheng Zhang xi-tao Wang Collaborative Innovation Center of Steel Technology University of Science and Technology BeijingBeijing100083China State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao066004HebeiChina Shandong Provincial Key Laboratory for High Strength Lightweight Metallic Materials Advanced Materials InstituteQilu University of Technology(Shandong Academy of Science)Jinan250353ShandongChina

Static recrystallization(SRX)behaviors and corresponding recrystallization mechanisms of 7Mo super-austenitic stainless steel were studied under different deformation conditions.The order of influence of deformation parameters on static recrystallization behaviors,from high to low,is followed by temperature,first-stage strain and strain rate.Meanwhile,the effect of holding time on static recrystallization behaviors is significantly controlled by temperature.In addition,with the increase in temperature from 1000 to 1200°C,the static recrystallization mechanism evolves from discontinuous static recrystallization and continuous static recrystallization(cSRX)to metadynamic recrystallization and cSRX,and finally to cSRX.The cSRX exists at all temperatures.This is because high stacking fault energy(56 mJ m−2)promotes the movement of dislocations,making the deformation mechanism of this steel is dominated by planar slip of dislocation.Large undissolved sigma precipitates promote static recrystallization through particle-stimulated nucleation.However,small strain-induced precipitates at grain boundaries hinder the nucleation of conventional SRX and the growth of recrystallized grains,while the hindering effect decreases with the increase in temperature.

关键词： 7Mo super-austenitic stainless steel Double-stage hot deformation Conventional static recrystallization Metadynamic recrystallization Strain-induced precipitation

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Fluoro-functionalized plant biomass adsorbent:Preparation and application in extraction of trace perfluorinated compounds from environmental water samples

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Journal of Environmental Sciences 2024年第3期137卷 703-715页

作者： xi Tan Yan shi Chun-Feng Ma Quan Chi Yu-Hang Yang Wen-xiang Zhang Hua-Ming xiao xian Wang Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission School of Chemistry and Materials ScienceSouth-Central Minzu UniversityWuhan 430074China School of Pharmaceutical Sciences South-Central Minzu UniversityWuhan 430074China Key Laboratory of Oilseeds Processing of Ministry of Agriculture Hubei Key Laboratory of Lipid Chemistry and NutritionOil Crops Research Institute of the Chinese Academy of Agricultural SciencesWuhan 430062China

Perfuorinated compounds(PFCs)are toxic and widely present in the environment,and therefore effective adsorbents are required to remove PFCs from environmental water.In the present study,a new type of fuorinated biomass materials was synthesized via an ingenious fuorosilanization reaction.These adsorbents were applied for the adsorption of 13typical PFCs,including perfuorocarboxylic acids(PFCAs)and perfuorosulfonic acids(PFSAs).By comparing their adsorption performance,Fluorinated cedar slag(FCS)was discovered to have the best absorption efficiency and enabled highly efficient enrichment of PFCs.The adsorption recovery of FCS with the investigated PFCs is greater than 90%under the optimal adsorption condition.Ascribed to the high affinity of F-F sorbent-sorbate interaction,FCS had good adsorption capacities of PFCs from aqueous solution,with the maximum adsorption capacity of 15.80 mg/g for PFOS and 10.71 mg/g for PFOA,respectively.Moreover,the adsorption time could be achieved in a short time(8 min).Using the FCS absorbent,an innovative FCS-solid phase extraction assisted with high performance liquid chromatography-electrospray-tandem mass spectrometry(FCS-SPE-HPLC-ESI-MS/MS)method was first developed to sensitively detect PFCs in the environmental water samples.The intra-day and inter-day recovery rates of the 13 compounds ranged from 90.7%-104.3%,with the RSD of 2.1%-4.7%(intra-day)and 2.5%-8.5%(inter-day),respectively.This research demonstrates the potential of the newly fuoro-functionalized plant biomass to adsorb PFCs from environmental water,with the advantages of high adsorption efficiencies,high antiinterference,easy operation and low economic cost.

关键词： Fluoro-functionalized biomass Perfuorinated compounds(PFCs) Adsorption efficiency Mass spectrometry(MS) Fluorinated cedar slag(FCS)

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