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Science China Chemistry 2024年第11期 3657-3661页

作者： Lu-Lu Ma Jiaqi Liu Kang Zhou Zixuan Cao Jiafeng Miao Guo-Ping yang yao-yu Wang Jing Li Hao Wang Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of PhysicoInorganic Chemistry College of Chemistry & Materials Science Northwest University Hoffmann Institute of Advanced Materials Shenzhen Polytechnic University Shenzhen Senior High School Department of Chemistry and Chemical Biology Rutgers University

Selective adsorption of paraffins over olefins（mostly C2 and C3） by porous solids could offer tremendous advantages for the purification of olefins, which is, however, challenging as it has stringent requirements on the pore dimensions and pore surface chemistry of the adsorbent. We report here a metal-organic framework（MOF） with novel topology, y3（μ3-OH）(TCMPB)2(denoted as HIAM-316, TCMPB4-= 1,2,4,5-tetra（4-carboxy-3-methylphenyl）benzene), which shows reversed separation of C2H6/C2H4and C3H8/C3H6simultaneously. The ideal adsorbed solution theory（IAST） selectivities for equimolar binary mixtures of C2H6/C2H4and C3H8/C3H6were calculated to be 1.67 and 1.23 at 1 bar and 298 K for HIAM-316. Its capability of removing paraffines from paraffin/olefin mixtures is validated by breakthrough measurements. Molecular simulations reveal that the preferential adsorption of paraffins over olefins by HIAM-316 may be attributed to the abundant carboxylate oxygen atoms along its channel.

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A MOF built on 8-connected ynodes demonstrates simultaneous reverse adsorptive separation: ethane over ethylene and propane over propylene

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Science China Chemistry 2024年

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Cr^(3+)掺杂y_(3)Al_(5)O_(12)-Al_(2)O_(3)的光致发光和温度传感特性研究

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燕山大学学报 2024年第2期48卷 171-180页

作者：徐伟姚淼燕山大学电气工程学院河北秦皇岛066004

为了开发具有高发光效率和高测温灵敏度的光学温度传感材料,采用高温固相法合成了一系列Cr^(3+)掺杂y_(3)Al_(5)O_(12)-xAl_(2)O_(3)(x=0,0.5,1.25,2,2.75,3.5)固熔体。利用x射线衍射、扫描电子显微镜、傅里叶红外光谱、稳态激发和发... 详细信息

为了开发具有高发光效率和高测温灵敏度的光学温度传感材料,采用高温固相法合成了一系列Cr^(3+)掺杂y_(3)Al_(5)O_(12)-xAl_(2)O_(3)(x=0,0.5,1.25,2,2.75,3.5)固熔体。利用x射线衍射、扫描电子显微镜、傅里叶红外光谱、稳态激发和发射光谱表征,详细研究了y_(3)Al_(5)O_(12)中Al_(2)O_(3)的掺杂浓度对其结构和发光性能的影响。研究表明,提高Al_(2)O_(3)掺杂量可以增加固熔体中的八面体配位,同时削弱了晶体场强度,有利于Cr^(3+)的发光。在303~773 K温度范围内,利用该材料中Cr^(3+)荧光寿命以及热耦合能级荧光强度比的温度依赖特性进行测温研究,两种方法的相对测温灵敏度分别在500 K时达到最大值0.802%K^(-1),在303 K时达到最大值0.977%K^(-1)。除此之外,本文首次提出利用激光强度与荧光强度之比作为测温参数的比率型测温方法,在773 K时取得最大相对测温灵敏度为1.036%K^(-1)。上述研究结果表明,Cr^(3+)掺杂y_(3)Al_(5)O_(12)-xAl_(2)O_(3)固熔体材料具有良好的光学温度传感特性,三种不同模式的测温方法为该材料在发光测温领域的应用提供了广阔的前景。

关键词：光谱测量 Cr^(3+)离子固熔体光致发光光学温度传感

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Coupling coordination analysis of Mazu culture,socio-economy and ecological environment of Meizhou Island

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Ecological Economy 2024年第1期20卷 85-100页

作者： FU Wei-jia WU ying-qi LUO Zi-xuan yao Jun-bing FU Li-jun College of International Management The University of SheffieldWestern BankSheffieldSouth YorkshireS102TNUK Faculty of Business Lingnan UniversityHongkong999077CHINA School of Business Administration Jimei UniversityXiamen 361021CHINA Putian Kelon Environmental Protection Technology Co. LTDPutian 351100CHINA

Taking the pilgrimage,tourism and cultural island of Meizhou Island as an example,the evaluation index system of the coupling and coordinated development of“Mazu culture,socio-economy,eco-environment”(MSE)compound system was *** index weights were determined by AHP-entropy method,and the coupling degree,coordinated degree,comprehensive evaluation index and grey correlation degree of MSE system of Mazu Island from 2012 to 2022 were *** results showed that:(1)the comprehensive evaluation indexes of the three subsystems was on the rise in general,but the evaluation index of the ecological subsystems increased relatively slowly.(2)The coupling degree was only in the running-in stage in 2012,and the other years were in the coordinated coupling stage.(3)The coupling coordination degree increased from 0.35 in 2012 to 0.82 in 2022,the coupling coordination level was changed from mild imbalance to good coordination.(4)Through the comparison of grey correlation degree,the 24 indexes in the evaluation index system had great influence on the coupling coordination degree of MSE *** coupling coordination degree was closely related to the development of socio-economy and the spread of Mazu *** the rapid development of tourism brought about by the spread of Mazu culture,the pressure on the ecological environment will be *** with the rapid growth of tourism and economy,it is equally important to strengthen environmental protection and pay attention to the quality of ecological environment development.

关键词： Meizhou Island Mazu culture socio-economy ecological environment comprehensive evaluation index coupling coordination degree

基于状态空间法的平面圆弧曲梁面外动力学分析

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工程力学 2024年第S1期41卷 89-97页

作者：刘兴喜姚媛徐荣桥浙江理工大学土木工程系浙江杭州310018 浙江理工大学图书馆浙江杭州310018 浙江大学土木工程系浙江杭州310058

该文通过选择广义位移和与其对偶的广义力作为状态变量,建立了平面圆弧曲梁面外动力学问题的状态方程列式,并求解了工程中常见的四种边界条件下圆弧曲梁面外自由振动的频率和模态。利用状态空间列式和辛内积的概念,建立了振动模态关于... 详细信息

该文通过选择广义位移和与其对偶的广义力作为状态变量,建立了平面圆弧曲梁面外动力学问题的状态方程列式,并求解了工程中常见的四种边界条件下圆弧曲梁面外自由振动的频率和模态。利用状态空间列式和辛内积的概念,建立了振动模态关于质量和旋转惯量以及关于刚度的正交关系式。基于建立的振动模态关于质量和旋转惯量的正交关系式,运用模态叠加法得到了非齐次状态方程即面外强迫振动控制方程的解析解,并具体考察了竖向移动荷载作用下圆弧曲梁的动力响应。给出了数值算例,并与已有结果进行了比较,验证了该文方法在进行圆弧曲梁面外自由振动和强迫振动分析时的准确性和可靠性。

关键词：平面圆弧曲梁面外自由振动面外强迫振动状态空间法辛内积模态正交性模态叠加法

Optimization of N18 Zirconium Alloy for Fuel Cladding of Water Reactors

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Journal of Materials Science & Technology 2012年第7期28卷 606-613页

作者： B.x. Zhou M. y. yao Z.K. Li x.M. Wang J. Zhoua C.S. Long Q. Liu B.F. Luan Laboratory for Mierostructures Shanghai University Shanghai 200444 China Institute of Materials Shanghai University Shaxighai 200072 China Northwest Institute for Non-ferrous Metal Research Xian 721014 China Key Laboratory for Nuclear Fuel and Materials Nuclear Power Institute of China Chengdu 610041 China College of Material Science and Engineering Chongqing University Chongqing 400044 China

In order to optimize the microstructure and composition of N18 zirconium alloy （Zr-1Sn-0.35Nb-0.35Fe-0.1Cr, in mass fraction, %）, which was developed in China in 1990s, the effect of microstructure and composition variation on the corrosion resistance of the N18 alloy has been investigated. The autoclave corrosion tests were carried out in super heated steam at 400 ~C/10.3 MPa, in deionized water or lithiated water with 0.01 mol/L LiOH at 360 ~C/18.6 MPa. The exposure time lasted for 300-550 days according to the test temperature. The results show that the microstructure with a fine and uniform distribution of second phase particles （SPPs）, and the decrease of Sn content from 1% （in mass fraction, the same as follows） to 0.8% are of benefit to improving the corrosion resistance; It is detrimental to the corrosion resistance if no Cr addition. The addition of Nb content with upper limit （0.35%） is beneficial to improving the corrosion resistance. The addition of Cu less than 0.1% shows no remarkable influence upon the corrosion resistance for N18 alloy. Comparing the corrosion resistance of the optimized N18 with other commercial zirconium alloys, such as Zircaloy-4, ZIRLO, E635 and Ell0, the former shows superior corrosion resistance in all autoclave testing conditions mentioned above. Although the data of the corrosion resistance as fuel cladding for high burn-up has not been obtained yet, it is believed that the optimized N18 alloy is promising for the candidate of fuel cladding materials as high burn-up fuel assemblies. Based on the theory that the microstructural evolution of oxide layer during corrosion process will affect the corrosion resistance of zirconium alloys, the improvement of corrosion resistance of the N18 alloy by obtaining the microstructure with nano-size and uniform distribution of SPPs, and by decreasing the content of Sn and maintaining the content of Cr is discussed.

关键词： Zirconium alloys Corrosion resistance Composition variation Microstructure

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连城姑田方言的复指代词“伊”

肇庆学院学报 2024年第3期45卷 80-85页

作者：蒋瑶陈瑶福建师范大学文学院福建福州350007

对连城姑田方言的“伊”字句的结构类型、使用条件进行考察,并从祈使句类、非祈使句类以及较为特殊的无宾语的“伊”字句角度分析“伊”的性质与功用。“伊”由于语义上的羡余,指代意义大为弱化,其在“伊”字句中的作用总体上相当于句... 详细信息

对连城姑田方言的“伊”字句的结构类型、使用条件进行考察,并从祈使句类、非祈使句类以及较为特殊的无宾语的“伊”字句角度分析“伊”的性质与功用。“伊”由于语义上的羡余,指代意义大为弱化,其在“伊”字句中的作用总体上相当于句末语气词,且在无宾语条件下增加了表达主观情感、转移焦点、礼貌调节等功能。姑田话“伊”字句的适用范围的特殊性,具有一定类型学上的意义。

关键词：连城方言姑田话复指代词 “伊” 处置句

Drug repurposing screen identifies vidofludimus calcium and pyrazofurin as novel chemical entities for the development of hepatitis E interventions

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Virologica Sinica 2024年第1期39卷 123-133页

作者： Hongbo Guo Dan Liu Kuan Liu yao Hou Chunyang Li Qiudi Li xiaohui Ding Monique M.A.Verstegen Jikai Zhang Lingli Wang yibo Ding Renxian Tang xiucheng Pan Kuiyang Zheng Luc J.Wvan der Laan Qiuwei Pan Wenshi Wang Department of Pathogen Biology and Immunology Jiangsu Key Laboratory of Immunity and MetabolismJiangsu International Laboratory of Immunity and MetabolismXuzhou Medical UniversityXuzhou221004China Department of Gastroenterology and Hepatology Erasmus MC-University Medical CenterRotterdamNL-3015 CNthe Netherlands Department of Surgery Erasmus MC Transplant InstituteUniversity Medical CenterRotterdam3015CENL-3015 CNthe Netherlands Department of Infectious Diseases The Affiliated Hospital of Xuzhou Medical UniversityXuzhou221002China

Hepatitis E virus(HEV)infection can cause severe complications and high mortality,particularly in pregnant women,organ transplant recipients,individuals with pre-existing liver disease and immunosuppressed ***,there are still unmet needs for treating chronic HEV ***,we screened a best-in-class drug repurposing library consisting of 262 drugs/*** screening,we identified vidofludimus calcium and pyrazofurin as novel anti-HEV *** calcium is the next-generation dihydroorotate dehydrogenase(DHODH)inhibitor in the phase 3 pipeline to treat autoimmune diseases or SARS-CoV-2 *** selectively targets uridine monophosphate synthetase(UMPS).Their anti-HEV effects were further investigated in a range of cell culture models and human liver organoids models with wild type HEV strains and ribavirin treatment failure-associated HEV ***,both drugs exhibited a sizeable therapeutic window against *** instance,the IC50 value of vidofludimus calcium is 4.6–7.6-fold lower than the current therapeutic doses in ***,their anti-HEV mode of action depends on the blockage of pyrimidine ***,two drugs robustly inhibited ribavirin treatment failure-associated HEV mutants(y1320H,G1634R).Their combination with IFN-αresulted in synergistic antiviral *** conclusion,we identified vidofludimus calcium and pyrazofurin as potent candidates for the treatment of HEV *** on their antiviral potency,and also the favorable safety profile identified in clinical studies,our study supports the initiation of clinical studies to repurpose these drugs for treating chronic hepatitis E.

关键词： Hepatitis Evirus(HEV) Drug repurposing Vidofludimus calcium Pyrazofurin Pyrimidine biosynthesis

Low temperature oxidation of Cr-alloyed MoSi_2

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中国有色金属学会会刊：英文版 2007年第6期17卷 1282-1286页

作者： E. Strom y. Cao y. M. yao Kanthal AB Box 502 SE-734 27 Hallstahammar Sweden Department of Materials and Manufacturing Technology Chalmers University Technology SE-412 96 Gothenburg Sweden

Cr-alloyed MoSi2 was compared with monolithic MoSi2 with respect to oxidation at 450 ℃ for 456 h. Phases formed on Cr-alloyed MoSi2 after exposure are Cr2(MoO4)3, MoO3, and cristobalite (SiO2) according to x-ray diffraction results. Monolithic MoSi2 forms MoO3 and mainly amorphous SiO2. x-ray photoelectron spectroscopy indicates that the main oxidation product on the outermost surface is SiO2 for all studied samples. The samples form a relatively loose oxide but the oxide adherence improves with increasing Cr content. It is indicated that Cr addition can benefit pesting control in MoSi2.

关键词：钼硅化合物合金有害物氧化作用

舰船舱内爆炸载荷下y形夹层板动响应及抗爆性能影响因素

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兵工学报 2024年第3期45卷 837-854页

作者：姚梦雷侯海量李典谢悦海军工程大学舰船与海洋学院湖北武汉430033

针对反舰武器攻击下舰船结构抗毁伤防护问题,采用小型舱室模型实验结合有限元数值分析的方法,分析不同爆距下y形夹层板结构的动响应特性,总结得到y形夹层板结构面板的7种变形模式,发现面板变形模式与爆距和与其相连芯层刚度的相对强弱有... 详细信息

针对反舰武器攻击下舰船结构抗毁伤防护问题,采用小型舱室模型实验结合有限元数值分析的方法,分析不同爆距下y形夹层板结构的动响应特性,总结得到y形夹层板结构面板的7种变形模式,发现面板变形模式与爆距和与其相连芯层刚度的相对强弱有关,爆距较小时面板易发生局部隆起变形,爆距较大则易发生整体碟形变形或板格变形,芯层强、面板弱时面板易发生板格变形,面板强、芯层弱时则易发生整体碟形变形,迎爆面板和V形芯层的刚度较大时背爆面面板则发生整体碟形变形。总结了y形芯层在舱内爆炸载荷作用下的3种典型变形情况,即V屈曲I失稳、V屈曲I不变、V不变I不变;探究了迎爆面面板厚度、V形芯层厚度和I形芯层厚度对y形夹层板结构抗爆性能的影响,发现增加迎爆面面板厚度和I形芯层厚度都可以显著降低背板变形,但增加迎爆面面板厚度会使得结构总吸能降低,增加I形芯层厚度则结构总吸能基本不变,增加V形芯层厚度则V形芯层吸能急剧下降,背板最大变形先增加再减小,结构总吸能下降。

关键词：舰船结构舱内爆炸 y形夹层板动响应变形模式抗爆性能