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Synthesis and Fluorescence Spectrum of a Novel Pyrazoline Derivative

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复旦学报（自然科学版） 2007年第5期46卷 591-592页

作者： x.y.han J.F.Li P.H.Lin D.x.Li C.Dong Department of Agriculture of Shanxi Province Institute of Chemistry and Chemical Engineering Shanxi University

1 Results 2-pyrazolines and carbaozole derivatives are well known fluorescent compounds with high quantum yields[1],and have been investigated in many other respects[2,3].In this paper,carbazole radical was introduced to pyrazoline ring on C-5,and a novel derivative,named 1-phenyl-3-biphenyl-5-(N-ethyl carbazole-3-yl)-2-pyrazoline (PBEP) (5) was synthesized: The product PBEP was characterized by IR,1H NMR,and elementary ***: 47.2%.M.P 104-106 ℃.1H NMR (CDCl3) δ/10-6: 1.5(3H,—CH3).2.4(2H,—...

关键词： synthesis fluorescence pyrazoline

SySTEMATIC CALCULATIONS OF ENERGy LEVELS ANDRADIATIVE RATES OF C-LIKE IONS WITH Z=13-36 USING AN COMBINED CONFIGURATION INTERACTION AND MANy-BODy PERTURBATION THEORy APPROACH

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SYSTEMATIC CALCULATIONS OF ENERGY LEVELS ANDRADIATIVE RATES ...

High Fe‑Loading Single‑Atom Catalyst Boosts ROS Production by Density Effect for Efficient Antibacterial Therapy

第五届全国计算原子与分子物理学术会议

作者： J.yan K.Wang D.F.Li H.T.Liu x.y.han B.Duan C.y.Li J.G.Li Institute of Applied Physics and Computational Mathematics

In the present work,we report the energy levels,and electric dipole,magnetic dipole,electric quadrupole and magnetic quadrupole transition properties for 46 levels of the 2s2p,2s2p,2p,2s2p3s,2s2p3p,and 2s2p3d configurations in the C-like ions with 13≤Z≤36,in an effort to provide a complete,self-consistent and accurate *** employ a combined relativistic

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Nano-Micro Letters 2025年第2期17卷 187-203页

作者： Si Chen Fang Huang Lijie Mao Zhimin Zhang han Lin Qixin yan xiangyu Lu Jianlin Shi Department of Cardiology Shanghai Tenth People’s HospitalSchool of MedicineTongji UniversityShanghai 200092People’s Republic of China Shanghai Institute of Ceramics Chinese Academy of SciencesShanghai 200050People’s Republic of China Shanghai Frontiers Science Center of Nanocatalytic Medicine School of MedicineTongji UniversityShanghai 200092People’s Republic of China

The current single-atom catalysts(SACs)for medicine still suffer from the limited active site ***,we develop a synthetic method capable of increasing both the metal loading and mass-specific activity of SACs by exchanging zinc with *** constructed iron SACs(h^(3)-FNC)with a high metal loading of 6.27 wt%and an optimized adjacent Fe distance of~4 A exhibit excellent oxidase-like catalytic performance without significant activity decay after being stored for six months and promising antibacterial ***,a“density effect”has been found at a high-enough metal doping amount,at which individual active sites become close enough to interact with each other and alter the electronic structure,resulting in significantly boosted intrinsic activity of single-atomic iron sites in h^(3)-FNCs by 2.3 times compared to low-and medium-loading ***,the overall catalytic activity of h^(3)-FNC is highly improved,with mass activity and metal mass-specific activity that are,respectively,66 and 315 times higher than those of commercial Pt/*** addition,h^(3)-FNCs demonstrate efficiently enhanced capability in catalyzing oxygen reduction into superoxide anion(O_(2)·^(−))and glutathione(GSH)*** in vitro and in vivo assays demonstrate the superior antibacterial efficacy of h^(3)-FNCs in promoting wound *** work presents an intriguing activity-enhancement effect in catalysts and exhibits impressive therapeutic efficacy in combating bacterial infections.

关键词： Nanocatalytic medicine Single-atom catalysts Reactive oxygen species(ROS) High metal loading Oxidase catalysis

Short-range ordering plays a determining role in the low-cycle fatigue life improvement of fcc metals: A conclusive study on low solid-solution hardening Ni-Cr alloys

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Journal of Materials Science & Technology 2023年第25期156卷 157-171页

作者： y.J.Zhang D.han x.W.Li Department of Materials Physics and Chemistry School of Materials Science and EngineeringNortheastern UniversityShenyang 110819China State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang 110819China Key Laboratory for Anisotropy and Texture of Materials Ministry of EducationNortheastern UniversityShenyang 110819China

The effect of short-range ordering (SRO) on the low-cycle fatigue (LCF) behavior of low solid-solution hardening Ni-Cr alloys with high stacking fault energies (SFEs) was systematically studied under cycling at constant total strain amplitude (Δε t /2) in the range of 0.1%–0.7%. The results show that an inducement of SRO structures can notably improve the fatigue life of the alloy regardless of Δε t /2, and several unique fatigue characteristics have been detected, including the transition of fatigue cracking mode from intergranular cracking to slip band cracking, the non-negligible evolution from non-Masing behavior in pure Ni to Masing behavior in the Ni-40Cr alloy, and the secondary cyclic hardening behavior in the Ni-10Cr and Ni-20Cr alloys. All these experimental phenomena are tightly associated with the transformation in cyclic deformation mechanisms that is induced by SRO based on the “glide plane softening” effect. Furthermore, a comprehensive fatigue life prediction model based on total hysteresis energy has been reasonably proposed, focusing on the analyses of the macroscopic model parameters (namely the fatigue cracking resistance exponent β and the crack propagation resistance parameter W 0 ) and microscopic damage mechanisms. In brief, on the premise that the effects of SFE and friction stress can be nearly ignored, as in the case of the present low solid-solution hardening Ni-Cr alloys with high SFEs, an enhancement of SRO in face-centered cubic metals has been convincingly confirmed to be an effective strategy to improve their LCF performance.

关键词： Ni-Cr alloy Short range ordering Low solid-solution hardening Low-cycle fatigue Slip mode Fatigue life prediction model

Recombinant chitinase-3-like protein 1 alleviates learning and memory impairments via M2 microglia polarization in postoperative cognitive dysfunction mice

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Neural Regeneration Research 2025年第9期20卷 2727-2736页

作者： yujia Liu xue han yan Su yiming Zhou Minhui xu Jiyan xu Zhengliang Ma xiaoping Gu Tianjiao xia Department of Anesthesiology Nanjing Drum Tower HospitalAffiliated Hospital of Medical SchoolNanjing UniversityNanjingJiangsu ProvinceChina Medical School Nanjing UniversityNanjingJiangsu ProvinceChina Jiangsu Key Laboratory of Molecular Medicine Nanjing UniversityNanjingJiangsu ProvinceChina State Key Laboratory of Pharmaceutical Biotechnology Nanjing UniversityNanjingJiangsu ProvinceChina Department of Anesthesiology Zhongshan HospitalFudan UniversityShanghaiChina

Postoperative cognitive dysfunction is a seve re complication of the central nervous system that occurs after anesthesia and surgery,and has received attention for its high incidence and effect on the quality of life of *** date,there are no viable treatment options for postoperative cognitive *** identification of postoperative cognitive dysfunction hub genes could provide new research directions and therapeutic targets for future *** identify the signaling mechanisms contributing to postoperative cognitive dysfunction,we first conducted Gene Ontology and Kyoto Encyclopedia of Genes and Genomes pathway enrichment analyses of the Gene Expression Omnibus GSE95426 dataset,which consists of mRNAs and long non-coding RNAs differentially expressed in mouse hippocampus3 days after tibial *** dataset was enriched in genes associated with the biological process"regulation of immune cells,"of which Chill was identified as a hub ***,we investigated the contribution of chitinase-3-like protein 1 protein expression changes to postoperative cognitive dysfunction in the mouse model of tibial fractu re *** were intraperitoneally injected with vehicle or recombinant chitinase-3-like protein 124 hours post-surgery,and the injection groups were compared with untreated control mice for learning and memory capacities using the y-maze and fear conditioning *** addition,protein expression levels of proinflammatory factors(interleukin-1βand inducible nitric oxide synthase),M2-type macrophage markers(CD206 and arginase-1),and cognition-related proteins(brain-derived neurotropic factor and phosphorylated NMDA receptor subunit NR2B)were measured in hippocampus by western *** with recombinant chitinase-3-like protein 1 prevented surgery-induced cognitive impairment,downregulated interleukin-1βand nducible nitric oxide synthase expression,and upregulated CD206,arginase-1,pNR2B,and brain-derived neurotropic factor expr

关键词： Chil1 hippocampus learning and memory M2 microglia neuroinflammation postoperative cognitive dysfunction(POCD) recombinant CHI3L1

IMPROVEMENT OF MEChanICAL PROPERTIES OF MARTENSITIC STAINLESS STEEL By PLASMA NITRIDING AT LOW TEMPERATURE

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Acta Metallurgica Sinica(English Letters) 2008年第1期21卷 21-29页

作者： y. T. xi D.x. Liu D. han Z.F. han Corrosion and Protection Research Lab Northwestern Polytechnical University Xi＇an 710072 China xi＇an Shaangu Power Co. Ltd Xi＇an 710611 China

A series of experiments were carried out to study the influence of low temperature plasma nitriding on the mechanical properties of AISI 420 martensitic stainless steel. Plasma nitriding experiments were carried out for 15 h at 350℃ by means of DC- pulsed plasma in 25%N2＋ 75%H2 atmosphere. The microstructure, phase composition, and residual stresses profiles of the nitrided layers were determined by optical microscopy and x-ray diffraction. The microhardness profiles of the nitridied surfaces were also studied. The fatigue life, sliding wear, and erosion wear loss of the untreated specimens and plasma nitriding specimens were determined on the basis of a rotating bending fatigue tester, a ball-on-disc wear tester, and a solid particle erosion tester. The results show that the 350℃ nitrided surface is dominated by c-Fe3N and ON, which is supersaturated nitrogen solid solution. They have high hardness and chemical stabilities. So the low temperature plasma nitriding not only increases the surface hardness values but also improves the wear and erosion resistance. In addition, the fatigue limit of AISI 420 steel can also be improved by plasma nitriding at 350℃ because plasma nitriding produces residual compressive stress inside the modified layer.

关键词： Martensitic stainless steel Plasma nitriding Low temperature Mechanical properties

Effect of Preparation Technique on Microstructure and Hydrogen Storage Properties of LaNi(3.8)Al(1.0)Mn(0.2) Alloys

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Journal of Materials Science & Technology 2016年第12期32卷 1332-1338页

作者： x.B.han y.Qian W.Liu D.M.Chen K.yang Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai 201800 China Institute of Metal Research Chinese Academy of Sdences Shenyang 110016 China

La Ni3.8Al1.0Mn0.2 alloy was prepared by vacuum induction melting and *** effects of different preparation techniques of the as-cast,cast then annealed,as-spun and spun then annealed alloys on the microstructure and hydrogen storage properties were *** results indicated that the non-Ca Cu5 phases in the alloy became tinier and more dispersive after annealing or melt-spinning compared to those of the as-cast *** in the spun then annealed alloy,the non-Ca Cu5 phases disappeared and only a single-phase with Ca Cu5 type structure was *** all the alloys,the cell volume was increased in an order of as-cast 〈 spun then annealed 〈 cast then annealed 〈 as-spun,and the change of plateau pressure showed the opposite trend with that of the cell *** plateau could be flattened after melt-spinning or annealing,and the spun then annealed alloy showed the minimum plateau *** absorption kinetics of the alloy was promoted after melt-spinning or *** is suggested that the change in cell volume and compositional homogeneity resulting from different preparation techniques contribute to the difference of the hydrogen storage properties of the investigated alloys.

关键词： Annealing Melt-spinning Metal hydride Hydrogen absorption

Reliability-based multidisciplinary design optimization using incremental shifting vector strategy and its application in electronic product design

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Acta Mechanica Sinica 2018年第2期34卷 285-302页

作者： Z.L.Huang y.S.Zhou C.Jiang J.Zheng x.han School of Mechanical and Electrical Engineering Hunan City University State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body College of Mechanical and Vehicle Engineering Hunan University

Use of multidisciplinary analysis in reliabilitybased design optimization(RBDO) results in the emergence of the important method of reliability-based multidisciplinary design optimization(RBMDO). To enhance the efficiency and convergence of the overall solution process,a decoupling algorithm for RBMDO is proposed ***, to decouple the multidisciplinary analysis using the individual disciplinary feasible(IDF) approach, the RBMDO is converted into a conventional form of RBDO. Secondly,the incremental shifting vector(ISV) strategy is adopted to decouple the nested optimization of RBDO into a sequential iteration process composed of design optimization and reliability analysis, thereby improving the efficiency significantly. Finally, the proposed RBMDO method is applied to the design of two actual electronic products: an aerial camera and a car pad. For these two applications, two RBMDO models are created, each containing several finite element models(FEMs) and relatively strong coupling between the involved disciplines. The computational results demonstrate the effectiveness of the proposed method.

关键词： Reliability-based design optimization(RBDO) Multidisciplinary design optimization(MDO) Incremental shifting vector(ISV) Decoupling algorithm Electronic product

Four Late-type Galaxies with Double Radio Lobes and Properties of Such Galaxies

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Research in Astronomy and Astrophysics 2024年第4期24卷 84-90页

作者： Z.S.yuan x.y.Gao Z.L.Wen J.L.han National Astronomical Observatories Chinese Academy of SciencesBeijing 100101China CAS Key Laboratory of FAST National Astronomical ObservatoriesChinese Academy of SciencesBeijing 100101China School of Astronomy and Space Sciences University of Chinese Academy of SciencesBeijing 100049China

The triggering mechanism for radio lobes from late-type galaxies is not fully *** samples are desired for a thorough investigation and *** utilizing the optical data from the newly released Dark Energy Spectroscopic Instrument imaging surveys and the radio sources from the NRAO VLA Sky Survey and the Faint Images of the Radio Sky at Twenty-centimeter,we identify four Late-type Galaxies with double Radio Lobes(La GRLs):J0217-3645,J0947+6220,J1412+3723 and J1736+*** previously known La GRLs,we confirm the correlation between radio power P_(1.4GHz)and stellar mass M_(*)of host ***(25/35)La GRLs belong to the blue cloud galaxies,while the newly identified cases in this work are located within the region of the red *** find a clear correlation between the differential radio power,i.e.,the offset from the P_(1.4GHz)-M_(*)relation,and the galaxy color,indicating that bluer galaxies at a fixed M_(*)tend to host more powerful radio ***,the majority(31/36)of La GRLs are either located in a galaxy group or displaying a disturbed *** suggest that all of the galaxy mass,color and surrounding environment could play important roles in triggering radio lobes in late-type galaxies.

关键词： galaxies:active galaxies:jets galaxies:spiral radio continuum:galaxies