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nano Research 2024年第4期17卷 2308-2319页

作者： Gang wang Longchao Sun Wanyi Liu Haijuan Zhan Shuxian Bi College of Chemistry and Chemical Engineering Ningxia UniversityYinchuan 750021China

A scalable strategy for the convenient and rapid preparation of nitrogen-doped carbon-coated iron-based alloy catalysts was *** controlling the type and amount of metal salts in the precursor,various types of nitrogen-doped carbon-coated alloy catalysts can be prepared in a targeted ***_(2)ni2@Cn materials with small particle sizes and relatively homogeneous basic sites showed promising results in the n-alkylation reaction of benzyl alcohol with aniline(optimum yield:99%).It is worth noting that the catalyst can also be magnetically separated and recovered after the reaction,and its performance can be regenerated through simple ***,it was confirmed by kinetic experiments that the activation of C–H at the benzyl alcohol benzylic position is the rate-determining step(RDS).According to density flooding theory calculations,Fe_(2)ni2@Cn catalysts require less energy than other materials(Fe@Cn and ni@Cn)for the RDS(dehydrogenation reaction)*** n-alkylation reactions are more easily carried out on Fe_(2)ni2@Cn catalysts,which may be the reason for the best catalytic activity of Fe-ni alloy *** carbon-coated alloy materials will show great potential in more types of heterogeneous catalysis.

关键词： iron-nickel alloy catalyst n-alkylation reaction magnetic separation reaction path dehydrogenation reaction

Effect of tillage state of paddy soils with heavy metal pollution on the nosZ gene of n_(2)O reductase

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Journal of Environmental Sciences 2024年第3期137卷 469-477页

作者： Liping Jiang Shiguang Liu Shanyun wang Libo Sun Guibing Zhu Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China School of Environmental and Civil Engineering Jiangnan UniversityWuxi 214122China

Paddy soils are an important source of atmospheric nitrous oxide(n_(2)O).However,numerous studies have focused on n_(2)O production during the soil tillage period,neglecting the n_(2)O production during the dry fallow *** this study,we conducted an incubation experiment using the acetylene inhibition technique to investigate n_(2)O emission and reduction rates of paddy soil profiles(0-1 m)from Guangdong Province and Jinlin Province in China,with different heavy-metal pollution *** abundance and community structures of denitrifying bacteria were determined via quantitative-PCR and Illumina MiSeq sequencing of nosZ,nirK,and nirS *** results showed that the potential n_(2)O emission rate,n_(2)O production rate,and denitrification rate have decreased with increasing soil vertical depth and heavy-metal *** importantly,we found that the functional gene type of n_(2)O reductase switched with the tillage state of paddy soils,which cladeⅡnos Z genes were the dominant gene during the tillage period,while cladeⅠnos Z genes were the dominant gene during the dry fallow *** heavy-metal pollution has less effect on the niche differentiation of the nos Z *** n_(2)O emission rate was significantly regulated by the genus Bradyhizobium,which contains both n_(2)O reductase and nitrite reductase *** findings suggests that the nos Z gene of n_(2)O reductase can significantly impact the n_(2)O emission from paddy soils.

关键词： Pappy soils n_(2)O reductase nosZ gene Heavy-metal pollution

Co/n co-doped flower-like carbon-based phase change materials toward solar energy harvesting

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Aggregate 2024年第1期5卷 321-330页

作者： xiao Chen Lei wang Yan Gao Yang Li xiaowei Zhang Yu Jiang Ge wang Institute of Advanced Materials Beijing Normal UniversityBeijingChina Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory of Function Materials for Molecule and Structure ConstructionSchool of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijingChina

The photothermal conversion capacity of pristine organic phase change materials(PCMs)is inherently insufficient in solar energy *** upgrade their photothermal conversion capacity,we developed bimetallic zeolitic imidazolate framework(ZIF)derived Co/n co-doped flower-like carbon(Co/n-FLC)-based composite PCMs toward solar energy harvesting.3D interconnected carbon framework with low interfacial thermal resistance,abundant carbon defects and high content of nitrogen doping,excellent localized surface plasmon resonance(LSPR)effect of Co nanoparticles,and light absorber Co_(3)ZnC in Co/n-FLC synergistically upgrade the photothermal capacity of(polyethylene glycol)PEG@Co/n-FLC composite PCMs with an ultrahigh photothermal conversion efficiency of 94.8%under 0.16 W/cm^(2).Uniformly anchored Co and Co_(3)ZnC nanoparticles in carbon framework guarantee excellent photon capture *** carbon nanotubes(CnTs)in 2D carbon nanosheets further accelerate the rapid transport of phonons by constructing cross-connected heat transfer ***,PEG@Co/n-FLC exhibits a thermal energy storage density of 100.69 J/g and excellent thermal stability and durable ***,PEG@Co/n-FLC composite PCMs are promising candidates to accelerate the efficient utilization of solar energy.

关键词： bimetallic ZIF Co/n co-doped carbon phase change materials photothermal conversion thermal energy storage

Flat Zn deposition at battery anode via an ultrathin robust interlayer

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nano Research 2024年第9期17卷 8104-8111页

作者： Yizhou wang Jianyu Chen Zibo Chen Qian He Zhengnan Tian Jin Zhao Yanwen Ma Husam n.Alshareef Materials Science and Engineering King Abdullah University of Science and Technology(KAUST)Thuwal 23955-6900Saudi Arabia State Key Laboratory of Organic Electronics and Information Displays(KLOEID)and Jiangsu Key Laboratory for Biosensors Institute of Advanced Materials(IAM)Nanjing University of Posts and TelecommunicationsNanjing 210023China Suzhou Vocational Institute of Industrial Technology Suzhou 215104China

Rechargeable aqueous zinc(Zn)ion batteries(AZIBs)using low-cost and safe Zn metal anodes are considered promising candidates for future grid-scale energy storage systems,but the Zn dendrite problem severely hinders the further prospects of *** Zn depositing behaviors toward horizontal alignment is highly effective and thus has received huge ***,such a strategy is usually based on previous substrate engineering,which requires complex preparation or expensive ***,it is essential to develop a novel solution that can realize horizontally aligned Zn flake deposition via easy operation and low ***,we report an ultrathin and robust Kevlar membrane as the interlayer to mechanically suppress Zn dendrite *** to the randomly distributed flaky dendrites in the control group,the deposited Zn sheets would grow into parallel alignment with the existence of such *** the dendrites are effectively suppressed,Zn||Cu asymmetric,Zn||Zn symmetric,and Zn||MnO_(2)full batteries using Kevlar interlayer deliver significantly improved cycling ***,the Zn||MnO_(2)pouch cell using a Kevlar interlayer delivers stable cycling performance and shows stable operation during multi-angle *** believe this work provides a new possibility for regulating Zn deposition from a crystallographic perspective.

关键词： Zn metal anodes Zn dendrites aqueous Zn ion batteries dendrite suppression (002)crystal plane

Metal-organic framework-derived CoSe_(2)@n-doped carbon nanocubes for high-performance lithium-ion capacitors

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Rare Metals 2024年第5期43卷 2150-2160页

作者： Lei wang xiong Zhang Yan-Yan Kong Chen Li Ya-Bin An xian-Zhong Sun Kai wang Yan-Wei Ma Institute of Electrical Engineering Chinese Academy of SciencesBeijing 100190China School of Engineering Sciences University of Chinese Academy of SciencesBeijing 100190China Institute of Electrical Engineering and Advanced Electromagnetic Drive Technology Qilu ZhongkeJinan 250013China School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China

Cobalt selenide(CoSe_(2))has garnered considerable attention as a prospective anode candidate for advanced lithium-ion storage,prompting comprehensive ***,CoSe_(2)-based anodes usually suffer from significant volume variation upon lithiation leading to unsatisfactory cycling ***,a versatile synthesis route is proposed for the in-situ fabrication of CoSe2nanoparticles embedded in n-dope carbon skeleton(CoSe_(2)@nC)through annealing treatment and selenization of a metal–organic framework-derived(MOF)*** n-doped carbon derived from the MOF serves not only as an excellent conductive substrate but also as a confined reactor,effectively inhibiting the structural instability and alleviating the inevitable volume change of CoSe_(2).Owing to their unique nanostructure,the as-prepared CoSe_(2)@nC exhibits a high capacity of 745.9mAh·g^(-1)at 0.1 A·g^(-1),while maintaining excellent rate capability and an impressive ***,the assembled lithium-ion capacitor(LIC)based on CoSe_(2)@nC demonstrates an energy density of 130Wh·kg^(-1),a power density of 24.6 kW·kg^(-1),and remarkable capacity retention of 90.8%after 8000 *** results highlight the great potential of CoSe_(2)@nC for practical applications.

关键词： Lithium capacitors Cobalt selenide Metal-organic frameworks n-doped carbon

Opportunities for production and property research of neutron-rich nuclei around n=126 at HIAF

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nuclear Science and Techniques 2024年第6期35卷 101-113页

作者： Shao-Bo Ma Li-na Sheng xue-Heng Zhang Shi-Tao wang Kai-Long wang Chun-wang Ma Hool-Jin Ong Zhi-Yu Sun Shu-Wen Tang Yu-Hong Yu x.n-Tong Du xiao-Bao Wei Institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China Advanced Energy Science and Technology Guangdong Laboratory Huizhou 516000China University of Chinese Academy of Sciences Beijing 100049China College of Physics Henan Normal UniversityXinxiang 453007China Institute of nuclear Science and Technology Henan Academy of ScienceZhengzhou 450046China Joint-Department for nuclear Physics Lanzhou University and Institute of Modern PhysicsLanzhou 730000China Research Center for nuclear Physics Osaka UniversityOsaka 567-0047Japan RIKEn nishina Center Saitama 351-0198Japan northwest normal University Lanzhou 730070China

The study of nuclide production and its properties in the n=126 neutron-rich region is prevalent in nuclear physics and astrophysics *** upcoming High-energy FRagment Separator(HFRS)at the High-Intensity heavy-ion Accelerator Facility(HIAF),an in-flight separator at relativistic energies,is characterized by high beam intensity,large ion-optical acceptance,high magnetic rigidity,and high momentum resolution *** provides an opportunity to study the production and properties of neutron-rich nuclei around n=*** this paper,an experimental scheme is proposed to produce neutron-rich nuclei around n=126 and simultaneously measure their mass and lifetime based on the HFRS separator;the feasibility of this scheme is evaluated through *** results show that under the high-resolution optical mode,many new neutron-rich nuclei approaching the r-process abundance peak around A=195 can be produced for the first time,and many nuclei with unknown masses and lifetimes can be produced with high *** the time-of-flight corrected by the measured dispersive position and energy loss information,the cocktails produced from 208 Pb fragmentation can be unambiguously ***,the masses of some neutron-rich nuclei near n=126 can be measured with high precision using the time-of-flight magnetic rigidity *** indicates that the HIAF-HFRS facility has the potential for the production and property research of neutron-rich nuclei around n=126,which is of great significance for expanding the chart of nuclides,developing nuclear theories,and understanding the origin of heavy elements in the universe.

关键词： HFRS Fragmentation neutron-rich nuclei around n=126 Mass measurement Lifetime

Synergistic coupling among Mg_(2)B_(2)O_(5),polycarbonate and n,ndimethylformamide enhances the electrochemical performance of PVDF-HFP-based solid electrolyte

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Journal of Energy Chemistry 2024年第7期94卷 158-168页

作者： Yutong Jing Qiang Lv Yujia Chen Bo wang Bochen Wu Cheng Li Shengbo Yang Zhipeng He Dianlong wang Huakun Liu Shixue Dou MIIT Key Laboratory of Critical Materials Technology for new Energy Conversion and Storage State Key Laboratory of Urban Water Resource and EnvironmentSchool of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001HeilongjiangChina Institute of Energy Material Science University of Shanghai for Science and TechnologyShanghai 200093China Institute for Superconducting&Electronic Materials Australian Institute of Innovative MaterialsUniversity of WollongongWollongongNSW 2500Australia

Polymer solid electrolytes(SPEs)based on the[solvate-Li+]complex structure have promising prospects in lithium metal batteries(LMBs)due to their unique ion transport ***,the solvation structure may compromise the mechanical performance and safety,hindering practical application of *** this work,a composite solid electrolyte(CSE)is designed through the organic-inorganic syner-gistic interaction among n,n-dimethylformamide(DMF),polycarbonate(PC),and Mg_(2)B_(2)O_(5) in poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP).Flame-retardant Mg_(2)B_(2)O_(5) nanowires provide non-flammability to the prepared CSEs,and the addition of PC improves the dispersion of Mg_(2)B_(2)O_(5) ***,the organic-inorganic synergistic action of PC plasticizer and Mg_(2)B_(2)O_(5) nanowires pro-motes the dissociation degree of LiTFSI and reduces the crystallinity of PVDF-HFP,enabling rapid Li ion ***,Raman spectroscopy and DFT calculations confirm the coordination between Mg atoms in Mg_(2)B_(2)O_(5) and n atoms in DMF,which exhibits Lewis base-like behavior attacking adjacent C-F and C-H bonds in PVDF-HFP while inducing dehydrofluorination of *** on the syner-gistic coupling of Mg_(2)B_(2)O_(5),PC,and DMF in the PVDF-HFP matrix,the prepared CSE exhibits superior ion conductivity(9.78×10^(-4) s cm^(-1)).The assembled Li symmetric cells cycle stably for 3900 h at a current density of 0.1 mA cm^(-2) without short *** LFP||Li cells assembled with PDL-Mg_(2)B_(2)O_(5)/PC CSEs show excellent rate capability and cycling performance,with a capacity retention of 83.3%after 1000 cycles at 0.5 *** work provides a novel approach for the practical application of organic-inorganic Synergistic CSEs in LMBs.

关键词： Composite solid electrolytes Safe Li metal batteries Synergistic coupling effect Poly(vinylidene fluoride-co-hexafluoropro pylene)

MnS–MnO heterogeneous nanocube@n,S-doped carbon as a highly efficient bifunctional water splitting electrocatalyst

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Rare Metals 2024年第5期43卷 1977-1988页

作者： xue-Qian wang xiang-Ying Ma wang-Zhi Wu Hui-Bing He nan-nan wang Ren-Ji Zheng Shao-Jian Ma Yan-Qiu Zhu Pei-Kang Shen Jin-Liang Zhu School of Resources Environment and MaterialsState Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite StructuresCollege of Chemistry and Chemical EngineeringGuangxi UniversityNanning 530004China School of Chemistry and Chemical Engineering Guangxi MinzuUniversity Nanning 530006 China School of Minerals Processing and Bioengineering Central South UniversityChangsha 410083China

A stable,efficient,and economical bifunctional electrolytic catalyst would be incredibly beneficial for the development of hydrogen production by electrocatalytic water *** this study,we synthesized a novel MnS–MnO heterogeneous nanocube@n,S-doped carbon(MnS–MnO@nSC).MnS–MnO nanocubes possess rich heterogeneous interfaces and plentiful catalytic active sites to promote electrochemical reactions,while the n,S-doped carbon shell possesses excellent conductivity and catalytic properties and protects the ***–MnO@nSC exhibited excellent electrochemical properties as an effective bifunctional electrocatalyst for the hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)in KOH *** the HER,the overpotential was as low as 124 mV at a current density of 10 mA·cm^(-2)while in the OER,it was only 340 mV at 100 mA·cm^(-2)under the same *** addition,a MnS–MnO@nSC||MnS–MnO@nSC electrolyzer exhibited almost comparable activity and higher steadiness than those exhibited by the state-of-the-art Pt/C||RuO_(2)/C system for full water splitting in KOH solution.

关键词： Manganese sulfide Manganese oxide Doped carbon Heterogeneous nanocube Water splitting

Cubic S/n co-doped TiO_(2) with rich oxygen vacancies from Ti-MOFs for efficient elimination of formaldehyde

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Chinese Chemical Letters 2024年第2期35卷 512-515页

作者： Qing Gao Lei Sun Zhihua wang Jiguang Deng State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China Beijing Key Laboratory for Green Catalysis and Separation Key Laboratory of Beijing on Regional Air Pollution ControlKey Laboratory of Advanced Functional MaterialsEducation Ministry of ChinaDepartment of Chemical EngineeringBeijing University of TechnologyBeijing 100124China

The cubic S/n co-doped TiO_(2)(TnSx,x is the calcination temperature)photocatalysts with rich oxygen vacancies were obtained by high temperature calcination of sulfur powder and titanium-based MOFs nH_(2)-MIL-125 for the photocatalytic removal of gaseous formaldehyde(a volatile organic compound).Among the obtained catalysts,the presence of oxygen vacancies restricted photogenerated electron and holes recombination.98.00%removal of gaseous formaldehyde in 150 min could be achieved over TnS600 by x.non *** removal efficiency for formaldehyde was well retained for five cycle *** results from PL,TRPL and EIS revealed that TnS600 had the best separation efficiency of photogenerated electrons and holes,and the enhanced charge separation led to a significant increase in photocatalytic *** photocatalytic oxidation mechanism indicated that the ^(•)OH and ^(•)O_(2)−radicals were mainly involved in the efficient elimination of gaseous formaldehyde and were able to mineralize formaldehyde to H_(2)O and CO_(2).

关键词： Metal-organic frameworks Photocatalysis Formaldehyde removal S/n co-doped TiO_(2) Oxygen vacancies

Multiwavelength Observations of the Infrared Dust Bubble n75 and its Surroundings

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Research in Astronomy and Astrophysics 2024年第4期24卷 262-270页

作者： Quan-Ling Cui Chuan-Peng Zhang Jun-Jie wang national Astronomical Observatories Chinese Academy of SciencesBeijing 100101China University of Chinese Academy of Sciences Beijing 100049China College of Science Qiqihar UniversityQiqihar 161006China Guizhou Radio Astronomical Observatory Guizhou UniversityGuiyang 550000China

Infrared dust bubbles play an important role in the study of star formation and the evolution of the interstellar *** this work,we study the infrared dust bubble n75 and the infrared dark cloud G38.93 mainly using the tracers C^(18)O,HCO^(+),HnC and n_(2)H^(+)observed by the 30 m IRAM *** also study the targets using data from large-scale surveys:GLIMPSE,MIPSGAL,GRS,nRAO VLA Sky Survey and Bolocam Galactic Plane *** found that the C^(18)O emission is morphologically similar to the Spitzer IRAC 8.0μm ***1.1 mm cold dust emission of G38.93 shows an elongated structure from southwest to *** ionized gas from G38.93 is surrounded by polycyclic aromatic hydrocarbon emission,which may be excited by radiation from *** found that the identified young stellar objects tend to cluster around G38.93 and are mostly in class II with several class I cases distributed around n75,but no class II *** also found evidence of expanding feedback,which could have triggered star formation.

关键词： ISM:bubbles infrared:ISM galaxies:star formation