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Micro-strain regulation strategy to stabilize perovskite lattice based on the categories and impact of strain on perovskite solar cells

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Journal of Energy Chemistry 2025年第1期100卷 578-604页

作者： Caixia li Wenwu liu Shiji Da lingbin Kong fen Ran State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of Technology School of Materials Science and Engineering Lanzhou University of Technology

Photovoltaic metal halide perovskite solar cells(PSCs) convert light to electricity more efficiently than crystalline silicon cells, and the cost of materials used to make them is lower than that of silicon *** efficiency is not a core issue affecting the application of perovskite solar cells in special *** present, stability is the major technical encounters that hinders its further commercial development. Microstrain in PSCs is currently a significant factor responsible for the device's instability. Strain-induced ion migration is widely believed to accelerate perovskite degradation even when external stimuli are ***, it is imperative to study strain to enhance the stability of PSCs. This paper reviews recent developments to understand strain's origin and effect mechanisms on performance of PSCs, including ion migration,failure behavior, defect formation, and its effect on photoelectric properties, stability, and ***, several well-known strain management strategies are systematically introduced based on the strain effect mechanism and strain engineering on the film, providing more clues for further preparation with increased stability. The manipulation of external physical strain applied from films to entire devices has been extensively studied. Furthermore, recommendations for future research directions and chemical approaches have been provided. It is emphasized that strain engineering plays a crucial role in improving the efficiency and longevity of PSCs. Tensile strain causes rapid degradation, while moderate compressive strain and external strain control could improve properties and stability. Efforts should focus on controlling compressive strain to mitigate residual tensile strain and introducing it in a controlled manner. Future research endeavors may focus on exploring these pathways to improve the efficiency and lifespan of PSCs.

关键词： Halide perovskite solar cells Strain origins Strain effects Strain management

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Effect of Vegetation Changes on Soil Erosion on the Loess Plateau

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Pedosphere 2006年第4期16卷 420-427页

作者： ZHENG fen-li State Key Laboratory of Soil Erosion and Dryland Farming in Loess Plateau Northwest A＆F University Yangling 712100 （China）.

Vegetation is one of the key factors affecting soil erosion on the Loess Plateau. The effects of vegetation destruction and vegetation restoration on soil erosion were quantified using data from long-term field runoff plots established on the eastern slope of the Ziwuling secondary forest region, China and a field survey. The results showed that before the secondary vegetation restoration period (before about 1866-1872), soil erosion in the Ziwuling region of the Loess Plateau was similar to the current erosion conditions in neighboring regions, where the soil erosion rate now is 8000 to 10000 t km-2 year-1. After the secondary vegetation restoration, soil erosion was very low; influences of rainfall and slope gradient on soil erosion were small; the vegetation effect on soil erosion was predominant; shallow gully and gully erosion ceased; and sediment deposition occurred in shallow gully and gully channels. In modern times when human activities destroyed secondary forests, soil erosion increased markedly, and erosion rates in the deforested lands reached 10000 to 24000 t km-2 year-1, which was 797 to 1682 times greater than those in the forested land prior to deforestation. Rainfall intensity and landform greatly affected the soil erosion process after deforestation. These results showed that accelerated erosion caused by vegetation destruction played a key role in soil degradation and eco-environmental deterioration in deforested regions.

关键词： deforestation Loess Plateau natural vegetation restoration soil erosion

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Effects of Accelerated Soil Erosion on Soil Nutrient Loss After Deforestation on the Loess Plateau

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Pedosphere 2005年第6期15卷 707-715页

作者： ZHENG fen-li State Key Laboratory of Soil Erosion and Dryland Farming in Loess Plateau Institute of Soil and Water ConservationChinese Academy of Sciences and Ministry of Water Resources Yangling 712100 （China）

Soil erosion and nutrient losses on newly-deforested lands in the Ziwuling Region on the Loess Plateau of China were monitored to quantitatively evaluate the effects of accelerated soil erosion, caused by deforestation, on organic matter, nitrogen and phosphorus losses. Eight natural runoff plots were established on the loessial hill slopes representing different erosion patterns of dominant erosion processes including sheet, rill and shallow gully (similar to ephemeral gully). Sediment samples were collected after each erosive rainfall event. Results showed that soil nutrients losses increased with an increase of erosion intensity. linear relations between the losses of organic matter, total N, NH4-N, and available P and erosion intensity were found. Nutrient content per unit amount of eroded sediment decreased from the sheet to the shallow gully erosion zones, whereas total nutrient loss increased. Compared with topsoil, nutrients in eroded sediment were enriched, especially available P and NH4-N. The intensity of soil nutrient losses was also closely related to soil erosion intensity and pattern with the most severe soil erosion and nutrient loss occurring in the shallow gully channels on loessial hill slopes. These research findings will help to improve the understanding of the relation between accelerated erosion process after deforestation and soil quality degradation and to design better eco-environmental rehabilitation schemes for the Loess Plateau.

关键词： accelerated soil erosion deforestation erosion intensity Loess Plateau nutrient loss

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AN UNSTRUCTURED FINITE-VOLUME ALGORITHM FOR NONliNEAR TWO-DIMENSIOAL SHALLOW WATER EQUATION

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Journal of Hydrodynamics 2005年第3期17卷 306-312页

作者： WANGZhi-li GENGYan-fen JINSheng StateKeyLaboratoryofCoastalandoffshoreEngineering DalianUniversityofTechnologyDalian116024China

An unstructured finite-volume numerical algorithm was presented for solution of the two-dimensional shallow water equations, based on triangular or arbitrary quadrilateral meshes. The Roe type approximate Riemann solver was used to the system. A second-order TVD scheme with the van Leer limiter was used in the space discretization and a two-step Runge-Kutta approach was used in the time discretization. An upwind, as opposed to a pointwise, treatment of the slope source terms was adopted and the semi-implicit treatment was used for the friction source terms. Verification for two-dimension dam-break problems are carried out by comparing the present results with others and very good agreement is shown.

关键词： shallow water equation dam break Riemann solver finite-volume method source terms

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Regulating FUS liquid-liquid Phase Separation via Specific Metal Recognition

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Chinese Journal of Polymer Science 2022年第9期40卷 1043-1049页

作者： fen li Yiyang lin Yan Qiao Beijing National Laboratory for Molecular Sciences(BNLMS) Laboratory of Polymer Physics and ChemistryCAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China State Key Laboratory of Chemical Resource Engineering Beijing Laboratory of Biomedical MaterialsBeijing University of Chemical TechnologyBeijing 100029China

liquid-liquid phase separation(LLPS)or biomolecular condensation that leads to formation of membraneless organelles plays a critical role in many biochemical *** study of regulating LLPS is therefore central to the understanding of protein aggregation and disease-relevant *** report a fused in sarcoma protein(FUS)-derived low complexity(LC)sequence that undergoes LLPS in the presence of metal *** LC protein was constructed by fusing a hexhistidine-tag to the N-terminal low complexity domain(the residues 1–165 in QGSY-rich segment)of *** condensation of the intrinsic disordered protein into coacervate droplets was observed in the presence of metal ions that chelate oligohistidine moieties to form protein *** demonstrate the key role of metal ion-histidine coordination in governing LLPS behaviours and the fluidity of biomolecular *** taking advantage of competitive binding using chelators,we show the possibility of regulating dynamic behaviors of disease-relevant protein droplets,and developing a potential approach towards controllable biological encapsulation/release.

关键词： FUS liquid-liquid phase separation Biomolecular condensate Membraneless organelles Protocells Metal coordination

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An Implicit Coupled 1D/2D Model for Unsteady Subcritical Flow in Channel Networks and Embayment

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China Ocean Engineering 2020年第1期34卷 110-118页

作者： GENG Yan-fen WANG Zhi-li School of Transportation Southeast UniversityNanjing 211189China State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering Nanjing Hydraulic Research InstituteNanjing 210024China

In this study, 1D and 2D shallow-water models were coupled to simulate unsteady flow in channel networks and embayment. The 1D model solved the 1D shallow-water equations (St. Venant) using the Preissmann box method and targeted long narrow reaches of the river networks, while the 2D model targeted broad channels and embayment and solved the 2D shallow-water equations using a semi-implicit scheme applied to an unstructured grid of triangular cells. The 1D and 2D models were solved simultaneously by building a matrix for the free surface elevation at every 1D junction and 2D cell center. Velocities were then computed explicitly based on the results at the previous time step and the updated water level. The originality of the scheme arose from a novel coupling method. The results showed that the coupled 1D/2D model produced identical results as the full 2D model in classical to benchmark problems with considerable savings in computational effort. Application of the model to the Pearl River Estuary in southern China showed that complex patterns of tidal wave propagation could be efficiently modeled.

关键词： 1D river network model 2D unstructured model full coupling model Pearl River Delta

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Atomically precise nickel-sulfur clusters for efficient electrochemical 2,5-hydroxymethylfurfural oxidation

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Nano Research 2025年第1期18卷 140-148页

作者： fen Wang Lu-Yu liu Sha-Sha Cui Ting-Ting li xiao-Meng Yang Zhijuan liu Yanyong Wang Henan Key Laboratory of Crystalline Molecular Functional Materials Henan International Joint Laboratory of Tumor Theranostical Cluster MaterialsGreen Catalysis Centerand College of ChemistryZhengzhou UniversityZhengzhou 450001China State Key Laboratory of Chem/Bio-sensing and Chemometrics College of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082China

Nickel sulfide exhibits excellent catalytic activity in the electrochemical 2,5-hydroxymethylfurfural oxidation reaction(HMFOR).However,due to the polydispersity of nanoparticles,it is difficult to establish a clear structure-activity relationship at the atomic *** this work,we have successfully synthesized atomically precise Ni_(6)(PET)_(12)and Ni_(4)(PET)_(8)clusters(PET:2-phenylethanethiol)for ***^(2+)and S_(2)-with atomic ratio of 1:2 was mainly existed in Ni_(6)(PET)_(12)and Ni_(4)(PET)_(8)to form Ni-S *** electrochemical test results have suggested both Ni_(6)(PET)_(12)and Ni_(4)(PET)_(8)displayed outstanding electrocatalytic ability for *** Ni_(6)(PET)_(12)exhibited better electrocatalytic ability than Ni_(4)(PET)_(8)with higher current density,lower overpotential and faster reaction *** superior electrochemical ability of Ni_(6)(PET)_(12)may be due to the enhanced adsorption towards HMF molecule with strong interaction towards hydroxyl group and furan ***,it found that the Ni^(2+)species in Ni_(6)(PET)_(12)could rapidly oxidized into Ni^(3+)species,which could spontaneously capture electron and proton from HMF for *** theoretical calculation demonstrated that the Ni_(6)(PET)_(12)process lower free energy barrier than Ni_(4)(PET)_(8)to display excellent electrocatalytic *** work is of great significance for designing efficient electrocatalysts for HMFOR.

关键词： atomically precise nickel nanoclusters 2 5-hydroxymethylfurfural electro-oxidation Ni3+species

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Influence of dissolved organic carbon on multimedia distribution and toxicity of fipronil and its transformation products in lotic waterways

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Journal of Environmental Sciences 2023年第8期130卷 52-64页

作者： Weizong li Hao Hu fen liu Huizhen li Jing You School of Environment and Guangdong Key Laboratory of Environmental Pollution and Health Jinan UniversityGuangzhou 511443China

Environmental fate and ecological impacts of fipronil and its transformation products(FIPs)in aquatic environment have caused worldwide attention,however,the influence of dissolved organic carbon(DOC)on multimedia distribution,bioavailability,and toxicity of FIPs in field waterways was largely ***,we collected 11 companion water and sediment samples along a lotic stream in Guangzhou,South *** were ubiquitous with total water concentrations ranging from 1.22 to 43.2 ng/L(14.8±12.9 ng/L)and fipronil sulfone was predominant in both water and *** than 70%of FIPs in aqueous phase were bound to DOC and the KDOC values of FIPs were approximately 1–2 orders of magnitude higher than K_(d-s)/K_(OC),emphasizing the significance of DOC in phase partitioning and transport of FIPs in aquatic *** and sediment samples were more toxic to Chironomus dilutus than Hyallela azteca,and FIPs(especially fipronil sulfone)pronouncedly contributed toxicity to *** units(TU)based on freely dissolved concentrations in water determined by solid phase microextraction significantly improved toxicity estimation of FIPs to the invertebrates compared to TUs based on aqueous *** present study highlights the significance of DOC association on fate and ecological risk of hydrophobic insecticides in lotic ecosystem.

关键词： Hydrophobic organic contaminant Bioavailability Partitioning Aquatic toxicity Passive sampler

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Clinical significance of serum biochemistry changes in mice with targeted disruption of βB2-crystallin gene

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International Journal of Ophthalmology(English edition) 2012年第1期5卷 55-58页

作者： fen-fen xiang, Wen-Jie li Department of Laboratory Diagnosis Changhai Hospital Second Military Medical University Shanghai 200433 China Department of Ophthalmology Changhai Hospital Second Military Medical University Shanghai 200433 China

AIM: To explore the pathogenesis, influencing factors, ways of medical intervention and evaluation indicators of cataract by observing changes in serum biochemical indices in mice with targeted disruption of βB2-crystallin. · METHODS: Nine 6-week-old male mice with targeted knockout of βB2-crystallin were used as the study group, and nine age- and sex-matched normal wild-type mice as the control group. The genetype of the modeled mice was identified by PCR technique. Tropicamide and phenylephrine eye drops were used as the cycloplegic agents to observe changes in lens opacity with a slit-lamp. The lens was then removed and blood was collected for biochemical evaluation in the serum. · RESULTS: Two genotypes were successfully identified by PCR technique. Slit-lamp observation showed that the lens cortex was opaque and GSH level in the lens cortex was remarkably decreased in mice with βB2-crystallin deficiency compared with the control group (P 0.05). · CONCLUSION: Compared with the wild-type mice, serum biochemical indices underwent significant changes in mice with targeted disruption of βB2-crystallin gene, especially with abnormal distribution of Na+&Ca2+, which induced the formation of cataract.

关键词： βB2-crystallin knockout cataract mice serum biochemistry

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Theoretical Study on Reaction Mechanism of Aluminum-Water System

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Chinese Journal of Chemical Physics 2008年第3期21卷 245-249页

作者： Yun-lan Sun Yan Tian Shu-fen li Department of Chemical Physics University of Science and Technology of China Hefei 230026 China School of Metallurgy and Resources Anhui University of Technology Maanshan 243002 China

A theoretical study on the reaction of aluminum with water in the gas phase was performed using the hybrid density functional B3LYP and QCISD（T） methods with the 6-311＋G（d,p） and the 6-311＋＋G（d,p） basis sets. The results show that there are three possible reaction pathways that involve four isomers, seven transition structures, and two possible products for the reaction of aluminum with water. The two most favorable reaction pathways were found, whose intermediates and products agreed quite well with experimental results. The enthalpy and Gibbs free energy change of the reaction between A1 and H2O at 298 and 2000 K were calculated. Some results are also in good agreement with the previous calculations or experimental results.

关键词： Aluminum Water Reaction mechanism Hybrid density functional theory

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