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Simplified quantitative analysis method and its application in the insitu synthesized copper-based azide chips

Defence Technology（防务技术） 2024年第2期32卷 309-316页

作者： Jie Ren Yunfeng Li Mingyu Li Xingyu wu Jiabao Wang Qingxuan zeng State Key Laboratory of Explosion and Technology Beijing Institute of TechnologyBeijing 100081China

Copper-based azide(Cu(N_(3))2 or CuN_(3),CA)chips synthesized by in-situ azide reaction and utilized in miniaturized explosive systems has become a hot research topic in recent ***,the advantages of in-situ synthesis method,including small size and low dosage,bring about difficulties in quantitative analysis and differences in ignition capabilities of CA *** aim of present work is to develop a simplified quantitative analysis method for accurate and safe analysis of components in CA chips to evaluate and investigate the corresponding ignition *** this work,Cu(N_(3))2 and CuN_(3)components in CA chips were separated through dissolution and distillation by utilizing the difference in solubility and corresponding content was obtained by measuring N_(3)-concentration through *** spectrophotometry method was optimized by studying influencing factors and the recovery rate of different separation methods was studied,ensuring the accuracy and reproducibility of test *** optimized method is linear in range from 1.0-25.0 mg/L,with a correlation coefficient R^(2)=0.9998,which meets the requirements of CA chips with a milligram-level content *** with the existing ICP method,component analysis results of CA chips obtained by spectrophotometry are closer to real component content in samples and have satisfactory ***,as its application in miniaturized explosive systems,the ignition ability of CA chips with different component contents for direct ink writing CL-20 and the corresponding mechanism was *** study provided a basis and idea for the design and performance evaluation of CA chips in miniaturized explosive systems.

关键词： Copper-based azide chips Spectrophotometry Separation method Quantitative analysis Ignition ability

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Role of methoxy and C_(α)-based substituents in electrochemical oxidation mechanisms and bond cleavage selectivity of β-O-4 lignin model compounds

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Green Energy & Environment 2024年第1期9卷 114-125页

作者： Yang Zhou Qiang zeng Hongyan He Kejia wu Fuqiao Liu Xuehui Li School of Chemistry and Chemical Engineering The Guangdong Provincial Key Laboratory of Green Chemical Product TechnologyState Key Laboratory of Pulp and Paper EngineeringSouth China University of TechnologyGuangzhouGuangdong510640China CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing100190China

In order to better understand the specific substituent effects on the electrochemical oxidation process of β-O-4 bond, a series of methoxyphenyl type β-O-4 dimer model compounds with different localized methoxyl groups, including 2-(2-methoxyphenoxy)-1-phenylethanone, 2-(2-methoxyphenoxy)-1-phenylethanol, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanol, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanol have been selected and their electrochemical properties have been studied experimentally by cyclic voltammetry, and FT-IR spectroelectrochemistry. Combining with electrolysis products distribution analysis and density functional theory calculations, oxidation mechanisms of all six model dimers have been explored. In particular, a total effect from substituents of both para-methoxy(on the aryl ring closing to Cα) and Cα-OH on the oxidation mechanisms has been clearly observed, showing a significant selectivity on the Cα-Cβbond cleavage induced by electrochemical oxidations.

关键词： Lignin model compounds β-O-4 dimers Electrochemical oxidation Oxidation mechanisms Substituent effect

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淋洗技术在污染土壤修复中的研究应用

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广东化工 2024年第10期51卷 99-100,80页

作者：王玉鹏宋树祥王薇曾武彭海榕崔晓荧广州环投环境服务有限公司广东广州510000 广州环投清洁能源投资有限公司广东广州510900 广州环净环保工程有限公司广东广州510540

我国土壤污染防治形势严峻,区域性、流域性土壤污染态势依然突出,土壤污染风险加大,农产品质量安全、人居环境安全和生态环境仍然面临较大威胁。本文主要分析了目前我国污染土壤化学淋洗修复技术的研究现状与研究进展,着重分析了淋洗修... 详细信息

我国土壤污染防治形势严峻,区域性、流域性土壤污染态势依然突出,土壤污染风险加大,农产品质量安全、人居环境安全和生态环境仍然面临较大威胁。本文主要分析了目前我国污染土壤化学淋洗修复技术的研究现状与研究进展,着重分析了淋洗修复过程中淋洗药剂的种类、pH,淋洗时间、淋洗剂的使用量等因素对淋洗修复效果的影响。同时在常规的淋洗技术基础上,本文也分析了超声强化、微波强化、化学氧化/还原强化等物理强化和化学强化淋洗技术研究进展,为土壤淋洗技术的研究作了进一步概述,并在最后对污染土壤淋洗修复技术进行了一系列展望。

关键词：环境污染土壤修复淋洗技术影响因素强化淋洗

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Personalized Lower Limb Gait Reconstruction Modeling Based on RFA-ProMP

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Computers, Materials & Continua 2024年第7期80卷 1441-1456页

作者： Chunhong zeng Kang Lu Zhiqin He Qinmu wu College of Electrical Engineering Guizhou UniversityGuiyang550025China

Personalized gait curves are generated to enhance patient adaptability to gait trajectories used for passive training in the early stage of rehabilitation for hemiplegic *** article utilizes the random forest algorithm to construct a gait parameter model,which maps the relationship between parameters such as height,weight,age,gender,and gait speed,achieving prediction of key points on the gait *** enhance prediction accuracy,an attention mechanism is introduced into the algorithm to focus more on the main ***,to ensure high similarity between the reconstructed gait curve and the normal one,probabilistic motion primitives(ProMP)are used to learn the probability distribution of normal gait data and construct a gait ***,using the specified step speed as input,select a reference gait trajectory from the learned trajectory,and reconstruct the curve of the reference trajectoryusing the gait keypoints predictedby the parametermodel toobtain the final *** results demonstrate that the method proposed in this paper achieves 98%and 96%curve correlations when generating personalized lower limb gait curves for different patients,respectively,indicating its suitability for such tasks.

关键词： Personalized lower limb gait prediction random forest probabilistic movement primitives

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基于红外光谱法的GIS设备SF_(6)气体泄漏识别研究

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电工技术 2024年第7期 146-148页

作者：曾武周鸿肖程威万晓丽陈治洁贵州电网有限责任公司六盘水供电局贵州六盘水553000

当前GIS设备SF_(6)气体泄漏识别的特征提取一般为独立形式,导致识别效率较低。为此进行基于红外光谱法的GIS设备SF_(6)气体泄漏识别研究。根据当前设备的需求及标准,首先进行气体泄漏异常数据的采集,并提取泄漏信号的共性特征,以此来提... 详细信息

当前GIS设备SF_(6)气体泄漏识别的特征提取一般为独立形式,导致识别效率较低。为此进行基于红外光谱法的GIS设备SF_(6)气体泄漏识别研究。根据当前设备的需求及标准,首先进行气体泄漏异常数据的采集,并提取泄漏信号的共性特征,以此来提高识别的效率;然后构建红外光谱SF_(6)气体泄漏识别模型,并采用多维修正的方式来强化识别结果。测试结果表明,针对随机选定的4台GIS设备,经过3个周期的测试,最终得出的泄漏位置识别数均可达到15次以上,说明在红外光谱法的辅助下,设计的GIS设备SF_(6)气体泄漏识别方法更加灵活且针对性强,具有实际的应用价值与创新意义。

关键词：红外光谱法 GIS设备 SF_(6)气体泄漏气体识别设备辅助

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Triassic integrative stratigraphy,biotas,and paleogeographical evolution of the Qinghai-Tibetan Plateau and its surrounding areas

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Science China Earth Sciences 2024年第4期67卷 1152-1194页

作者： Guichun wu Zhansheng JI Gary GLASH Qinggao zeng Jianxin YAO Key Laboratory of Stratigraphy and Palaeontology Ministry of Natural ResourcesInstitute of GeologyChinese Academy of Geological SciencesBeijing 100037China SinoProbe Laboratory Chinese Academy of Geological SciencesBeijing 100094China Department of Geology and Environmental Sciences State University of New York-FredoniaFredoniaNY 14063USA Xizang Autonomous Region Geological and Mineral Exploration and Development Burea Lhasa 850010China

Rocks of the Qinghai-Tibetan Plateau(QTP)host abundant Triassic *** far,the well established marine fossil sequences based on ammonoids,conodonts,bivalves,brachiopods,radiolarians,and terrestrial spora-pollen sequence have become standard for biostratigraphic correlation of the *** much of Triassic time,the QTP occupied a marine setting as suggested by the dominance of marine *** main sedimentary types represented in the Triassic successions include littoral to shallow marine clastic rocks,shallow marine carbonate platform carbonates,bathyal to abyssal slope carbonates intercalated with clastic and siliceous deposits,coal-bearing clastic strata contained within paralic facies deposits,and littoral and terrestrial volcaniclastic *** deposits are organized into four stages in ascending order:(1)Early Triassic deposits that record marine transgression,including extensive shallow marine carbonate platform strata.(2)Middle Triassic Ladinian to Late Triassic Carnian deposits,including thin-bedded limestone,fine clastics,and siliceous rocks,that accumulated at greater depths than underlying Early Triassic strata and reflect the peak of the *** activity appears to have occurred in some areas during this stage.(3)Late Triassic Norian deposits that record the onset of marine regression as suggested by the widespread occurrence of platform *** is noteworthy that stage 3 deposits of the Qin-Qi-Kun area in the northernmost region of the QPT is dominated by terrestrial strata and displays evidence of local erosion.(4)Late Triassic Rhaetian littoral and shallow marine clastic and coal-bearing deposits that preserve the record of continued marine regression *** Indus-Yarlungzangbo Suture Zone(IYSZ)appears to have been the rifting axis during Triassic time as suggested by sedimentary facies trends that reflect deepening to south and ***,the Himalaya Block to the south of the IYSZ was part of the passive margin

关键词： Qinghai-Tibetan Plateau Triassic Biostratigraphy Lithostratigraphy Palaeobiogeography Sedimentary palaeogeography

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Evaluation of Well Spacing for Primary Development of Fractured Horizontal Wells in Tight Sandstone Gas Reservoirs

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Fluid Dynamics & Materials Processing 2024年第5期20卷 1015-1030页

作者： Fang Li Juan wu Haiyong Yi Lihong wu Lingyun Du Yuan zeng Exploration and Development Research Institute PetroChina Southwest Oil&Gas Field CompanyChengdu610041China Oil and Gas Resources Department PetroChina Southwest Oil&Gas Field CompanyChengdu610000China

Methods for horizontal well spacing calculation in tight gas reservoirs are still adversely affected by the complexity of related control factors,such as strong reservoir heterogeneity and seepage *** this study,the stress sensitivity and threshold pressure gradient of various types of reservoirs are quantitatively evaluated through reservoir seepage *** the basis of these experiments,a numerical simulation model(based on the special seepage mechanism)and an inverse dynamic reserve algorithm(with different equivalent drainage areas)were *** well spacing ranges of Classes I,II,and III wells in the Q gas field are determined to be 802–1,000,600–662,and 285–400 m,respectively,with their average ranges as 901,631,and 342.5 m,*** considering both the pairs of parallel well groups and series well groups as examples,the reliability of the calculation results is *** is shown that the combination of the two models can reduce errors and provide accurate results.

关键词： Well spacing for primary development tight gas reservoir fractured horizontal well threshold pressure gradient stress sensitivity

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Evaluation of the binding affinity and antioxidant activity of phlorizin to pepsin and trypsin

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Food Science and Human Wellness 2024年第1期13卷 392-400页

作者： Jing Zhang Lan Tang Xia Hu Zhen zeng Wen wu Fang Geng Hui Li Di wu Meat Processing Key Laboratory of Sichuan Province School of Food and Biological EngineeringChengdu UniversityChengdu 610106China School of Chemical Engineering Sichuan UniversityChengdu 610065China

Phlorizin(PHL)is a natural compound with strong antioxidant properties mainly found in *** this paper,the interaction mechanism of PHL with pepsin and trypsin was comparatively evaluated by computer simulation,fluorescence spectra,circular dichroism(CD),and Fourier transform infrared(FT-IR)spectra at a molecular *** spectra showed that PHL quenches the pepsin/trypsin by static *** parameters indicated that PHL binds to pepsin mainly through hydrogen bonds and van der Waals forces,and that of trypsin was electrostatic *** ground state complexes PHL and protease have a moderate affinity of 105 L/mol PHL binds more strongly to trypsin than to *** and FT-IR spectra results showed that pepsin/trypsin decreased theβ-sheet content and slightly changed its secondary structure upon *** experimental results are mutually verified with the predicted computer-aid simulation *** PHL and trypsin binding,the antioxidant capacity of PHL was ***,the antioxidant capacity of PHL was decreased after binding to *** work elucidates the binding of PHL binding mechanisms to pepsin/trypsin and provides useful information for the digestion of PHL to improve the application of PHL in food processing.

关键词： Interaction Phlorizin Pepsin Trypsin Antioxidation

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High-order time-reversal symmetry breaking normal state

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Science China(Physics,Mechanics & Astronomy) 2024年第3期67卷 136-148页

作者： Meng zeng Lun-Hui Hu Hong-Ye Hu Yi-Zhuang You Congjun wu Department of Physics University of CaliforniaSan DiegoCalifornia 92093USA Department of Physics Zhejiang UniversityHangzhou 310058China New Cornerstone Science Laboratory Department of PhysicsSchoolof ScienceWestlake UniversityHangzhou 30024China Institute for Theoretical Sciences Westlake UniversityHangzhou 310024China Key Laboratory for Quantum Materials of Zhejiang Province School of ScienceWestlake UniversityHangzhou 310024China Institute of Natural Sciences Westlake Institute for Advanced StudyHangzhou 310024China

Spontaneous time-reversal symmetry breaking plays an important role in studying strongly correlated unconventional *** two superconducting gap functions with different symmetries compete,the relative phase channel(θ_(-)≡θ_(1)-θ_(2))exhibits an Ising-type Z_(2) symmetry due to the second order Josephson coupling,where θ_(1,2) are the phases of two gap *** contrast,the U(1) symmetry in the channel of θ_(+)≡(θ_(1)+θ_(2))/2 is *** phase locking,i.e.,ordering of θ_(-),can take place in the phase fluctuation regime before the onset of superconductivity,i.e.,when θ_(+) is *** θ_(-) is pinned at ±π/2,then timereversal symmetry is broken in the normal state,otherwise,if θ_(-)=0,or,π,rotational symmetry is broken,leading to a nematic normal *** both cases,the order parameters possess a 4-fermion structure beyond the scope of mean-field theory,which can be viewed as a high order symmetry *** employ an effective two-component XY-model assisted by a renormalization group analysis to address this *** a natural by-product,we also find the other interesting intermediate phase corresponds to ordering of θ_+ but with θ_(-)*** is the quartetting,or,charge-4e,superconductivity,which occurs above the low temperature Z_(2)-breaking charge-2e superconducting *** results provide useful guidance for studying novel symmetry breaking phases in strongly correlated superconductors.

关键词： superconductivity strong correlation time-reversal breaking charge-4e

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Simultaneous removal of Cd(Ⅱ)and As(Ⅴ)by ferrihydrite-biochar composite:Enhanced effects of As(Ⅴ)on Cd(Ⅱ)adsorption

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Journal of Environmental Sciences 2024年第5期139卷 267-280页

作者： Wenjun zeng Yang Lu Jingyan Zhou Jie Zhang Yuanxiao Duan Changxun Dong Wencheng wu College of Sciences Nanjing Agricultural UniversityNanjing 210095China South China Institute of Environmental Sciences Ministry of Ecology and EnvironmentGuangzhou 510655China Guangdong Engineering&Technology Research Center for System Control of Livestock and Poultry breeding Pollution Guangzhou 510655China

The coexistence of cadmium(Cd(Ⅱ))and arsenate(As(Ⅴ))pollution has long been an environmental ***,a porous carbonaceous material with tunable functionality,has been used for the remediation of contaminated ***,it is still challenging for the dynamic quantification and mechanistic understanding of the simultaneous sequestration of multi-metals in biochar-engineered environment,especially in the presence of *** this study,ferrihydrite was coprecipitated with biochar to investigate how ferrihydritebiochar composite affects the fate of heavy metals,especially in the coexistence of Cd(Ⅱ)and As(Ⅴ).In the solution system containing both Cd(Ⅱ)and As(Ⅴ),the maximum adsorption capacities of ferrihydrite-biochar composite for Cd(Ⅱ)and As(Ⅴ)reached 82.03μmol/g and 531.53μmol/g,respectively,much higher than those of the pure biochar(26.90μmol/g for Cd(Ⅱ),and 40.24μmol/g for As(Ⅴ))and ferrihydrite(42.26μmol/g for Cd(Ⅱ),and 248.25μmol/g for As(Ⅴ)).Cd(Ⅱ)adsorption increased in the presence of As(Ⅴ),possibly due to the changes in composite surface charge in the presence of As(Ⅴ),and the increased dispersion of ferrihydrite by *** microscopic and mechanistic results showed that Cd(Ⅱ)complexed with both biochar and ferrihydrite,while As(Ⅴ)was mainly complexed by ferrihydrite in the Cd(Ⅱ)and As(Ⅴ)coexistence *** posed vital importance for the co-adsorption of Cd(Ⅱ)and As(Ⅴ).The different distribution patterns revealed by this study help to a deeper understanding of the behaviors of cations and anions in the natural environment.

关键词： Ferrihydrite Biochar Cadmium Arsenate Simultaneous sequestration Binding mechanisms

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