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In-silico synthesis of lowest-pressure high-T_(c) ternary superhydrides

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npj Computational Materials 2022年第1期8卷 1119-1125页

作者： Roman Lucrezi Simone Di Cataldo wolfgang von der linden Lilia Boeri Christoph Heil Institute of Theoretical and Computational Physics Graz University of TechnologyNAWI Graz8010GrazAustria Dipartimento di Fisica Sapienza Universitàdi Roma00185RomeItaly Enrico Fermi Research Center Via Panisperna 89 A00184RomeItaly

We report the theoretical prediction of two high-performing hydride superconductors BaSiH_(8)and SrSiH_(8).They are thermodynamically stable above pressures of 130 and 174 GPa,respectively,and metastable below *** anharmonic phonon calculations,we determine the minimum pressures of dynamical stability to be around 3 GPa for BaSiH8 and 27 GPa for SrSiH_(8),and using the fully anisotropic Migdal-Eliashberg theory,we predict Tc’s around 71 and 126 K,*** also introduce a method to estimate the lowest pressure of synthesis,based on the calculation of the enthalpy barriers protecting the BaSiH_(8)Fm3¯m structure from decomposition at various *** kinetic pressure threshold is sensibly higher than the one based on dynamic stability,but gives a much more rigorous limit for synthesizability.

关键词： synthesis stability high

The impact of prehospital blood sampling on the emergency department process of patients with chest pain:a pragmatic non-randomized controlled trial

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World Journal of Emergency Medicine 2023年第4期14卷 257-264页

作者： Johan L.van Nieuwkerk M.Christien van der linden Rolf J.Verheul Merel van Loon-van Gaalen Marije Janmaat Naomi van der linden Emergency Department Haaglanden Medical Centre&Emergency Medical Services Haaglandenthe Hague 2501 CBthe Netherlands Research and Development Haaglanden Medical Centrethe Hague 2501 CKthe Netherlands Laboratory Services Haaglanden Medical Centrethe Hague 2501 CKthe Netherlands Emergency Department Haaglanden Medical Centrethe Hague 2501 CKthe Netherlands Faculty of Health University of Applied Sciences LeidenLeiden 2300 AJthe Netherlands Faculty of Technology Policy and ManagementDelft University of TechnologyDelft 2628 BXthe Netherlands

BACKGROUND:In patients with chest pain who arrive at the emergency department(ED)by ambulance,venous access is frequently established prehospital,and could be utilized to sample *** blood sampling may save time in the diagnostic *** this study,the association of prehospital blood draw with blood sample arrival times,troponin turnaround times,and ED length of stay(LOS),number of blood sample mix-ups and blood sample quality were ***:The study was conducted from October 1,2019 to February 29,*** patients who were transported to the ED with acute chest pain with low suspicion for acute coronary syndrome(ACS),outcomes were compared between cases,in whom prehospital blood draw was performed,and controls,in whom blood was drawn at the *** analyses were used to assess the association of prehospital blood draw with the time ***:Prehospital blood draw was performed in 100 *** 406 patients,blood draw was performed at the *** blood draw was independently associated with shorter blood sample arrival times,shorter troponin turnaround times and decreased LOS(P0.05).CONCLUSION:For patients with acute chest pain with low suspicion for ACS,prehospital blood sampling is associated with shorter time intervals,while there were no significant differences between the two groups in the validity of the blood samples.

关键词： Blood specimen collection Crowding Emergency medical services Troponin

Markets in crypto‑assets regulation:Does it provide legal certainty and increase adoption of crypto‑assets?

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Financial Innovation 2023年第1期9卷 509-538页

作者： Tina van der linden Tina Shirazi Faculty of Law Transnational Legal StudiesVrije Universiteit Amsterdam1081 HV AmsterdamThe Netherlands Zurich Switzerland

This study discusses the European Union’s proposal for a Regulation on Markets in Crypto-Assets,now subject to formal approval by the European *** objective is to explore whether it will positively impact the adoption of crypto-assets in the financial *** use of crypto-assets is ***,some stakeholders in the financial service sector remain skeptical and hesitant to adopt assets that are yet to be defined and have an unclear legal *** regulatory uncertainty has been identified as the primary reason for the reluctant *** proposed regulation(part of the EU’s Digital Finance Strategy)aims to provide this legal certainty for currently unregulated *** study investigates whether or not the proposed regulation can be expected to have the intended effect by reviewing the proposed regulation itself,the opinions and reactions of the various stakeholders,and secondary *** reveal that such regulation will most likely not accelerate the adoption of crypto-assets in the EU financial services sector,at least not sufficiently or as *** suggestions are made to improve the proposal.

关键词： MiCA regulation Crypto-assets Legal certainty Blockchain Distributed ledger technology Utility tokens Stablecoins Asset-referenced tokens e-money tokens

Predicting nitrogen use efficiency,nitrogen loss and dry matter intake of individual dairy cows in late lactation by including mid‑infrared spectra of milk samples

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Journal of Animal Science and Biotechnology 2023年第3期14卷 1287-1299页

作者： Rui Shi Wenqi Lou Bart Ducro Aart van der linden Han A.Mulder Simon J.Oosting Shengli Li Yachun Wang Laboratory of Animal Genetics Breeding and ReproductionMinistry of Agriculture of ChinaNational Engineering Laboratory of Animal BreedingCollege of Animal Science and TechnologyChina Agricultural UniversityBeijing 100193China Wageningen University&Research Animal Breeding and Genomics P.O.Box 3386700 AH Wageningenthe Netherlands Animal Production System Group Wageningen University&ResearchP.O.Box 3386700 AH Wageningenthe Netherlands

Background Nitrate leaching to groundwater and surface water and ammonia volatilization from dairy farms have negative impacts on the ***,the increasing demand for dairy products will result in more pollution if N losses are not ***,a more efficient,and environmentally friendly production system is needed,in which nitrogen use efficiency(NUE)of dairy cows plays a key *** genetically improve NUE,extensively recorded and cost-effective proxies are essential,which can be obtained by including mid-infrared(MIR)spectra of milk in prediction models for *** study aimed to develop and validate the best prediction model of NUE,nitrogen loss(NL)and dry matter intake(DMI)for individual dairy cows in *** A total of 86 lactating Chinese Holstein cows were used in this *** data editing,704 records were obtained for calibration and *** prediction models with three different machine learning algorithms and three kinds of pre-processed MIR spectra were developed for each *** showed that the coefficient of determination(R2)of the best model in within-herd validation was 0.66 for NUE,0.58 for NL and 0.63 for *** external validation,reasonable prediction results were only observed for NUE,with R2 ranging from 0.58 to 0.63,while the R2 of the other two traits was below *** infrared waves from 973.54 to 988.46 cm−1 and daily milk yield were the most important variables for *** The results showed that individual NUE can be predicted with a moderate accuracy in both within-herd and external *** model of NUE could be used for the datasets that are similar to the calibration *** prediction models for NL and 3-day moving average of DMI(DMI_a)generated lower accuracies in within-herd *** also indicated that information of MIR spectra variables increased the predictive ability of ***,pre-processed MIR spectra do not result in higher acc

关键词： Dairy cow Environment Mid-infrared spectra Nitrogen use efficiency Prediction

Optimizing the oxide support composition in Pr-doped CeO_(2) towards highly active and selective Ni-based CO_(2) methanation catalysts

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Journal of Energy Chemistry 2022年第8期31卷 547-561,I0015页

作者： Anastasios I.Tsiotsias Nikolaos D.Charisiou Ayesha AlKhoori Safa Gaber Vlad Stolojan Victor Sebastian Bart van der linden Atul Bansode Steven J.Hinder Mark A.Baker Kyriaki Polychronopoulou Maria A.Goula Laboratory of Alternative Fuels and Environmental Catalysis(LAFEC) Department of Chemical EngineeringUniversity of Western MacedoniaGR-50100Greece Department of Mechanical Engineering Khalifa University of Science and TechnologyAbu DhabiP.O.Box 127788United Arab Emirates Center for Catalysis and Separations Khalifa University of Science and TechnologyAbu DhabiP.O.Box 127788United Arab Emirates Advanced Technology Institute Department of Electrical and Electronic EngineeringUniversity of SurreyGuildford GU24DLUK Department of Chemical Engineering and Environmental Technology Universidad de ZaragozaCampus Río Ebro-Edificio I+D50018 ZaragozaSpain Instituto de Nanociencia y Materiales de Aragón(INMA) Universidad de Zaragoza-CSICc/María de Luna 350018 ZaragozaSpain Networking Research Center on Bioengineering Biomaterials and NanomedicineCIBERBBN28029 MadridSpain Department of Chemical Engineering Delft University of TechnologyVan der Massweg 92629 HZ DelftThe Netherlands The Surface Analysis Laboratory Faculty of Engineering and Physical SciencesUniversity of SurreyGuildford GU24DLUK

In this study,Ni catalysts supported on Pr-doped Ce O_(2) are studied for the CO_(2) methanation reaction and the effect of Pr doping on the physicochemical properties and the catalytic performance is thoroughly *** is shown,that Pr^(3+)ions can substitute Ce^(4+)ones in the support lattice,thereby introducing a high population of oxygen vacancies,which act as active sites for CO_(2) *** doping can also act to reduce the crystallite size of metallic Ni,thus promoting the active metal *** performance evaluation evidences the promoting effect of low Pr loadings(5 at%and 10 at%)towards a higher catalytic activity and lower CO_(2) activation *** the other hand,higher Pr contents negate the positive effects on the catalytic activity by decreasing the oxygen vacancy population,thereby creating a volcano-type trend towards an optimum amount of aliovalent substitution.

关键词： Power-to-gas CO_(2)methanation Ni-based catalyst Pr-doped CeO_(2) Oxygen vacancy Catalytic activity Activation energy

Ellipticity on spaces with higher singularities

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Science China Mathematics 2017年第11期60卷 2053-2076页

作者： CHANG der-Chen SCHULZE Bert-wolfgang Department of Mathematics and Statistics Georgetown University Department of Mathematics Fu Jen Catholic University Institute of Mathematics University of Potsdam

We study corner-degenerate pseudo-differential operators of any singularity order and develop ellipticity based on the principal symbolic hierarchy, associated with the stratification of the underlying space. We construct parametrices within the calculus and discuss the aspect of additional trace and potential conditions along lower-dimensional strata.

关键词：空间椭圆奇异伪微分算子椭圆度微积分层相低维

Vagus-preserving Merendino-Procedure for Early Carcinoma ofthe Gastroesophageal Junction

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The Chinese-German Journal of Clinical Oncology 2004年第4期3卷 226-228页

作者： Christian A. Gutschow wolfgang Schrder Department of Visceral- and Vascular Surgery University of CologneDepartment of Visceral- and Vascular Surgery University of Cologne Cologne GermanyCologne Germany

Optimal therapy for early carcinoma of the gastroesophageal junction remains uncertain. Treat- ment alternatives discussed today reach from endoluminal techniques to radical esophagectomy with 2- or 3-?eld lymphadenectomy. In this context, the Merendino procedure with preservation of the vagal innerva- tion to the stomach appears as an interesting therapeutic alternative. This paper summarizes indications, operative technique, and functional results with respect to postoperative quality of life, based upon 2 cases operated in our department.

关键词：迷走神经 Merendino术胃食管连接部早期癌肿瘤消化系统

Increased food intake after starvation enhances sleep in Drosophila melanogaster

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Journal of Genetics and Genomics 2017年第6期44卷 319-326页

作者： Josue M.Regalado McKenna B.Cortez Jeremy Grubbs Jared A.Link Alexander van der linden Yong Zhang Department of Biology University of Nevada-Reno

Feeding and sleep are highly conserved,interconnected behaviors essential for *** has been shown to potently suppress sleep across species;however,whether satiety promotes sleep is still *** we use the fruit fly,Drosophila melanogaster,as a model organism to address the interaction between feeding and *** first monitored the sleep of flies that had been starved for 24 h and found that sleep amount increased in the first 4 h after flies were given *** sleep after starvation was due to an increase in sleep bout number and average sleep bout *** of translin or adipokinetic hormone,which fail to suppress sleep during starvation,still exhibited a sleep increase after starvation,suggesting that sleep increase after starvation is not a consequence of sleep loss during *** also found that feeding activity and food consumption were higher in the first 10-30 min after *** food consumption in starved flies to 30 min was sufficient to increase sleep for 1 *** flies ingested a comparable amount of food at differing sucrose concentrations,sleep increase after starvation on a lower sucrose concentration was *** together,our results suggest that increased food intake after starvation enhances sleep and reveals a novel relationship between feeding and sleep.

关键词： Drosophila Feeding Sleep Starvation Satiety

Surface functionalized N-C-TiO_(2)/C nanocomposites derived from metal-organic framework in water vapour for enhanced photocatalytic H generation

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Journal of Energy Chemistry 2021年第6期30卷 485-495,I0012页

作者： Mian Zahid Hussain Zhuxian Yang Bart van der linden Zheng Huang Quanli Jia Erik Cerrato Roland A.Fischer Freek Kapteijn Yanqiu Zhu Yongde Xia College of Engineering Mathematics and Physical SciencesUniversity of ExeterExeter EX44QFUnited Kingdom Department of Chemistry and Catalysis Research Center Technical University of MunichGarching 85748Germany Catalysis Engineering Chemical Engineering DepartmentDelft University of Technologyvan der Maasweg92629 HZ DelftNetherlands Henan Key Laboratory of High Temperature Functional Ceramics Zhengzhou UniversityZhengzhou 450052HenanChina Department of Chemistry University of TurinVia P.Giuria710125 TurinItaly

Surface-functionalized nitrogen/carbon co-doped polymorphic TiO_(2) phase junction nanoparticles uniformly distributed in porous carbon matrix were synthesized by a simple one-step pyrolysis of titanium based metal-organic framework(MOF),NH_(2)-MIL^(-1)25(Ti) at 700℃ under water vapour *** water vapour during the pyrolysis of NH_(2)-MIL^(-1)25(Ti) not only functionalizes the derived porous carbon matrix with carboxyl groups but also forms additional oxygen-rich N like interstitial/intraband states lying above the valence band of TiO2 along with the self-doped carbo n,which further narrows the energy band gaps of polymorphic TiO2 nanoparticles that enhance photocatalytic charge transfer *** co-catalyst,sample N-C-TiO2/CArW demonstrates H_(2) evolution activity of 426 μmol gcat-1h^(-1),which remarkably outperforms commercial TiO_(2)(P-25) and N-C-TiO_(2)/CAr with a 5-fold and 3-fold H_(2) generation,*** study clearly shows that water vapour atmosphere during the pyrolysis increases the hydrophilicity of the Ti-MOF derived composites by functionalizing porous carbon matrix with carboxylic groups,as well as enhancing the electrical conductivity and charge transfer efficiency due to the formation of additional localized oxygen-rich N like interstitial/intraband *** work also demonstrates that by optimizing the anatase-rutile phase composition of the TiO2 polymorphs,tuning the energy band gaps by N/C co-doping and functionalizing the porous carbon matrix in the N-C-TiO2/C nanocomposites,the photocatalytic H_(2) generation activity can be further enhanced.

关键词： Metal-organic framework TiO_(2) Porous carbon Nanocomposite Photocatalysis Hydrogen generation