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Based on non-targeted metabolomics for differential components screening of Rosae Chinensis Flos and Rosae Rugosae Flos and their quality evaluation

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Traditional Medicine Research 2025年第2期10卷 1-15页

作者： Xu Liang Ni-Hui Zhang Zhi-Lai Zhan Guang-Lu Chang Yan Gao Xia Li wen-Yuan Gao School of Pharmaceutical Science and Technology Faculty of MedicineTianjin UniversityTianjin 300193China State Key Laboratory for Quality Ensurance and Sustainable Use of Dao-di Herbs China Academy of Chinese Medical SciencesBeijing 100700China Key Laboratory of Modern Chinese Medicine Resources Research Enterprises Tianjin 300402China

Background:Rosa chinensis *** Rosa rugosa *** not only of ornamental value,but also edible flowers and the flower buds have been listed in the Chinese Pharmacopoeia as traditional *** two plants have some differences in efficacy,but the flower buds are easily confused for similar *** addition,large-scale cultivation of ornamental rose flowers may lead to a decrease in the effective components of medicinal ***,it is necessary to study the chemical composition and make quality evaluation of Rosae Chinensis Flos(Yueji)and Rosae Rugosae Flos(Meigui).Methods:In this study,40 batches of samples including Meigui and Yueji from different regions in China were collected to establish high-performance liquid chromatography ***,the fingerprints data was analyzed using principal component analysis,hierarchical cluster analysis,and partial least squares discriminant analysis analysis chemometrics to obtain information on intergroup differences,and non-targeted metabolomic techniques were applied to identify and compare chemical compositions of samples which were chosen from groups with large *** compounds were screened by orthogonal partial least-squares discriminant analysis and S-plot,and finally multi-component quantification was performed to comprehensively evaluate the quality of Yueji and ***:The similarity between the fingerprints of 40 batches roses and the reference print R was 0.73 to 0.93,indicating that there were similarities and differences between the *** principal component analysis and hierarchical cluster analysis of fingerprints data,the samples from different origins and varieties were intuitively divided into four *** least-squares discriminant analysis analysis showed that Meigui and Yueji cluster into two categories and the model was reliable.A total of 89 compounds were identified by high resolution mass spectrometry,mainly were flavonoids and flavon

关键词： Rosa chinensis Jacq. Rosa rugosa Thunb. metabolomics chemometrics multiple component quantification quality evaluation

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前提·问题·破题:高校德育与公共人培育之耦合同构

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黑龙江高教研究 2025年第2期43卷 95-101页

作者：吕文欢魏继才湘潭大学湖南湘潭411105

高校德育与公共人培育之耦合同构命题提出的核心旨归在于扭转大学生公共向度的沦落式微之势。二者耦合同构命题的成立在逻辑理路上互构共荣,即在育人结构优化上二者延异互构,相互有效嵌入并成为对方整体结构重要组成部分;在育人功能提... 详细信息

高校德育与公共人培育之耦合同构命题提出的核心旨归在于扭转大学生公共向度的沦落式微之势。二者耦合同构命题的成立在逻辑理路上互构共荣,即在育人结构优化上二者延异互构,相互有效嵌入并成为对方整体结构重要组成部分;在育人功能提升上二者属性对接,在二者基因属性互通互融互补互成中实现相互赋能进而激发功能叠加的倍增效应;在育人伦理规范上二者并非价值中立工具,而是承载着特定伦理规范、道德约束等价值负荷。后乡土社会高校德育与大学生公共精神培育工作耦合协同需要突破“群”“己”关系尺度失衡之困、“同”“异”审视偏差之困、话语权单向度之三大梗阻困顿。在厘清梗阻的基础上提出从“群”“己”极化走向“尺度平衡”、从“把握通约性”走向“尊重异质化”、从“围剿”走向“共存”的路径图景,最终期待高校德育与大学生公共精神培育工作共荣共建,产出“1+1>2”的育公共人之耦合效应。

关键词：后乡土社会高校德育公共人耦合

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基于微流控芯片评估富血小板血浆促进子宫内膜细胞的增殖

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中国组织工程研究 2025年第10期29卷 2091-2096页

作者：闻哲嘉吕芳苏州大学附属第二医院生殖中心江苏省苏州市215004

背景:富血小板血浆可促进薄型子宫内膜细胞的增殖,但存在剂量难以控制、取样困难等问题。微流控芯片具有高通量、低消耗、操作简便等优点,为模拟子宫内膜细胞在体微环境提供了新途径。目的:利用三通道微流控芯片构建富血小板血浆促进子... 详细信息

背景:富血小板血浆可促进薄型子宫内膜细胞的增殖,但存在剂量难以控制、取样困难等问题。微流控芯片具有高通量、低消耗、操作简便等优点,为模拟子宫内膜细胞在体微环境提供了新途径。目的:利用三通道微流控芯片构建富血小板血浆促进子宫内膜细胞增殖的研究模型。方法:从1名女性外周静脉血中提取富血小板血浆。采用含不同浓度[0%(对照),0.5%,1%,2%]富血小板血浆的无血清细胞培养基培养人子宫内膜间质细胞,采用划痕实验检测细胞迁移,CCK-8法检测细胞增殖。利用聚二甲基硅氧烷胶制备微流控芯片,该微流控芯片设计有3个通道,中间通道为细胞外基质水凝胶通道,左右两侧分别为人子宫内膜间质细胞及富血小板血浆通道,3个通道之间保存有可以相互沟通以及实现物质交换的面积,实验组两侧通道分别加入人子宫内膜间质细胞(绿色荧光蛋白GFP标记)和含0.5%富血小板血浆的无血清培养基,对照组两侧通道分别加入人子宫内膜间质细胞(绿色荧光蛋白GFP标记)和无血清细胞培养基,共培养48 h后,采用Ki67免疫荧光染色观察细胞增殖与迁移。结果与结论:(1)细胞划痕实验和CCK-8检测结果显示,与对照组相比,0.5%,1%,2%浓度的富血小板血浆可促进人子宫内膜间质细胞的迁移与增殖(P <0.05),并且0.5%浓度富血小板血浆的促进细胞迁移与增殖作用强于其他2个浓度(P <0.05);(2)Ki67免疫荧光染色结果显示,与对照组相比,实验组人子宫内膜间质细胞的增殖和迁移能力更强;(3)实验证实通过三通道微流控芯片可以模拟子宫内膜细胞的微环境,同时利用该系统验证了富血小板血浆可显著促进子宫内膜间质细胞的增殖与迁移。

关键词：微流控芯片富血小板血浆子宫内膜间质细胞子宫内膜增殖迁移细胞外基质薄型子宫内膜子宫内膜相关疾病

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马克思“机器论片段”语境下的数字技术再反思

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海南大学学报（人文社会科学版） 2025年第1期43卷 60-67页

作者：王文陶厚兴中国人民大学重阳金融研究院北京100872 兰州大学马克思主义学院甘肃兰州730000

马克思“机器论片段”重点论述了机器体系的产生及其在社会生产中的应用所引起的劳动资料技术化、一般智力对象化、固定资本扩大化、人机关系异化等一系列深刻变革。数字技术具有物质技术与社会历史双重属性,其一方面作为人造的“物体系... 详细信息

马克思“机器论片段”重点论述了机器体系的产生及其在社会生产中的应用所引起的劳动资料技术化、一般智力对象化、固定资本扩大化、人机关系异化等一系列深刻变革。数字技术具有物质技术与社会历史双重属性,其一方面作为人造的“物体系”,克服与弥补人类自身劳动力的不足,另一方面作为生产关系与资本权力的物性表达。数字技术的广泛应用导致工业时代的“机器悖论”演化为数字时代的“智能悖论”,集中表现为“劳动悖论”“时间悖论”与“解放悖论”。马克思“机器论片段”的机器技术思想对我们在数字时代审思数字技术,探索扬弃技术的权力与宰制,消解人与技术的异化关系,使技术真正摆脱压迫、剥削人的工具地位,成为提高劳动生产率,缩短必要劳动时间和增加自由支配时间,促进人类劳动解放与自由全面发展的现实路径依然具有理论与实践价值。

关键词：马克思机器论片段一般智力固定资本数字技术

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Bioinspired Ultrasensitive Flexible Strain Sensors for Real‑Time Wireless Detection of Liquid Leakage

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Nano-Micro Letters 2025年第3期17卷 310-327页

作者： Weilong Zhou Yu du Yingying Chen Congyuan Zhang Xiaowei Ning Heng Xie Ting Wu Jinlian Hu Jinping Qu Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationHubei Key Laboratory of Material Chemistry and Service Failure and Hubei Engineering Research Center for Biomaterials and Medical Protective MaterialsSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China School of Materials Science and Engineering Wuhan Institute of TechnologyWuhan 430205People’s Republic of China Department of Biomedical Engineering City University of Hong KongHong KongSAR 999077People’s Republic of China

Liquid leakage of pipeline networks not only results in considerableresource wastage but also leads to environmental pollution and ecological *** response to this global issue, a bioinspired superhydrophobic thermoplastic polyurethane/carbon nanotubes/graphene nanosheets flexible strain sensor (TCGS) hasbeen developed using a combination of micro-extrusion compression molding andsurface modification for real-time wireless detection of liquid leakage. The TCGSutilizes the synergistic effects of Archimedean spiral crack arrays and micropores,which are inspired by the remarkable sensory capabilities of scorpions. This designachieves a sensitivity of 218.13 at a strain of 2%, which is an increase of 4300%. Additionally, it demonstrates exceptional durability bywithstanding over 5000 usage cycles. The robust superhydrophobicity of the TCGS significantly enhances sensitivity and stability indetecting small-scale liquid leakage, enabling precise monitoring of liquid leakage across a wide range of sizes, velocities, and compositionswhile issuing prompt alerts. This provides critical early warnings for both industrial pipelines and potential liquid leakage scenariosin everyday life. The development and utilization of bioinspired ultrasensitive flexible strain sensors offer an innovative and effectivesolution for the early wireless detection of liquid leakage.

关键词： Thermoplastic polyurethane Bioinspired Cracks Liquid leakage Flexible strain sensor

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简牍所见秦及西汉初期的未成年“户人”研究

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南都学坛 2025年第1期45卷 13-20页

作者：文霞广东第二师范学院历史与社会发展学院广东广州510303

秦及西汉初期的简牍中出现了一些未成年“户人”,他们均为男性。未成年人成为“户人”的主要影响因素包括性别、尊卑及家庭规模等,年龄不是重要考量因素。未成年男性或担任“户人”,或提前服役,过于繁重的赋役迫使未成年男性作为劳动力... 详细信息

秦及西汉初期的简牍中出现了一些未成年“户人”,他们均为男性。未成年人成为“户人”的主要影响因素包括性别、尊卑及家庭规模等,年龄不是重要考量因素。未成年男性或担任“户人”,或提前服役,过于繁重的赋役迫使未成年男性作为劳动力的价值得到提升。未成年人“户人”被提前成人化,既体现了国家在行政管理上对个人身份信息的漠视,也说明了皇帝和官僚集团极尽可能压榨人民的剩余劳动。

关键词：简牍未成年人户人女户

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ADMM-based Distributed State Estimation for Integrated Energy System

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CSEE Journal of Power and Energy Systems 2019年第2期5卷 275-283页

作者： Yaxin du wen Zhang Tingting Zhang Key Laboratory of Power System Intelligent Dispatch and Control of Ministry of Education Shandong UniversityJinan 250061China

In order to have an accurate knowledge of system-wide operation states,it is necessary to perform state estimation for the integrated energy system(IES)as the basis of energy man-agement and *** state estimation is practically infeasible for IES due to the unreliability of communication,the barrier on privacy,and the large scale of integrated *** paper proposes a distributed state estimation algorithm based on the alternating direction method of multipliers(ADMM)for IES containing electricity,heat,and natural *** coupling units are taken into full consideration in modeling of IES state estimation to reflect the harmonization of multi *** the basis of bilinear measurement model,the state estimation considering nonlinear measurements can be replaced by an equivalent three-stage problem containing two linear state estimations and an intermediate transformation to avoid non-convex *** three-stage procedure for IES state estimation can be further decoupled over three sub-systems with coordination on coupling units,yielding a fully distributed scheme based on ADMM.A modified ADMM with the self-adjusting penalty parameter is also adopted to enhance the *** results demonstrate the validity and superiority of the proposed algorithm.

关键词： Alternating direction method of multipliers coupling units distributed state estimation integrated energy system

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SPATIAL DIFFERENTIATION OF LAND TRANSFER——Case Study of Shanghai, Nanjing and Taizhou in Changjiang River Delta

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Chinese Geographical Science 2006年第1期16卷 24-31页

作者： du wen-xing HUANG Xian-jin ZHAI wen-xia PENG Bu-zhuo Department of Urban and Resources Sciences Nanjing University Nanjing 210093 P. R. China Department of Urban Plnnning and Resources Sciences Xianning College Xianning 437005 P. R. China

The policy of land transfer has greatly influenced the macro economy of China with the commencement of another innovation of land use system. Therefore, it is urgent to put forward some rational and feasible suggestions for local government to manage the market of land transfer. Moreover, it is important in the field of study on agricultural land use change to analyze the spatial differentiation and structural specification of land transfer, which are caused by rural households＇ behavior. This paper selected I l factors covering four aspects of rural households＇ family structure, family location, family income structure and the natural quality of land resources, all of which influence the behavior differentiation of rural households, to establish the index model indicating spatial differentiation of land transfer. Results show that the spatial differentiation of land transfer can be divided into four degrees and three categories through analyzing rural households＇ questionnaires from Shanghai, Nanjing and Taizhou in the Changjiang （Yangtze） River Delta. Since up to 80% of rural households belong to middle degrees, it can be concluded that the rural land market develops evenly in the study areas. And it is also indicated that the natural quality of land resources and the maximum income of rural land are most important factors influencing the spatial differentiation of land transaction. Considering different factors, the countermeasures can be carried out to enhance the spatial differentiation of land transfer so as to promote economic development and social security of rural China. All in all, both micro- factors and macro-factors influencing rural households＇ behavior of rural land transfer should be taken into account in order to make spatial differentiation and structural specification of rural land transfer notable.

关键词： land transfer spatial differentiation land transaction Changjiang River Delta

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Quantum Dynamics of Li+HF/DF Reaction Investigated by a State-to-State Time-dependent Wave Packet Approach

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Chinese Journal of Chemical Physics 2015年第4期28卷 -页

作者： wen-tao Li Mao-du Chen Zhi-gang Sun School of Physics and Optoelectronic Technology Dalian University of Technology Dalian 116024ChinaState Key Laboratory of Molecular Reaction Dynamics and Center for Theoretical Computational Chemistry Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 China School of Physics and Optoelectronic Technology Dalian University of Technology Dalian 116024China State Key Laboratory of Molecular Reaction Dynamics and Center for Theoretical Computational Chemistry Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 China

Using the reactant coordinate based time-dependent wave packet method, on the APW potential energy surface, the differential and integral cross sections of the Li+DF/HF(v=0, j=0, 1) reactions were calculated over the collision energy range from the threshold to 0.25 eV. The initial state-specified reaction rate constants of the title reaction were also calculated. The results indicate that, compared with the Li+DF reaction, the product LiF of Li+HF reaction is a little more rotationally excited but essentially similar. The initial rotational excitation from j=0 to 1 has little effect on the Li+DF reaction. However, the rotational excitation of DF does result in a little more rotationally excited product LiF. The different cross section of both reactions is forward biased in the studied collision energy range, especially at relatively high collision energy. The resonances in the Li+HF reaction may be identifiable as the oscillations in the product ro-vibrational state-resolved integral cross sections and backward scattering as a function of collusion energy. For the Li+HF reaction, the rate constant is not sensitive to the temperature and almost has no change in the temperature range considered. For the Li+DF reaction, the rate constant increase by a factor of about 10 in the temperature range of 100–300 K. Brief comparison for the total reaction probabilities and integral cross section of the Li+HF reaction has been carried out between ours and the values reported previously. The agreement is good, and the difference should come from the better convergence of our present calculations.

关键词： Quantum wavepacket Integral and differential cross section Reaction rate constant Li+HF/DF Isotope effect

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Recent progress in metal-organic frameworks(Part II—material application)

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Science China Chemistry 2025年

作者： Jiandong Pang wentao Jiang Xue-wen Zhang Hao-Long Zhou Yuxiu Sun Wei Gong Bin Wang Fuyin Ma Linwei He Long Chen Qiang Chen He-Qi Zheng Yuanjing Cui wen-Jie Shi Chao Zhang Mei Wang Yue-Biao Zhang Jie-Peng Zhang Chongli Zhong Yong Cui Shuao Wang Jian-Rong Li Guodong Qian Tong-Bu Lu Huan Pang Xian-He Bu Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology School of Chemistry and Chemical Engineering Yangzhou University School of Materials Science and Engineering Nankai University School of Physical Science and Technology ShanghaiTech University MOE Key Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering School of Chemistry IGCMESun Yat-sen University Department of Chemistry Shantou University School of Chemical Engineering and Technology Tiangong University School of Chemistry and Chemical Engineering Shanghai Jiao Tong University State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences Soochow University College of Materials Science & Engineering Beijing University of Technology State Key Laboratory of Silicon and Advanced Semiconductor Materials Cyrus Tang Center for Sensor Materials and ApplicationsSchool of Materials Science & Engineering Zhejiang University

As a class of functional crystalline porous materials, metal-organic frameworks(MOFs) gained rapid development in the past three decades and a large number of MOFs with ordered structures, high surface areas, and functionalized channels have been investigated. MOFs and MOF-derived/composite materials show great potential in many application fields. In this review, we discussed the main applications of MOFs and MOF-derived/composite materials in small molecule storage, separation, luminescence, sensing, multitype catalysis, and energy storage. In addition, challenges and problems in the future research of MOFsrelated fields are also discussed.

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