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Boosting nitrogen electrocatalytic fixation by three-dimensional TiO_(2-δ)N_δnanowire arrays

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Journal of Energy Chemistry 2022年第12期75卷 293-300,I0008页

作者： Jianjia Mu xuan-wen Gao Zhaomeng Liu wen-Bin Luo Zhenhua Sun Qinfen Gu Feng Li School of Metallurgy Northeastern UniversityShenyang 110819LiaoningChina Institute of Metal Research Chinese Academy of SciencesShenyang 110016LiaoningChina Australian Synchrotron(ANSTO) 800 Blackburn RdClayton 3168VictoriaAustralia

Owing to the environmental and inherent advantages,nitrogen reduction reaction(NRR)by electrocatalysts attracts global *** surface engineering is widely employed to enhance the electrocatalytic activity by atomic defects and heterostructure effects.A three-dimensional(3D)free-standing integrated electrode was fabricated by numerous nearly-single-crystal TiO_(2-δ)N_δnanowire *** on the high electronic conductivity network,it exposes numerous active sites as well to facilitate the selective nitrogen adsorption and*H adsorption *** synergistic effects between Ti^(3+)and oxygen vacancy(O_v)boost the intrinsic catalytic activity,in which Ti^(3+)acquired electrons via Ovcan effectively activate the N≡N bond and make it easy to bind with *** energy barrier of primary protonation process(*N_(2)+H^(+)+e^(-)→*NNH)can be dramatically *** highest ammonia yield rate(14.33μg h^(-1)mgcat^(-1))emerges at-0.2 V,while the optimal ammonia Faradaic efficiency(9.17%)is acquired at-0.1 *** functional theory(DFT)calculation reveals that the Ti^(3+)can be served as the active sites for nitrogen adsorption and activation,while ammonia synthesis is accomplished by the distal *** high electronic conductivity integrated network and synergistic effects can significantly facilitate nitrogen absorption and accelerate electrocatalytic reaction kinetic,which are responsible for the excellent NRR performance at room temperature.

关键词： Nanowires TiO_(2-δ)N_δ Electrocatalysis NRR DFT

Physical mechanism of the rapid increase in intense and long-lived extreme heatwaves in the Northern Hemisphere since 1980

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Science China Earth Sciences 2024年第7期67卷 2103-2121页

作者： Yuqing WANG wen zhou Chunzai WANG Key Laboratory of Polar Atmosphere-ocean-ice System for Weather and Climate of the MOE Department of Atmospheric and Oceanic Sciences&Institute of Atmospheric SciencesFudan UniversityShanghai 200438China Key Laboratory for Polar Science of the MNR Polar Research Institute of ChinaShanghai 201209China State Key Laboratory of Tropical Oceanography South China Sea Institute of OceanologyChinese Academy of SciencesGuangzhou 510301China Global Ocean and Climate Research Center South China Sea Institute of OceanologyChinese Academy of SciencesGuangzhou 510301China

Since 1980,both the intensity and duration of summer heatwaves in the middle and high latitudes of the Northern Hemisphere have significantly increased,leading this region to become a critical area for a significant increase in the frequency of intense and long-lived extreme *** found that stronger and more persistent high-pressure systems and lower soil moisture before the events were the main drivers of intense and long-lived extreme heatwaves in western Europe and the middle and high latitudes of North ***,in eastern Europe and Siberia,lower cloud cover before events is also a main driver of this type of extreme heatwave,in addition to the above *** factors are coupled with each other and can change heatwave intensity and duration by influencing surface radiation processes during *** the self-organizing map classification method,we found that 6 weather patterns with increased frequency,intensity,and duration were the main dynamic reasons leading to the increase in intense and long-lived extreme heatwaves after *** addition,the decrease in summer average soil moisture in most areas of the mid-high latitudes of the Northern Hemisphere and the decrease in average cloud cover in eastern Europe and Siberia are found to be the main thermodynamic reasons leading to the increase in these extreme heatwaves.

关键词： High intensity Long duration Extreme heatwaves High pressure system Soil moisture Cloud cover

Adsorbed and free gas occurrence characteristics and controlling factors of deep shales in the southern Sichuan Basin,China

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Petroleum Science 2023年第3期20卷 1301-1311页

作者： Shang-wen zhou Dong-Xiao Zhang Department of Energy and Resources Engineering College of EngineeringPeking UniversityBejing100871China PetroChina Research Institute of Petroleum Exploration and Development Beijing100083China School of Environmental Science and Engineering Southern University of Science and TechnologyShenzhenGuangdong 518055China

Deep shale gas(3500-4500 m)will be the important succeeding field for the growth of shale gas production in *** the condition of high temperature and high pressure in deep shale gas reservoirs,its gas occurrence characteristics are markedly different from those of medium and shallow *** elucidate the gas occurrence characteristics and controlling factors of deep shales in the Wufeng-Longmaxi Formation,methane adsorption,low-temperature N2,and cO2 adsorption experi-ments were *** results show that in deep shales,the mesopores provide approximately 75%of the total specific surface area(SA)and 90%of the total pore volume(PV).Based on two hypotheses and comparing the theoretical and actual adsorption capacity,it is speculated that methane is adsorbed in deep shale in the form of micropore filling,and free gas is mainly stored in the *** analysis demonstrated that ToC is the key material constraint for the adsorption capacity of deep shale,and micropore SSA is the key spatial *** minerals and mesopore parameters have limited effect on the amount of adsorbed ***,the free gas content ranges from 2.72 m^(3)/t to 6.20 m^(3)/t,with an average value of 4.60 m^(3)/t,and the free gas content ratio is approximately 58%,suggesting that the deep shale gas reservoirs are dominated by free *** ratio may also increase to approximately 70%when considering the formation temperature effect on adsorbed *** density,porosity,and gas saturation are the main controlling factors of free gas content,resulting in significantly larger free gas content in deep shale than in shallower formations.

关键词： Adsorbedgas Free gas Gas occurrence characteristics Deep shale

A NONMONOTONE SECOND-ORDER STEPLENGTH METHOD FOR UNCONSTRAINED MINIMIZATION

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Journal of Computational Mathematics 2007年第1期25卷 104-112页

作者： Qun-yan zhou wen-yu Sun Department of Basic Science Jiangsu Teachers University of Technology Changzhou 213001 China School of Mathematics and Computer Science Nanjing Normal University Nanjin9 210097 China School of Mathematics and Computer Science Nanjing Normal University Nanjing 210097 China

In this paper, a nonmonotone method based on McCormick＇s second-order Armijo＇s step-size rule [7] for unconstrained optimization problems is proposed. Every limit point of the sequence generated by using this procedure is proved to be a stationary point with the second-order optimality conditions. Numerical tests on a set of standard test problems are presented and show that the new algorithm is efficient and robust.

关键词： Nonmonotone method Armijo's line search Direction of negative curvature,Unconstrained optimization.

Synthesis of High-purity Fe_(2)AlB_(2) and the Effect as Sintering Additive for ZrB_(2)

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Chinese Journal of Structural Chemistry 2021年第3期40卷 283-290,271页

作者： WANG Rui XU wen-Tao QIN Zi-xuan LING Jun-Rong zhou You-Fu Fujian Normal University College of Chemistry and Materials ScienceFuzhou 350007China Key Laboratory of Optoelectronic Materials Chemistry and Physics Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of Sciences Beijing 100039China

Fe_(2)AlB_(2) powder material was prepared by the direct reaction of iron,aluminum and boron powders in a tubular *** effects of different Al contents,temperature and raw material pretreatment on the purity of product were *** mixed powder with the stoichiometric ratio of 1.5Al/2Fe/2B was processed by CIP (Cold Isostatic Pressing),and then calcined at 1150℃ for 120 *** product containing a small amount of impurities is treated with alkaline solution to obtain high-purity Fe_(2)Al B_(2) *** B_(2)-Fe_(2)Al B_(2) composite ceramic was successfully prepared at 1250℃ by hot pressing *** density,hardness and fracture toughness were 96.2%,22±0.3 GPa and 5.78±0.5 MPa·m^(1/2),respectively.

关键词： MAB phase ternary layered structure high purity ZrB_(2)

Optimal design of the gas storage surface pipeline system with injection and withdrawal conditions

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Petroleum 2021年第1期7卷 102-116页

作者： Jun zhou Liuling zhou Guangchuan Liang Shaobo Wang Tiantian Fu xuan zhou Jinghong Peng Petroleum Engineering School Southwest Petroleum UniversityChengduPR China CNPC Beijing Oil and Gas Control Center BeijingPR China

Underground natural gas storage(UNGS)is an important part of the natural gas supply system to ensure a balanced energy *** surface system,as an important part of the gas storage,undertakes the functions of gas injection and gas production of the gas storage,and its investment economy is of vital *** fact,the UNGS surface pipeline network has two-way injection and production characteristics,which is different from the one-way production characteristics of conventional oil&gas gathering and transportation *** paper takes the minimum investment of the pipeline network as the objective function,considers the gas injection and gas withdrawal flow conditions and esablishes a mixed integer non-linear programming model(MINLP)for the surface pipeline network of the UNGS to optimize its pipeline layout and diameter *** including the well affiliation,the number of stations,the gathering radius,the processing capacity and the flow/pressure equilibrium equations,are also taken into *** an UNGS in China as an example,the results of the optimal structure and diameter of the pipeline network,as well as the pipe flow,node pressure,and maximum/minimum flowrate during gas injection and gas withdrawal are ***,the effects of constraints such as processing capacity and radius on the structure layout and investment of the UNGS are analyzed,verifying the reliability and effectiveness of the model.

关键词： Optimal design Pipeline network Natural gas storage Injection and withdrawal

A Length-Adaptive Non-Dominated Sorting Genetic Algorithm for Bi-Objective High-Dimensional Feature Selection

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IEEE/CAA Journal of Automatica Sinica 2023年第9期10卷 1834-1844页

作者： Yanlu Gong Junhai zhou Quanwang Wu MengChu zhou Junhao wen College of Computer Science Chongqing UniversityChongqing 400044China IEEE Department of Electrical and Computer Engineering New Jersey Institute of TechnologyNewarkNJ 07102 USA College of Big Data and Software Engineering Chongqing UniversityChongqing 400044China

As a crucial data preprocessing method in data mining,feature selection(FS)can be regarded as a bi-objective optimization problem that aims to maximize classification accuracy and minimize the number of selected *** computing(EC)is promising for FS owing to its powerful search ***,in traditional EC-based methods,feature subsets are represented via a length-fixed individual *** is ineffective for high-dimensional data,because it results in a huge search space and prohibitive training *** work proposes a length-adaptive non-dominated sorting genetic algorithm(LA-NSGA)with a length-variable individual encoding and a length-adaptive evolution mechanism for bi-objective highdimensional *** LA-NSGA,an initialization method based on correlation and redundancy is devised to initialize individuals of diverse lengths,and a Pareto dominance-based length change operator is introduced to guide individuals to explore in promising search space ***,a dominance-based local search method is employed for further *** experimental results based on 12 high-dimensional gene datasets show that the Pareto front of feature subsets produced by LA-NSGA is superior to those of existing algorithms.

关键词： Bi-objective optimization feature selection(FS) genetic algorithm high-dimensional data length-adaptive

Construction of fault diagnosis system for control rod drive mechanism based on knowledge graph and Bayesian inference

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Nuclear Science and Techniques 2023年第2期34卷 58-75页

作者： Xue‑Jun Jiang wen zhou Jie Hou Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China University of Chinese Academy of Sciences Beijing 100049China

Knowledge graph technology has distinct advantages in terms of fault *** this study,the control rod drive mechanism(CRDM)of the liquid fuel thorium molten salt reactor(TMSR-LF1)was taken as the research object,and a fault diagnosis system was proposed based on knowledge *** subject–relation–object triples are defined based on CRDM unstructured data,including design specification,operation and maintenance manual,alarm list,and other forms of expert *** this study,we constructed a fault event ontology model to label the entity and relationship involved in the corpus of CRDM fault events.A three-layer robustly optimized bidirectional encoder representation from transformers(RBT3)pre-training approach combined with a text convolutional neural network(TextCNN)was introduced to facilitate the application of the constructed CRDM fault diagnosis graph database for fault *** RBT3-TextCNN model along with the Jieba tool is proposed for extracting entities and recognizing the fault query intent *** on the dataset collected from TMSR-LF1 CRDM fault diagnosis unstructured data demonstrate that this model has the potential to improve the effect of intent recognition and entity ***,a fault alarm monitoring module was developed based on WebSocket protocol to deliver detailed information about the appeared fault to the operator ***,the Bayesian inference method combined with the variable elimination algorithm was proposed to enable the development of a relatively intelligent and reliable fault diagnosis ***,a CRDM fault diagnosis Web interface integrated with graph data visualization was constructed,making the CRDM fault diagnosis process intuitive and effective.

关键词： CRDM Knowledge graph Fault diagnosis Bayesian inference RBT3-TextCNN Web interface

Transformations of N-arylpropiolamides to indoline-2,3-diones and acids via C≡C triple bond oxidative cleavage and C(sp^2)–H functionalization

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Science China Chemistry 2020年第2期63卷 222-227页

作者： Ming-Bo zhou Yang Li xuan-Hui Ouyang Jin-Heng Li Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Nanchang Hangkong UniversityNanchang 330063China Key Laboratory of Chemical Biology&Traditional Chinese Medicine Research(Ministry of Education) Hunan Normal UniversityChangsha 410081China State Key Laboratory of Applied Organic Chemistry Lanzhou University'Lanzhou 730000China

A new palladium-catalyzed oxidative conversion of N-arylpropiolamides and H2O to various indoline-2,3-diones and acids through the C≡C triple bond cleavage and C(sp2)–H functionalization is described,which is promoted by a cooperative action of catalytic CuBr2,2,2,6,6-tetramethyl-1-piperidinyloxy(TEMPO)and *** method provides a practical tool for transformations of alkynes by means of a C–H functionalization strategy,which enables the formation of one C–C bond and multiple C–O bonds in a single reaction with high substrates compatibility and excellent functional group tolerance.

关键词： alkynes indoline-2,3-diones acids C≡C bond oxidative cleavage C–H functionalization