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Engineering of Fe d-band center in Fe_(3)O_(4)/CeO_(2)hetero-nanoparticles via orbital coupling for high-efficiency oxygen reduction electrocatalysis

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Nano Research 2025年第1期18卷 129-139页

作者： Jiayi Liu Jingwen Yin Yingzi lin Mingxin Pang Huan Pang Songtao Zhang lin Xu Jun yang Yawen Tang Jiangsu Key Laboratory of New Power Batteries Jiangsu Collaborative Innovation Center of Biomedical Functional MaterialsSchool of Chemistry and Materials ScienceNanjing Normal UniversityNanjing 210023Chin a 2 State Key Laboratory of Multiphase Complex Systems Center of MesoscienceInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemistry and Chemical Engineering Yangzhou UniversityYangzhou 225009China Testing Center Yangzhou UniversityYangzhou 225009China

The deliberate engineering of the d-band center of metal site represents an effective strategy to boost the intrinsic electrocatalytic performance toward the oxygen reduction reaction(ORR).Herein,following a heterointerfaceinduced orbital coupling rationale,we report a judicious design of an efficient ORR electrocatalyst consisting of Fe_(3)O_(4)/CeO_(2)hetero-nanoparticles in-situ encased into N-doped carbon nanofibers(abbreviated as Fe_(3)O_(4)/CeO_(2)@N-CNFs hereafter).The theoretic calculations uncover that the Fe_(3)O_(4)/CeO_(2)heterointerface-triggered orbital coupling can cause the down shift of the d-band center positions of Fe sites,which leads to the weakened chemisorption of oxygenated groups and lowered energy barrier for the potential-determining step,ultimately dramatically boosting the ORR intrinsic *** a consequence,the well-designed Fe_(3)O_(4)/CeO_(2)@N-CNFs display admirable ORR activity with a half-wave potential of 0.84 V and outstanding structural/electrochemical stability in an alkaline electrolyte,surpassing the commercial Pt/C benchmark and a majority of recently reported Fe_(3)O_(4)-based *** encouragingly,the Fe_(3)O_(4)/CeO_(2)@N-CNFsincorporated Zn-air battery outperforms the Pt/C-assembled counterpart with higher power density,larger energy density,and excellent cycling stability,serving as a competent candidate for ORR-involved renewable energy *** study offers an innovative approach for the rational manipulation of the d-band center and interfacial electron behavior of active sites toward the optimization of electrocatalytic performance.

关键词： hetero-nanoparticles electrospinning interfacial engineering orbital coupling oxygen reduction reaction

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Photothermal probiotics delivery of photodynamic agents for enhanced immunogenic cell death within hypoxia center of solid tumors

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Nano Research 2025年第1期18卷 642-652页

作者： wen Luo Shiyu Du Yateng Jiang Bangshun He Jun Tang Jingjing yang Yujun Song Jiangsu Key Laboratory of Artificial Functional Materials State Key Laboratory of Analytical Chemistry for Life ScienceNational Laboratory of Solid State MicrostructuresCollege of Engineering and Applied SciencesNanjing UniversityNanjing 210023China Department of Laboratory Medicine Nanjing First HospitalNanjing Medical UniversityNanjing 210006China Department of Anesthesiology Jinling HospitalMedical School of Nanjing UniversityNanjing 210000China Department of Biochemistry and Molecular Biology School of Medicine&Holistic Integrative MedicineJiangsu Collaborative Innovation Center of Chinese Medicinal Resources IndustrializationNanjing University of Chinese MedicineNanjing 210023China

Resulting from harsh hypoxic environmental conditions,central cells in the core of solid tumors are usually more aggressive and malignant with a less stable ***,therapeutic agents with improved penetration for the activation of immunity in tumor centers exhibit promising potential in ***,polydopamine-coated Escherichia coli Nissle 1917(EcN)bearing chlorin e6(Ce6)-loaded and polyethyleneimine(PEI)-coated hollow manganese dioxide(shorted as EP-ChP)are applied for enhanced immunotherapy in deep *** accumulation in tumor center through hypoxia targeting,manganese dioxide is degradated under the tumor microenvironment with released Ce6 and thus generates reactive oxygen species(ROS)upon 660 nm laser irradiation,which can further lower thermalresistance of cancer cells via HSP90α*** to that,heating induced by polydopamine upon 808 nm laser irradiation can achieve effective tumor *** upon dual laser induces enhanced immunogenic cell death,while bacterial infections in tumor tissues also trigger innate *** bacteria-based approach provides enhanced antitumor immune responses in deep tumors with great potential in the reshaping of immunosuppression tumor microenvironment.

关键词： bacteria phototherapies immunotherapy hypoxia targeting tumor penetration

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Light tuning CO/H_(2)composition on Ag:Unraveling CO_(2)mass transfer and electron-phonon coupling in plasmon-enhanced electrocatalysis

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Nano Research 2025年第1期18卷 173-185页

作者： Rui lin Dong Fan Luca MBerger Thomas Possmayer Yu Zhou Jiexin Zhu Xingbao Chen wen Luo Lars Allmendinger Andreas Tittl Leonardo de Souza Menezes Guillaume Maurin Shihe yang and Stefan AMaier Nanoinstitute Munich Faculty of PhysicsLudwig-Maximilians-Universität München80539 MunichGermany Institut Charles Gerhardt Montpellier UMR 5253 CNRS ENSCM UniversitéMontpellierPlace E.Bataillon34090 MontpellierFrance Guangdong Provincial Key Lab of Nano-Micro Material Research School of Advanced MaterialsPeking University Shenzhen Graduate SchoolShenzhen 518055China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Faculty of Chemistry and Pharmacy Ludwig-Maximilians-Universität München81377 MunichGermany Departamento de Física Universidade Federal de Pernambuco50670-901 Recife-PEBrazil School of Physics and Astronomy Monash University Clayton CampusMelbourneVictoria 3800Australia Department of Physics Imperial College LondonSW72AZ LondonUK

Plasmon-enhanced electrocatalysis(PEEC)is an emerging approach to mitigate CO_(2)*** mechanisms behind CO_(2)adsorption and reduction at the catalyst-electrolyte interface in PEEC still need to be further ***,we employ a well-defined Ag nanostructure to elucidate these pivotal *** shining light with wavelengths of 625,525,405 nm on Ag,an adjustable CO/H_(2)ratio from 35 to 1 can be *** reaction pathway changing under plasmonic excitation does not originate from the lowered CO_(2)mass transfer in the vicinity of Ag,as the electrochemical quartz crystal microbalance results unravel that a slightly elevated temperature in bulk electrolyte caused by light irradiation cannot weaken the CO_(2)adsorption at the Ag catalyst-electrolyte *** calculations reveal that optical excitation towards shorter wavelengths leads to a progressive lowered energy barrier for H_(2)formation together with an enhanced energy barrier for^(*)COOH *** thermodynamically suppressed,CO_(2)reduction can still be improved kinetically by optimizing the excitation wavelength and intensity,being accompanied with the enhanced *** absorption spectroscopy results further correlate the higher photocurrent with a prolonged electron-phonon coupling time,verifying that the improvement of CO_(2)reduction kinetics in PEEC can be realized by hot electron harnessing.

关键词： plasmonic catalysis photoelectrochemical CO_(2)reduction CO/H_(2)ratio hot electron generation electronphonon coupling thermal effect

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磁性边界反射特性的研究

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西南交通大学学报 2004年第5期39卷 699-702页

作者：官正涛张双文刘运林杨儒贵西南交通大学电磁所四川成都610031

为了进一步研究磁性媒质天线罩的传输特性,对平面波在空气与磁性媒质边界上的反射特性进行了理论探讨.通过改变磁性媒质参数,分析了边界上功率反射系数和反射系数相位与平面波入射角的关系,并讨论了媒质磁性对功率反射系数和反射系数相... 详细信息

为了进一步研究磁性媒质天线罩的传输特性,对平面波在空气与磁性媒质边界上的反射特性进行了理论探讨.通过改变磁性媒质参数,分析了边界上功率反射系数和反射系数相位与平面波入射角的关系,并讨论了媒质磁性对功率反射系数和反射系数相位的影响.结果表明,当磁性媒质的相对复介电常数和相对复磁导率相等时,通过空气与磁性媒质边界的平面波不存在退极化效应.

关键词：电磁波磁性边界功率反射系数反射系数相位

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Effect of SIRT1 gene on cardiac function and life in mice

Effect of SIRT1 gene on cardiac function and life in mice

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第十三次全国心血管病学术会议

作者： GU Xiao-song,LEI Jun-ping,SHI Jian-bo,LIAN wen-lin,yang Xiang,ZHENG Xing Department of Cardiology,Changhai Hospital of Second Military Medical University,200433 Shanghai,China

Objective To observe effect of SIRT1 gene on cardiac function and life in mice and on myocardial expressβ adrenal receptors, *** SIRT(+/-) mice heart function was examined on Langendorff perfused hearts with SIRT1 (+/- )(n= 4) and wild type(WT)(n = 5) ***β1 adrenoceptor and AMPK expressions were examined by Western

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Influence of resveratrol on cardiac function and mortality of rats with myocardial infarction

Influence of resveratrol on cardiac function and mortality o...

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第十三次全国心血管病学术会议

作者： GU Xiao-song,LEI Jun-ping,SHI Jian-bo, LIAN wen-lin,yang Xiang,ZHENG Xing Department of Cardiology,Changhai Hospital of Second Military Medical University,200433 Shanghai,China

Objective To identify the influence of resveratrol upon heart function and mortality of rats with myocardial infarction and the regulation effect of resveratrol on the expression of AMPK andβ1 adrenoceptor of *** myocardial infarction were set up by ligating left anterior descending *** treatment group was given resveratrol 2.5mg/kg/d *** Compared with the heart failure group,Resveratrol treatment group demonstrated a sharp decrease in mor-

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Resveratrol regulates β1 adrenoceptor and AMPK expressions via SIRT1 activity in H9c2 cells

Resveratrol regulates β1 adrenoceptor and AMPK expressions ...

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第十三次全国心血管病学术会议

作者： GU Xiao-song,LEI Jun-ping,SHI Jian-bo,LIAN wen-lin,yang Xiang,ZHENG Xing Department of Cardiology,Changhai Hospital of Second Military Medical University,200433 Shanghai,China

Objective To Identify expression changes of β1 adrenoceptor and AMPK on H9c2 cells which was dealed with resveratrol, overexpressing *** After H9c2 cells had been cultivated with different concentrations of resveratrol for 24 hours,cells were collected for detecting SIRT1,β1 adrenal receptors,AMPK expression in the Western bloting *** have constructed the overexpression SIRT1 gene plasmid,transfected H9c2 cells and established SIRT1 overexpression H9c2

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Janus MXene film with gradient structure for highly efficient terahertz and infrared electromagnetic absorption

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Nano Research 2025年第1期18卷 434-442页

作者： Shaodian yang Weiqiang Huang Zhiqiang lin Zibo Chen Rongliang yang Yi Jia Xuebin Liu Rui Wang Zhiping Zeng Yougen Hu Huanjun Chen Xuchun Gui11 State Key Laboratory of Optoelectronic Materials and Technologies School of Electronics and Information TechnologySun Yat-sen UniversityGuangzhou 510275China National Key Laboratory of Materials for Integrated Circuits Shenzhen Institute of Advanced Electronic MaterialsShenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China China Academy of Aerospace Science and Innovation Beijing 100176China Guangdong Province Key Laboratory of Display Material and Technology Guangzhou 510275China School of Materials Science and Engineering Sun Yat-sen UniversityGuangzhou 510275China

Electromagnetic interference (EMI) shielding inhigh-frequency range, especially the rapidly growing terahertz(THz) frequency range, attracts increasing attention due tothe potential application of terahertz in 6G wirelesscommunication, and security inspection. However, traditionalconductive EMI films typically achieve high shieldingeffectiveness through strong reflection, which may causesecondary pollution to other devices. Here, a gradientstructure strategy was proposed to constructTi_(3)C_(2)Tx/hydroxypropyl methyl cellulose (HPMC) film, in whichthe content of Ti_(3)C_(2)Tx gradually increases along the thicknessdirection, resulting in different conductivity of the two surfaces(surface-M and surface-H) for the film. The obtained gradientfilmexhibits an EMI shielding efficiency of over 48.5 dB in theTHz range (0.2-1.6 THz) at a thickness of 40 μm. Especially,as the THz waves incident from the surface-H to the film, the absorption effectiveness reaches 48.2 dB (average absorbedpower loss up to 91.4%), and the reflection effectiveness is only 0.3 dB. In additions, the gradient-film also demonstrates ahigh absorption rate of 95.5% in the infrared band (2.5-16.7 μm). Moreover, the gradient-film exhibits an excellent tensilestress and Young’s modulus value of 173.1 MPa and 2.8 GPa, respectively. Therefore, the gradient-film proposed in thiswork, with excellent electromagnetic absorption in both THz and infrared band, provides a promising candidate for the nextgenerationEMI shielding applications.

关键词： electromagnetic interference shielding Janus film terahertz MXene

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“Zero‑Strain” NiNb_(2)O_(6) Fibers for All‑Climate Lithium Storage

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Nano-Micro Letters 2025年第1期17卷 348-360页

作者： Yan Zhao Qiang Yuan Liting yang Guisheng Liang Yifeng Cheng Limin Wu Chunfu lin Renchao Che College of Physics Donghua UniversityShanghai 201620People’s Republic of China School of Materials Science and Engineering Institute of Materials for Energy and EnvironmentQingdao UniversityQingdao 266071People’s Republic of China Laboratory of Advanced Materials Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsAcademy for Engineering&TechnologyFudan UniversityShanghai 200438People’s Republic of China Zhejiang Laboratory Hangzhou 311100People’s Republic of China Inner Mongolia University Hohhot 010021People’s Republic of China

Niobates are promising all-climate Li^(+)-storage anode material due to their fast charge transport,large specific capacities,and resistance to electrolyte ***,their moderate unit-cellvolume expansion(generally 5%–10%)during Li^(+)storage causes unsatisfactory long-term ***,“zero-strain”NiNb_(2)O_(6) fibers are explored as a new anode material with comprehensively good electrochemical *** Li^(+)storage,the expansion of electrochemical inactive NiO_(6) octahedra almost fully offsets the shrinkage of active NbO_(6) octahedra through reversible O *** superior volume-accommodation capability of the NiO_(6) layers guarantees the“zero-strain”behavior of NiNb_(2)O_(6) in a broad temperature range(0.53%//0.51%//0.74%at 25//−10//60℃),leading to the excellent cyclability of the NiNb_(2)O_(6) fibers(92.8%//99.2%//91.1%capacity retention after 1000//2000//1000 cycles at 10C and 25//−10//60℃).This NiNb_(2)O_(6) material further exhibits a large reversible capacity(300//184//318 mAh g−1 at 0.1C and 25//−10//60℃)and outstanding rate performance(10 to 0.5C capacity percentage of 64.3%//50.0%//65.4%at 25//−10//60℃).Therefore,the NiNb_(2)O_(6) fibers are especially suitable for large-capacity,fast-charging,long-life,and all-climate lithium-ion batteries.

关键词： NiNb_(2)O_(6)porous fiber “Zero-strain”mechanism Electrochemical property Harsh-temperature operation Operando characterization

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德、日刑法定罪模式与刑法机能的实现

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现代法学 2003年第6期25卷 99-103页

作者：逄锦温杨林湖北省高级人民法院湖北武汉430071 武汉大学法学院湖北武汉430071

定罪机制是刑法与社会联为一体的中介 ,是刑法机能实现的重要途径。德、日刑法定罪模式是一种构成要件论的定罪模式 ,只有顺次通过构成要件该当性、违法性、有责性三重判断的行为才能认定为犯罪行为 ,保障了被告人及其他人的自由 ;同时 ... 详细信息

定罪机制是刑法与社会联为一体的中介 ,是刑法机能实现的重要途径。德、日刑法定罪模式是一种构成要件论的定罪模式 ,只有顺次通过构成要件该当性、违法性、有责性三重判断的行为才能认定为犯罪行为 ,保障了被告人及其他人的自由 ;同时 ,在构成要件该当性、违法性、有责性的判断过程中 ,通过有意识地放弃刑法干预特定领域内的行为的方式 ,保护了社会的进步和发展。促进刑法人权保障机能的实现是德。

关键词：定罪机制刑法机能德国日本定罪模武犯罪行为犯罪构成

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