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The inner～40 pc radial distribution of the star formation rate for a nearby Seyfert 2 galaxy M51

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Research in Astronomy and Astrophysics 2015年第6期15卷 802-810页

作者： Li-Ling Fang Xiao-Lei Jiang Zhi-Cheng He wei-hao bian Department of Physics and Institute of Theoretical Physics Nanjing Normal University

We investigate the spatially resolved specific star formation rate （SSFR） in the inner -40 pc for a nearby Seyfert 2 galaxy, M51 （NGC 5194） by analyzing spectra obtained with the Hubble Space Telescope （HST） Space Telescope Imaging Spectrograph （STIS）. We present 24 radial spectra measured along the STIS long slit in M51, extending - 1＂ from the nucleus （i.e., -41.5 pc to 39.4 pc）. By simple stellar population synthesis, the stellar contributions in these radial optical spectra are modeled. It is found that the mean flux fraction of young stellar populations （younger than 24.5 Myr） is about 9%. Excluding some regions with zero young flux fraction near the center （from -6 pc to 2 pc）, the mean mass fraction is about 0.09%. The young stellar populations are not required in the center inner -8 pc in M51, suggesting a possible SSFR suppression in the circumnuclear region （- 10 pc） from the feedback of active galactic nuclei （AGNs）. The radial distribution of SSFR in M51 is not symmetrical with respect to the long slit in STIS. This unsymmetrical SSFR distribution is possibly due to the unsymmetrical AGN feedback in M51, which is related to its jet.

关键词： galaxies active - galaxies Seyfert - galaxies starburst

Radio Luminosity,Black Hole Mass and Eddington Ratio for Quasars from the Sloan Digital Sky Survey

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Chinese Journal of Astronomy and Astrophysics 2008年第5期8卷 522-536页

作者： wei-hao bian Yan-Mei Chen Chen Hu Kai Huang Yan Xu Department of Physics and Institute of Theoretical Physics Nanjing Normal University Nanjing210097 China Key Laboratory for Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China

We investigate the MBH-σ＊ relation for radio-loud quasars with redshifl z 〈 0.83 in Data Release 3 of the Sloan Digital Sky Survey （SDSS）. The sample consists of 3772 quasars with better models of the H/4 and [O Ⅲ] lines and available radio luminosity, including 306 radio-loud quasars, 3466 radio-quiet quasars with measured radio luminosity or upper-limit of radio luminosity （181 radio-quiet quasars with measured radio luminosity）. The virial supermassive black hole mass （MBH） is calculated from the broad Hβline, and the host stellar velocity dispersion （σ＊） is traced by the core [O Ⅲ] gaseous velocity dispersion. The radio luminosity and radio loudness are derived from the FIRST catalog. Our results are as follows：（1） For radio-quiet quasars, we confirm that there is no obvious deviation from the MBH-σ＊ relation defined for inactive galaxies when the uncertainties in ~IBH and the luminosity bias are concerned. （2） We find that the radio-loud quasars deviate more from the MBH-σ＊ relation than do the radio-quiet quasars. This deviation is only partly due to a possible cosmological evolution of the MBH-σ＊ relation and the luminosity bias. （3） The radio luminosity is proportional to MBH1.28＋0.23-0.16（LBol/LEdd） ^1.29＋0.31-0.24 for radio-quiet quasars and to -MBH3.10＋0.60-0.70（LBol/LEdd）^4.18＋1.40-1.10 - for radio-loud quasars. The weaker dependence of the radio luminosity on the mass and the Eddington ratio for radio-loud quasars shows that other physical effects would account for their radio luminosities, such as the spin of the black hole.

关键词： quasars emission lines - galaxies nuclei -galaxies bulges - black hole physics

Feedback of Active Galactic Nuclei in Seyfert 2 Galaxies

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Chinese Journal of Astronomy and Astrophysics 2008年第5期8卷 537-546页

作者： En-Peng Zhang wei-hao bian Chen Hu wei-Ming Mao A-Li Luo Yong-Heng Zhao National Astronomical Observatory Chinese Academy of Sciences Beijing 100012 China Department of Physics and Institute of Theoretical Physics Nanjing Normal University Nanjing 210097 China Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China

It is well accepted that feedback from active galactic nuclei （AGNs） plays an important role in the coevolution of the supermassive black hole （SMBH） and its host galaxy, but the concrete mechanism of feedback remains unclear. A considerable body of evidence suggests that AGN feedback suppresses star formation in the host galaxy. We assemble a sample of Seyfert 2 galaxies with recent observational data of compact nuclear starbursts and estimate the gas surface density as a function of column density to illuminate the relation between feedback and AGN properties. Although there are some uncertainties, our data still imply the deviation from the star formation law （Kennicutt-Schmidt law）. Further, they indicate that：（1） Feedback correlates with the Eddington ratio, rather than with the mass of SMBH, as a result of decreasing star formation efficiency. （2） The SMBH and the torus are probably undergoing coevolution. Conclusions presented here can be refined through future high resolution CO or HCN observations.

关键词： galaxies active - galaxies Seyfert- feedback

On the Black Hole - Bulge Mass Ratios in Narrow-Line Seyfert 1 Galaxies

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Chinese Journal of Astronomy and Astrophysics 2003年第2期3卷 119-124页

作者： wei-hao bian and Yong-Heng Zhao1 National Astronomical Observatories, Chinese Academy of Sciences, Beijing 1000122 Department of Physics, Nanjing Normal University, Nanjing 210097 Department of Physics Nanjing Normal University Nanjing 210097

We present estimated ratios of the central black hole mass to the bulge mass (Mbh/Mbulge) for 15 Narrow Line Seyfert 1 galaxies (NLS1s). It is found that NLS1s apparently have lower mass ratios: the average mass ratio is about 1 × 10-4 with a spread of 2, which is one order of magnitude lower than for Broad Line AGNs and quiescent galaxies. This lower value, as compared to that established essentially for all other types of galaxies, can be accounted for by an underestimation of the black hole masses and an overestimation of the bulge masses in the NLS1s.

关键词： galaxies: active - galaxies: nuclei - galaxies: bulges - quasars -galaxies: Seyfert

Role of iron ore in enhancing gasification of iron coke:Structural evolution,influence mechanism and kinetic analysis

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 58-69页

作者： Jie Wang wei Wang Xuheng Chen Junfang Bao Qiuyue hao Heng Zheng Runsheng Xu School of Chemistry and Materials Science Hubei Engineering UniversityXiaogan 432000China Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education Wuhan University of Science and TechnologyWuhan 430081China Institue of Ironmaking Technology Baosteel Central Research InstituteShanghai 201999China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China

The utilization of iron coke provides a green pathway for low-carbon *** uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was ***,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric *** findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and *** provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron *** the heating rate in non-isothermal gasification can enhance the reactivity of iron *** metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon *** kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore ***,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.

关键词： low-carbon ironmaking iron coke gasification structural evolution kinetic model

A mild, configurable, flexible CoNi-LDH（v）/Zn battery based on H-vacancy-induced reversible Zn2+ intercalation

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Journal of Energy Chemistry 2025年第1期100卷 498-508页

作者： Xinyue Cheng Dingsheng Wu hao Gao Qingqing Wang Pengfei Lv Sam S.Yoon Qufu wei Key Laboratory of Eco-textiles Ministry of Education Jiangnan University School of Mechanical Engineering Korea University

Flexible Zn-based batteries have attracted increasing research interest as essential components of wearable energy storage ***,the advancement of flexible aqueous Zn-based batteries based on Co-Ni layered double hydroxide （CoNi-LDH） as the cathode material is hampered by their poor cycling stability and the corrosiveness of alkaline ***,CoNi-LDH nanosheets enriched with H vacancies (CoNi-LDH（v）) were constructed on a flexible carbon cloth （CC） substrate via electrochemical deposition and *** Zn-based battery comprising CoNi-LDH（v）@CC as the cathode exhibited highly reversible conversion reactions and stable operation in 3 M ZnSO4electrolyte （pH=4）.The battery delivered an excellent specific capacity (225 mA h g-1,0.26 mA h cm-2),acceptable cycling stability（53.9%,900 cycles）,and high discharging *** abundant H vacancies served as active sites for the reversible intercalation of Zn2+and the extravasation of NO3-generated channels and space for Zn2+transport and storage,together enabling an excellent Zn2+storage ***,a sandwich-structured solid-state CoNi-LDH（v）@CC//Zn@CC battery was fabricated and was found to exhibit a noteworthy electrochemical performance and mechanical *** a proof of concept,the unencapsulated battery powered a digital watch under various deformation conditions and operated stably for 80 ***,the flexible battery displayed outstanding customizability,maintaining an open-circuit voltage of 1.42 V even after being cut *** proposed engineering strategy contributes to the realization of textiles with truly wearable energy-storage devices.

关键词： CoNi/Zn battery H vacancies Mild aqueous electrolyte Tailorable battery Wearable energy storage device

MoS_(2)Lubricate‑Toughened MXene/ANF Composites for Multifunctional Electromagnetic Interference Shielding

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Nano-Micro Letters 2025年第2期17卷 358-371页

作者： Jiaen Wang wei Ming Longfu Chen Tianliang Song Moxi Yele hao Zhang Long Yang Gegen Sarula Benliang Liang Luting Yan Guangsheng Wang School of Physical Science and Engineering Beijing Jiaotong UniversityBeijing 100044People’s Republic of China Key Laboratory of Bio‑Inspired Smart Interfacial Science and Technology of Ministry of Education School of ChemistryBeihang UniversityBeijing 100191People’s Republic of China

The design and fabrication of high toughness electromagnetic interference(EMI)shielding composite films with diminished reflection are an imperative task to solve electromagnetic pollution *** MXene/ANF(aramid nanofibers)–MoS_(2)composite films with nacre-like layered structure here are fabricated after the introduction of MoS_(2)into binary MXene/ANF composite *** introduction of MoS_(2)fulfills an impressive“kill three birds with one stone”improvement effect:lubrication toughening mechanical performance,reduction in secondary reflection pollution of electromagnetic wave,and improvement in the performance of photothermal *** the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 50:50),the strain to failure and tensile strength increase from 22.1±1.7%and 105.7±6.4 MPa and to 25.8±0.7%and 167.3±9.1 MPa,*** toughness elevates from 13.0±4.1 to 26.3±0.8 MJ m^(−3)(~102.3%)*** the reflection shielding effectiveness(SE_(R))of MXene/ANF(mass ratio of 50:50)decreases~10.8%.EMI shielding effectiveness(EMI SE)elevates to 41.0 dB(8.2–12.4 GHz);After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 60:40),the strain to failure increases from 18.3±1.9%to 28.1±0.7%(~53.5%),the SE_(R)decreases~22.2%,and the corresponding EMI SE is 43.9 *** MoS_(2)also leads to a more efficient photothermal conversion performance(~45 to~55℃).Additionally,MXene/ANF–MoS_(2)composite films exhibit excellent electric heating performance,quick temperature elevation(15 s),excellent cycle stability(2,2.5,and 3 V),and long-term stability(2520 s).Combining with excellent mechanical performance with high MXene content,electric heating performance,and photothermal conversion performance,EMI shielding ternary MXene/ANF–MoS_(2)composite films could be applied in many industrial *** work broadens how to achieve a balance between mechanical properties and versatility of composites in the case of high-function fillers.

关键词： MXene-MoS_(2) Lubrication toughening EMI shielding Photothermal conversion Electric heating performance

Deciphering the role of ultra-low-loaded rhodium in NiFe-MIL-53 for superior oxygen evolution reaction

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Journal of Energy Chemistry 2025年第1期100卷 77-86页

作者： Jinzhi Jia Jinhua Zhang Kailu Guo Lanyue Zhang Gening Du hao You Junfeng Huang Mudong Tu Hua Li Yong Peng wei Dou Cailing Xu State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering School of Materials and Energy Lanzhou University College of Chemistry and Chemical Engineering Luoyang Normal University

Designing highly active and stable electrocatalysts of oxygen evolution reaction （OER） is one of the crucial *** this study,a novel OER electrocatalyst,NiFe-MIL-53 modified with ultra-low rhodium（Rh@NiFe-MIL-53）,is successfully prepared via the hydrothermal ***-situ Raman spectroscopy and electrochemical impedance spectroscopy reveal that the doped Rh accelerates the phase transformation of NiFe-MIL-53 and the in-situ formed Rh@NiFeOOH is the actual active *** importantly,the enhanced reversibility of electrochemical reconstruction between NiFeOOH and NiFe（OH）2after doping Rh is beneficial for improving the electrochemical stability of the catalyst.X-ray photoelectron spectroscopy spectra show the strong electronic interaction between single-atom Rh and Ni/Fe in Rh@***,theoretical calculations confirm that the integration of single-atom Rh into the NiFeOOH successfully reduces the band gap,regulates the d-band center （εd）,accelerates the charge transfer,and optimizes the adsorption behavior of oxygen-containing intermediates,thereby lowering the energy barrier of rate-determining ***,the optimized Rh@NiFe-MIL-53 exhibits excellent OER activity （240 mV） with a small Tafel slope of 48.2 mV dec-1and long-term durability (over1270 h at 10 m A cm-2and 110 h at 200 mA cm-2).This work presents a new perspective on designing highly efficient OER electrocatalysts.

关键词： X ray photoelectron spectroscopy

Cobalamin-dependent radical S-adenosyl-L-methionine protein functions with a partner to successively methylate tricyclic indole alkaloid for chuangxinmycin maturation and derivatization

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Science China Chemistry 2025年第1期 308-316页

作者： Sili Wang Jiancheng Huang Yanan Du wei Huang Yufeng Xue Xiaokun Xu Guannan Zhong Yuanyuan Shi Bin Hong Xiaoying bian Wen Liu State Key Laboratory of Chemical Biology Shanghai Institute of Organic Chemistry University of Chinese Academy of SciencesChinese Academy of Sciences State Key Laboratory of Microbial Technology Shandong University National Health Commission (NHC) Key Laboratory of Biotechnology for Microbial Drugs Institute of Medicinal BiotechnologyChinese Academy of Medical Science & Peking Union Medical College

Cobalamin(Cbl)-dependent radical S-adenosyl-L-methionine(SAM) proteins constitute the largest collection of the radical SAM superfamily that has hundreds of thousands of individual members. Many of these proteins are involved in the biosynthesis of pharmaceutically important natural products to catalyze chemically demanding reactions. In the biosynthetic pathway of chuangxinmycin(CXM), a unique indole alkaloid antibiotic with potent anti-infective activity, functionalization of the characteristic thiopyrano[4,3,2-cd]indole scaffold by regio-and stereoselective C3-methylation is believed to rely on a Cbl-dependent radical process, which, however, remained to be reconstituted biochemically. We here report the dissection of this enzymatic process, which requires the incorporation of Cxm8, a Cbl-dependent radical SAM protein, with Cxm9, a DUF5825family protein that shares no homology to any proteins of known functions. Cxm8 and Cxm9 function together by forming an unexpected heterodimeric complex that selectively catalyzes C3-methylation of the tricyclic indole-S-hetero ring system in a successive manner, achieving CXM and a recently identified, C3-dimethylated congener. Detailed biochemical characterization,isotope labeling, structural simulation and bioinformatics analysis rationalized the catalysis of the Cxm8/Cxm9 complex and particularly the necessity of the DUF5825 protein for C3-methylase activity. This is the first example that a Cbl-dependent protein acts with a partner to exhibit radical SAM activity.

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