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Potassium ions and cyano group modified g-C3N4 for effective generation of H2O2 through two-electron oxygen reduction

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Science China Chemistry 2025年第1期 192-200页

作者： dongying Wang Shulan Pu Yongmin Chen Ke Lei Yujie Duan Linjiao Mao Xuhui zeng Xi Luo Yuntao Zhang Yuqin dong Jin Zhong Zhang Yan Sun School of Mechanical Engineering Chengdu University Department of Chemistry and Biochemistry University of California

Potassium ions （K+） doped graphitic carbon nitride （g-C3N4） was prepared by a thermal etching method using potassium hydroxide （KOH） as an ion *** transform infrared spectroscopy （FTIR） and X-ray photoelectron spectroscopy （XPS）results showed that the generation of the cyano group was detected while introducing K+.Under simulated sunlight irradiation,the sample with a K+doping amount of 10%showed the highest hydrogen peroxide （H2O2） generation rate of2,140.2μmol *** apparent quantum yield （AQY） at 400 nm and the solar-to-chemical conversion （SCC） are 4.35%and1.23%,respectively.K+acted as a bridge between g-C3N4layers,which enhanced charge transfer ***,the cyano group enhanced the adsorption capacity of protons （H+） and promoted the yield of *** catalyst exhibited excellent photocatalytic stability based on four-cycle *** addition,a mechanism study showed that superoxide radicals （·O2-）were the most important active species in the reaction *** production of H2O2was achieved through consecutive single-electron *** study deepens the understanding of the oxygen reduction reaction process and opens up a new venue for improving H2O2generation.

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Copper-catalyzed C–H bond functionalization enabled by programmed alternating current

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Science China Chemistry 2025年第1期 10-11页

作者： Zhoumei Tan Kun Xu Chengchu zeng Beijing Key Laboratory of Environmental and Viral Oncology College of Chemistry and Life Science Beijing University of Technology

Synthetic electrochemistry has been selected as one of the Top Ten Emerging Technologies in Chemistry in 2023 by International Union of Pure and Applied Chemistry (IUPAC)[1]. It has emerged as a sustainable platform for organic synthesis and has exhibited a wide range of applications from academia to industry [2]. However, electrosynthesis has been predominantly performed by using direct current (DC).

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Transient simulation and analysis of the simultaneous load rejection process in pumped storage power stations using a 1-D-3-D coupling method

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Journal of Hydrodynamics 2021年第5期33卷 979-991页

作者： Cheng-cheng Yin wei zeng Jian-dong Yang State Key Laboratory of Water Resources and Hydropower Engineering Science Wuhan UniversityWuhan 430072China School of Civil Environmental and Mining EngineeringThe University of AdelaideAdelaideAustralia

The load rejection imposes a danger in the pumped storage hydropower plants(PSPs),especially when two or more pump turbines reject their loads *** this paper,the simultaneous load rejection scenarios in the PSPs are simulated and analyzed by using a 1-D,3-D coupling *** PSP pipe system is modeled by using the 1-D method of characteristics(MOC)and one pump turbine is modeled by using the 3-D computational fluid dynamics(CFD).The simulated flow and head are transmitted between the 1-D,3-D regions through the interfaces between these two *** assuming that the installed pump turbines are of the same type and the corresponding branch pipes have the same properties,the variations of the transient pressures and the flowrates in different pump turbines will be ***,only one pump turbine is modeled by the CFD in this study.A new branching junction boundary is proposed to assign the simulated dynamic pressures and flowrates obtained by the 3-D model to other pump *** 1-D-3-D coupling method is validated by experiments with only one pump turbine rejecting its *** simultaneous load rejection of two pump turbines is then simulated and validated by comparing the results with those of the 1-D *** building only one pump turbine 3-D model,a large amount of computational resources can be *** simultaneous load rejection scenario is then analyzed and compared with the single load rejection *** water hammer pressures and a larger rotational speed occur in the simultaneous load rejection scenario,which leads to larger pressure pulsations in the pump *** larger pressure pulsations can be further explained by the flow patterns in the runner channels,in which heavier flow separations and vortexes can be observed in the simultaneous load rejection scenario.

关键词： Pump-turbine,pumped hydro computational fluid dynamics(CFD) hydraulic transient load rejection

Role of metabolic dysfunction and inflammation along the liver-brain axis in animal models with obesity-induced neurodegeneration

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Neural Regeneration Research 2025年第4期20卷 1069-1076页

作者： Evridiki Asimakidou Eka Norfaishanty Saipuljumri Chih Hung Lo Jialiu zeng Department of Clinical Neurosciences University of CambridgeCambridgeUK School of Applied Science Republic PolytechnicSingaporeSingapore Lee Kong Chian School of Medicine Nanyang Technological UniversitySingaporeSingapore

The interaction between metabolic dysfunction and inflammation is central to the development of neurodegenerative diseases such as Alzheimer’s disease and Parkinson’s ***-related conditions like type 2 diabetes and non-alcoholic fatty liver disease exacerbate this *** lipid accumulation,particularly in the liver,initiates a cascade of inflammatory processes that extend to the brain,influencing critical metabolic regulatory *** and palmitate,key lipid components,along with lipid transporters lipocalin-2 and apolipoprotein E,contribute to neuroinflammation by disrupting blood–brain barrier integrity and promoting *** insulin resistance further exacerbates brain insulin resistance and *** interventions targeting peripheral lipid metabolism and insulin signaling pathways have shown promise in reducing neuroinflammation in animal ***,translating these findings to clinical practice requires further investigation into human *** conclusion,metabolic dysfunction,peripheral inflammation,and insulin resistance are integral to neuroinflammation and *** these complex mechanisms holds potential for identifying novel therapeutic targets and improving outcomes for neurodegenerative diseases.

关键词： Alzheimer’s disease inflammatory cytokines insulin resistance lipid

新疆萨尔托海超基性岩体及铬铁矿床的地质特征和成因

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西北地质科学 1987年第2期 57-145页

作者：魏文中董显扬曾河清高纪璞

萨尔托海铬铁矿是我国大型铬矿床之一。本文论述了该区超基性岩与地表、浅部和深部铬铁矿床的地质特征。根据岩体产状、内部构造、岩石矿物学、岩石组构及通过稀土元素和锶同位素的分析对比、矿物包裹体的研究结果等,提出萨尔托海超基... 详细信息

萨尔托海铬铁矿是我国大型铬矿床之一。本文论述了该区超基性岩与地表、浅部和深部铬铁矿床的地质特征。根据岩体产状、内部构造、岩石矿物学、岩石组构及通过稀土元素和锶同位素的分析对比、矿物包裹体的研究结果等,提出萨尔托海超基性岩体是岩浆成因的,是在造山带区域应力场作用下成岩、成矿与变形、变质的。该区铬铁矿主要产于纯橄岩申,其次为斜辉辉橄岩,而橄榄岩仅有少量矿化。主要成矿地段的岩相均有自上而下由偏酸性到偏基性的垂直分带现象,工业矿体赋存于中下部纯橄岩—辉橄岩杂岩带的纯橄岩内或偏基性的辉橄岩中,其构造位置处在岩体基底凹槽之上;地表矿体则多是由形成浅部或中深部矿床的矿浆派生、沿裂隙贯入的脉状矿体。在造矿铬尖晶石中发现了原生硅酸盐熔体包裹体;肯定了褪色岩石富含Cl、B、S等挥发组分,岩石发生蚀变褪色在空间上和成因上与铬矿成矿作用有关;并从岩相、构造、地球化学及矿床特征等方面探讨了岩浆分异及铬矿床的形成作用。超基性岩及铬铁矿结晶温度介于1300—700℃之间。

关键词：纯橄岩辉橄岩橄榄岩纯橄榄岩深成岩超基性岩超基性岩体铬矿物铬尖晶石铬铁矿床萨尔托海地质特征新疆

Boosting hydrocarbon conversion via Cu-doping induced oxygen vacancies on CeO2 in CO2 electroreduction

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Journal of Energy Chemistry 2025年第1期100卷 66-76页

作者： Lei Xue Tong Shi Chenhui Han Heng Zhang Fenrong Liu Haorun Li Yan Wang Xiaojun Gu Shanghong zeng Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials School of Chemistry and Chemical Engineering Inner Mongolia University State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of Sciences Institute of Catalysis Department of Chemistry Zhejiang University National Key Laboratory of Baiyunobo Rare Earth Resource Research and Comprehensive Utilization Baotou Research Institute of Rare Earths

Conversion of CO2back to hydrocarbons is the most direct way of closing the“carbon cycle”,and its significance is further enlarged if this process is driven by renewable energies such as ***,precisely controlling the product selectivity towards hydrocarbons against the competitive hydrogen evolution remains challenging,especially for Cu-based ***,we report a novel defect engineering strategy,by which Cu-doping-induced oxygen vacancies on CeO2nanorods were effectively created,with adjustable vacancy/Cu *** resulting optimum catalyst shows up to 79% catalytic current density to hydrocarbons （excluding CO）,with 49% faradaic efficiency to *** and density functional theory unveil that the ratio between oxygen vacancy and Cu affects significantly the formation of*CHO and activation of H2O,which leads to the following deep hydrogenation to *** findings may spur new insights for designing and developing more controllable chemical process relevant to CO2utilization.

关键词： Oxygen vacancy Hydrocarbon production Reaction mechanism

卵泡刺激素和表皮生长因子对小鼠精原细胞增殖的影响

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细胞生物学杂志 2007年第4期29卷 565-568页

作者：张大雷米玉玲王凯明曾卫东张才乔浙江大学动物科学学院杭州310029

利用生殖细胞-体细胞体外无血清共培养模型研究了卵泡刺激素(FSH)和表皮生长因子(EGF)对小鼠A型精原细胞增殖的影响。精原细胞在ITS培养液(添加胰岛素、转铁蛋白和亚硒酸钠的DMEM)中培养24h后进行c-kit免疫细胞化学鉴定和EGF及其受体(EG... 详细信息

利用生殖细胞-体细胞体外无血清共培养模型研究了卵泡刺激素(FSH)和表皮生长因子(EGF)对小鼠A型精原细胞增殖的影响。精原细胞在ITS培养液(添加胰岛素、转铁蛋白和亚硒酸钠的DMEM)中培养24h后进行c-kit免疫细胞化学鉴定和EGF及其受体(EGFR)免疫细胞化学检测,72h后测定其形成集落数的情况。结果表明:ITS培养液能维持生殖细胞的活性,增殖细胞核抗原(PCNA)的表达增高。A型精原细胞呈c-kit阳性,EGF和EGFR主要表达于精原细胞。单独的FSH(1～100ng/ml)或EGF(1～10ng/ml)显著促进精原细胞集落数的增加。此外,EGF(0.1ng/ml)联合FSH(10ng/ml)具有加性效应,但更高剂量的EGF(1～10ng/ml)则降低了FSH的刺激作用。结果说明FSH可联合适量的EGF促进精原细胞的增殖。

关键词：精原细胞卵泡刺激素表皮生长因子细胞增殖

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三草酸合铁(Ⅲ)酸钾合成工艺的优化

化学试剂 2017年第10期39卷 1108-1112,1131页

作者：马少妹袁爱群白丽娟韦冬萍黄增尉周泽广尹显洪钟莲云广西民族大学化学化工学院广西林产化学与工程重点实验室广西南宁530006

以硫酸亚铁铵、草酸为主要原料,双氧水为氧化剂合成三草酸合铁(Ⅲ)酸钾。采用响应面法优化三草酸合铁(Ⅲ)酸钾的制备工艺,用XRD、FT-IR、SEM对产物进行表征。结果表明,产物化学式为K[Fe(C_2O_4)_3]·3H_2O,形貌为微米块状颗粒。优化工... 详细信息

以硫酸亚铁铵、草酸为主要原料,双氧水为氧化剂合成三草酸合铁(Ⅲ)酸钾。采用响应面法优化三草酸合铁(Ⅲ)酸钾的制备工艺,用XRD、FT-IR、SEM对产物进行表征。结果表明,产物化学式为K[Fe(C_2O_4)_3]·3H_2O,形貌为微米块状颗粒。优化工艺条件:草酸亚铁制备中草酸用量为28.00 m L、反应时间为18.00 min;氧化配位反应中草酸钾用量为17.00 m L、H_2O_2用量为6.00 m L,清除H_2O_2时间为5.00 min;酸溶配位中草酸用量为11.00 m L,在该条件下重复实验,产品均为翠绿色晶体,产率均在89.89%~90.57%之间。

关键词：硫酸亚铁铵三草酸合铁(Ⅲ)酸钾响应面法

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车辆动力学性能方向性地面监测研究

铁道机车车辆 2009年第6期29卷 28-30,80页

作者：扈海军于卫东曾宇清周忠良张岩中国铁道科学研究院机车车辆研究所北京100081

利用TPDS采集到的货车动力学相关参数,结合HMIS及ATIS的相关信息,分析货车运行方向对动力学的影响,建议对GB5599-85修订中添加试验车辆必须双向运行的内容。

关键词：动力学轮轴脱轨系数动轮比标准