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Europium-bearing organic framework with excellent X-ray scintillating luminescence

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Journal of Rare Earths 2024年第2期42卷 251-255,I0001页

作者： Yugang zhang Lanhua chen Xia Wang wei Liu Shu'ao Wang State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences(RAD-X)and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education InstitutionsSoochow UniversitySuzhou215123China School of Environmental and Materials Engineering Yantai UniversityYantai264005China

Two europium-bearing organic frameworks,termed as EuTPO-1 and EuTPO-2(H_(3)TPO=tris(4-carboxylphenyI)-phosphineoxide),are reported in this work.A series of characterizations of EuTPO-1and EuTPO-2,such as X-ray crystallography and photoluminescence spectroscopy,was performed to expatiate their structure and physicochemical *** of them are constructed by dimers of the europium-oxygen subunit of [Eu_(2)O_(16)] and TPO *** from high X-ray stopping attenuation and excellent luminescence efficiency,they emit sufficient luminescence when irradiated with ***,they possess stable light outputs when exposed to high humidities and strong radiation dose,outperforming the commercial scintillator CsI:*** result paves the way for developing new scintillator and enriches the compound of europium-bearing organic framework with X-ray scintillating luminescence.

关键词： Metal-organic frameworks Scintillating material Luminescence efficiency Rare earths

Conductive and stable polyphenylene/CNT composite membrane for electrically enhanced membrane fouling mitigation

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Frontiers of Environmental Science & Engineering 2024年第1期18卷 35-47页

作者： Huijuan Xie Haiguang zhang Xu Wang Gaoliang wei Shuo chen Xie Quan Key Laboratory of Industrial Ecology and Environmental Engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China

Nanocarbon-based conductive membranes, especially carbon nanotube (CNT)-based membranes, have tremendous potential for wastewater treatment and water purification because of their excellent water permeability and selectivity, as well as their electrochemically enhanced performance (e.g., improved antifouling ability). However, it remains challenging to prepare CNT membranes with high structural stability and high electrical conductivity. In this study, a highly electroconductive and structurally stable polyphenylene/CNT (PP/CNT) composite membrane was prepared by electropolymerizing biphenyl on a CNT hollow fiber membrane. The PP/CNT membrane showed 3.4 and 5.0 times higher electrical conductivity than pure CNT and poly(vinyl alcohol)/CNT (PVA/CNT) membranes, respectively. The structural stability of the membrane was superior to that of the pure CNT membrane and comparable to that of the PVA/CNT membrane. The membrane fouling was significantly alleviated under an electrical assistance of −2.0 V, with a flux loss of only 11.7% after 5 h filtration of humic acid, which is significantly lower than those of PP/CNT membranes without electro-assistance (56.8%) and commercial polyvinylidene fluoride (PVDF) membranes (64.1%). Additionally, the rejection of negatively charged pollutants (humic acid and sodium alginate) was improved by the enhanced electrostatic repulsion. After four consecutive filtration-cleaning cycle tests, the flux recovery rate after backwashing reached 97.2%, which was much higher than those of electricity-free PP/CNT membranes (67.0%) and commercial PVDF membranes (61.1%). This study offers insights into the preparation of stable conductive membranes for membrane fouling control in potential water treatment applications.

关键词： Polyphenylene CNTs Membrane Electro-assistance Membrane fouling mitigation

Hovering rotor aerodynamics in extreme ground effect

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Chinese Journal of Aeronautics 2024年第7期37卷 204-219页

作者： Zhenlong WU Tianyu zhang Huijun TAN Haoyu ZHOU wei chen Maixiang XIE College of Energy and Power Engineering Nanjing University of Aeronautics and AstronauticsNanjing 210016China China Aviation Power Machinery Research Institute Zhuzhou 412002China

This paper presents an experimental and numerical study of the aerodynamics of a moderate-scale rotor hovering in the Extreme Ground Effect(EGE)where rotor height-offground is below half the rotor *** tip vortex field was visualized by using the PIV *** aerodynamic performance,tip vortex trajectory,wall jet characteristics,surface pressure and velocity fields were measured and *** explore more deeply the flow mechanisms of the extreme ground effect,Detached Eddy Simulation(DES)was conducted on completely structured *** results showed significant deviations of the rotor performance in EGE from that in Regular Ground Effect(RGE)with the rotor heights of more than half the rotor ***,the flow structures of the rotor in EGE are considerably complex,such as the wall jet and groundwash flow *** rotor wake flow and tip vortices impact the ground more frequently,resulting in distinctive characteristics of the surface pressure and velocity fields in EGE.

关键词： Rotor Ground effect Tip vortex Detached Eddy Simulation(DES) Groundwash

Propagation form of internal cracks induced by continuous casting soft reduction and control strategy for internal quality

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Journal of Iron and Steel Research International 2024年第3期31卷 622-633页

作者： Pu Wang Liang chen Qun-wei Tang wei-tao Li Shao-xiang Li Jia-quan zhang School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China weifang Special Steel Group Co..Ltd. Weifang 262400ShandongChina School of Materials Science and Engineering Tsinghua UniversityBeijing 100084China

The propagation form of internal cracks induced by continuous casting soft reduction and the control strategy for enhancing the internal quality of 45 steel through industrial trials and a three-dimensional flow-heat transfer-solidification coupling model were *** results showed that the internal cracks induced by soft reduction exhibited a characteristic of being"coarse in the middle and fine at both ends",and displayed an elliptical arc distribution on the loose side of the strand cross *** cracks originated within the brittle temperature range and propagated inward to the liquid impenetrable temperature and outward to the zero ductility temperature or *** control strategy for enhancing the internal quality of the 45 steel strand through soft reduction is to adjust the casting speed or the reduction zone appropriately,ensuring that the central solid fraction of the reduction zone falls within the range of *** this point,a reasonable reduction amount is allocated to eliminate the center shrinkage cavities and center segregation,even if it results in minor reduction-induced cracks.

关键词： Continuous casting Soft reduction Crack propagation Internal quality Control strategy

A novel long persistent luminescent material CaGeO_(3):Tb^(3+)with photo-stimulation properties

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Journal of Rare Earths 2024年第7期42卷 1233-1239,I0002页

作者： wei Meng Xiaoyan Fu Tongyan Lin Zewen Liu Naihui chen Jiaxu zhang Runyao Liu Rujun Yang Long chen Hongwu zhang School of Chemistry and Material Sciences Ludong UniversityYantai264025China College of Materials Science and Engineering Xiamen University of TechnologyXiamen361024China College of Materials Xiamen UniversityXiamen361005China

A novel green long afterglow material CaGeO_(3):Tb^(3+)was synthesized by high temperature solid phase *** to the experimental results,CaGeO_(3):Tb^(3+)is a green long persistent luminescent(LPL)material with excellent ***_(3):Tb^(3+)shows LPL emission peak at 442,490.9,548.7,588.5 and 623.8 nm,corresponding to ^(5)D_(3) to^(7)F_(4)and^(5)D_(4)to^(7)F_(J)(J=6,5,4,3)transitions of Tb^(3+).Its CIE coordinates are(0.27,0.50),indicating that the afterglow emission is close to the light of green *** addition,after the excitation source is turned off,the afterglow time is longer than 90 *** an interval of 7 h,the photo-stimulation luminescence(PSL)can be observed by using 980 nm laser cyclic *** thermoluminescence(ThL)results show that there are three types of traps in the material and their depths are 0.666,0.774 and 0.892 eV respectively,which are caused by the doping of Tb^(3+).All the results show that CaGeO_(3):Tb^(3+)is an excellent long afterglow luminescent material.

关键词： Long persistent luminescence Photo-stimulation Trap CaGeO_(3):Tb^(3+) Rare earths

Novel modular quasi-zero stiffness vibration isolator with high linearity and integrated fluid damping

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Frontiers of Mechanical Engineering 2024年第1期19卷 105-128页

作者： wei zhang Jixing CHE Zhiwei HUANG Ruiqi GAO wei JIANG Xuedong chen Jiulin WU State Key Laboratory of Intelligent Manufacturing Equipment and Technology Huazhong University of Science and TechnologyWuhan 430074China School of Mechanical Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China

Passive vibration isolation systems have been widely applied due to their low power consumption and high ***,the design of vibration isolators is usually limited by the narrow space of installation,and the requirement of heavy loads needs the high supporting stiffness that leads to the narrow isolation frequency *** improve the vibration isolation performance of passive isolation systems for dynamic loaded equipment,a novel modular quasi-zero stiffness vibration isolator(MQZS-VI)with high linearity and integrated fluid damping is *** MQZS-VI can achieve high-performance vibration isolation under a constraint mounted space,which is realized by highly integrating a novel combined magnetic negative stiffness mechanism into a damping structure:The stator magnets are integrated into the cylinder block,and the moving magnets providing negative-stiffness force also function as the piston supplying damping force *** analytical model of the novel MQZS-VI is established and verified *** effects of geometric parameters on the characteristics of negative stiffness and damping are then elucidated in detail based on the analytical model,and the design procedure is proposed to provide guidelines for the performance optimization of the ***,static and dynamic experiments are conducted on the *** experimental results demonstrate the proposed analytical model can be effectively utilized in the optimal design of the MQZS-VI,and the optimized MQZS-VI broadened greatly the isolation frequency band and suppressed the resonance peak simultaneously,which presented a substantial potential for application in vibration isolation for dynamic loaded equipment.

关键词： vibration isolation quasi-zero stiffness damping magnetic spring integrated design

Cation-Anion Redox Active Organic Complex for High Performance Aqueous Zinc Ion Battery

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Energy & Environmental Materials 2024年第1期7卷 60-67页

作者： Lilin zhang Yining chen Zongyuan Jiang Jingwei chen Cong wei Wenzhuo Wu Shaohui Li Qun Xu School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China Henan Institute of Advanced Technology Zhengzhou UniversityZhengzhou 450001China School of Materials Science and Engineering Ocean University of China Qingdao 266100China

Organic redox compounds are attractive cathode materials in aqueous zinc-ion batteries owing to their low cost,environmental friendliness,multiple-electron-transfer reactions,and resource ***,the realized energy density is constrained by the limited capacity and low ***,copper-tetracyanoquinodimethane(CuTCNQ),an organic charge-transfer complex is evaluated as a zinc-ion battery cathode owing to the good electron acceptation ability in the cyano groups that improves the voltage *** electrochemical activation,electrolyte optimization,and adoption of graphene-based separator,CuTCNQ-based aqueous zinc-ion batteries deliver much improved rate performance and cycling stability with anti-self-discharge *** structural evolution of CuTCNQ during discharge/charge are investigated by ex situ Fourier transform infra-red(FT-IR)spectra,ex situ X-ray photoelectron spectroscopy(XPS),and in situ ultraviolet visible spectroscopy(UV-vis),revealing reversible redox reactions in both cuprous cations(Cu^(+))and organic anions(TCNQ^(x-1)),thus delivering a high voltage output of 1.0 V and excellent discharge capacity of 158 mAh g^(-1).The remarkable electrochemical performance in Zn//CuTCNQ is ascribed to the strong inductive effect of cyano groups in CuTCNQ that elevated the voltage output and the graphene-modified separator that inhibited CuTCNQ dissolution and shuttle effect in aqueous electrolytes.

关键词： cathode materials cyano groups electrochemical activation organic charge-transfer complex zinc-ion battery

Acute Bacillus cereus endophthalmitis caused by ocular perforation injury and occult intravitreal cilium implantation:a case report

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International Journal of Ophthalmology(English edition) 2024年第5期17卷 976-978页

作者： Ling zhang Bin chen wei-Min He Department of Ophthalmology West China HospitalSichuan UniversityChengdu 610041Sichuan ProvinceChina Department of Ophthalmology the People’s Hospital of LeshanLeshan 614000Sichuan ProvinceChina

Dear Editor,We present a case of acute Bacillus cereus(***)endophthalmitis in a patient with an intraocular perforation injury combined with occult intravitreal cilium *** endophthalmitis is a severe intraocular infection commonly caused by post-traumatic *** often leads to significant vision loss or even eye loss within 12-48h[1].The presence of an intraocular foreign body(IOFB)increases the risk of infection,while early surgical removal of IOFBs can prevent endophthalmitis,some IOFBs are difficult to detect *** Medical Ethics Review Board of West China Hospital of Sichuan University waived application for a clinical study because this was a retrospective report of a single patient based on imaging and because no human experimentation was *** patient provided written informed consent to use the imaging data for publication.

关键词： endophthalmitis ilium injuries

Heterogeneous information phase space reconstruction and stability prediction of filling body–surrounding rock combination

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International Journal of Minerals,Metallurgy and Materials 2024年第7期31卷 1500-1511页

作者： Dapeng chen Shenghua Yin weiguo Long Rongfu Yan Yufei zhang Zepeng Yan Leiming Wang wei chen School of Civil and Resources Engineering University of Science and Technology of BeijingBeijing 100083China Production Technology Department Longshou MineJinchuan Group Co.Ltd.Jinchang 737100China School of Civil Engineering and Architecture East China Jiaotong UniversityNanchang 330013China

Traditional research believes that the filling body can effectively control stress concentration while ignoring the problems of unknown stability and the complex and changeable stress distribution of the filling body–surrounding rock combination under high-stress *** monitoring data processing methods cannot fully consider the complexity of monitoring objects,the diversity of monitoring methods,and the dynamics of monitoring *** solve this problem,this paper proposes a phase space reconstruction and stability prediction method to process heterogeneous information of backfill–surrounding rock *** three-dimensional monitoring system of a large-area filling body–surrounding rock combination in Longshou Mine was constructed by using drilling stress,multipoint displacement meter,and *** information,such as the stress and displacement of the filling body–surrounding rock combination,was continuously *** with the average mutual information method and the false nearest neighbor point method,the phase space of the heterogeneous information of the filling body–surrounding rock combination was then *** this paper,the distance between the phase point and its nearest point was used as the index evaluation distance to evaluate the stability of the filling body–surrounding rock *** evaluated distances(ED)revealed a high sensitivity to the stability of the filling body–surrounding rock *** new method was then applied to calculate the time series of historically ED for 12 measuring points located at Longshou *** moments of mutation in these time series were at least 3 months ahead of the roadway return *** the ED prediction experiments,the autoregressive integrated moving average model showed a higher prediction accuracy than the deep learning models(long short-term memory and Transformer).Furthermore,the root-mean-square error distribution of the prediction results peaked at 0

关键词： deep mining filling body–surrounding rock combination phase space reconstruction multiple time series stability prediction