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Synthesis, Structure Characterization and Biological Activity of Layered Vanadium Oxides [NH_3(CH_2)_2NH(CH_2)_2NH_3][V_6O_(14)]

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Chemical Research in Chinese Universities 2005年第5期21卷 509-511页

作者： FU ping-ping wang Xin-long wang en-bo QIN Chao xu lin Institute of Polyoxometalate Chemistry Department of Chemistry Northeast Normal University Changchun 130024 P. R. China China-Japan Union Hospital Jilin University Changchun 130024 P. R. China

A new layered vanadium oxide [ NH3 （ CH2 ）2NH（ CH2 ）2NH3 ] [ V6O14 ] （ compound 1 ） was synthesized and characterized by elemental analysis, IR spectrometry and single crystal X ray diffraction. The compound crystallizes ina monoclinic space group P2（1）/n with a = 1.0254（2） nm, b =0.6739（2） nm, c = 1.2400（2） nm, ,8 = 93.88 （ 3 ） °, V = 0. 8549 （ 3 ）nm^3, Z = 2, R1 = 0. 0366, wR2 = 0. 1038. Compound 1 consists of two-dimensional mixed-valence vanadium oxide layers parallelling to the bc plane. The anti-tumor activity of the compound was estimated in three human tumor cell lines in vitro.

关键词： Polyoxometalate,Vanadium oxide Crystal structure Anti-tumor activity

Association between autoimmune gastritis and gastric polyps:Clinical characteristics and risk factors

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World Journal of Gastrointestinal Oncology 2025年第1期17卷 73-87页

作者： Jing-Zheng Jin Xiao Liang Shu-Peng Liu Rui-Lan wang Qing-Wei Zhang Yu-Feng shen Xiao-bo Li Division of Gastroenterology and Hepatology Renji HospitalShanghai Jiao Tong University School of MedicineShanghai 200127China Division of Gastroenterology and Hepatology Shanghai Institute of Digestive DiseasesShanghai 200001China Division of Gastroenterology and Hepatology Renji Hospital Affiliated to Shanghai Jiao Tong University School of MedicineShanghai 200127China Division of Gastroenterology and Hepatology Sichuan Armed Police Corps HospitalLeshan 610041Sichuan ProvinceChina Division of Gastroenterology and Hepatology NHC Key Laboratory of Digestive DiseasesRenji HospitalShanghai Jiao Tong University School of MedicineShanghai 200127China Department of Gastroenterology Renji Hospital Affiliated to Shanghai Jiao Tong University School of Medicine Shanghai Institute of Digestive DiseasesShanghai 200127China

BACKGROUND The relationship between autoimmune gastritis(AIG)and gastric polyps(GPs)is not well *** To explore the clinical characteristics and risk factors of AIG with GPs in *** This double center retrospective study included 530 patients diagnosed with AIG from July 2019 to July *** collected clinical,biochemical,serological,and demographic data were of each *** regression analyses,both multivariate and univariate,were conducted to pinpoint independent risk factors for GPs in patients with AIG *** operating characteristic curves were utilized to establish the optimal cutoff values,sensitivity,and specificity of these risk factors for predicting GPs in patients with *** Patients with GPs had a higher median age than those without GPs[61(52.25-69)years vs 58(47-66)years,P=0.006].The gastrin-17 levels were significantly elevated in patients with GPs compared with those without GPs[91.9(34.2-138.9)pmol/mL vs 60.9(12.6-98.4)pmol/mL,Pbody(PCA)antibody was higher in these patients than in those without GPs(88.6%vs 73.6%,Pen II(OR=1.053,P=0.015),and enterochromaffin like cells hyperplasia(OR=3.116,Pen I was identified as a protective *** PCA positivity and enterochromaffin like cells hyperplasia are significant risk factor for the development of GPs in patients with *** gastrin-17 levels may also play a role in this *** findings suggest potential targets for further research and therapeutic intervention in managing GPs in patients with AIG.

关键词： Autoimmune gastritis Gastric polyps Neuroendocrine tumor Risk factors Nomogram

Hydrothermal Synthesis, Structural Characterization and Properties of Mixed Valent Decavanadium Oxide [Co_2Cl_8V_(10) O_(18)(H_2O)]Cl_2·6H_2O with Novel Three-dimensional Framework

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Chemical Research in Chinese Universities 2003年第2期19卷 135-139页

作者： WU ping song xu lin wang en bo HU Chang wen Faculty of Chemistry Northeast Normal UniversityChangchun 130024P.R.China

Decavanadium oxide [Co 2Cl 8V 10 O 18 (H 2O)]Cl 2·6H 2O was synthesized hydrothermally with NH 4VO 3, Na 2MoO 4·2H 2O, H 3PO 4(85%), CoCl 2·6H 2O and hexamethylenetetraamine. The X ray diffraction analysis showed that [Co 2Cl 8V 10 O 18 (H 2O)]Cl 2·6H 2O crystallized in a monoclinic crystal system, the space group was C2/m with cell parameters a =1 6065(3) nm, b =2 2699(5) nm, c =1 3897(3) nm, β = 125.29(3)°, V =4 1363(14) nm 3, Z =2 and the final R =0 06, wR =0 1926. Its crystal structure is a 3 D open framework constructed by VO x polyhedra and CoCl 4 tetrahedra with channels along the crystallographic axes a, b, and c .

关键词： Hydrothermal synthesis Polyoxometalate Crystal structure

Ultrathin Multilayer Films Incorporating Keggin-type Heteropolyanion Clusters

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Chinese Chemical Letters 2001年第12期12卷 1127-1130页

作者： lin xu en bo wang Zhuang LI hong Yu ZHANG Chao QIN Department of Chemistry Northeast Normal UniversityChangchun 130024 Changchun Institute of Applied Chemistry Academia SinicaChangchun 130022

Two new ultrathin multiplayer films have been successfully prepared fi-om Keggin-type heteropoly acids H-4[SiW12O40] and H-3[PMo12O40] with polyelectrolytes PEI, PSS, and PAH, using the electrostatic layer-by-layer self-assembly, technique. The XR results reveal their film thickness at nanoscale (similar to 20 nm). According to the AFM images, it is believed that the surface roughness (rough degree of film surface) of the polyelectrolyte-polyoxometalate film greatly depends on the kind of polyoxometalates.

关键词： materials multiplayer polyelectrolyte-polyoxometalate layer-by-layer

A new extended structural compound based on saturated Wells-Dawson polyoxoanions

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Chinese Chemical Letters 2009年第11期20卷 1381-1385页

作者： Min xu Jia Liu en bo wang Key Laboratory of Polyoxometalate Science of Ministry of Education Institute of Polyoxometalate Chemistry Department of Chemistry Northeast Normal University Changchun Jilin 130024 China Department of Chemistry Tonghua Normal University Tonghua Jilin 134002 China

A new 3D extended structural compound, （dpdo）2H2{[Cu（2,2＇-bipy）212（P2W18O62）}.SH2O 1 （dpdo = 4,4＇-bipyridine-N,N＇- dioxide; 2,2＇-bipy = 2,2＇-bipyridine）, has been hydrothermally synthesized and characterized by elemental analyses, IR, TG analyses, cyclic voltammetry, and single-crystal X-my diffraction. Compound 1 is built up of [P2WlsO62]6- cluster as the structural motif covalently linked by [Cu（2,2＇-bipy）2]^2＋ coordination complexes to yield the 1D chains, which axe further in close contact forming a 3D supramolecular framework via aromatic π-π stacking interactions and extensive hydrogen-bonding interactions among polyoxoanions, coordinated 2,2＇-bipy organic ligands, free dpdo organic molecules and lattice water molecules.

关键词： 3D extended structures Dawson-type polyoxometalates Copper-organic complexes

Effect of phosphate conversion film on fatigue and corrosion fatigue behavior of an as-rolled Mg–3.08Zn–0.83Al(in wt.%)alloy

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Journal of Iron and Steel Research International 2023年第12期30卷 2557-2565页

作者： Bao-jie wang Dao-kui xu Shuo wang Xiang-bo xu en-hou Han School of environmental and Chemical engineering Shenyang Ligong UniversityShenyang110159LiaoningChina Key Laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of SciencesShenyang110016LiaoningChina Binzhou Institute of Technology Binzhou256606ShandongChina Shandong Key Laboratory of Advanced Aluminium Materials and Technology Binzhou256606ShandongChina Key Lab of Electromagnetic Processing of Materials Ministry of EducationNortheastern UniversityShenyang110819LiaoningChina

Through investigating and comparing the fatigue behavior of an as-rolled Mg–3.08Zn–0.83Al(in wt.%)alloy performing surface phosphate conversion film treatment,it revealed that the determined fatigue strength of surface treated samples at 106 cycles in air was 65 MPa,whereas the fatigue strength was only 35 MPa when tested in 3.5 wt.%NaCl *** analysis demonstrated that in air,the fatigue crack initiation was mainly dominated by the interaction between the retarding effect of phosphate conversion film on cyclic slips occurring in the underneath *** the matrix cannot endure the accumulated stress concentration due to the irreversibility of cyclic slips,the fatigue crack will preferentially initiate at sample *** the phosphate conversion film cracked easily under the cyclic loading and lost its protectiveness on the substrate in 3.5 wt.%NaCl solution,fatigue cracks were preferentially nucleated at the localized corrosion pits.

关键词： Mg alloy Corrosion fatigue Surface film Pitting Crack initiation

Ce(H_2O)_7Al(OH)_6Mo_6O_(18)·4H_2O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster linked by Cerium Ions

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Chemical Research in Chinese Universities 2005年第6期21卷 637-640页

作者： JIN Hua QI Yan-fei QIN Chao wang Xin-long wang en-bo xu lin Institute of Polyoxometalate Chemistry Faculty of Chemistry Northeast Normal University Changchun 130024 P. R. China

A new cerium polyoxomolybdate { [Ce （ H2 O） 7 Al （ OH ） 6 Mo6 O18 ] · 4H20 } （ compound 1 ） was synthesized and characterized by X-ray diffraction analysis, elemental analysis, TG analysis and IR spectrometry. Compound 1 exhibits a zigzag chain-like structure, which is constructed from an Anderson type anion and rare earth metal, Ce（ Ⅲ ）. These 1-D chains are further extended into a 3-D network by the aid of muhipoint hydrogen-bonding interactions.

关键词： One-pot reaction Zigzag chain-like polymer Rare earth metal Polyoxometalate

Synthesis of Coordination Polymers Using Different Maleic Acid Ligands under Hydrothermal Conditions

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Chemical Research in Chinese Universities 2007年第3期23卷 245-249页

作者： wang Xiao-lan wang en-bo xu Xin-xin Institute of Polyoxometalate Chemistry School of Chemistry Northeast Normal University Changchun 130024 P. R. China Department of Chemistry Baicheng Education Normal College Baicheng 137000 P. R. China

A novel coordination polymer, [ Ni （mal）（1,10＇-phen）（ H2O） ] n （ 1 ）（ mal = malate, 1,10＇-phen = 1,10- phenanthroline） was synthesized using malic acid which was generated from maleic acid via hydrothermal reaction. Complex 1, which displays a two-dimensional supramolecular network, was formed by the addition reaction of Ni and maleic acid with water molecules. To our knowledge, several coordination polymers have been directly synthesized from malic acid, but these types of complexes have seldom been synthesized from maleic acid via hydrothermal reactions. When Ni（ Ⅱ ） ion was changed to Zn（ Ⅱ） ion under the same condition, two-dimensional covalent complex 2 [ Zn2 （fma） 2 （1,10＇-phen） 2 ] n （fma = fumatic acid） was formed. Furthermore, complex 2 exhibits intense photolumi- nescent property at room temperature.

关键词： Maleic acid Hydrothermal reaction Mixed ligands Photoluminescent property

Synthesis and Crystal Structural Characterization of （NH＿4）＿5H＿3Mn＿3V＿（12）O＿（40）·15H＿2O

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Chemical Research in Chinese Universities 1995年第4期11卷 360-363页

作者： wang zuo-ping LIU Jing-fu and wang en-bo(Depatment of Chemistry,Northeast Normal University,Changchun,130024) NE NORMAL UNIV DEPT CHEMCHANGCHUN 130024PEOPLES R CHINA

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关键词： Heteropolyvanadomanganate Structure Synthesis