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Boron isotopic fractionation in laboratory inorganic carbonate precipitation:Evidence for the incorpora-tion of B(OH)_3.into carbonate

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Science china Earth Sciences 2008年第12期51卷 1776-1785页

作者： XIAO YingKai1,2, LI HuaLing1,3. liu WeiGuo4, wang XiuFang1 & JIANG ShaoYong5 1 Qinghai institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008,{3. 2 {3. key laboratory of environmental geochemistry, institute of geochemistry, Chinese Academy of Sciences, guiyang 550002,{3. 3.Nanjing institute of Geology and Mineral Resources, Nanjing 210016,{3. 4 {3. key laboratory of Loess and Quaternary Geology, institute of Earth Environment, Chinese Academy of Sciences, Xi’an 710075,{3. 5 {3. key laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 210093.{3. 1. Qinghai institute of Salt Lakes Chinese Academy of Sciences Xining 810008 China 2. state key laboratory of {3. {3. Institute of Geochemistry Chinese Academy of Sciences Guiyang 550002 China 3. Nanjing institute of Geology and Mineral Resources 210016 Nanjing China 4. state key laboratory of Loess and Quaternary Geology Institute of Earth Environment Chinese Academy of Sciences Xi’an 710075 China 5. state key laboratory for Mineral Deposits Research Department of Earth Sciences Nanjing University Nanjing 210093 China

A laboratory inorganic carbonate precipitation experiment at high pH of 8.96 to 9.3. was conducted, and the boron isotopic fractionations of the precipitated carbonate were measured. The data show that boron isotopic fractionation factors (αcarb-3. between carbonate and B(OH)3.in seawater range 0.93. and 0.965, with an average value of 0.953. Our results together with those reported by Sanyal and collabo-rators show that the αcarb-3.values between carbonate and B(OH)3.in solution are not constant but are negatively correlated with the pH of seawater. The measured boron isotopic compositions of carbonate precipitation (δ11Bcarb) do not exactly lie on the best-fit theoretical δ 11B4-pH curves and neither do they exactly parallel any theoretical δ 11B4-pH curves. Therefore, it is reasonable to argue that a changeable proportion of B(OH)3.with pH of seawater should also be incorporated into carbonate except for the dominant incorporation of B(OH)4- in carbonate . Hence, in the reconstruction of the paleo-pH of sea-water from boron isotopes in marine biogenic carbonates, the use of theoretical boron isotopic frac-tionation factor (α4-3. between B(OH)4- and B(OH)3.is not suitable. Instead, an empirical equation should be established.

关键词： boron isotopic fractionation biogenic carbonate B(OH)3 incorporation

Regulation mechanism of EM parameters in natural ferrite and its application in microwave absorbing materials

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Science china(Technological Sciences) 2006年第1期49卷 38-49页

作者： ZHENG Yongchun1,2, wang Shijie2, FENG Junming2, LI Chunlai1, OUYANG Ziyuan1,2, liu Jianzhong1 & LI Xiaobiao2 1. National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012, china 2. {3. key {3. of environmental geochemistry, institute of geochemistry, Chinese Academy of Sciences, guiyang 550002, china 1. National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China 2. state key laboratory of {3. {3. Institute of Geochemistry Chinese Academy of Sciences Guiyang 550002 China

Electromagnetic (EM) parameters (ε ′, ε ″, μ ′, μ″ ) of several M2+Fe2O4 and Fe2O3.type natural ferrites with different geological occurrences are measured in this pa-per. The measurement results show that EM parameters of a magmatic-occurring natural ferrite is very different from other types occurring from sedimentary-metamorphic iron deposit, hydrothermal vein iron deposit, outer contact of magmatic iron deposit. It has potential to be used as magnetic absorbent in microwave absorbing materials. After min-eral separation and concentration, this magmatic-occurring natural ferrite was processed into type A ferrite absorbent. Type A natural ferrite absorbent is a kind of magnetic material with low dielectric constants, high magnetic conductivity and high EM loss. Its EM pa-rameters are ε ′ = 58.60, ε ″ = 10.0, μ ′ = 1.2-1.5, μ ″ = 1.0-1.2, respectively. In order to illuminate the regulation mechanism of EM parameters, we studied the chemical and mineral composition of type A ferrite absorbent. There is high concentration of natural impurities, which regulate the EM parameters of type A ferrite greatly. For comparison, the other types of natural ferrite, single-phase magnetite and two-phase iron minerals (ilmen-ite and magnetite), have few impurity. Thus regulation mechanism of EM parameters was absent in these ferrites. As a result, the regulation of EM parameters is advantageous to develop type A natural ferrite as excellent absorbent, lowers the reflectivity coefficients and enhances the absorbing efficiency of MAM made from it. Furthermore, the impurities in type A natural ferrite and its effects on EM parameters are very difficult to simulate in the synthesize ferrite. The carbonyl-iron powder is another kind of absorbent that is used ex-tensively in MAM. To compare the absorbing properties of these two absorbent, type A natural ferrite and carbonyl-iron powder were mixed with rubber and processed into mi-crowave absorbing sheets with the same procedures and tec

关键词： natural impure ferrite, complex permittivity, complex permeability, microwave absorbing materials.

Assessment of tree-ring mercury radial translocation and age effect in Masson pine:Implications for historical atmospheric mercury reconstruction

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Journal of environmental Sciences 2024年第4期138卷 266-276页

作者： Xu liu Xun wang Dingyong wang College of Resources and Environment Southwest UniversityChongqing 400715China state key laboratory of {3. {3. Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China

The tree ring has been regarded as an emerging archive to reconstruct historical atmospheric mercury(Hg)trends,but with the large knowledge gaps in the *** this study,we comprehensively evaluated the Hg source,radial translocation and age effect of Masson pine(Pinus massoniana)tree ring at *** in Chongqing,to assess the suitability of such tree ring as the archive of atmospheric *** showed that distinct variabilities among Masson pine tree-ring Hg concentration *** Hg concentration significantly increased along with stem height(P<0.05),indicating the Hg in tree rings mainly derived from foliage uptake atmospheric *** found a distinct age effect that the tree ring of young trees had the higher Hg ***,we used the advection-diffusion model to demonstrate how Hg concentration shifted by the advection or/and diffusion in tree *** modeling results showed that the advection induced radial translocation during the young growth period of tree was a plausible mechanism to result in the tree-ring Hg record largely different from the trend of anthropogenic Hg emissions in *** finally suggest that in further Hg dendrochemistry,better discarding the tree-ring Hg profile of the young growth period to reduce impacts of the radial translocation and age effect.

关键词： Masson pine Tree-ring mercury Radial translocation Tree age effect

Rebuilding the theory of isotope fractionation for evaporation of silicate melts under vacuum condition

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Acta Geochimica 2024年第4期43卷 661-676页

作者： Jie wang Yun liu Research Center for Planetary Science College of Earth and Planetary SciencesChengdu University of TechnologyChengdu 610059China state key laboratory of Ore Deposit {3. Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China CAS Center for Excellence in Comparative Planetology Hefei 230026China

Isotope eff ects are pivotal in understanding silicate melt evaporation and planetary accretion *** on the Hertz-Knudsen equation,the current theory often fails to predict observed isotope fractionations of laboratory experiments due to its oversimplified ***,we point out that the Hertz-Knudsen-equation-based theory is incomplete for silicate melt evaporation cases and can only be used for situations where the vaporized species is identical to the one in the *** propose a new model designed for silicate melt evaporation under *** model considers multiple steps including mass transfer,chemical reaction,and *** derivations reveal a kinetic isotopic fractionation factor(KIFF orα)αour model=[m(^(1)species)/m(^(2)species)]^(0.5),where m(species)is the mass of the reactant of reaction/nucleation-limiting step or species of diffusion-limiting step and superscript 1 and 2 represent light and heavy isotopes,*** model can eff ectively reproduce most reported KIFFs of laboratory experiments for various elements,i.e.,Mg,Si,K,Rb,Fe,Ca,and ***,the KIFF-mixing model referring that an overall rate of evaporation can be determined by two steps jointly can account for the eff ects of low P_(H2)pressure,composition,and *** addition,we find that chemical reactions,diffusion,and nucleation can control the overall rate of evaporation of silicate melts by using the fitting slope in ln(−ln f)versus ln(t).Notably,our model allows for the theoretical calculations of parameters like activation energy(E_(a)),providing a novel approach to studying compositional and environmental eff ects on evaporation processes,and shedding light on the formation and evolution of the proto-solar and Earth-Moon systems.

关键词： Evaporation Kinetic isotopic fractionation Chemical kinetics Hertz-Knudsen equation CAIS