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World Journal of Gastrointestinal Oncology 2024年第5期16卷 2181-2199页

作者： bo-Na Liu xiao-Li Gao Ying Piao Department of Oncology General Hospital of Northern Theater CommandShenyang 110015Liaoning ProvinceChina

BACKGROUND Recent reviews have outlined the main nanomaterials used in relation to gastrointestinal tumors and described the basic properties of these ***,the research hotspots and trends in the application of nanomaterials in gastric cancer(GC)remain *** To demonstrate the knowledge structure and evolutionary trends of research into the application of nanomaterials in *** Publications related to the application of nanomaterials in GC were retrieved from the Web of Science Core Collection for this systematic review and bibliometric *** and CiteSpace were used for bibliometric and visualization *** From 2000 to 2022,the application of nanomaterials in GC developed *** keyword co-occurrence analysis showed that the related research topics were divided into three clusters:(1)The application of nanomaterials in GC treatment;(2)The application and toxicity of nanomaterials in GC diagnosis;and(3)The effects of nanomaterials on the biological behavior of GC ***,silver nanoparticles,and green synthesis are the latest high-frequency keywords that represent promising future research *** The application of nanomaterials in GC diagnosis and treatment and the mechanisms of their effects on GC cells have been major themes in this field over the past 23 years.

关键词： Nanomaterials Gastric cancer Bibliometrics Drug delivery VOSviewer CiteSpace Systematic review

Vibration response and safety control for blasting vibration of the existing tunnel with defects

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Underground Space 2024年第2期15卷 76-89页

作者： Junying Xia bo wang Xinxin Guo Zhuoxiong Xie Key Laboratory of Transportation Tunnel Engineering Ministry of EducationSouthwest Jiaotong UniversityChengdu 610031China College of Environment and Civil Engineering Chengdu University of TechnologyChengdu 610059China Guangdong Communication Planning&Design Institute Group Co. LtdGuangzhou 510507China

Current studies on blasting construction of small clear-distance tunnels have not considered the impact of existing tunnel lining defects when establishing safety *** paper offers a series of study results based on the blasting project of a new tunnel adjacent to the existing defect Xinling tunnel to thoroughly examine the dynamic response,safety control standards,and measures of the existing defect ***,structural models were developed to investigate the influence of the presence or absence of specific defects(like lining cracks and cavities behind the lining)on the dynamic response of the current tunnel lining to identify the most unfavorable defect ***,establish safety control standards for intact linings and those with the most unfavorable ***,two types of control measures,single safe charge and reasonable delay time,were studied based on the established safety control *** particular,the most adverse position of cracks was the wall facing the explosion,the rise in depth was more unfavorable for vibration response,and the impact of the longitudinal crack was restricted to the vicinity of the *** the vault was the most adverse cavity position,the rise in cavity area was more damaging,and the influence range varied with longitudinal cavity ***,the impact of cracks was mainly evident in the amplification effect of stress at the crack *** contrast,cavities had varied degrees of amplification effects on the vibration velocity and stress response and a relatively extensive influence *** control research was conducted,when the tunnel was intact,with a right wall crack,a vault cavity,and both vault cavity and crack for this project,the peak particle velocity(PPV)of the safety control standard for vibration velocity was 13,10,13,and 8 cm/s,respectively,and the respective single safe charge could be adjusted at 64,53,37,and 25 ***,the presence of different defects had a relati

关键词： Existing tunnel Defect Blasting construction Vibration response Control standards and measures

Bifunctional two-carbon reagent made from acetylene via 1,2-difunctionalization and its applications

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Science China Chemistry 2024年第3期67卷 936-944页

作者： bo Yang Kangkui Li Yongdong wang Shifa Zhu Key Laboratory of Functional Molecular Engineering of Guangdong Province School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640China School of Chemistry and Chemical Engineering Zhejiang Sci-Tech UniversityHangzhou 310018China Singfar Laboratories Guangzhou 510670China

There are very limited approaches to directly gluing two molecules for the production of internal alkenes using the vastly abundant acetylene via 1,2-difunctionalization. Conversion of gaseous acetylene to internal alkenes via 1,2-difunctionalization in a desired manner is not as easy as it might be expected due to the potential competition reactions between acetylene and alkene produced and the difficulty in handling this harmful reagent and controlling the regio-and stereoselectivity. In this work, we designed an efficient catalytic system for the incorporation of acetylene gas into tremendous(E)-β-bromo vinylsulfones, which are bench-stable, easy to operate, and can function as bifunctional acetylene and show a rich reactivity profile in Sonogashira coupling, Heck coupling, substituted reaction, and various desulfonylation transformations, providing numerous internal alkenes.

关键词： acetylene 1 2-difunctionalization photocatalysis vinylsulfone

Rectification and electroluminescence of nanostructured GaN/Si heterojunction based on silicon nanoporous pillar array

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Chinese Physics B 2015年第10期24卷 432-437页

作者：王小波李勇闫玲玲李新建 Department of Physics and Laboratory of Material Physics Zhengzhou University College of Physics and Electrical Engineering Anyang Normal University Department of Physics Pingdingshan University

A GaN/Si nanoheterojunction is prepared through growing Ga N nanocrystallites（nc-GaN） on a silicon nanoporous pillar array（Si-NPA） by a chemical vapor deposition（CVD） technique at a relatively low temperature. The average size of nc-Ga N is determined to be ~10 nm. The spectral measurements disclose that the photoluminescence（PL） from GaN/SiNPA is composed of an ultraviolet（UV） band and a broad band spanned from UV to red region, with the feature that the latter band is similar to that of electroluminescence（EL）. The electron transition from the energy levels of conduction band and, or, shallow donors to that of deep acceptors of Ga N is indicated to be responsible for both the broad-band PL and the EL luminescence. A study of the I-V characteristic shows that at a low forward bias, the current across the heterojunction is contact-limited while at a high forward bias it is bulk-limited, which follows the thermionic emission model and space-charge-limited current（SCLC） model, respectively. The bandgap offset analysis indicates that the carrier transport is dominated by electron injection from n-GaN into the p-Si-NPA, and the EL starts to appear only when holes begin to be injected from Si-NPA into GaN with biases higher than a threshold voltage.

关键词： GaN/Si-NPA heterojunction rectification electroluminescence (EL)

Pressure effects on metal/covalent-organic frameworks:structural and optical properties

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Science China Chemistry 2024年第9期67卷 2890-2903页

作者： Yixuan wang Yunfeng Yang Xinyi Yang bo Zou Synergetic Extreme Condition High-Pressure Science Center State Key Laboratory of Superhard MaterialsCollege of PhysicsJilin UniversityChangchun 130012China

Metal-organic frameworks(MOFs)and covalent organic frameworks(COFs)with highly ordered porous structure,tunable bandgap,large specific surface area and structural diversity,provide an appealing platform for the development of stimulus response,sensing,imaging and *** various tuning methods,pressure engineering using the diamond anvil cell is a highly powerful in-situ technique,which can efficiently modulate the structural and optical properties of MOFs/*** is beyond the realization of traditional chemical *** review outlines the research progress in the experimentoriented discovery of new phases or unique properties under high pressure,including phase transition,abnormal compression,photoluminescence(PL)discoloration and ***,the improvement of PL quantum yield in MOFs could be achieved by pressure-treated engineering and hydrogen-bonding cooperativity *** also propose and establish the relationship between structure and optical properties under high ***,the challenge and outlook of the current fields are *** hope that this review will supply guidance for comprehending the development of high-pressure MOF/COF-related research fields,and offer novel strategies for designing more high-performance MOF/COF materials to ultimately expand their applications.

关键词： metal/covalent-organic frameworks pressure engineering phase transition abnormal compressive behaviors piezochromic behaviors emission enhancement

Energy modeling and optimization of building condenser water systems with all-variable speed pumps and tower fans:A case study

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Building Simulation 2024年第7期17卷 1085-1111页

作者： Yong Cao Chuang wang Sheng wang xiao Fu Xinguo Ming School of Mechanical Engineering Shanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Air-Conditioning Equipment and System Energy Conservation Zhuhai 519070China GREE Electric Appliances Inc.of ZhuhaiZhuhai 519070China School of Environment and Energy Engineering Beijing University of Civil Engineering and ArchitectureBeijing 100044China Beijing Advanced Innovation Centerfor Future Urban Design Beijing University of Civil Engineering and ArchitectureBeijing 100044China

The emergence of building condenser water systems with all-variable speed pumps and tower fans allows for increased efficiency and flexibility of chiller plants in partial load operation but also increases the control complexity of condenser water *** study aims to develop an integrated modeling technique for evaluating and optimizing the energy performance of such a condenser water *** proposed system model is based on the semi-physical semi-empirical chiller,pump,and cooling tower models,with capabilities of fully considering the hydraulic and thermal interactions in the condenser water loop,being solved analytically and much faster than iterative solvers and supporting the explicit optimization of the pump and tower fan frequency.A mathematical approach,based on the system model and constrained optimization technique,is subsequently established to evaluate the energy performance of a typical dual setpoint-based variable speed strategy and find its energy-saving potential and most efficient operation by jointly optimizing pumps and tower *** all-variable speed chiller plant from Wuhan,China,is used for a case study to validate the system model’s accuracy and explore its *** results showed that the system model can accurately simulate the condenser water system’s performance under various operating *** optimizing the frequencies of pumps and tower fans,the total system energy consumption can be reduced by 12%–13%compared to the fixed dual setpoint-based strategy with range and approach setpoints of 4℃and 2℃.In contrast,the energy-saving potential of optimizing the cooling tower sequencing is insignificant.A simple joint speed control method for optimizing the pumps and tower fans emerged,i.e.,the optimal pump and fan frequency are linearly correlated(if both are non-extremes)and depend on the chiller part load ratio only,irrespective of the ambient wet-bulb temperature and chilled water supply *** was also foun

关键词： all-variable speed chiller plant model-based optimization hydraulic and thermal coupling analytical solution dual setpoint-based variable speed control optimal joint speed control

Full-domain collaborative deployment method of multiple interference sources and evaluation of its deployment effect

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Defence Technology（防务技术） 2024年第2期32卷 572-595页

作者： Yue wang Fuping Sun Xian wang Jinming Hao Kai xiao School of Geospatial Information The PLA Information Engineering UniversityZhengzhou 450001HenanChina

This paper realizes the full-domain collaborative deployment of multiple interference sources of the global satellite navigation system(GNSS)and evaluates the deployment effect to enhance the ability to disturb the attacker and the capability to defend the GNSS during navigation *** evaluation indicators for the jamming effect of GNSS suppressive and deceptive jamming sources are first created,their evaluation models are built,and their detection procedures are sorted out,as the basis for determining the deployment *** principles for collaboratively deploying multi-jamming sources are developed to obtain the deployment structures(including the required number,structures in demand,and corresponding positions)of three single interference sources required by collaboratively ***,simulation and hardware-in-loop testing results are presented to determine a rational configuration of the collaborative deployment of multi-jamming sources in the set situation and further realize the full-domain deployment of an interference network from ground,air to *** evaluation indices for the deployment effect are finally developed to evaluate the deployment effect of the proposed configuration and further verify its reliability and rationality.

关键词： Jamming effect Multiple interference sources Collaborative deployment Effect evaluation Defense capability

Control of fine particulate nitrate during severe winter haze in“2+26”cities

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Journal of Environmental Sciences 2024年第2期136卷 261-269页

作者： Chuang Qin xiao Fu Tao wang Jian Gao Jiaqi wang Institute of Environment and Ecology Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055China Department of Civil and Environmental Engineering Hong Kong Polytechnic UniversityHong Kong 99907China State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental SciencesBeijing 10084China

The“2+26”cities,suffering the most severe winter haze pollution,have been the key region for air quality improvement in *** prominent nitrate pollution is one of the most challenging environmental issues in this region,necessitating development of an effective control ***,we use observations,and state-of-the-art model simulations with scenario analysis and process analysis to quantify the effectiveness of the future SO_(2)-NO_(X)-VOC-NH_(3) emission control on nitrate pollution mitigation in“2+26”*** on a serious winter haze episode,we find that limited NO_(X)emission reduction alone in the short-term period is a less effective choice than VOC or NH_3emission reduction alone to decrease nitrate concentrations,due to the accelerated NO_(X)-HNO_(3)conversion by atmospheric oxidants and the enhanced HNO_(3)to NO_(3)^(-)partition by ammonia,although deep NO_(X)emission reduction is essential in the long-term *** synergistic NH_(3) and VOC emission control is strongly recommended,which can counteract the adverse effects of nonlinear photochemistry and aerosol chemical feedback to decrease nitrate *** extra benefits will be reduced if the synergistic NH_(3) and VOC reduction is delayed,and thus reducing emission of multiple precursors is urgently required for the effective control of increasingly severe winter nitrate pollution in“2+26”cities.

关键词： Nitrate Winter haze pollution Emission reduction “2+26”cities

The mechanisms of thermal solidification agent promoting steam diversion in heavy oil reservoirs

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Petroleum Science 2024年第3期21卷 1902-1914页

作者： Zhan-Xi Pang Qian-Hui wang Qiang Meng bo wang Dong Liu State Key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing102249China Liaohe Oilfield Institute CNPC ChinaPanjin124000LiaoningChina Henan Oilfield Institute Sinopec ChinaNanyang473400HenanChina Tianjin Branch of China National Offshore Oil Company(CNOOC)Ltd. Tianjin300452China

At high cycles of steam huff&puff,oil distribution in reservoirs becomes stronger heterogeneity due to steam *** solidification agent can be used to solve this *** solution is a lowviscosity liquid at normal temperature,but it can be solidified above 80℃.The plugging degree is up to 99%at 250℃.The sweep efficiency reaches 59.2%,which is 7.3%higher than pure steam *** addition,simultaneous injection of viscosity reducer and/or nitrogen foams can further enhance oil *** mechanism of this technology depends on its strong plugging ability,which changes the flowing pattern of steam to effectively mobilize remaining *** reducer and nitrogen foams further expand the sweep range and extends the effective ***,thermal solidification agent can plug steam channeling paths and adjust steam flowing direction to significantly enhance oil recovery at high cycles of steam huff&puff.

关键词： Heavy oil reservoir Steam huff&puff Steam channeling Steam diversion Plugging performance Mechanism analysis

The preparation and performance analysis of zirconium-modified aluminum phosphate-based high-temperature(RT-1500℃)resistant adhesive for joining alumina in extreme environment

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Journal of Advanced Ceramics 2024年第7期13卷 911-932页

作者： Jingxuan Liu Yange Wan bo xiao Jiancun Li Zhanming Hu Ruoyu Zhang xiaoxia Hu Jiachen Liu Guoshuai Cai Hongli Liu Mingchao wang College of Science Civil Aviation University of ChinaTianjin 300300China Department of Safety Engineering Civil Aviation University of ChinaTianjin 300300China Binzhou Beicheng Construction Engineering Materials Testing Co. Ltd.Binzhou 256602China Department of Aviation Engineering Civil Aviation University of ChinaTianjin 300300China School of Materials and Engineering Key Lab of Advanced Ceramics and Machining Technology of Ministry of EducationTianjin UniversityTianjin 300072China

High-temperature-resistant adhesives are critical materials in the aerospace *** zirconium-modified aluminum phosphate-based adhesives developed in this work had the advantage of adjustable thermal expansibility,achieving a high matching of coefficient of thermal expansion(CTE)with *** introduction of zirconium can significantly improve the thermal stability of the adhesive matrix,and the Zr/Al ratio substantially affects the various reaction processes inside the adhesive,especially the types of zirconium-containing *** of the zirconium-containing compounds in the A7Z3 adhesive were ZrO_(2) only when the mass ratio of zirconium hydroxide to aluminum hydroxide was 3:7,which was the key reason why it had the highest *** room-temperature bonding strength of A7Z3 after heat treatment at 1500℃reached 67.2 *** pretreatment at 1500℃,the high-temperature bonding strength of A7Z3 was greater than 50 MPa in the range of(room temperature)RT-1000℃.After 40 thermal cycles between RT and 1500℃,the bonding strength still reached 10 *** bonding occurred at temperatures below 1000℃,while chemical bonding dominated above 1000℃based on the generation of Al5bo9 and mullite at the interfaces.

关键词： high-temperature-resistant adhesive thermal expansion property zirconium-modified aluminum phosphate bonding performance thermal cycling bonding mechanism