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Transactions of Nonferrous Metals Society of China 2024年第8期34卷 2658-2670页

作者： Xiu-feng GONG Jin YAO Bin YANG wan-zhong yin Yu-lian wanG Ya-feng FU School of Resources and Civil Engineering Northeastern UniversityShenyang 110819China School of Chemical Engineering China University of Mining and TechnologyXuzhou 221163China School of Materials Science and Engineering Shenyang Ligong UniversityShenyang 110159China Ansteel Beijing Research Institute Co. Ltd.Beijing 102200China

To achieve efficient flotation separation of brucite and calcite,flotation separation experiments were conducted on two minerals using dodecylamine(DDA)as the collector and potassium dihydrogen phosphate(PDP)as the *** action mechanism of DDA and PDP was explored through contact angle measurement,zeta potential detection,solution chemistry calculation,FTIR analysis,and XPS *** flotation results showed that when DDA dosage was 35 mg/L and PDP dosage was 40 mg/L,the maximum floating difference between brucite and calcite was 79.81%,and the selectivity separation index was *** detection analysis showed that the main dissolved component HPO_(4)^(2−)of PDP is selectively strongly adsorbed on the Ca site on the surface of calcite,promoting the adsorption of the main dissolved component RNH_(3)^(+)of DDA on calcite surface,while brucite is basically not affected by ***,PDP is an effective regulator for the reverse flotation separation of brucite and calcite in DDA system.

关键词： brucite calcite selective adsorption flotation separation

Interactive effect of minerals on complex ore flotation: A brief review

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International Journal of Minerals,Metallurgy and Materials 2020年第5期27卷 571-583页

作者： wan-zhong yin Yuan Tang School of Resources and Civil Engineering Northeastern UniversityShenyang 110819China

Froth flotation is the most effective industrial method used to separate fine-grained minerals. The main problem of complex ore flotation is the negative effect of interactions among minerals in slurry, leading to variation in surface properties during separation. In this review,studies on the interactive effect among minerals on the flotation of iron ores, magnesite ores, and scheelite ores are summarized, and the main problems and mechanisms that diminish the separation efficiency of minerals are revealed in detail. Recent research progress on the flotation of these ores has confirmed that mineral aggregation, coating, and dissolution, as well as other factors caused by interacting behavior, explain the depressing effects of fine particles on mineral separation. Solvable methods for these effects are further discussed. Novel flotation processes and more selective reagents are critical for further investigations on various approaches to improve the beneficiation efficiency of these *** review aims to provide a good reference for conducting studies related to complex ore flotation.

关键词： interactive effect flotation iron ores magnesite ores scheelite ores

Structure–activity relationship and mechanisms of reagents used in scheelite flotation

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Rare Metals 2015年第12期34卷 882-887页

作者： wan-zhong yin Ji-Zhen wang zhong-Mei Sun School of Resource and Civil Engineering Northeastern University Design & Research Institute of Zijin

Effects of carboxylic acid collector, benzohydroxamic acid (BHA), sodium hexametaphosphate (SHAP), sodium silicate, and oxalic acid on scheelite flotation were studied through flotation tests, quantum chemical calculation, and flotation solution computational chemistry. In terms of the calculation results, the relationship between chemical reactions occurring on the scheelite surface and molecular structures of the reagents were analyzed. The results show that BHA and carboxylic acid collectors interact with scheelite in different forms and the recovery of scheelite using sodium oleate as collector declines successively from SHAP, sodium silicate, to oxalic acid. Moreover, it is found that the performance of depressant in scheelite flotation is directly related to the group electronegativity, indicating that the latter is a dominant factor that determines the former. These findings will be helpful to the academic research communities of scheelite flotation.

关键词： Scheelite Flotation Flotation reagents Structure–activity relationship

Optimization and mechanism of gold-bearing sulfide flotation

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Rare Metals 2014年第3期33卷 363-368页

作者： zhong-Mei Sun Chun-Bao Sun Ji-Zhen wang wan-zhong yin School of Civil and Environmental Engineering University of Science and Technology Beijing Zijin Research Institute of Mining and Metallurgy School of Materials & Metallurgy Northeastern University College of Zi Jin Mining Fuzhou University

In order to overcome the difficulty of extracting gold from gold-bearing sulfide ore by cyanide process flotation was adopted based on mineralogical analysis Mineralogy shows that gold particles are of superfine structure and mainly enclosed by sulfide ores. Primary gold-bearing sulfide ore is fine-grained pyrite and arsenopyrite. The paper describes the effects of ratios and dosage of activators and collectors on the recovery and grade of gold concentrate. A proper flotation flowsheet was then proposed based on experimental condition and closedcircuit test. The gold concentrate with the gold grade of25.14 g ton-1and the recovery of 86.94 % is obtained after one rougher, three cleaners, and four scavengers from fine grinding flotation process. Furthermore, the mechanisms of combined activators and combined collectors were studied by thermodynamic calculation, and structure-activity relationship of flotation reagent was also explained

关键词： Gold Pyrite Arsenopyrite Activator Combined reagent Flotation

Effect and mechanism of siderite on reverse flotation of hematite

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International Journal of Minerals,Metallurgy and Materials 2016年第4期23卷 373-379页

作者： wan-zhong yin Dong Li Xi-mei Luo Jin Yao Qian-yu Sun College of Resources and Civil Engineering Northeastern University College of Zijin Mining Fuzhou University Faculty of Land Resource Engineering Kunming University of Science and Technology

The effects of siderite on reverse flotation of hematite were investigated using micro flotation, adsorption tests, and Fourier transform infrared spectroscopy. The flotation results show that interactions between siderite and quartz are the main reasons that siderite significantly influences the floatability. The interactions are attributed to dissolved siderite species and fine siderite particles. The interaction due to the dissolved species is, however, dominant. Derjaguin-Landau-Verwey-Overbeek（DLVO） theoretical calculations reveal that adhesion on quartz increases when the siderite particle size decreases and that fine particles partly influence quartz floatability. Chemical solution calculations indicate that the dissolved species of siderite might convert the surface of active quartz to CaCO_3 precipitates that can be depressed by starch. The theoretical calculations are in good agreement with the results of adsorption tests and FTIR spectroscopy and explain the reasons why siderite significantly influences reverse flotation of hematite.

关键词： hematite siderite reverse flotation solution chemistry

Synthesis and formation mechanism of micro/nano flower-like MgCO_3·5H_2O

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International Journal of Minerals,Metallurgy and Materials 2014年第3期21卷 304-310页

作者： wan-zhong yin Yu-lian wang Qiang-dong Ji Jin Yao ying Hou Lei wang Wen-xing zhong School of Resources & Civil Engineering Northeastern University Mining Metallurgy &Materials Research Institute General Research Institute for Nonferrous Metals Beijing

Micro/nano magnesium carbonate pentahydrate（MgCO3 ·5H2 O） with flower-like morphology was synthesized using magnesite as a substrate and potassium dihydrogen phosphate as an additive. The synthesized samples were characterized by scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetry and differential scanning calorimetry. The influence of pyrolysis time on crystal morphology was explored. The formation mechanism was investigated on the basis of the characterized results and the crystal structure of MgCO3 ·5H2 O. The results showed that the flower-like MgCO3 ·5H2 O was 1.5-3.0 μm in length and 100-500 nm in diameter and was successfully obtained with a pyrolysis time of 30 min. The formation mechanism of flower-like MgCO3 ·5H2 O is suggested to be the selective adsorption of potassium dihydrogen phosphate on the surface. The process of flower-like crystal growth is as follows： amorphous nanoparticles formation, acicular and rod monocrystal formation, flower-like monocrystal formation, and flower-like polymers（MgCO3 ·5H2 O） crystallization. In the MgCO3 ·5H2 O crystal, the magnesium ion presents two different octahedral coordinations corresponding to2 26 Mg（H O）＋and2 2 2 4 23 [Mg（H O）（CO） ]--, and the chemical formula of the crystal is2 2 6 2 4 23 Mg（H O） Mg（H O）（CO）2.

关键词： magnesium carbonate hydrates synthesis morphology crystal growth

Solution chemistry of carbonate minerals and its effects on the flotation of hematite with sodium oleate

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International Journal of Minerals,Metallurgy and Materials 2017年第7期24卷 736-744页

作者： Dong Li wan-zhong yin Ji-wei Xue Jin Yao Ya-feng Fu Qi Liu School of Resources and Civil Engineering Northeastern University College of Zijin Mining Fuzhou University Department of Chemical and Materials Engineering University of Alberta

The effects of carbonate minerals（dolomite and siderite） on the flotation of hematite using sodium oleate as a collector were investigated through flotation tests, supplemented by dissolution measurements, solution chemistry calculations, zeta-potential measurements, Fourier transform infrared（FTIR） spectroscopic studies, and X-ray photoelectron spectroscopy（XPS） analyses. The results of flotation tests show that the presence of siderite or dolomite reduced the recovery of hematite and that the inhibiting effects of dolomite were stronger. Dissolution measurements, solution chemistry calculations, and flotation tests confirmed that both the cations（Ca^（2＋） and Mg^（2＋）） and CO_3^（2＋）ions dissolved from dolomite depressed hematite flotation, whereas only the 23CO-ions dissolved from siderite were responsible for hematite depression. The zeta-potential, FTIR spectroscopic, and XPS analyses indicated that Ca^（2＋）, Mg^（2＋）, and CO_3^（2-）（HCO_3^-） could adsorb onto the hematite surface, thereby hindering the adsorption of sodium oleate, which was the main reason for the inhibiting effects of carbonate minerals on hematite flotation.

关键词： hematite carbonate minerals solution chemistry sodium oleate flotation

Effect of sodium alginate on reverse flotation of hematite and its mechanism

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International Journal of Minerals,Metallurgy and Materials 2018年第10期25卷 1113-1122页

作者： Ya-feng Fu wan-zhong yin Bin Yang Chuang Li Zhang-lei Zhu Dong Li School of Resources & Civil Engineering Northeastern University The State Key Laboratory of Mineral Processing Beijing General Research Institute of Mining & Metallurgy

Given the gradual increase in the chlorite content of hematite ores, pulp properties seriously deteriorate during flotation. The traditional anion reverse flotation of hematite cannot effectively eliminate the effects of chlorite, leading to a significant decrease in the total Fe(TFe) grade of the concentrate. In this work, the effect of sodium alginate on the reverse flotation of hematite was systematically investigated. Flotation tests of artificially mixed ores were conducted, and the results showed that sodium alginate can significantly improve the removal rates of quartz and chlorite. The adsorption measurements, infrared spectroscopy, and contact angle tests demonstrated that sodium alginate adsorbs on the quartz surface by chelating with calcium ions, thereby weakening the steric hindrance of oleate ions and increasing the adsorption capacity of sodium oleate to ultimately improve the removal rate of quartz. Furthermore, owing to its lower density and fine particle size, chlorite is easily entrained into the foam layer. Sodium alginate dramatically increases the liquid-to-gas ratio of the foam layer by increasing pulp viscosity, thereby increasing the entrainment rate of chlorite and finally improving its removal rate. The core content of this thesis bears significance in improving the Fe grade in the reverse flotation of chlorite-containing hematite.

关键词： hematite reverse flotation sodium alginate pulp viscosity entrainment rate

Research on new beneficiation process of low-grade magnesite using vertical roller mill

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International Journal of Minerals,Metallurgy and Materials 2020年第4期27卷 432-442页

作者： Chuang Li Chuan-yao Sun Yu-lian wang Ya-feng Fu Peng-yun Xu wan-zhong yin School of Resources and Civil Engineering Northeastern UniversityShenyang 110819China State Key Laboratory of Mineral Processing Beijing 102628China National Engineering Research Center of WEEE Recycling Engineering Jingmen 448124China School of Materials Science and Engineering Shenyang Ligong UniversityShenyang 110159China College of Zijin Mining Fuzhou UniversityFuzhou 350108China

We investigated whether the vertical roller mill can be efficiently used in the beneficiation of low-grade magnesite and whether it can improve upon the separation indices achieved by the ball *** conducted experiments involving the reverse flotation and positive flotation of low-grade magnesite to determine the optimum process parameters,and then performed closed-circuit beneficiation experiments using the vertical roller mill and ball *** results show that the optimum process parameters for the vertical roller mill are as follows:a grinding fineness of 81.6wt%of particles less than 0.074 mm,a dodecyl amine(DDA)dosage in magnesite reverse flotation of 100 g·t?1,and dosages of Na2CO3,(NaPO3)6,and NaOL in the positive flotation section of 1000,100,and 1000 g·t?1,*** with the ball mill,the use of the vertical roller mill in the beneficiation of low-grade magnesite resulted in a 1.28%increase in the concentrate grade of MgO and a 5.88%increase in the recovery of *** results of our causation mechanism analysis show that a higher specific surface area and greater surface roughness are the main reasons for the better flotation performance of particles ground by the vertical roller mill in the beneficiation of lowgrade magnesite.

关键词： low-grade magnesite vertical roller mill reverse flotation positive flotation new beneficiation process

Improving the sulfidation-flotation of fine cuprite by hydrophobic flocculation pretreatment

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International Journal of Minerals,Metallurgy and Materials 2018年第11期25卷 1256-1262页

作者： Qian-yu Sun wan-zhong yin Dong Li Ya-feng Fu Ji-wei Xue Jin Yao College of Resources and Civil Engineering Northeastern University College of Zijin Mining Fuzhou University

Hydrophobic flocculation pretreatment was performed to assess its effect on the recovery of fine cuprite in sulfidation-flotation. The results of the micro-flotation experiment showed that cuprite recovery is related to the particle size, and that an excessive content of fine particles(<18 μm) impacted the recovery of coarse particles. When hydrophobic flocculation pretreatment was used, the recovery of fine cuprite in sulfidation-flotation increased from 60.3% to 86.3% under optimum conditions(pH 9.5; sodium oleate concentration, 2 × 10^(-4) mol×L^(-1); stirring time, 6 min; stirring speed, 1600 r×min^(-1)). The laser particle size analysis and optical microscopy results indicate that hydrophobic flocculation pretreatment effectively reduces the content of fine cuprite, and augments the apparent particle size in the pulp. We performed the Derjaguin–Landau–Verwey–Overbeek(DLVO) theory and extended DLVO theory calculations to further support the interpretation of the results.

关键词： fine cuprite sulfidation-flotation hydrophobic flocculation pretreatment extened DLVO theory calculation