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Journal of Energy Chemistry 2013年第1期22卷 130-135页

作者： Olga v. Zalomaeva Nataliya v. Maksimchuk Andrey M. Chibiryaev Konstantin A. Kovalenko vladimir P. Fedin Bair S. Balzhinimaev Boreskov Institute of Catalysis pr. Akademika Lavrentieva 5 vorozhtsov Novosibirsk Institute of Organic Chemistry pr Akademika Lavrentieva 9 Nikolaev Institute of Inorganic Chemistry pr. Akademika Lavrentieva 3

Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbon- ates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions （8 bar CO2, 25 ~C）. Styrene and propylene carbonates were formed with high yields （95% and 82%, respectively）. Catalytic performance of Cr-MIL-101 was compared with other MOFs： Fe-MIL-101, Zn-MOF-5 and HKUST-1, The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW12/Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H202 as oxidants at 8-100bar CO2 and 25-80 ~C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.

关键词： carbon dioxide cyclic carbonates cycloaddition heterogeneous catalysis metal-organic framework oxidative carboxylation quaternary am-monium salts

Advanced Ramming Mix Based on Fused Zirconia Stabilized by Com-bined Additives of CaO and MgO for Lining of Carbon Black Production Reactor

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China's Refractories 2017年第3期26卷 1-7页

作者： valeriy v.MARTYNENKO vladimir v.PRIMACHENKO Irina G.SHULIK Dmitriy A.SHISHKOvSKIY Eleonora L.KARYAKINA vladimir v.vARGANOv PJSC "The Ukrainian Research Institute of Refractories named after A.S.Berezhnoy"

Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characteristics of these materials are determined. It is shown that, the materials of all compositions have low water absorption; they are characterized by equal struc-ture. The materials stabilized by the combined additive consisting of CaO and MgO are presented by generally the cubic phase and a small amount of tetragonal and monoclinic ZrO2 phases. Depending on CaO： MgO ratio in the materials the tetragonal ZrO2 phase settles down in a cubic matrix in the form of separate grains, and sites of net like structure in the form of a ＂woven＂ interlacing （2.9% of CaO and 2. 6% of MgO ）. An influence of the above mentioned fused stabilized ZrO2 materials and quantity of monoclinic zirconia, on the forming of zirconia mix on a phosphate bond and properties of＂ .fired samples is studied. The samples from mix based on ZrO2 stabilized by the combined additive consisting of 2.9% CaO and 2.6% MgO with 20% of monoclinic Zr02 are characterized by the highest properties： after .firing at 1 580 ~C open porosity of 14. 3% - 14. 8%, apparent density of 4. 67 -4. 69 g · cm^-5, cold crushing strength of 62 - 68 MPa, thermal shock resistance （ 1 300℃←→air） of 15 thermal cycles, linear growth of 0. 2%. The manufacturing technology of powders mix-ture for ramming mix based on the new fused material .from ZrO2 stabilized by the combined additive is developed and its production is mastered. From this mixture the large-size, shaped products on the phosphate bond are made at one carbon black production plant, which are installed in the combustion chamber of the carbon black production reactor.

关键词： fused stabilized zirconia combined additives calcia and magnesia ramming mix carbon black production reactor

Intestinal microbiome changes in an infant with right atrial isomerism and recurrent necrotizing enterocolitis:A case report and review of literature

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World Journal of Clinical Cases 2022年第29期10卷 10583-10599页

作者： Aleksandra Kaplina Ekaterina Zaikova Artem Ivanov Yulia volkova Tatiana Alkhova vladimir Nikiforov Alexander Latypov Marina Khavkina Tatiana Fedoseeva Tatiana Pervunina Yulia Skorobogatova Svetlana volkova vladimir Ulyantsev Olga Kalinina Stanislav Sitkin Natalia Petrova Research Laboratory of Physiology and Diseases of Newborns Almazov National Medical Research CentreSt.Petersburg 197341Russia Research Laboratory of Autoimmune and Autoinflammatory Diseases Almazov National Medical Research CentreSt.Petersburg 197341Russia vladimir Ulyantsev International Laboratory of Computer TechnologiesITMO UniversitySt.Petersburg 197101Russia Department of Cardiovascular Surgery for Children Almazov National Medical Research CentreSt.Petersburg 197341Russia Department of Neonatal Physiology with an ICU Ward Almazov National Medical Research CentreSt.Petersburg 197341Russia Pediatric Cardiac Intensive Care Unit Almazov National Medical Research CentreSt.Petersburg 197341Russia Neonatal and Preterm Special Care Unit(2nd Stage Care) Almazov National Medical Research CentreSt.Petersburg 197341Russia Institute of Perinatology and Pediatrics Almazov National Medical Research CentreSt.Petersburg 197341Russia Express Laboratory of Perinatal Centre Almazov National Medical Research CentreSt.Petersburg 197341Russia Clinical Diagnostic Laboratory Almazov National Medical Research CentreSt.Petersburg 197341Russia Epigenetics and Metagenomics Group Institute of Perinatology and PediatricsAlmazov National Medical Research CentreSt.Petersburg 197341Russia Department of Internal Diseases Gastroenterology and DieteticsNorth-Western State Medical University named after I.I.MechnikovSt.Petersburg 191015Russia

BACKGROUND Necrotizing enterocolitis(NEC)is a multifactorial disease that predominantly affects premature *** dysbiosis plays a critical role in NEC pathogenesis in premature *** main risk factor for NEC in term infants is mesenteric hypoperfusion associated with ductaldependent congenital heart disease(CHD)that eventually leads to intestinal *** incidence of NEC in neonates with critical CHD is 6.8%-13%.However,the role of the intestinal microbiome in NEC pathogenesis in infants with ductal-dependent CHD remains *** SUMMARY A male term neonate with right atrial isomerism underwent modified Blalock-Taussig shunt placement on the 14^(th)day of life and had persistent mesenteric hypoperfusion after *** patient had episodes of NEC stageⅡA on the 1^(st)and 28^(th)days after cardiac *** microbial composition was analyzed before and after cardiac surgery by sequencing region v4 of the 16S rRNA *** surgery,species belonging to genera veillonella and Clostridia and class Gammaproteobacteria were detected,Bifidobacteriaceae showed a low *** first NEC episode was associated with postoperative hemodynamic instability,intestinal ischemiareperfusion injury during cardiopulmonary bypass,and a high abundance of Clostridium paraputrificum(Clostridium sensu stricto I)(56.1%).Antibacterial therapy after the first NEC episode resulted in increased abundance of Gammaproteobacteria,decreased abundance of Firmicutes,and low alpha *** changes in the microbial composition promoted the growth of Clostridium sensu strictoⅠ(72.0%)before the second NEC *** A high abundance of Clostridium sensu strictoⅠand mesenteric hypoperfusion may have contributed to NEC in the present case.

关键词： Necrotizing enterocolitis Congenital heart disease Ivemark syndrome Heterotaxy Right atrial isomerism Intestinal microbiome Case report

Mantle Transects in Africa According to Data of Mantle Xenocrysts and Diamond Inclusions

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Acta Geologica Sinica(English Edition) 2021年第S1期95卷 15-17页

作者： Igor v.ASHCHEPKOv vladimir N.ZINCHENKO Alexandr S.IvANOv v.S.Sobolev Institute of Geology and Mineralogy SB RAS Novosibirsk 630090Russia CATOCA Mining Society СatocaMoscow 127473Russia ALROSA Ltd. Mirny 678174Russia

We designed the mantle transects using the PTXFO2 diagrams(Ashchepkov et al.,2010,2013,2017)constructed(Figs.1 a–c)for mantle columns beneath kimberlite and sections of the lithospheric mantle(SCLM)under the Kaapvaal... 详细信息

关键词： mantle lithosphere craton transect monomineral thermobarometry oxygen fugacity peridotite eclogite garnet clinopyroxene

Formally Inferring Galileo Galilei Principle of Relativity of Motion in an Axiomatic System “Sigma+v” from a Triple of Nontrivial Assumptions

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Journal of Applied Mathematics and Physics 2022年第8期10卷 2459-2498页

作者： vladimir Olegovich Lobovikov Laboratory for Applied System Investigations Ural Federal University Yekaterinburg Russia

The present paper submits a result of applying a hitherto unknown logically formalized axiomatic axiology-and-epistemology theory “Sigma+v” to the relativity principle formulated by Galileo Galilei. By this application, the author has continued checking the remarkable (paradigm-breaking) hypothesis that formal-axiological interpreting strictly universal laws of classical theoretical mechanics could have a heuristic value for the theory proper. Along with systematical studying proper algebraic structure of formal axiology of nature, the axiomatic (hypothetic-deductive) method is used in this research as well. The investigation accomplishments are the followings. Galileo Galilei principle of relativity of motion has been represented in a two-valued algebraic system of formal axiology by a wonderful formal-axiological equation which could be called a “formal-axiological analog of Galileo relativity principle”. A precise definition of that algebraic system is given. The remarkable formal-axiological equation has been created (and checked) in that algebraic system by attentive computing relevant compositions of evaluation-functions. Precise definitions of the relevant evaluation-functions are accomplished by tables. The remarkable formula modeling Galileo Galilei principle of relativity of motion (given the appropriate interpretation of the formal theory) has been formally-logically inferred within Sigma+v from a couple of nontrivial assumptions, namely, 1) a precisely defined assumption of a-priori-ness of knowledge, 2) the above-mentioned formal-axiological analog of the relativity principle by Galileo Galilei. A not-manifest but quite exact axiomatic definition of “a-priori-ness of knowledge” is provided. The formal-logical inference is performed in perfect accordance with the mathematical rigor norms formulated within the formalism doctrine by D. Hilbert, therefore, examining the formal deductive inference submitted in the paper can be accomplished easily. Being a no

关键词： Galileo-Galilei-Principle-of-Relativity-of-Motion Formal-Axiomatic-Theory-Σ+v Two-valued-Algebraic-System-of-Metaphysics-as-Formal-Axiology Formal-Inference-from-Assumptions Pure-a-Priori--Knowledge

Composition of the Diamond Indicator Minerals on the Mitchell Chart――Criteria of CLIPPIR Diamonds in Kimberlites and Conditions of their Mantle Crystallization

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Acta Geologica Sinica(English Edition) 2021年第S1期95卷 121-124页

作者： vladimir N.ZINCHENKO Alexandr S.IvANOv Igor v.ASHCHEPKOv CATOCA Mining Society СatocaAngola ALROSA Ltd. MirnyRussia v.S.Sobolev Institute of Geology and Mineralogy SB RAS NovosibirskRussia

In the last decade,researchers have been particularly interested in IIa CLIPPIR type diamonds,which differ in composition and physical characteristics from diamonds of peridotite related"P"and eclogite related"E"***(Moore,2009)sought them as mantle kimberlite related megacrysts,but light C isotopy and chemical features needs special explanation.

关键词： CLIPPIR diamonds kimberlite mantle pyrope clinopiroxene chromite ilmenite

Post-seismic relaxation from geodetic and seismic data

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Geodesy and Geodynamics 2017年第1期8卷 13-16页

作者： Mikhail v.Rodkin vladimir I.Kaftan Institute of Earthquake Prediction Theory and Mathematical Geophysics Russian Academy of Sciences Institute of Marine Geology and Geophysics FEB RAS Geophysical Center Russian Academy of Sciences(GC RAS) Peoples' Friendship University of Russia PFUR

We have examined the aftershock sequence and the post-seismic deformation process of the Parkfield earthquake （2004, M = 6, California, USA） source area using GPS data. This event was chosen because of the possibility of joint analysis of data from the rather dense local GPS network （from SOPAC Internet archive） and of the availability of the rather detailed aftershock sequence data （http：]/***[ ncedc[***）. The relaxation process of post-seismic deformation prolongs about the same 400 days as the seismic aftershock process does. Thus, the aftershock process and the relaxation process in deformation could be the different sides of the same process. It should be noted that the ratio of the released seismic energy and of the GPS obtained deformation is quite different for the main shock and for the aftershock stage. The ratio of the released seismic energy to the deformation value decreases essentially for the post-shock process. The similar change in the seismic energy[deformation value ratio is valid in a few other strong earthquakes. Thus, this decrease seems typical of aftershock sequences testifying for decrease of ratio of elastic to inelastic deformation in the process of post-shock relaxation when the source area appears to be mostly fractured after the main shock occurs, but the healing process had no yet sufficient time to develop.

关键词： Post-seismic relaxationEarth's surface deformationGPSpost-shock fracturing

New look at territories of traditional nature use–traditional nature management lands at the coastal zone of the Ice Silk Road:a case study for the Russian Arctic

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International Journal of Digital Earth 2019年第8期12卷 948-961页

作者： Alexander v.Evseev Tatiana M.Krasovskaya vladimir S.Tikunov Irina N.Tikunova Geographical Faculty Lomonosov Moscow State UniversityMoscowRussia

Territories of traditional nature use(TTNU)of indigenous population in the Arctic zone presents a historical model of sustainable development whose main principles are valuable for modern practice of economic activities in this region as *** peoples traditional nature management practice in the Russian Arctic nowadays exists only within tribal community lands,though their virtual limits may be larger and known to indigenous population,helping to preserve regional *** of TTNU in the course of modern economic development,including the Northern Silk Road coastal infrastructure,is important for regional ecological and social *** may be regarded as ecological buffer zones,restoring ecosystem functions important for regional sustainable development,though modern market economy treats them mainly as economic units less valuable for incomes than industrial.A new look at TTNU may be supported by their ecologicaleconomic assessment.A case study in the coastal Nenets TTNU belonging to family-clan community‘Ya’Erv’demonstrates its possible input to local sustainable development.

关键词： Indigenous peoples Russian Arctic traditional nature management ecosystem services value sustainable development Ice Silk Road

Element selection for functional materials discovery by integrated machine learning of elemental contributions to properties

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npj Computational Materials 2023年第1期9卷 639-648页

作者： Andrij vasylenko Dmytro Antypov vladimir v.Gusev Michael W.Gaultois Matthew S.Dyer Matthew J.Rosseinsky Department of Chemistry University of LiverpoolCrown StreetLiverpool L697ZDUnited Kingdom Department of Computer Science University of LiverpoolAshton StreetLiverpool L693BXUnited Kingdom

The unique nature of constituent chemical elements gives rise to fundamental differences in *** materials based on their phase fields,defined as sets of constituent elements,before specific differences emerge due to composition and structure can reduce combinatorial complexity and accelerate screening,exploiting the distinction from composition-level *** and evaluation of novelty of materials classes align with the experimental challenge of identifying new areas of *** address this,we present PhaseSelect,an end-to-end machine learning model that combines representation,classification,regression and novelty ranking of phase *** leverages elemental characteristics derived from computational and experimental materials data and employs attention mechanisms to reflect the individual element contributions when evaluating functional performance of phase *** demonstrate this approach for high-temperature superconductivity,high-temperature magnetism,and targeted bandgap energy applications,showcasing its versatility and potential for accelerating materials exploration.

关键词： materials phase elements

Alien species of mammals and their impact on natural ecosystems in the biosphere reserves of Russia

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Integrative Zoology 2008年第2期3卷 83-94页

作者： valery M.NERONOv Ludmila A.KHLYAP vladimir v.BOBROv Andrey A.WARSHAvSKY A.N.Severtsov Institute of Ecology and Evolution Russian Academy of SciencesMoscowRussia

The paper analyses the results of a survey of 37 Russian biosphere reserves using questionnaires concerning thepresence of alien species of mammals, their pathways of penetration, and their impacts on protected *** penetration of alien mammals into terrestrial ecosystems of Russia is extensive, both in places with maximumhuman environmental impact (inhabited areas and agricultural lands) and in biosphere reserves with minimal humanimpact. There are 62 mammal species registered as alien in Russian ecosystems and they account for 22% of theterrestrial mammal fauna of Russia. The percentage of alien species in biosphere reserves is 32.6% at most. In mostregions, Castor fiber, Ondatra zibethicus, Nyctereutes procyonoides, Canis familiaris, Neovison vison and Susscrofa are very dangerous, and both Castor fiber and Sus scrofa can have environment-forming impacts.

关键词： alien species biosphere reserves invasions mammals(Mammalia) Russia.