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Nano-Micro Letters 2020年第12期12卷 1-12页

作者： Yan Zhang Yuanye Huang vesna srot Peter A.van Aken Joachim Maier Yan Yu Max Planck Institute for Solid State Research Stuttgart 70569Germany Hefei National Laboratory for Physical Sciences at the Microscale Department of Materials Science and EngineeringKey Laboratory of Materials for Energy ConversionChinese Academy of Sciences(CAS)University of Science and Technology of ChinaHefei 230026AnhuiPeople’s Republic of China Dalian National Laboratory for Clean Energy(DNL) Chinese Academy of Sciences(CAS)Dalian 116023LiaoningPeople’s Republic of China

Pseudo-capacitive mechanisms can provide higher energy densities than electrical double-layer capacitors while being faster than bulk storage ***,they suffer from low intrinsic electronic and ion conductivities of the active ***,taking advantage of the combination of TiS2 decoration,sulfur doping,and a nanometer-sized structure,as-spun TiO2/C nanofiber composites are developed that enable rapid transport of sodium ions and electrons,and exhibit enhanced pseudo-capacitively dominated *** a scan rate of 0.5 mV s−1,a high pseudo-capacitive contribution(76%of the total storage)is obtained for the S-doped TiS2/TiO2/C electrode(termed as TiS2/S-TiO2/C).Such enhanced pseudocapacitive activity allows rapid chemical kinetics and significantly improves the high-rate sodium storage performance of *** TiS2/S-TiO2/C composite electrode delivers a high capacity of 114 mAh g−1 at a current density of 5000 mA g−*** capacity maintains at high level(161 mAh g−1)even after 1500 cycles and is still characterized by 58 mAh g−1 at the extreme condition of 10,000 mA g−1 after 10,000 cycles.

关键词： Sodium-ion battery Pseudo-capacitive Anodes TiO2/C nanofibers Sulfur doped

Initial nucleation of amorphous Si–B–C–N ceramics derived from polymer-precursors

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Journal of Materials Science & Technology 2019年第12期35卷 2851-2858页

作者： Ling-yan Li Hui Gu vesna srot Peter van Aken Joachim Bill Materials Genome Institute School of Materials Science and EngineeringShanghai University99 Shangda RoadShanghai200444China Stuttgart Center for Electron Microscopy Max-Planck-lnstitute for Solid-State ResearchHeisen bergs trasse 370569StuttgartGermany Institute of Materials Science University of StuttgartHeisenbergstrasse 570569StuttgartGermany

Nucleation behavior of amorphous Si–B–C–N ceramics derived from boron-modified polyvinylsilazane procusors was systematically investigated by transmission electron microscopy(TEM) combined with spatially-resolved electron energy-loss spectroscopy(EELS) analysis. The ceramics were pyrolyzed at1000℃ followed by further annealing in N2, and SiC nano-crystallites start to emerge at 1200℃ and dominate at 1500℃. Observed by high-angle annular dark-field imaging, bright and dark clusters were revealed as universal nano-structured features in ceramic matrices before and after nucleation, and the growth of cluster size saturated before reaching 5 nm at 1400℃. EELS analysis demonstrated the gradual development of bonding structures successively into SiC, graphetic BNCxand Si3N4 phases, as well as a constant presence of unexpected oxygen in the matrices. Furthermore, EELS profiling revealed the bright SiC clusters and less bright Si3N4-like clusters at 1200–1400℃. Since the amorphous matrix has already phase separated into SiCN and carbon clusters, another phase separation of SiCN into SiC and Si3N4-like clusters might occur by annealing to accompany their nucleation and growth, albeit one crystallized and another remained in amorphous structure. Hinderance of the cluster growth and further crystallization was owing to the formation of BNCxlayers that developed between SiC and Si3N4-like clusters as well as from the excessive oxygen to form the stable SiO2.

关键词： Precursor derived ceramics Si–B–C–N Nucleation High-angle annular dark-field imaging Electron energy-loss spectroscopy

跃变比判别热解Si-C-N陶瓷EELS定量分析的有效性

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电子显微学报 2009年第2期28卷 168-174页

作者：李凌燕顾辉 vesna srot PETER van Aken 中国科学院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室上海200050 Max-Planck-Institute for Metal Research Stuttgart Center for Electron Microscopy

电子能量损失谱(EELS)分析方法的运用为材料研究领域提供了有力的定性和定量手段。通过对内壳层电子激发谱跃变比的计算,能够获得样品相对厚度的参考信息。这一方法弥补了实验条件在同步采集等离子激发谱和内壳层电子激发谱方面的局限性... 详细信息

电子能量损失谱(EELS)分析方法的运用为材料研究领域提供了有力的定性和定量手段。通过对内壳层电子激发谱跃变比的计算,能够获得样品相对厚度的参考信息。这一方法弥补了实验条件在同步采集等离子激发谱和内壳层电子激发谱方面的局限性,并为辨别EELS定量的可靠性提供依据。本文以Si3N4为例,对跃变比随样品相对厚度的变化规律进行了研究,并在低于最佳样品厚度的范围内得到了可靠的定量结果。类似的跃变比变化规律能够运用于成份均一的Si-C-N热解样品,然而对于非均一的Si-C-N退火样品则不适用。

关键词：电子能量损失谱(EELS) 跃变比(jump ratio) 相对厚度(relative thickness)

Stability of M13 Phage in Organic Solvents

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Journal of Biomaterials and Nanobiotechnology 2016年第2期7卷 72-77页

作者： Pouya Moghimian vesna srot Benoit P. Pichon Sandra J. Facey Peter A. van Aken Stuttgart Center for Electron Microscopy Max Planck Institute for Solid State Research Stuttgart Germany Institut de Physique et Chimie des Matériaux de Strasbourg UMR 7504 CNRS—Université de Strasbourg Strasbourg France Institute of Technical Biochemistry University of Stuttgart Stuttgart Germany

The effect of different types of organic solvents on the structural integrity of M13 phages has been directly visualized by transmission and scanning electron microscopy. The exposure of M13 phages to apolar hexane had no effect on the structure of the phages for up to 8 h. In contrast, phages showed ~10-fold contraction into rod-like I-forms and to flattened spheroids with ~12 nm diameter upon exposure to polar organic solvents. We show that this finding can be beneficial for the macromolecular self-assembly and in broader aspects, to enhance the spatial arrangement of desired inorganic nanoparticles in the rapidly developing field of virotronics.

关键词： M13 Phage Organic Solvent Structural Integrity Self-Assembly Electron Microscopy

Biomineralization of Zinc-Phosphate-Based Nano Needles by Living Microalgae

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Journal of Biomaterials and Nanobiotechnology 2012年第3期3卷 362-370页

作者： Giulia Santomauro vesna srot Birgit Bussmann Peter A. van Aken Franz Brümmer Horst Strunk Joachim Bill Institute for Biology Depart- ment of Zoology University of Stuttgart Stuttgart Germany 4Institute for Materials Science Chair in Material Physics University of Stuttgart Stuttgart Germany. Institute for Materials Science Chair in Chemical Material Synthesis University of Stuttgart Stuttgart Germany Institute for Materials Science University of Stuttgart Stuttgart Germany Stuttgart Center for Electron Microscopy – StEM Max Planck Institute for Intelligent Systems Stuttgart Germany Stuttgart Center for Electron Microscopy–StEM Max Planck Institute for Intelligent Systems Stuttgart Germany

Up to now, chemical synthesis routes only provide restricted opportunities for the formation of structured nano particles. In contrast, living microorganisms generate nano materials of well defined shapes by the precise control of biomineralization. Here we reveal new principles for the generation of functional nano materials through the process of biomineralization. We used the detoxification mechanism of the unicellular alga Scenedesmus obliquus to generate a techno logically interesting zinc-phosphate-based nano material. The algae were incubated in media with a sublethal zinc concentration (6.53 mg Zn dm-3) for 4 weeks. Using BF-and ADF-STEM imaging combined with analytical XEDS we could show that nano needles containing phosphorus and zinc were formed inside the living cells. Further more, the cells incubated with zinc show a strong fluorescence. Our findings indicate that the algae used polyphosphate bodies for detoxification of the zinc ions, leading to the generation of intracellular zinc-phosphate-based nano needles. Beside the technological application of this material, the fluorescent cells can be used for labeling of e.g. biological probes. This new experimental protocol for the production of an inorganic functional material can be applied also for other substances.

关键词： Nano Needles Biomineralization Zinc Phosphate Microalgae Fluorescence

Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1215-1230页

作者： Ivana Cvijović-Alagić Slađana Laketić MilošMomčilović Jovan Ciganović Jelena Bajat vesna Kojić Vinča Institute of Nuclear Sciences-National Institute of the Republic of Serbia University of BelgradeMike Petrovića Alasa 12-1411000BelgradeSerbia Faculty of Technology and Metallurgy University of BelgradeKarnegijeva 411000BelgradeSerbia Oncology Institute of Vojvodina Faculty of MedicineUniversity of Novi SadPut Doktora Goldmana 4Sremska Kamenica21204Sremska KamenicaSerbia

The Ti-45Nb (mass%) alloy’s corrosive and biocompatible response in simulated physiological conditions was investigated before and after its additional high-pressure torsion (HPT) and laser irradiation processing. The grain size reduction from 2.76 µm to ~ 200 nm and the appearance of laser-induced morphologically altered and highly oxidized surface led to the significant improvement of alloy corrosion resistance and cell–implant interaction. Moreover, an additional increase of the laser pulse energy from 5 to 15 mJ during the alloy irradiation in the air led to an increase in the surface oxygen content from 13.64 to 23.89% accompanied by an increase of excellent cell viability from 127.18 to 134.42%. As a result of the controlled alloy microstructural and surface modifications, the formation of protective bi-modal mixed Ti- and Nb-oxide external scale was enabled. The presence of this surface oxide scale enhanced the alloy’s resistance to corrosion deterioration and simultaneously boosted cell viability and proliferation.

关键词： Ti-45Nb alloy High-pressure torsion Laser surface scanning Corrosion resistance Biocompatible properties

Breeding phase and outcome determine space use in European rollers Coracias garrulus prior to migration

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Current Zoology 2024年第2期70卷 137-149页

作者： Flavio Monti Sanja Barisic Sebastian Cannarella Davor Cikovic vesna Tutis JelenaKralj Carlo Catoni aUniversity of Siena Department of Physical SciencesEarth and EnvironmentVia Mattioli 453100 SienaItaly Institute of Ornithology Croatian Academy of Sciences and ArtsGunduliceva 24HR-1000 ZagrebCroatia Ornis italica Piazza Crati 1500199 RomeItaly

The breeding period is a demanding and time-constrained phase for migratory bird *** outcome and duration can interact with the extent and duration of post-breeding movements,resulting in individual differences in space use ultimately influencing later stages of the annual *** present space-use and home range estimates during the breeding season for 21 European rollers Coracias garrulus tracked between 2018 and 2022,in Italy and *** high-resolution spatial GPS data coupled with regular nest-box monitoring,we analyzed dif-ferences in space use during the incubation/nestling period versus post-breeding period prior to migration,accounting for the breeding outcome(successful ***).We found that adult movements were strongly reduced during the first phase,whereas increased in the post-breeding phase,especially for failed *** breeders remained in the surroundings of the nest site,whereas unsuccessful ones tended to abandon the nest and visit distant areas(up to 500 km)for long periods(60.5±6.2 days).Breeding outcome did not influence the departure date of autumn migration,suggesting that failed breeders used this period for exploratory movements but not for advancing the onset of *** exploratory movements may be functional to prospect and inform settlement decisions in failed breeders in search of new breeding opportunities and may be particularly important in migratory species,which generally have a limited period to gather information prior to autumn *** study demonstrates the need to investigate seasonal movements in different populations and the potential importance of pros-pectingpost-breeding movements for long-distance migratory species.

关键词： animal movement biologging conservation Coracidae Mediterranean nest-box population monitoring prospecting movements reproduction.

Bifurcation Analysis of a Nonlinear Vibro-Impact System with an Uncertain Parameter via OPA Method

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工程与科学中的计算机建模(英文) 2024年第1期138卷 509-524页

作者： Dongmei Huang Dang Hong Wei Li Guidong Yang vesna Rajic School of Mathematics and Statistics Xidian UniversityXi’an710071China Department of Mathematics Changzhi UniversityChangzhi046011China Department for Statistics and Mathematics Faculty of EconomicsUniversity of BelgradeBelgrade11000Serbia

In this paper,the bifurcation properties of the vibro-impact systems with an uncertain parameter under the impulse and harmonic excitations are ***,by means of the orthogonal polynomial approximation(OPA)method,the nonlinear damping and stiffness are expanded into the linear combination of the state *** condition for the appearance of the vibro-impact phenomenon is to be transformed based on the calculation of themean ***,the stochastic vibro-impact systemcan be turned into an equivalent high-dimensional deterministic non-smooth *** different Poincarésections are chosen to analyze the bifurcation properties and the impact numbers are identified for the periodic ***,the numerical results verify the effectiveness of the approximation method for analyzing the considered nonlinear ***,the bifurcation properties of the system with an uncertain parameter are explored through the high-dimensional deterministic *** can be found that the excitation frequency can induce period-doubling bifurcation and grazing *** the randomintensitymay result in a diffusion-based trajectory and the impact with the constraint plane,which induces the topological behavior of the non-smooth system to change *** is also found that grazing bifurcation appears in advance with increasing of the random *** stronger impulse force can result in the appearance of the diffusion phenomenon.

关键词： Orthogonal polynomial approximation vibro-impact systems non-smooth systems grazing bifurcation

On Some Topological Properties of Normed Boolean Algebras

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Advances in Pure Mathematics 2024年第5期14卷 367-387页

作者： vesna Gotovac Đogaš Faculty of Science University of Split Split Croatia

This paper concerns the compactness and separability properties of the normed Boolean algebras (N.B.A.) with respect to topology generated by a distance equal to the square root of a measure of symmetric difference between two elements. The motivation arises from studying random elements talking values in N.B.A. Those topological properties are important assumptions that enable us to avoid possible difficulties when generalising concepts of random variable convergence, the definition of conditional law and others. For each N.B.A., there exists a finite measure space ( E,ℰ,μ ) such that the N.B.A. is isomorphic to ( ℰ ˜ , μ ˜ ) resulting from the factorisation of initial σ-algebra by the ideal of negligible sets. We focus on topological properties ( ℰ ˜ , μ ˜ ) in general setting when μ can be an infinite measure. In case when μ is infinite, we also consider properties of ℰ ˜ fin ⊆ ℰ ˜ consisting of classes of measurable sets having finite measure. The compactness and separability of the N.B.A. are characterised using the newly defined terms of approximability and uniform approximability of the corresponding measure space. Finally, conditions on ( E,ℰ,μ ) are derived for separability and compactness of ℰ ˜ and ℰ ˜ fin .

关键词： Compact Locally Compact Polish Space Separable

Acute pancreatitis as a complication of acute COVID-19 in kidney transplant recipients

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World Journal of Clinical Cases 2024年第6期12卷 1104-1110页

作者： Nikolina Basic-Jukic Ivana Juric Lea Katalinic vesna Furic-Cunko Vibor Sesa Anna Mrzljak Department of Nephrology Arterial HypertensionDialysis and TransplantationUniversity Hospital Centre ZagrebZagreb 10000Croatia Department of Medicine School of MedicineZagreb 10000Croatia Department of Gastroenterology and Hepatology University Hospital Centre ZagrebZagreb 10000Croatia

BACKGROUND Acute pancreatitis is a rare extrapulmonary manifestation of coronavirus disease 2019(COVID-19)but its full correlation with COVID-19 infection remains *** To identify acute pancreatitis’occurrence,clinical presentation and outcomes in a cohort of kidney transplant recipients with acute *** A retrospective observational single-centre cohort study from a transplant centre in Croatia for all adult renal transplant recipients with a functioning kidney allograft between March 2020 and August 2022 to record cases of acute pancreatitis during acute *** were obtained from hospital electronic medical *** acute respiratory syndrome coronavirus 2(SARS-CoV-2)infection was proven by a positive SARS-CoV-2 real-time reverse transcriptase-polymerase chain reaction on the nasopharyngeal *** Four hundred and eight out of 1432(28.49%)patients who received a renal allograft developed COVID-19 *** analyzed cohort included 321 patients(57%males).One hundred and fifty patients(46.7%)received at least one dose of the anti-SARS-CoV-2 vaccine before the *** hundred twenty-five(39.1%)patients required hospitalization,141(44.1%)developed pneumonia and four patients(1.3%)required mechanical *** included immunosuppression modification in 233 patients(77.1%)and remdesivir in 53 patients(16.6%),besides the other supportive *** the study cohort,only one transplant recipient(0.3%)developed acute pancreatitis during acute COVID-19,presenting with abdominal pain and significantly elevated pancreatic *** survived without complications with a stable kidney allograft *** Although rare,acute pancreatitis may complicate the course of acute COVID-19 in kidney transplant *** mechanism of injury to the pancreas and its correlation with the severity of the COVID-19 infection in kidney transplant recipients warrants further research.

关键词： Acute pancreatitis COVID-19 Kidney transplant Angiotensin-converting enzyme-2 receptor Immunosuppressive agents