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Phlogopite in mantle xenoliths and kimberlite from the Grib pipe,Arkhangelsk province,Russia:Evidence for multi-stage mantle metasomatism and origin of phlogopite in kimberlite

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Geoscience Frontiers 2019年第5期10卷 1941-1959页

作者： A.v. Kargin L.v. Sazonova A.A. Nosova N.M. Lebedeva Yu.A. Kostitsyn E.v. Kovalchuk v.v. tretyachenko Ya.S. Tikhomirova Institute of Geology of Ore Deposits PetrographyMineralogyand GeochemistryRussian Academy of Sciences (IGEM RAS)MoscowRussia Lomonosov Moscow State University MoscowRussia vernadsky Institute of Geochemistry and Analytical Chemistry of Russian Academy of Sciences MoscowRussia AC ALROSA Research Geological Prospecting Enterprise ArkhangelskRussia

We present petrography and mineral chemistry for both phlogopite,from mantle-derived xenoliths (garnet peridotite,eclogite and clinopyroxene-phlogopite rocks) and for megacryst,macrocryst and groundmass flakes from the Grib kimberlite in the Arkhangelsk diamond province of Russia to provide new insights into multi-stage metasomatism in the subcratonic lithospheric mantle (SCLM) and the origin of phlogopite in *** on the analysed xenoliths,phlogopite is characterized by several *** first generation (Phl1) occurs as coarse,discrete grains within garnet peridotite and eclogite xenoliths and as a rock-forming mineral within clinopyroxene-phlogopite *** second phlogopite generation (Phl2) occurs as rims and outer zones that surround the Phl1 grains and as fine flakes within kimberlite-related veinlets filled with carbonate,serpentine,chlorite and *** garnet peridotite xenoliths,phlogopite occurs as overgrowths surrounding garnet porphyroblasts,within which phlogopite is associated with Cr-spinel and minor *** eclogite xenoliths,phlogopite occasionally associates with carbonate bearing veinlet ***,from the kimberlite,occurs as megacrysts,macrocrysts,microcrysts and fine flakes in the groundmass and matrix of kimberlitic *** phlogopite grains within the kimberlite are characterised by signs of deformation and form partly fragmented grains,which indicates that they are the disintegrated fragments of previously larger ***1,within the garnet peridotite and clinopyroxeneephlogopitexenoliths,is characterised bylow Ti and Cr contents (TiO292) typical of primary peridotite phlogopite in mantle peridotite xenoliths from global kimberlite *** formed during SCLM metasomatism that led to a transformation from garnet peridotite to clinopyroxene-phlogopite rocks and the crystallisation of phlogopite and high-Cr clinopyroxene megacrysts before the

关键词： Mantle metasomatism Kimberlite Phlogopite Mantle xenoliths Megacrysts

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Adsorption and photo-catalytic properties of layered lepidocrocite-like quasi-amorphous compounds based on modified potassium polytitanates

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Particuology 2014年第6期12卷 22-28页

作者： E.v.tretyachenko A.v.Gorokhovsky G.Y.Yurkov F.S.Fedorov M.A.vikulova D.S.Kovaleva E.E.Orozaliev Department of Chemistry Saratov State Technical University

TiO2 compounds possess relatively high adsorption abilities and exhibit high photocatalytic activities that exhibit potential for the destruction of organic pollutants in natural and waste *** potassium polytitanates modified using transition metals and their oxides/hydroxides generate new nanomaterials that operate in the visible spectral *** study presents the synthesis and investigation of the structure,composition and photocatalytic activity of powdered nanoscale quasi-amorphous potassium polytitanates particles modified with iron,zinc,copper,cobalt and nickel sulfate in aqueous *** of the powders investigated in this work exhibit a high adsorption capacity for methylene blue dye（15-20mg/g） related to the welldeveloped surface of the layered potassium polytitanate *** transition metals and their oxides/hydroxides influences the electronic structure of the obtained systems.A high photocatalytic activity was observed for systems containing iron,zinc,nickel and their oxides/hydroxides in the ultraviolet and visible ranges.

关键词： Layered potassium titanate Chemical modification Heterostructured particles Photocatalytic activity Adsorption

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