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Active and passive modulation of solar light transmittance in a uniquely multifunctional dual-band single molecule for smart window applications

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Journal of Energy Chemistry 2024年第1期88卷 293-305,I0007页

作者： Pooja v.Chavan Pramod v.Rathod Joohyung Lee Sergei v.Kostjuk Hern Kim Department of Energy Science and Technology Environmental Waste Recycle InstituteMyongji UniversityYonginGyeonggi-do 17058Republic of Korea Department of Chemical Engineering Myongji UniversityYonginGyeonggi-do 17058Republic of Korea Research Institute for Physical Chemical Problems of the Belarusian State University MinskBelarus

Functional materials may change color by heat and electricity separately or simultaneously in smart *** materials have not only demonstrated remarkable potential in the modulation of solar radiation but are also leading to the development of indoor environments that are more comfortable and conducive to improving individuals'quality of ***,dual-responsive materials have not received ample research attention due to economic and technological *** a consequence,the broader utilization of smart windows faces *** address this new generational multistimulus responsive chromic materials,our group has adopted a developmental strategy to create a poly(NIPAM)n-Hv as a switchable material by anchoring active viologen(Hv)onto a phase-changing poly(NIPAM)n-based smart material for better utility and *** constructed smart windows facilitate individualistic reversible switching,from a highly transparent state to an opaque state(thermochromic)and a red state(electrochromic),as well as facilitate a simultaneous dual-stimuli response reversible switching from a clear transparent state to a fully opaque(thermochromic)and orange(electrochromic)*** privacy can be attained in smart windows designed for exclusive settings by achieving zero *** unique chromic mode operates independently and modulates visible and near-infrared(NIR)light in a distinct ***,these smart windows with thermal and electric dual-stimuli responsiveness demonstrate remarkable heat regulation capabilities,rendering them highly attractive for applications in building facades,energy harvesting,privacy protection,and color display.

关键词： Smart windows Thermochromism Electrochromism Energy saving Dual-responsive material

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Progress in ileal endogenous amino acid flow research in poultry

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Journal of Animal Science and Biotechnology 2021年第2期12卷 415-425页

作者： v.Ravindran Monogastric Research Centre School of Agriculture and EnvironmentMassey UniversityPalmerston North 4442New Zealand

The progress in our understanding of the endogenous protein concept over the past century is *** proteins found in the digesta at the terminal ileum of poultry,known as endogenous protein loss,are comprised of digestive secretions,mucus and sloughed gut epithelial *** measurement of this loss is of fundamental importance because it is an indicator of gut metabolism and is essential to adjust apparent estimates of ileal amino acid *** ileal endogenous amino acid losses comprise of two components,namely basal and specific *** basal losses are fixed and associated with feed dry matter intake,whereas the specific losses are variable and induced by the presence of dietary components such as fibre and *** there is no methodology available to directly measure the specific endogenous losses and these losses are calculated by determining the basal and total(basal plus specific)losses and,then subtracting the basal losses from total *** seminal features,specific applications and shortcomings of available methodologies are briefly outlined as well as the practical challenges faced in using the published endogenous amino acid loss values for true digestibility *** relevance of taurine as a component of endogenous protein flow in poultry is identified for the first time.

关键词： Basal loss Digestible amino acids Endogenous amino acid losses Poultry Specific loss

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Structural traits of woody plants and geomorphological conditions to the vegetation recovery at Ksudach caldera(Southern Kamchatka) since the explosive eruption in 1907

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Journal of Mountain Science 2020年第7期17卷 1613-1635页

作者： KOPANINA Anna v LEBEDEvA Ekaterina v vLASOvA Inna I TALSKIKH Anastasia v Institute of Marine Geology and Geophysics Far Eastern Branch of the Russian Academy of SciencesNauka street1 B693022Yuzhno-SakhalinskRussia Institute of Geography Russian Academy of SciencesStaromonetny s-str.29119017MoscowRussia

This study considers the restoration of the plant cover destroyed by a catastrophic volcano eruption in the south of Kamchatka Peninsula(the Ksudach caldera,Shtyubel cone),with a particular attention to the role of woody *** aims to qualitatively estimate(at a qualitative level)the rate of the primary succession development depending on the microrelief and the modern relief-forming *** vegetation recovery in the caldera after the Shtyubel cone eruption 109 years ago proceeds slowly and *** proceeds most slowly on a thick tephra mantle continuously disturbed by water and wind erosion,lahars,debris flows,landslides,*** conditions are most typical of the western part of the caldera dominated by pumice fields with occasional patches of pioneer herbs and dwarf *** tundra communities with gradually expanding patches of shrub alder develop in the southern,eastern and northeastern parts of the Ksudach *** 1997 the area of the shrub alder communities has increased by 1.9 times,while the alpine tundra–by 1.3 times *** woody plants(dwarf shrubs and prostrate shrubs)are of particular importance in the process of the vegetation recovery on pumice *** suggest that the bark thickness of woody plants is an integrated indicator,which may serve for estimating the state of ecosystem in the course of the primary succession development on juvenile *** extremely inhospitable environments cause changes in physiological processes in the plant body and in its bark in *** results show that woody plants have a"thin"bark and develop some structural-functional arrangements for keeping bark tissues at their ***,the woody plant structure and the rate of changes in plant communities are under control of the geomorphic conditions and primarily–of physicochemical features of the pyroclastic cover.

关键词： Ksudach caldera Pioneer species Woody plants Bark Pyroclastic deposits Geomorphological processes

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On the asteroid-comet hazard mitigation problem for the earth

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Journal of Harbin Institute of Technology(New Series) 2003年第4期10卷 358-362页

作者： v v Ivashkin M v Keldysh Institute of Applied Mathematics

In frame of the asteroid-comet hazard problem study, a qualitative analysis of some methods for the effect on a celestial near-Earth object (NEO)-an asteroid, a comet — is carried out. The goal of the effect is a correction of this object’s orbit, its deflection from the Earth to prevent their collision. There are studied a mechanical impact-kinetic effect of the spacecraft (SC), a thermonuclear effect, an effect on a cometary nucleus for a controlled change of its dusty mantle and, therefore, its sublimation activity. Qualitative models of these effects are developed. Numerical analysis results are given for a group of NEOs such as some asteroids from the Apollo family (Apollo, Castalia, Nereus, Orpheus, Phaethon, Toutatis, etc.) and from the Aten family (Aten, Hathor, Khufu, etc.) as well as some short-periodic comets like the comet P/Biela. There are studied some characteristics of the effects on the NEOs such as the velocity impulse (or acceleration) applied to the celestial body, its deflection from the Earth. The study is supported by the Russian Foundation of Basic Studies (Grant N 01-01-00133).

关键词： hazard mitigation asteroid-comet hazard impact-kinetic effect

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Development of Mg-Zn-Y-Zr casting magnesium alloy with high thermal conductivity

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Journal of Magnesium and Alloys 2021年第5期9卷 1583-1593页

作者： v.E.Bazhenov A.v.Koltygin M.C.Sung S.H.Park Yu.v.Tselovalnik A.A.Stepashkin A.A.Rizhsky M.v.Belov v.D.Belov K.v.Malyutin National University of Science and Technology“MISiS” Leninskiy pr.4Moscow 119049 Russia LG Electronics Inc. Yeoui-daeroYeongdeungpo-gu.128LG Twin TowerSeoul 07336 Republic of Korea

Magnesium alloys are used in aircraft because of their light ***,for these alloys to be applied in electronic devices,high thermal conductivities are *** high-potential compositions of Mg-Zn-Y-Zr alloys were selected by phase composition and their freezing ranges calculated using Thermo-Calc *** alloys were prepared,and their fluidity,hot tearing susceptibility,mechanical properties,and thermal conductivity were obtained and *** alloy composed of Mg-4 wt%Zn-3 wt%Y-0.3 wt%Zr was selected for further investigation,because of its high thermal conductivity and satisfactory mechanical *** Mg-4 wt%Zn-3 wt%Y-0.3 wt%Zr alloy’s fluidity and hot tearing susceptibility were similar to those of the widespread AZ91 commercial casting magnesium *** influence of a heat treatment regime on the microstructure,thermal conductivity,and mechanical properties of the developed alloy was also *** was established that the room temperature thermal conductivity of the Mg-4 wt%Zn-3 wt%Y-0.3 wt%Zr alloy after aging at 300℃for 5 h was 105 W/m K^(-1).Additionally,the following tensile test results were obtained in aged condition:120 MPa yield strength,200 MPa ultimate tensile strength,and 4%*** utilization of solid solution heat treatment at 520℃for 8 h prior to aging can promote up to 9%increase in *** Mg-4 wt%Zn-3 wt%Y-0.3 wt%Zr casting alloy can be used as a high thermal conductivity material with industrial applications.

关键词： Magnesium alloy Mg-Zn-Y-Zr Thermal conductivity Phase composition Fluidity Hot tearing susceptibility

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A review of the effects of dietary organic acids fed to swine

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Journal of Animal Science and Biotechnology 2016年第1期7卷 67-77页

作者： Mocherla v A N Suiryanrayna J v Ramana Livestock Research Station Sri Venkateswara Veterinary University

Animal production depends on nutrient utilization and if done there is an accelerated momentum towards growth with a low cost to feed ratio Public concern over the consumption of pork with antibiotic residues of the animals fed with antibiotic growth promoters （AGP） has paved the way to use other additives like herbs and their products, probiotics, prebiotics etc. Numerous feed additives are in vogue for achieving this target and one such classical example is the usage of organic acids and their salts. Usage of organic acids was in progress for over four decades. Early weaned piglets are （3-4 weeks age） exposed to stress with a reduced feed intake, little or no weight gain. This post weaning lag period is due to a limited digestive and absorptive capacity due to insufficient production of hydrochloric acid, pancreatic enzymes and sudden changes in feed consistency and intake. Lowering dietary pH by weak organic acids was found to overcome these problems. The main activity of organic acids is associated with a reduction in gastric pH converting the inactive pepsinogen to active pepsin for effective protein hydrolysis. Organic acids are both bacteriostatic and bactericidal. Lactic acid has been reported to reduce gastric pH and delay the multiplication of an enterotoxigenic E. coil These acids are the intermediary products in Kreb＇s cycle and thus act as an energy source preventing the tissue breakdown resulting from gluconeogenesis and lipolysis. Excretion of supplemental minerals and nitrogen are minimized with organic acids as these form complexes with minerals and aids for their bio-availability. Short chain fatty cids like acetic, propionic and n-butyric acid produced by microbial fermentation of dietary fibre in the large intestines may increase the proliferation of epithelial cells and have stimulatory effects on both endocrine and exocrine pancreatic secretions in pigs. Organic acids also enhances apparent total tract digestibility and improves growth performa

关键词： Chelation Improved productivity Organic acids Pathogen inhibition Protein utility Swine

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Synthesis of Pharmaceutical Intermediates by Toluene Benzylation over Heteropoly Acids on Different Support

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Journal of Natural Gas Chemistry 2007年第2期16卷 186-192页

作者： v. v. Bokade G. D. Yadav Catalysis Division National Chemical LaboratoryPune 411008India University Institute of Chemical TechnologyMumbai-19India University Institute of Chemical Technology Mumbai-19India

Selective formation of pharmaceutical intermediates like diphenylmethane, dimethyldiphenylmethane, benzyl toluene and benzoic acid by liquid phase, toluene benzylation with benzyl chloride as a benzylating agent, was systematically studied over plane clay （K-10, montmorillonite）, plane H-Beta, plane MFI structured titanosilicate （TS-1） and heteropoly acids [HPA, namely dodecatungstophosphoric acid [H3PO4.12WOa-xH2O] （TPA）, dodeca-molybdo phosphoric acid ammonium salt hydrate [H12Mo12N3040P＋aq] （DMAA）, sodium tungstate hydrated purified [Na12WO4.2H2O] （STH）] supported on clay, H-beta and TS-1. The 20%TPA/Clay, 30%TPA/H-Beta and 30%TPA/TS-1, were observed to be the best catalyst samples over plane clay, plane H-Beta and plane TS-1. The catalyst samples are compared with respect to benzyl chloride conversion and selectivities for diphenylmethane, dimethyl-diphenylmethane, benzyl toluene and benzoic acid. The reaction follows the pseudo-first order rate power law model. The apparent rate constants are calculated and compared with the reported ones.

关键词： toluene benzylation benzyl chloride heteropolyacid diphenylmethane dimethyl-diphenyl methane benzyl toluene benzoic acid

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ZrB_(2)-SiC based composites for thermal protection by reaction sintering of ZrO_(2)+B_(4)C+Si

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Journal of Advanced Ceramics 2017年第4期6卷 320-329页

作者： R.v.KRISHNARAO v.v.BHANUPRASAD G.MADHUSUDHAN REDDY Defence Metallurgical Research Laboratory KanchanbaghHyderabad-500058India

Synthesis and sintering of ZrB_(2)-SiC based composites have been carried out in a single-step pressureless reaction sintering(PLRS)of ZrO_(2),B_(4)C,and Si.Y_(2)O_(3) and Al_(2)O_(3) were used as sintering *** effect of ratios of ZrO_(2)/B_(4)C,ZrO_(2)/Si,and sintering additives(Y_(2)O_(3) and Al_(2)O_(3)),was studied by sintering at different temperatures between 1500 and 1680℃in argon ***_(2),SiC,and YAG phases were identified in the sintered *** as high as 4.2 g/cm^(3),micro hardness of 12.7 GPa,and flexural strength of 117.6 MPa were obtained for PLRS *** material was also prepared by PLRS for tungsten inert gas(TIG)welding of the ZrB_(2)-SiC based *** shear strength of the weld was 63.5 *** PLRS ZrB_(2)-SiC composites exhibited:(i)resistance to oxidation and thermal shock upon exposure to plasma flame at 2700℃for 600 s,(ii)thermal protection for Cf-SiC composites upon exposure to oxy-propane flame at 2300℃for 600 s.

关键词： ZrB_(2) SiC reactive sintering synthesis composites

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Disproportionation of ethylbenzene in the presence of C_8 aromatics

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Journal of Natural Gas Chemistry 2009年第3期18卷 369-374页

作者： N.Sharnappa S.Pai v.v.Bokade Catalysis Division National Chemical Laboratory

The selective synthesis of p-diethylbenzene （p-DEB） by disproportionation of ethylbenzene （EB） in the presence of aromatics like m- and p- xylene isomers has been studied over a pore size regulated HZSM-5 catalyst. The industrial feed having different compositions of ethylbenzene and xylene isomers was used for the experimentation. Hence, they were expected to hinder the movement of reactant molecules both on the external surface and within the zeolite channels. It was observed that irrespective of the different feed compositions the concentration of the xylene isomers was intact in the product. There is no other byproducts formation like para-ethylmethyl benzene. The effects of varying the concentration of aromatic compounds in the feed on ethylbenzene conversion and product distribution over the parent and modified H-ZSM-5 catalyst have been discussed. Ethylbenzene disproportionation reaction follows the pseudo first order reaction with an activation energy of 8.6 kcal/mol.

关键词： ethylbenzene xylene isomers catalyst disproportionation diethylbenzene

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Cladophora mats in a Crimean hypersaline lake:structure,dynamics,and inhabiting animals

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Journal of Oceanology and Limnology 2018年第6期36卷 1930-1940页

作者： Alexandr v.PRAZUKIN Elena v.ANUFRIIEvA Nickolai v.SHADRIN The A.O.Kovalevsky Institute of Marine Biological Research of RAS 2 Nakhimov Av.Sevastopol 299011Russia

Filamentous green algae play an important functional role in element cycling and productivity in the diff erent water bodies. In hypersaline lakes and lagoons of the Crimea, filamentous green algae are present and form bottom and floating mats that occupy large areas with high biomass, up to 4–5 kg(wet biomass)/m2. Cladophora spp. dominated in those mats. Five species of filamentous green algae(Chlorophyta) in Lake Chersonesskoye: C ladophora vadorum(Aresch.) Kütz., C. siwaschensis C. Meyer, C. echinus(Biasol.) Kütz., Ulothrix implexa(Kütz.) Kütz., Rhizoclonium tortuosum(Dillw.) Kütz., and seagrass(Angiospermae) R uppia cirrhosa(Petagna) Grande were found. Cladophora spp. and R. cirrhosa were found in the lake throughout the year, other types of algae were encountered episodically. In most cases the biomass of bottom mat exceeded that of the floating mat. In general, the total biomass of the bottom and floating mats in the lake areas at depths up to 30 cm was in a stable range of values from 100 to 290 mg(dry weight)/cm2. Animal and infusorian average abundance in mats reach high values: infusorians—up to 15 000 000 ind./m2, Cletocamptus retrogressus(Copepoda, Harpacticoida)—up to 730 000 ind./m2, Eucypris mareotica(Ostracoda)—up to 91 000 ind./m2 and Chironomidae larvae(Insecta, Diptera)—up to 140 ind./m2. Those values were much higher than in the plankton.

关键词： green algae mats hypersaline lake photosynthesis invertebrates

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