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Thermo-and pH-sensitive Polymer with Pendant spacer-linked Imidazole Cycles

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Chinese Journal of Polymer science 2024年第4期42卷 437-445页

作者： natalya v.Zakharova stanislav n.Zelinskiy Mariya s.strelova Elena n.Danilovtseva vadim v.Annenkov Institute of Macromolecular Compounds of the Russian Academy of sciences Saint Petersburg199004Russia Limnological Institute of siberian Branch of the Russian Academy of sciences Irkutsk664033Russia

By the reaction of poly(acryloyl chloride) with n-(3-aminopropyl)imidazole, poly(n-(3-(1H-imidazol-1-yl)propyl)acrylamide) was synthesized. The new polymer contains an imidazole ring removed from the main chain by a spacer of five bonds. The structure and purity, molecular weight, hydrodynamic and thermosensitive properties of the obtained sample were studied by1H-and13C-nMR, FTIR spectroscopy, acid-base titration, light scattering, turbidimetry and viscometry. The observed ability of the imidazole-containing polymer to form and destroy associates in water-salt solutions at pH 6.6-7.4 and temperatures of 29-48℃ indicates that these are promising candidates for designing complex biomedical systems. The new polymer is able to form complexes with oligo-DnA more actively than poly(1-vinylimidazole), which is of interest for gene delivery applications. The polymer cross-linked with epichlorohydrin gives micro-relief coatings on the plastic surface, and the modified surface is able to attach negatively charged objects. This thermo-and pH-sensitive polymer modification can be applied to create finely controlled surfaces for cell culturing.

关键词： Imidazole-containing polymer Thermolability pH-sensitivity The modified surface DnA immobilization

Transition from oceanic subduction to continental collision:Insights from volcanogenic-sedimentary rocks of the Tannuola terrane(northern Central Asian Orogenic Belt)

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Geoscience Frontiers 2024年第4期15卷 41-60页

作者： E.v.vetrov n.I.vetrova v.s.sobolev Institute of Geology and Mineralogy sB RAs Koptyuga ave.3NovosibirskRussia

Magmatism associated with oceanic subduction plays a dominant role in crustal growth during the Earth's *** Tannuola terrane,situated in the northern Central Asian Orogenic Belt(CAOB),is a key area to understanding oceanic subduction and initial collision processes in the northern *** order to investigate the switch from subduction to collision settings,detailed field mapping,zircon sHRIMP U-Pb geochronological and whole-rock geochemical studies of volcanogenic-sedimentary rocks from the Tannuola terrane were carried *** U-Pb ages indicate multi-stage volcanism lasted at least 30 Ma from~540 to~510 Ma,that can be divided into three events:the late Ediacaran(before~540 Ma),the early Cambrian(~520 Ma)and the middle Cambrian(~510 Ma).These ages are inter-preted to the initial,main and final stages of oceanic subduction during the late Proterozoic-early *** the late Ediacaran,tholeiitic basalts with highεnd(t)values(from+7.4 to+8.5)were *** forming by the 10%-30%partial melting of spinel-garnet mantle source during slab *** the early Cambrian,transitional from tholeiitic to calc-alkaline basaltic rocks withεnd(t)value(+5.6)and coeval intermediate-felsic volcanic rocks with similarεnd(t)values(+5.9 and+6.5)*** early Cambrian basaltic rocks are interpreted to be derived by 10%-30%partial melt-ing of a depleted mantle source metasomatized by slab-derived fluids released from the subducting ocea-nic *** middle Cambrian calcalkaline basaltic rocks withεnd(t)value of+6.2 might be emplaced as a result of low(5%-10%)degree partial melting of a metasomatized mantle followed by fractional crys-tallization of clinopyroxene and *** intermediate-felsic volcanic rocks withεnd(t)values from+6.0 to+6.8 were formed through fractionation of the juvenile neoproterozoic *** middle Cambrian volcanism is interpreted to be triggered by the slab break-off during the transition to a collisional se

关键词： Island-arc magmatism Ediacaran Cambrian zircon U-Pb dating nd isotopes Central asian orogenic belt

Ion heat transport in electron cyclotron resonance heated L-mode plasma on the T-10 tokamak

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Plasma science and Technology 2024年第4期26卷 52-60页

作者： v.A.KRUPIn M.R.nURGALIEv A.R.nEMETs I.A.ZEMTsOv s.D.sUnTsOv T.B.MYALTOn D.s.sERGEEv n.A.sOLOvEv D.v.sARYCHEv D.v.RYJAKOv s.n.TUGARInOv n.n.nAUMEnKO national Research Centre“Kurchatov Institute” Moscow 123182Russia Bauman Moscow state Technical University Moscow 105005Russia Institution“Project Center ITER” Moscow 123098Russia JsC“sOLAR” Minsk 220034Belarus

Anomalous ion heat transport is analyzed in the T-10 tokamak plasma heated with electron cyclotron resonance heating(ECRH) in second-harmonic extra-ordinary mode. Predictive modeling with empirical scaling for Ohmical heat conductivity shows that in ECRH plasmas the calculated ion temperature could be overestimated, so an increase of anomalous ion heat transport is required. To study this effect two scans are presented: over the EC resonance position and over the ECRH power. The EC resonance position varies from the high-field side to the low-field side by variation of the toroidal magnetic field. The scan over the heating power is presented with on-axis and mixed ECRH regimes. Discharges with high anomalous ion heat transport are obtained in all considered regimes. In these discharges the power balance ion heat conductivity exceeds the neoclassical level by up to 10 times. The high ion heat transport regimes are distinguished by three parameters: the ratio Te/Ti, the normalized electron density gradient R/■, and the ion–ion collisionality νii~*. The combination of high Te/Ti, high νii~*, and R/■=6-10 results in values of normalized anomalous ion heat fluxes up to 10 times higher than in the low transport scenario.

关键词： tokamak L-mode electron cyclotron resonance heating ion heat transport

nanomotion of bacteria to determine metabolic profile

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nanotechnology and Precision Engineering 2024年第1期7卷 1-9页

作者： s.n.Pleskova E.v.Lazarenko n.A.Bezrukov R.n.Kriukov A.v.Boryakov M.E.Dokukin s.I.surodin Research Laboratory of scanning Probe Microscopy Lobachevsky State University of Nizhny NovgorodNizhny Novgorod 603950Russia Department of nanotechnology and Biotechnology Nizhny Novgorod State Technical University n.a.R.E.AlekseevNizhny Novgorod 603950Russia sarov Physics and Technology Institute National Research Nuclear University MEPhISarov 607186Russia

In addition to their visible motion such as swimming(e.g.,with the help ofﬂagella),bacteria can also exhibit nanomotion that is detectable only with highly sensitive instruments,and this study shows that it is possible to detect bacterial nanomotion using an AFM detection *** results show that the nanomotion characteristics depend on the bacterial strain,and that nanomotion can be used to sense the metabolic activity of bacteria because the oscillations are sensitive to the food preferences of the bacteria and the type of surrounding medium.

关键词： nanomotion Bacteria Cantilever Oscillation Atomic force microscopy Metabolism

Antibacterial HA-coatings on bioresorbable Mg alloy

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Journal of Magnesium and Alloys 2024年第5期12卷 1965-1985页

作者： K.v.nadaraia D.v.Mashtalyar M.A.Piatkova A.I.Pleshkova I.M.Imshinetskiy M.s.Gerasimenko E.A.Belov v.v.Kumeiko D.n.Kozyrev K.A.Fomenko v.v.Mostovaya B.R.Torpanov A.R.Biktimirov I.s.Osmushko s.L.sinebryukhov s.v.Gnedenkov Institute of Chemistry FEB RAs 159 Pr.100-letiya VladivostokaVladivostok 690022Russia Far Eastern Federal University 10 Ajax BayRussky IslandVladivostok 690922Russia A.v.Zhirmunsky national scientific Center of Marine Biology FEB RAs 17 St.PalchevskogoVladivostok 690041Russia Regional Clinical Dermatovenerological Dispensary 18 V St.GamarnikaVladivostok 690033Russia nMIC“Treatment and Rehabilitation Center” 3 Ivankovskoe highwayMoscow 125367Russia

In this study,a calcium-phosphate coating was formed on a Mg-Mn-Ce alloy by the plasma electrolytic oxidation(PEO).The antibiotic vancomycin,widely used in the treatment of infections caused by staphylococcus aureus(***),was impregnated into the *** with vancomycin showed high bactericidal activity against *** mechanical and electrochemical properties of the formed coatings were studied,as well as in vitro cytotoxicity tests and in vivo tests on mature male rats were *** to sEM,EDs,XRD and XPs data,coatings had a developed morphology and contained hydroxyapatite,which indicates high *** analysis of roughness of coatings without and with vancomycin did not reveal any differences,confirming the high roughness of the *** electrochemical tests,an increase in corrosion resistance by more than two times after the application of PEO coatings was *** to the results of an in vivo study,after 28 days of the implantation of samples with calcium phosphate PEO coating and vancomycin,no signs of inflammation were observed,while an inflammatory reaction developed in the area of implantation of bare alloy,followed by *** release tests from the coatings show a sharp decrease in the concentration of the released antibiotic on day 7 and then a gradual decrease until day *** the experiment,no significant deviations in the condition and behavior of the animals were observed;clinical tests did not reveal a systemic toxic reaction.

关键词： Bioactive coatings Biocompatibility Mg alloy Plasma electrolytic oxidation Hydroxyapatite vancomycin

Effect of proton irradiation on the optical properties of thermal control coating based on polystyrene with silica filler

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Propulsion and Power Research 2024年第1期13卷 1-11页

作者： n.I.Cherkashina v.I.Pavlenko M.M.Mikhailov A.n.Lapin s.A.Yuriev R.v.sidelnikov D.s.Romanyuk Belgorod state Technological University named after v.G.shoukhov Kostyukov Str.46Belgorod 308012Russia Tomsk state University of Control systems and Radioelectronics 40Prospect LeninaTomsk 634050Russia

This paper presents the results of studying the surface properties changes of a ther-moregulating coating based on polystyrene and silicaﬁller after proton irradiation with an en-ergy of 50 kev at afluence of 3�1015 cm�*** proton irradiation,the values of the contact angle of wetting with water increase by 3.5%and 14.9%for polystyrene and the coating,*** free surface energy(energy of the surface layer)of polystyrene and the coat-ings before and after proton irradiation was calculated using the Owens-Wendt-Rabel-Kaelble *** was a signiﬁcant increase in the polarity of the polystyrene surface(gp increased by a factor of 2.2)after proton *** the coating,an increase in gp by a factor of 3.89 was observed after proton *** changes in the coating were presented by IR Fourier spectroscopy.A slight decrease in the absorption intensity of all characteristic bands compared to the unirradiated sample was *** was found that the irradiation of the coating with protons led to the formation of macromolecules with hydroxyl,carbonyl,and carboxyl bonds,as well as the formation of dimeric and oligomeric siloxane *** was also found that after irradiation of a pure polystyrene sample with protons,the value of the solar absorption as increased by only 4.2%;whereas for the coating with silicaﬁller,the value of as increased by 28.6%.

关键词： Thermal control coating Proton irradiation Hydrophobicity Free surface energy Radiation crosslinking

Measurement of yields and angular distributions ofγ-quanta from the interaction of 14.1 Mev neutrons with oxygen,phosphorus,and sulfur

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Chinese Physics C 2024年第3期48卷 79-92页

作者： D.n.Grozdanov n.A.Fedorov s.B.Dabylova Yu.n.Kopatch I.n.Ruskov v.R.skoy T.Yu.Tretyakova C.Hramco P.I.Kharlamov G.v.Pampushik P.G.Filonchik A.v.Andreev Joint Institute for nuclear Research(JInR) DubnaRussia Institute for nuclear Research and nuclear Energy Bulgarian Academy of SciencesSofiaBulgaria Faculty of Physics Lomonosov Moscow State UniversityMoscowRussia L.n.Gumilyov Eurasian national University AstanaKazakhstan skobeltsyn Institute of nuclear Physics Moscow State UniversityMoscowRussia Institute of Chemistry of Moldova ChisinauRepublic of Moldova Moscow Institute of Physics and Technology MoscowRussia

A study of the inelastic scattering of neutrons with an energy of 14.1 Mev on the nuclei of oxygen,phosphorus,and sulfur was performed at the TAnGRA facility at JInR(Dubna).The experiment aimed to refine existing data and obtain new data on the yields and angular distributions ofγ-quanta emitted by the studied nuclei due to neutron-induced nuclear reactions using the tagged neutron *** types of detector systems were used to registerγ-***γ-ray yields were measured using a high-purity germanium(HPGe)*** angular distributions ofγ-rays were obtained using a system of 18 scintillation detectors based on bismuth germanite Bi_(4)Ge_(3)O_(12)(BGO)located around the *** performed experiments measured the yields of two transitions for the reaction of tagged neutrons with 16O,nine transitions for the reaction with ^(31)P,and nine transitions for the reaction with ^(32)s for the first *** angular anisotropy of theγ-radiation accompanying the inelastic scattering of neutrons with an energy of 14.1 Mev on ^(31)P nuclei was also measured for the first time.

关键词： tagged neutron method yields of gamma-quanta high-resolution gamma-spectrometry neutron-nuclear reactions neutron scattering

Telluric iron assemblages as a source of prebiotic phosphorus on the early Earth:Insights from Disko Island,Greenland

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Geoscience Frontiers 2024年第5期15卷 415-429页

作者： Oleg s.vereshchagin Maya O.Khmelnitskaya Larisa v.Kamaeva natalia s.vlasenko Dmitrii v.Pankin v.adimir n.Bocharova sergey n.Britvin saint Petersburg state University University Embankment 7-9St.Petersburg 199034Russia Udmurt Federal Research Center Ural BranchRussian Academy of SciencesIzhevsk 426067Russia nanomaterial Research Center Kola Science CentreRussian Academy of SciencesApatity 184209Russia

Phosphorus is one of the key elements,which determined the emergence of primordial life on our *** source of prebiotic phosphorus was most likely to be easily soluble compounds containing phosphorus in the negative form of oxidation(e.g.,phosphides).The present paper is the first thorough investigation of phosphide-bearing mineral assemblages confined to telluric(terrestrial)native iron from volcanic rocks of Disko Island,*** speciation in given assemblages varies from the solid solution in native iron(up to 0.3 wt.%P),different phosphides–schreibersite Fe_(3)P,nickelphosphide ni_(3)P,barringerite Fe_(2)P,and phosphates,including fluorapatite,anhydrous Fe-na phosphates,phosphoran olivine and pyroxene(up to 1 wt.%P).The diversity of observed phosphorus speciation can be explained by the steep changes of redox conditions during subsurface crystallization of iron-phosphide-bearing *** on the available data on likely redox conditions on the early Earth,we hypothesize that reactive prebiotic phosphorus may have originated from shallow crustal rocks.

关键词： Prebiotic phosphorus native iron Phosphide Reduced mineral assemblages

Elucidating elusive quaternary selenide EuCeCuse3:synthesis,crystal structure,properties and theoretical studies

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Journal of Rare Earths 2024年第1期42卷 163-171,I0006页

作者： Maxim v.Grigoriev Anna v.Ruseikina Maxim s.Molokeev v.adimir A.Chernyshev Aleksandr s.Aleksandrovsky Alexander s.Krylov svetlana n.Krylova nikolai P.shestakov Dmitriy A.velikanov Alexander A.Garmonov Alexey v.Matigorov Evgeny A.Ostapchuk Thomas schleid Damir A.safin Laboratory of Theory and Optimization of Chemical and Technological Processes University of TyumenVolodarskogo Str.6625003TyumenRussian Federation Kirensky Institute of Physics Federal Research Center KSC SB RASAkademgorodok 50 Bld.38660036KrasnoyarskRussian Federation Department of Physics Far Eastern State Transport UniversitySerysheva Str.47680021KrasnoyarskRussian Federation Institute of natural sciences and Mathematics Ural Federal University Named After the First President of Russia B.N.YeltsinMira Str.19620002EkaterinburgRussian Federation Department of Photonics and Laser Technology Siberian Federal UniversitySvobodnii Ave.79660079KrasnoyarskRussian Federation Institute of Physics and Technology University of TyumenVolodarskogo Str.6625003 TyumenRussian Federation Institute for Inorganic Chemistry University of StuttgartPfaffenwaldring 55D-70569StuttgartGermany scientific and Educational and Innovation Center for Chemical and Pharmaceutical Technologies Ural Federal University named after the First President of Russia B.N.YeltsinMira Str.19620002 EkaterinburgRussian Federation University of Tyumen Volodarskogo Str.6625003TyumenRussian Federation

We report on the novel heterometallic quaternary selenide EuCeCuse3,the fabrication of which has been a challenge until this *** structure of the reported selenide was elucidated from the powder X-ray diffraction data,which revealed the formation of EuCeCuse3with excellent yield(96.7%)accompanied with a minor fraction of Cese2(3.3%),and was best solved in orthorhombic space group Pnma with the BaLaCus3structural ***,the crystal structure of the title compound completes the row of the heterometallic quaternary selenides EuRECuse3(RE=La,Pr,nd,sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y),of which the cerium-based derivative exclusively belongs to the BaLaCus3structural *** distortion of the Cuse4polyhedron was compared for the whole series of EuRECuse3compounds using theτ4-descriptor for four coordinated ions,which revealed the highest degree of distortion for the Ce3+-containing selenide,followed by the La3+-based ***,the crystallographic and geometrical parameters of the reported selenide were discussed in comparison to the Ce3+-based sulfides srCeCus3and *** initio calculations of the crystal structure,a phonon spectrum and elastic constants for the crystal of EuCeCuse3were also *** types and wavenumbers of fundame ntal modes were determined and the involvement of ions participating in the phonon modes was *** experimental IR spectrum of the reported selenide was interpreted and found to be in agreement with the calculated *** experimental direct band gap of EuCeCuse3was measured to be 1.36 ev that is consistent with the concept of its origin due to interband transitions between orbitals emerging mainly from 4f(valence band)and 5d(conduction band)levels of the Eu2+*** dependence of the Young’s modulus on the direction demonstrates the anisotropy of the elastic properties,while the vickers hardness for EuCeCuse3was calculated to be 5.2 ***,the title compound is paramagnetic above 4 K.

关键词： Quaternary selenide synthesis Crystal structure Ab initio calculations Magnetic measurements spectroscopy