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Dynamics of a fluid-filled curvilinear pipeline

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Applied Mathematics and Mechanics(English Edition) 2018年第6期39卷 905-922页

作者： v.A.RUKAvISHNIKov o.P.tkachenko Computing Center of Far-Eastern Branch Russian Academy of Sciences

A mathematical model is presented, and numerical experiments are performed to describe the mechanics of the slow movement of a pipeline. The problem reduction algorithm to one-dimensional formulation is offered. Results of numerical experiment for the model problem are adduced. The proposed mathematical model is found to adequately describe the dynamics of known phenomena of pipes. The cross-sections of the extended curvilinear thin-walled pipeline are numerically demonstrated to experience warping, which has experimental confirmation in the literature.

关键词： bent pipeline numerical experiment hydroelasticity shell theory

Substituted diamides of dipicolinic acid as extractants and ionophores for rare earth metals

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Journal of Rare Earths 2023年第8期41卷 1234-1241,I0005页

作者： Yingchao Ren valery A.Polukeev Ekaterina v.Kenf Liudmila I.tkachenko Mikhail Yu Alyapyshev vasily A.Babain Andrey v.Nechaev Andrey v.Legin Dmitry o.Kirsanov Institute of Chemistry Saint-Petersburg UniversityPeterhofUniversitetsky Prospect 26198504Saint-PetersburgRussia JSvC vekton Ul.2-oy Luch 9192019Saint-PetersburgRussia Khlopin Radium Institute 194021282nd Murinsky avRussia ThreeArc Mining LLC Pr.Narodnogo Opolchenia 10198216Saint-PetersburgRussia Rusredmet Vosstanovleniya str.15bl.3198320St.PeterburgKrasnoe seloRussia

The variety of newly synthesized diamides of dipicolinic acid(DPA)bearing methyl-and oxymethyl substituents in various positions of phenyl ring was investigated as potential ligands for liquid-liquid extraction of rare earth metal ions and as membrane active compounds in plasticized polymeric membranes of potentiometric *** is found that scandium is extracted with 2,6-pyridinedicarboxylic acid diamides similarly to heavy lanthanides,while yttrium is extracted together with light group *** shows high selectivity for the separation of cadmium/zinc,lead/nickel or copper/nickel *** four out of six studied ligands demonstrate significant potentiometric sensitivity towards scandium,yttrium and lanthanides in 10^(-7)-10^(-3)mol/L concentration range in nitric acid *** trends in sensitivity values vary depending on a ligand structure and the highest values are observed for Sc^(3+)and heavy *** to the evaluated selectivity Sm^(3+)is the most preferred ion,while La^(3+)is the most *** differences in sensor behavior in rare earth metal solutions assume that such devices can be applied in sensor arrays for potentiometric analysis of lanthanide mixtures.

关键词： Dipicolini cacid diamides Scandium Yttrium Lanthanides Extraction Potentiometric sensors

Synthesis and Structure of Binary Copper/Silver-Arsenic Clusters Derived from Zintl Ion As_(7)^(3-)

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Chinese Journal of Chemistry 2022年第1期40卷 65-70页

作者： Wei-Qiang Zhang Nikolay v.tkachenko Lei Qiao Alexander I.Boldyrev Zhong-Ming Sun State Key Laboratory of Elemento-organic Chemistry Tianjin Key Lab for Rare Earth Materials and ApplicationsSchool of Materials Science and EngineeringNankai UniversityTianjin 300350China Department of Chemistry and Biochemistry Utah State University 0300 Old Main HillLoganUT 84322-0300USA

Polyarsenides containing coinage metals,[As_(7)Cu(PPh_(3))]^(2-)(1)and[M_(2)As_(14)]^(4-)(M=Cu,2;Ag,3),were synthesized by reactions of the nominal composition K_(3)As_(7) with Group 11 metal *** possible intermediate,cluster 1,was isolated from the solution phase through subtle changes in reaction conditions in the formation process of complex ***,we establish the pathway of the bimetallic bridged clusters[Cu_(2)As_(14)]^(4-)by the oxidation of the[As_(7)Cu(PPh_(3))]^(2-).Quantum chemical calculations reveal the presence of metallophilic interaction in clusters 2 and 3.

关键词： Polyarsenide cluster Reaction mechanism Zintl ions Covalently bound Metallophilic interaction

Ruthenium-mediated assembly and enhanced stability of heterometallic polystannides[Ru_(2)Sn_(19)]^(4−)and[Ru_(2)Sn_(20)]^(6−)

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Nano Research 2022年第6期15卷 5705-5711页

作者： Wei-Xing Chen Nikolay v.tkachenko Alvaro Muñoz-Castro Alexander I.Boldyrev Zhong-Ming Sun State Key Laboratory of Elemento-organic Chemistry Tianjin Key Lab of Rare Earth Materials and ApplicationsSchool of Materials Science and EngineeringNankai UniversityTianjin 300350China Department of Chemistry and Biochemistry Utah State University0300 Old Main HillLoganUT 84322-0300USA Grupo de Química Inorgánicay Materiales Moleculares Facultad de IngenieriaUniversidad Autonoma de ChileEl Llano SubercaseauxSantiago 2801Chile

In this work,we report the synthesis and characterization of two novel Ru-containing Zintl clusters:[Sn_(19){Ru(CoD)(en)}_(2)]^(4−)and[Sn_(20){Ru(CoD)}_(2)]^(6−).The synthesized compounds not only expand the family of Ru-Sn cluster systems but also shed light on the structure of heterometallic complexes in a previously unknown range of tin *** single-crystal X-ray diffraction(XRD)analysis reveals the dimeric nature of the *** different assembly patterns of the formal[Sn(η^(3)-Sn_(9))]monomer were observed:the dimerization through the vertex fusion process and the direct dimerization through the formation of 2c–2e Sn–Snσ*** both clusters,the density functional theory calculations reveal the locallyσ-aromatic nature of the[Sn(η^(3)-Sn_(9))]monomer resulting in two independent magnetic shielding *** believe that our findings will help the community to further explore the fascinating chemistry of polystannide clusters.

关键词： heterometallic clusters aromaticity polystannide ruthenium Zintl anion

PNN-SvM Approach of Ti-Based Powder’s Properties Evaluation for Biomedical Implants Production

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Computers, Materials & Continua 2022年第6期71卷 5933-5947页

作者： Ivan Izonin Roman tkachenko Michal Gregus Zoia Duriagina Nataliya Shakhovska Lviv Polytechnic National University Lviv79013Ukraine Comenius University in Bratislava Bratislava82005Slovak Republic The John Paul II Catholic University of Lublin Lublin20-708Poland

The advent of additive technologies has provided a significant breakthrough in the production of medical *** has reduced costs,increased productivity and accuracy of the implant manufacturing ***,there are problems associated with assessing defects in the microstructure,mechanical and technological properties of alloys,both during their production by powder metallurgy and in the process of 3D *** traditional research methods of alloys properties demand considerable human,material,and time *** the same time,artificial intelligence tools create opportunities for intelligent evaluation of the conformity for the microstructure,phase composition,and properties of titanium powder’s *** provides new possibilities for the efficient production of biocompatible implants for various functional ***,the accuracy of the methods and models used should be as high as *** this paper we designed a hybrid PNN-SvM(Probabilistic Neural Network-Support vector Machine)high-precision approach for the intelligent evaluation of alloy properties for additive manufacturing of biomedical *** have proposed a new approach for extending the dimensionality of input data space by the outputs of the summation layer of the modified PNN *** classification based on the expanded dataset is performed using *** conducted experimental modeling of the proposed approach using a data set on the properties of titanium alloys Ti-6Al-4v and *** have demonstrated a significant increase in the accuracy of the PNN-SvM scheme compared to the single classifiers that form it and other machine learning methods.

关键词： PNN SvM hybrid systems classification accuracy medical implants additive manufacturing 3D printing titanium alloys

First results of turbulence investigation on Globus-M2 using radial correlation Doppler reflectometry

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Plasma Science and Technology 2024年第10期26卷 49-55页

作者： A.PoNoMARENKo A.YASHIN v.GUSEv E.KISELEv G.KURSKIEv v.MINAEv Y.PETRov N.SAKHARov P.SHCHEGoLEv E.tkachenko N.ZHILTSov Peter the Great St.Petersburg Polytechnic University St.Petersburg 195251Russia Ioffe Institute St.Petersburg 194064Russia

The first results of investigation of the turbulence structure using Doppler backscattering(DBS)on the Globus-M2 tokamak are presented.A one-channel DBS system with a variable probing frequency within the 18–26 GHz range was installed to investigate the edge plasma at normalized minor radiiρ=0.9–*** correlation Doppler reflectometry was used to study the changes in turbulence eddies after the LH *** analysis was applied to the phase derivative of complex in-phase and quadrature(IQ)signals of the DBS diagnostic as it contains information about the poloidal plasma rotation *** L-mode,the radial correlation length L_(r)is estimated to be 3 cm and after transition to H-mode reduces to approximately 2 *** modelling in a linear local approximation using code GENE indicates that the instability with positive growth rate at the normalized minor radiusρ=0.75 in L-mode and H-mode on Globus-M2 was the ion temperature gradient(ITG)mode.

关键词： tokamak turbulence Doppler backscattering correlation reflectometry

Human chemerin induces eryptosis at concentrations exceeding circulating levels

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BIoCELL 2024年第8期48卷 1197-1208页

作者： MARYNA tkachenko ANAToLII oNISHCHENKo LILIYA TRYFoNYUK DMYTRo BUTov KATERYNA KoT vIKToRIIA NovIKovA LIWEI FAN voLoDYMYR PRoKoPIUK YURII KoT ANToN tkachenko Department of Internal Medicine No.2 Clinical Immunology and AllergologyKharkiv National Medical UniversityKharkiv61022Ukraine Research Institute of Experimental and Clinical Medicine Kharkiv National Medical UniversityKharkiv61022Ukraine Institute of Health National University of Water and Environmental EngineeringRivne61022Ukraine Department of Infectious Diseases and Phthisiology Kharkiv National Medical UniversityKharkiv61022Ukraine Biochemistry Department V.N.Karazin Kharkiv National University Ministry of Education and Science of UkraineKharkiv61022Ukraine Department of Chemistry BiochemistryMicrobiology and Food HygieneState Biotechnological UniversityKharkiv61022Ukraine Clinical Research Innovation Lab Floor 26 Block D Qidi Technology Building 8Tsinghua Technology ParkBeijing100084China Department of Cryobiochemistry Institute for Problems of Cryobiology and Cryomedicine of the National Academy of Sciences of UkraineKharkiv61015Ukraine

Introduction:Human chemerin is an adipokine that regulates chemotaxis,inflammation,and glucose *** addition,accumulating evidence suggests that chemerin promotes apoptosis,autophagy,and ***,there are no data on its impact on *** current study aimed to analyze the effects of human active Glu^(21)-Ser^(157) chemerin on eryptosis in *** and Methods:Human chemerin 0-2-10-50μg/mL was incubated for 24 h with human erythrocytes(hematocrit 0.4%)obtained from eight healthy *** cytometry-based determination of phospholipid scrambling,reactive oxygen species(RoS)production,and intracellular Ca^(2+)levels was *** supplement data on RoS and Ca^(2+)signaling in chemerin-mediated eryptosis,incubation in the presence or absence of antioxidants vitamin C and N-acetylcysteine and Ca^(2+)-binding agent EGTA was carried out,*** microscopy-based techniques were used to detect reactive nitrogen species(RNS)generation,involvement of caspase-3 and caspase-8,as well as the state of lipid order in cell membranes of erythrocytes exposed to human Glu^(21)-Ser^(157) ***:our observations suggest that human Glu^(21)-Ser^(157) chemerin had no impact on eryptosis parameters at 2μg/***,chemerin stimulated phosphatidylserine externalization,RoS production,and Ca^(2+)accumulation at higher concentrations suggesting activation of ***^(2+)uptake turned out to be at least partly required for chemerin-mediated ***-mediated erythrotoxicity was additionally mediated by RNS,caspase-3,and ***,Glu^(21)-Ser^(157) chemerin promoted reduction in the liquid-ordered phase of cell membranes in ***:The present study first discloses that human chemerin can induce eryptosis via Ca^(2+)-dependent mechanisms at concentrations noticeably exceeding circulating ***,chemerin-induced eryptosis can hardly contribute to eryptosis-mediated anemia in disease

关键词： Adipokine Cell death Chemerin oxidative stress Eryptosis

Modeling of ultrafast X-ray induced magnetization dynamics in magnetic multilayer systems

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npj Computational Materials 2022年第1期8卷 2044-2052页

作者： K.J.Kapcia v.tkachenko F.Capotondi A.Lichtenstein S.Molodtsov L.Müller A.Philippi-Kobs P.Piekarz B.Ziaja Center for Free-Electron Laser Science CFEL Deutsches Elektronen-Synchrotron DESYNotkestr.8522607HamburgGermany Institute of Spintronics and Quantum Information Faculty of PhysicsAdam Mickiewicz University in PoznańPoznańPoland Institute of Nuclear Physics Polish Academy of SciencesKrakówPoland European XFEL GmbH SchenefeldGermany Elettra-Sincrotrone Trieste S.C.p.A TriesteBasovizzaItaly University of Hamburg HamburgGermany Deutsches Elektronen-Synchrotron DESY Notkestr.8522607HamburgGermany

In this work,we report on modeling results obtained with our recently developed simulation tool enabling nanoscopic description of electronic processes in X-ray irradiated ferromagnetic *** this tool,we have studied the response of Co/Pt multilayer system irradiated by an ultrafast extreme ultraviolet pulse at the M-edge of Co(photon energy~60 ev).It was previously investigated experimentally at the FERMI free-electron-laser facility,using the magnetic small-angle X-ray scattering *** simulations show that the magnetic scattering signal from cobalt decreases on femtosecond timescales due to electronic excitation,relaxation,and transport processes both in the cobalt and in the platinum layers,following the trend observed in the experimental *** confirmation of the predominant role of electronic processes for X-ray induced demagnetization in the regime below the structural damage threshold is a step toward quantitative control and manipulation of X-ray induced magnetic processes on femtosecond timescales.

关键词： magnetization multilayer cobalt

Production of Dissimilar Metals Materials by the Method of Solid-State Joining

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open Journal of Metal 2014年第2期4卷 40-47页

作者： B. v. Borts I. M. Korotkova o. o. Lopata v. I. Sytin v. I. tkachenko I. o. vorobyov National Science Center “Kharkov Institute of Physics & Technology” Kharkov Ukraine

Mechanisms taking place while hot rolling in vacuum of dissimilar materials joined in solid phase are described. It is shown that at joining of materials in solid phase redistribution of atoms from one material into another occurs on the interface of joining. on the base of calculation and experimental results it is concluded that the ultimate strength of the interface of joint is always higher than the ultimate strength of less durable material. Pair zirconium-stainless steel SS (Type AISI 321) and carbon steel (Type C22E) those are used in nuclear power are investigated.

关键词： vacuum Hot Roll Bonding Solid Phase Ultimate Strength Interface