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Hybrid bimetallic cluster ZrO2/Rh@N,S co-doped porous carbon nanosheets for efficient hydrogen evolution in acid electrolytes

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Tungsten 2024年第4期6卷 657-662页

作者： Xin-Yi Zhang Igor v.Zatovsky Jun-Ming Cao Xing-Long Wu Faculty of Chemistry Northeast Normal University F.D.Ovcharenko Institute of Biocolloidal Chemistry NAS Ukraine MOE Key Laboratory for Uv Light-Emitting Materials and Technology Northeast Normal University

Acid hydrogen evolution reaction (HER) is a critical energy conversion process,which is significantly important in hydrogen energy manufacturing and storage [1].Although the performance of noble metal platinum (Pt)-based catalysts in acidic HER is well known,the challenges are high cost,limited reserves,poor stability,and susceptibility to toxic substances [2].Therefore,it is urgent to design and manufacture acidic HER catalysts with high reactivity,high stability,and low cost.

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The influence of resistance exercise training prescription variables on skeletal muscle mass,strength,and physical function in healthy adults:An umbrella review

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Journal of Sport and Health Science 2024年第1期13卷 47-60页

作者： Jonathan C.Mcleod Brad S.Currier Caroline v.Lowisz Stuart M.Phillips Department of Kinesiology Faculty of ScienceMcMaster UniversityHamilton L8S4L8Canada

Purpose:The aim of this umbrella review was to determine the impact of resistance training(RT)and individual RT prescription variables on muscle mass,strength,and physical function in healthy ***:Following Preferred Reporting Items for Systematic Reviews and Meta-Analyses(PRISMA)guidelines,we systematically searched and screened eligible systematic reviews reporting the effects of differing RT prescription variables on muscle mass(or its proxies),strength,and/or physical function in healthy adults aged>18 ***:We identified 44 systematic reviews that met our inclusion *** methodological quality of these reviews was assessed using A Measurement Tool to Assess Systematic Reviews;standardized effectiveness statements were *** found that RT was consistently a potent stimulus for increasing skeletal muscle mass(4/4 reviews provide some or sufficient evidence),strength(4/6 reviews provided some or sufficient evidence),and physical function(1/1 review provided some evidence).RT load(6/8 reviews provided some or sufficient evidence),weekly frequency(2/4 reviews provided some or sufficient evidence),volume(3/7 reviews provided some or sufficient evidence),and exercise order(1/1 review provided some evidence)impacted RT-induced increases in muscular *** discovered that 2/3 reviews provided some or sufficient evidence that RT volume and contraction velocity influenced skeletal muscle mass,while 4/7 reviews provided insufficient evidence in favor of RT load impacting skeletal muscle *** was insufficient evidence to conclude that time of day,periodization,inter-set rest,set configuration,set end point,contraction velocity/time under tension,or exercise order(only pertaining to hypertrophy)influenced skeletal muscle adaptations.A paucity of data limited insights into the impact of RT prescription variables on physical ***:Overall,RT increased muscle mass,strength,and physical function compared to no ***

关键词： Hypertrophy Resistance training Resistance training prescription variables Strength Umbrella review

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Outcomes and variables that impact pneumatic retinopexies

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International Journal of Ophthalmology(English edition) 2024年第3期17卷 564-569页

作者： Maria v.Castanos Daniel vail Oscar Otero-Marquez Yash Shah Avnish Deobhakta New York Eye and Ear Infirmary of Mount Sinai New York 10003New YorkUSA

●AIM:To evaluate the efficacy of pneumatic retinopexy(PR)in patients undergoing PR as primary treatment for rhegmatogenous retinal detachment(RRD)and analyze the factors associated with success and failure in the studied population.●METHODS:A retrospective chart review was done of patients with RRD treated with PR as primary management method treated at New York Eye and Ear Infirmary of Mount Sinai between January 2017 and December *** outcome measured success or failure of *** outcome measured best corrected visual acuity(BCvA)after PR.A separate risk analysis was done to identify and stratify risks associated with success and failure of PR.●RESULTS:A total of 179 eyes from 179 patients were included for final *** 83 patients(46.37%)achieved anatomical reattachment of the retina after primary PR with no need for additional *** 96 patients(53.63%)had a failed primary PR and required a PPv and 6 of them required pars plana vitrectomy(PPv)with scleral buckle(SB).In total,19 cases(10.61%)were done as temporizing pneumatics,18(94.74%)underwent PPv,and 1(5.26%)did not require further *** visual acuities at postoperative month 1(POM1)for patients who underwent primary PR successfully and for those that underwent PPv after,were 0.58(20/80)and 1.03(20/200)*** who met Pneumatic Retinopexy versus vitrectomy for the Management of Primary Rhegmatogenous Retinal Detachment Outcomes Randomized Trial(PIvOT)criteria had a statistically significant decreased risk of primary PR failing(hazard ratio 0.29,P=0.00).Majority of missed or new breaks were found superotemporally.●CONCLUSION:PR is a good treatment option for treating RRDs in patients that meet PIvOT criteria and can be conducted as a temporizing *** criteria and fovea on status decrease the risk of PR failure.

关键词： retina pneumatic retinopexy rhegmatogenous retinal detachment

Specificity of electrophysical and gas-sensitive properties of nanocomposite ZnO–TiO_(2) films formed by solid-phase pyrolysis

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ChemPhysMater 2024年第3期3卷 314-319页

作者： victor v.Petrov Maria G.volkova Alexsandra P.Ivanishcheva Gleb v.Tolstyak Ekaterina M.Bayanb Institute of Nanotechnologies Electronicsand Equipment EngineeringSouthern Federal UniversityTaganrog 347922Russia Faculty of Chemistry Southern Federal UniversityRostov-on-Don 344090Russia

ZnO–TiO_(2) thin films containing 0.5 mol%,1.0 mol%,and 5.0 mol%ZnO were synthesized by oxidative solidphase *** materials contained anatase and rutile phases with particle size of 6–13 nm,as confirmed using X-ray phase analysis and scanning electron *** a certain number of ZnO crystallites appeared in the TiO_(2) film structure in the temperature range of room temperature to 220℃,a two-level response of the film resistance was observed,differing by approximately 10%,as obtained by electrophysical *** two-level response correlates with the formation of two donor energy levels of 0.28 and 0.33 ev in the band structure of the ZnO–TiO_(2) *** donor level with a higher activation energy corresponded to the Ti vacancy(v−Ti),and that with a lower activation energy corresponded to the Zn vacancy(v−Zn).Two levels of gas-sensitive properties were noted for 0.5ZnO–TiO_(2),1ZnO–TiO_(2),and 5ZnO–TiO_(2) under the influence of 50 ppm NO_(2) at 250℃.Such two-level responses can be ascribed to the pinning of the Fermi level on ZnO and TiO_(2) *** mechanism of the beak-shaped and two-level responses of sensors based on composite nanomaterials when exposed to various gases was elucidated.

关键词： Thin film ZnO TiO_(2) Nanocomposites Pyrolysis Gas sensors

Challenging the term symbiosis in plant-microbe associations to create an understanding across sciences

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Journal of Integrative Plant Biology 2024年第1期66卷 7-11页

作者： Anna Neubauer Daniela Aros‐Mualin vicente Mariscal Péter Szövényi Department of Systematic and Evolutionary Botany University of ZurichZurich 8008Switzerland Zurich‐Basel Plant Science Center Zurich 8092Switzerland Instituto de Bioquímica vegetal y Fotosíntesis CSIC y Universidad de SevillaSevilla 41092Spain

THE IMPORTANCE OF WELL DEFINED TERMINOLOGY,Effective communication across fields and disciplines relies on well defined *** use of accurate definitions has been advocated by scientists across various disciplines(PySek... 详细信息

关键词： terminology definition fields

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Agglomeration of coal and polyethylene mixtures during fixed‑bed co‑gasification

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International Journal of Coal Science & Technology 2024年第2期11卷 91-100页

作者： Igor G.Donskoy Aleksandr N.Kozlov Maksim v.Penzik Denis A.Svishchev Lu Ding Melentiev Energy Systems Institute Russian Federation130 Lermontova StreetIrkutskRussia 664033 East China University of Science and Technology 130 Meilong RoadShanghai 200237China

The article presents the results of experimental studies on the gasification of mixtures of brown coal and polyethylene(up to 20 wt%fraction)in a laboratory *** work aims to study the agglomeration process during the heating and oxidation of the *** measurement results(gas composition,pressure drop)provide indirect information on the dynamics of thermal decomposition and structural changes in the fuel *** have shown that the interaction between polyethylene and a coal surface leads to the formation of dense agglomerates,in which the molten polymer acts as a *** form as a result of interfacial interactions between components and filtration flow *** hydrogen/carbon ratio in the solid residue of coal-polyethylene co-gasification increases from 0.07–0.2 to 1.11,indicating the formation of stable hydrocarbon compounds on the carbon *** conducted research makes it possible to identify possible interactions between chemical reactions and transfer processes that lead to agglomeration in mixtures of coal with polyethylene.

关键词： Coal Polyethylene Gasification Combustion Agglomeration

Ion Channel Dysregulation Following Intracerebral Hemorrhage

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Neuroscience Bulletin 2024年第3期40卷 401-414页

作者： Xiangyu Zhang Yan Zhang Qiuyang Su Yang Liu Zhe Li v.Wee Yong Mengzhou Xue Department of Cerebrovascular Diseases The Second Afliated Hospital of Zhengzhou UniversityZhengzhou 450000China Academy of Medical Science Zhengzhou UniversityZhengzhou 450000China Hotchkiss Brain Institute and Department of Clinical Neurosciences University of CalgaryCalgaryAB T2N 1N4Canada

Injury to the brain after intracerebral hemorrhage(ICH)results from numerous complex cellular *** present,effective therapy for ICH is limited and a better understanding of the mechanisms of brain injury is necessary to improve *** is increasing evidence that ion channel dysregulation occurs at multiple stages in primary and secondary brain injury following *** channels such as TWIK-related K+channel 1,sulfonylurea 1 transient receptor potential melastatin 4 and glutamate-gated channels affect ion homeostasis in *** in turn participate in the formation of brain edema,disruption of the blood-brain barrier,and the generation of *** this review,we summarize the interaction between ions and ion channels,the effects of ion channel dysregulation,and we discuss some therapeutics based on ion-channel modulation following ICH.

关键词： Intracerebral hemorrhage Ion dyshomeostasis Sulfonylurea 1 transient receptor potential melastatin 4 TWIK-related K+channel 1 N-methyl-Daspartate receptor Transient receptor potential vanilloid 4

Determining the Checkpoint of Transition from Thin to Thick Periodontal Phenotypes in the Maxillary and Mandibular Anterior Regions of South Indian Population

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Journal of Forensic Science and Medicine 2024年第1期10卷 55-61页

作者： Mohan Kumar Pasupuleti Rasagna Chowdary G Gautami SPenmetsa vivek Bypalli Ramesh S.v.Konathala Sruthima N.v.S.Gottumukkala Department of Periodontics and Implantology Vishnu Dental CollegeBhimavaramAndhra PradeshIndia2Vishnu Dental CollegeBhimavaramAndhra PradeshIndia

Aim:The aim of this study was to compare and investigate the tissue thickness at the maxillary and mandibular central incisors utilizing the probe visibility method and traditional way of measuring gingival thickness(GT)by endodontic ***:In 200 selected patients,the GT was measured at both the maxillary and mandibular anterior using an endodontic file after local infiltration at the mid-distance from the gingival margin to the mucogingival *** checkpoint of transition from thin to thick periodontal phenotype was determined by probe visibility method in the following age groups:Group A:21-30 years;Group B:31-40 years;Group C:41-50 years;and Group D:51-60 ***:GT varied from 0.3 to 1.9 *** translucency was observed up to the thickness of 0.7 *** 0.8 mm of GT,there was no probe ***:According to the present research,the gingiva appears transparent up to a thickness of around 0.7 *** checkpoint of transition between thin and thick periodontal phenotypes at both the maxillary and mandibular anterior was associated with a GT of 0.8 mm.

关键词： Gingiva periodontal phenotype probe visibility

Chemical Effect on K Shell X-ray Fluorescence Parameters and Radiative Auger Ratios of Co, Ni, Cu, and Zn Complexes

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Chinese Journal of Chemical Physics 2010年第2期23卷 138-144,I0001页

作者： Erhan Cengiz Zekeriya Biyiklioglu Nuray Kup Ayhkcl volkan aylikci Gokhan Apaydin Engin Tirasglu Halit Kantekin 黑海技术大学理学院物理系特拉布宗61080土耳其黑海技术大学理学院化学系特拉布宗61080土耳其

The production cross-sections, intensity ratios, and radiative Auger intensity ratios of Co, Ni, Cu, and Zn elements in different complexes were measured. The chemical effects on the K shell fluorescence parameters and the radiative Auger intensity ratios of these elements were investigated and the changes in these parameters were interpreted according to the charge transfer process. The samples were excited by 59.5 kev γ-rays from a ^241Am annular radioactive source. K X-rays emitted by samples were counted by an Ultra-LEGe detector with a resolution of 150 ev at 5.9 kev.

关键词： Charge transfer Cross-section Radiative Auger intensity ratio Ultra-LEGe detector Chemical effect