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Microstructural Features During Strain Induced Ferrite Transformation in 08 and 20Mn Steels

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Journal of university of science and technology beijing 2001年第2期8卷 105-110页

作者： Ping Yang, Feng-e Cui, Fuming Wang (Materials science and Engineering School, university of science and technology beijing, beijing 100083, China) (Metallurgy School, university of science and technology beijing, beijing 100083, China) Materials Sci. and Eng. School University of Science and Technology Beijing 100083 China

The microstructure evolution during strain induced ferrite transformation was followed in thermal-simulation tests of clean 08 and 20Mn steels. The influences of carbon equivalence and initial austenite grain size on ferrite grain refinement and the volume fraction of ferrite during straining were inspected. The results revealed that the accelerating effect of ferrite transformation by strain was increased as the carbon equivalence decreased. However, finer ferrite grains were obtained at higher carbon content. At strain of similar to1.5 ferrite grains less than 3 mum and 2 mum can be obtained in 08 and 20Mn steels respectively. Whereas the ferrite grain refinement in 08 steel was due to both effects of strain induced transformation and ferrite dynamic recrystallization, that in 20Mn was mainly due to strain induced transformation. Heavy strain can produce fine ferrite grains in coarse austenite grained 08 steel, but it would lead to band microstructure in coarse austenite grained 20Mn.

关键词： clean carbon steel strain induced transformation grain refinement ferrite dynamic recrystallization

Distribution of Nb atom in the TiAl+Nb system

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Rare Metals 2001年第1期20卷 5-12页

作者： Xiaodong Ni, Xidong Hui, Guoliang Chen (Applied science School, university of science and technology beijing, beijing 100083, China State Key Laboratory for Advanced Metals and Materials, university of science and technology beijing, China) Appl. Sci. Sch. Univ. of Sci. and Technol. Beijing Beijing 100083 China

Based on MEAM (the modified embedded atom method) potential and an average atom model similar to B-W (Bragg-Williams) method, the distribution of Nb atoms in TiAl+Nb compounds with various composition was calculated. The calculation results showed that Nb atoms prefer to occupy the Ti sublattice of L10 structure for all compounds in question. With increasing atomic fraction of Nb and Al, Nb atoms exhibited a trend of ordered distribution on the Ti sublattice and result in a new L10 derivative superlattice structure.

关键词： Computer simulation Intermetallics Superlattices Ternary systems

Calculating Model of Mass Action Concentrations for Mn-C Melts and Optimization of Thermodynamic Parameters

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International Journal of Minerals,Metallurgy and Materials 1998年第4期12卷 208-211页

作者： Jian Zhang(Metallurgy School, university of science and technology beijing, beijing 100083, China) Metallurgy School University of Science and Technology Beijing Beijing 100083 China

Based on the phase diagram, the coexistence theory of the metallic melt structure involving compoundformation and the regularity of melts containing saturated phase, a calculating model of mass action concentrationsfor Mn-C melts was formulated. According to the activities (or activity coefficients AM. and γc.), obtained by theUnified Interaction Parameter Model (UIPM), the thermodynamic parameters G and G at higher temperatures (1628～1873 K) were optimized by the repeated try and error method. It is testified that G G(873～1273 K) and G (298～1623 K), obtained at lower temperatures, can also be used at the above-mentionedhigher temperatures. The calculated N. and N agree well with ac. and ac obtained by UIPM. This result showsthat the deduced model can reflect the structural reality of Mn-C melts.

关键词： Mn-C melts activity coexistence theory mass action concentration

A Back Look on the Binary Phase Diagrams of Metals from the Mass Action Law and the Coexistence Theory of Metallic Melts

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Journal of university of science and technology beijing 2001年第1期8卷 15-19页

作者： Jian Zhang Metallurgy School, university of science and technology beijing, beijing 100083, China Metallurgy School Univ. of Science/Technology Beijing Beijing 100083 China

According to the mass action law and the coexistence theory of metallic melts, the mass action concentrations of Cu-Mg, Bi-Tl and Ni-Al melts involving compound formation have been calculated. The calculated results show that, except the ultimate case of pure element, when two elements are present in the melts, all structural units (atoms and molecules) without exception will be present in the melts, i.e., their concentrations may change from great to small, but they will not vanish into nothing, and only under such conditions, the calculated results both agree with practice and obey the law of mass action. In view of that over considerable wide composition range, the activities of both elements of the three solid binary alloys mentioned above have been measured, this seems in contradiction with the present relevant phase diagrams, in which the structural units are determined by composition range, so the latter needs further investigation and consideration.

关键词： activity phase diagram the mass action law the coexistence theory

Calculating Models of Mass Action Concentrations for Ni-Mn and Co-Mn Melts and Optimization of Their Thermodynamic Parameters

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International Journal of Minerals,Metallurgy and Materials 2000年第4期14卷 246-250页

作者： Jian Zhang (Metallurgy School, university of science and technology beijing, beijing 100083, China) Metallurgy School University of Science and Technology Beijing Beijing 100083 China

According to phase diagrams, measured activities as well as the coexistence theory of motallic melts structure involving compound formation, the calculating models of mass action concentrations for Ni-Mn and Co-Mn melts are formulated and their thermodynamic parameters are optimized. As a result, the calculated mass action concentrations agree well with the corresponding measured activities, showing that these models can reflect the structural characteristics of both Ni-Mn and Co-Mn melts.

关键词： activity metallic melts coexistence theory mass action concentration

Calculating Models of Mass Action Concentrations for Fe-P and Cr-P Melts and Optimization of Their Thermodynamic Parameters

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International Journal of Minerals,Metallurgy and Materials 1999年第3期13卷 174-177页

作者： Jian Zhang(Metallurgy School, university of science and technology beijing, beijing 100083, China) Metallurgy School University of Science and Technology Beijing Beijing 100083 China

Based on the phase diagrams, reliable reference experimental data and the coexistence theory of metallic melts structure involving compound formation, calculating models of mass action concentrations for Fe-P and Cr-P melts have been formulated. At the same time, some of their thermodynamic parameters have been optimized. The calculated results not only agree well with the measuredvalues, but also obey the mass action law rigorously, this in turn shows that these models can reflect the structural characteristics of corresponding melts.

关键词： activity phase diagram coexistence theory mass action concentration

MECHANISM FOR DIFFUSION OF BORON IN γ-Fe

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Acta Metallurgica Sinica(English Letters) 1992年第5期5卷 318-323页

作者： YU Zongsen CHEN Ning university of science and technology beijing,beijing,China beijing Univ of science and Technology Beijing China

Mechanism for diffusion of B in γ-Fe is believed to be mainly by means of boron-vacancy complexes other than as interstitial atoms *** was made of calculation on the ba- sis of theoretical model proposed by the *** calculated diffusion coefficient of B in γ-Fe after this mechanism is consistent with the experimental *** addition,this is also supported by the non-equilibrium segregation phenomenon of B at grain boundaries of γ-Fe and the lattice constant measurement of Fe-B alloy.

关键词： boron vacancy diffusion non-equilibrium segregation γ-Fe

Theory for Constructing Generalized Synchronization and Applications

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International Journal of Minerals,Metallurgy and Materials 2000年第3期14卷 225-228页

作者： Xiaodan Zhang, Lequan Min (Applied science School, university of science and technology beijing, beijing 100083, China) Applied science School University of Science and Technology Beijing Beijing 100083 China

The approaches for constructing directionally coupled generalized synchronization (GS) systems are presented, which are available for the driving system and the respond system that are in GS via a given diffeomorphi... 详细信息

关键词： Chaos generalized synchronization predictability

Comparison of Some Methods on Prediction of Activity Interaction Coefficient

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International Journal of Minerals,Metallurgy and Materials 1998年第1期12卷 13-15页

作者： Changxiang Xiang Ningxin Zhang (Applied science School, university of science and technology beijing, beijing 100083, China) Applied science School University of Science and Technology Beijing Beijing 100083 China

Based on Miedema's semiempirical formation enthalpy model for binary alloys, free volume theory and ageneral solution model, a new model for prediction of activity interaction coefficient ε is proposed. The calculatedresults are better in agreement with the experimental values than the two previous models. The related theories andmodels are discussed according to the degree of agreement with experimental values.

关键词： Miedema's semiempirical formation enthalpy model activity interaction coefficient free volume theory similarity coefficient