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A NEW APPROACH TO ESTIMATE KINETIC DECOMPOSITION FROM TG-DTG OR DSC CURVE

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Chinese Chemical Letters 1993年第6期4卷 521-522页

作者： Yu Ting ZHAO Jian Hua ZHANG tong shan sun Department of Chemistry,shandong University,Jinan,250100Zhao He YANG Institute of Crystal Materials,shandong University,Jinan,250100

This paper reports a new approach to estimate kinetic parameters for the thermal decomposition of the solid state from TG-DTG or DSC *** equations are derived for the first *** validity of these equations was demonstr... 详细信息

关键词： DTG AI RT rate DSC A NEW APPROACH TO ESTIMATE KINETIC DECOMPOSITION FROM TG-DTG OR DSC CURVE

Interfacial Zn2+-solvation regulator towards reversible and stable Zn anode

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Journal of Energy Chemistry 2025年第1期100卷 684-692页

作者： Miao Zhou Xiongbin Luo Hang Li shan Guo Zhuang tong Xiaotao Zhou Xu Li Zhaohui Hou Shuquan Liang Guozhao Fang College of Mechanical Engineering Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials Hunan Institute of Science and Technology School of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province Central South University College of Materials and Metallurgy Guizhou University National Energy Metal Resources and New Materials Key Laboratory Central South University

Aqueous zinc-ion batteries （AZIBs） are fundamentally challenged by the instability of the electrode/electrolyte interface,predominantly due to irreversible zinc （Zn） deposition and hydrogen ***,the intricate mechanisms behind the electrochemical discrepancies induced by interfacial Zn2+-solvation and deposition behavior demand comprehensive *** molecules endowed with special functional groups （such as hydroxyl,carboxyl,etc.） have the potential to significantly optimize the solvation structure of Zn2+and regulate the interfacial electric double layer （EDL）.By increasing nucleation overpotential and decreasing interfacial free energy,these functional groups facilitate a lower critical nucleation radius,thereby forming an asymptotic nucleation model to promote uniform Zn ***,this study presents a pioneering approach by introducing trace amounts of n-butanol as solvation regulators to engineer the homogenized Zn （H-Zn） anode with a uniform and dense *** interfacial reaction and structure evolution are explored by in/ex-situ experimental techniques,indicating that the H-Zn anode exhibits dendrite-free growth,no by-products,and weak hydrogen evolution,in sharp contrast to the bare ***,the H-Zn anode achieves a remarkable Zn utilization rate of approximately 20% and simultaneously sustains a prolonged cycle life exceeding 500 ***,the H-Zn//NH4V4O10（NVO） full battery showcases exceptional cycle stability,retaining 95.04%capacity retention after 400 cycles at a large current density of 5 A *** study enlightens solvation-regulated additives to develop Zn anode with superior utilization efficiency and extended operational lifespan.

关键词： Solvation

Microspheres trigged-stress concentration regulating piezoelectric properties of PVDF/elastomer composites

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Science China Chemistry 2025年

作者： Wenxian Zhang Jiahong Yang Qijun sun Lu Peng tong Lin Shouke Yan Xiaoli sun State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of Sciences State Key Laboratory of Separation Membranes and Membrane Processes School of Textile Science and EngineeringTiangong University Key Laboratory of Rubber-Plastics of Ministry of Education Shandong Provincial Key Laboratory of Rubber-PlasticsQingdao University of Science & Technology

Wearable self-powered piezoelectric pressure sensors are attracting tremendous ***,fabricating a high-sensitive elastic piezoelectric sensor for a broad response range remains ***,we assemble polar poly（vinylidene fluoride）(PVDF) microsphere-elastomer composites,achieving high-sensitive and wide-responsive pressure *** polar PVDF microspheres are produced cost-effectively through phase separation,enabling *** piezoelectric composite （PC） film demonstrates low Young’s modulus,and excellent anti-fatigue ***,the PC-based piezoelectric sensor exhibits a rather high sensitivity of 540 mV N-1in a wide sensing range （5–40 N）,240 times greater than the PVDF film-based sensor and comparable to the inorganic piezoelectric *** excellent performance is attributed to the highest average stress concentration on the spherical PVDF coupled with the remarkable deformation of dipoles of spherical PVDF in the flexible *** on excellent performance,this piezoelectric sensor achieves precise recognition of motions and sound *** high-sensitive flexible piezoelectric sensor enabling large area production with ultralow price exerts great potential in smart monitoring and intelligent robots.

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生物高分子聚合物生态固沙效果初探

岩土工程学报 2025年第1期47卷 144-152页

作者：童小东慈祥孙任运东南大学土木工程学院江苏南京211189 东南大学混凝土及预应力混凝土结构教育部重点实验室江苏南京211189 上海市政工程设计研究总院(集团)有限公司上海200092

沙漠化治理是一个全球性的难题。相较于传统的沙漠固沙技术,作为环境友好型固化材料的生物高分子聚合物,不仅能有效胶结沙漠砂以抵抗风蚀作用,还能提高沙漠砂的促生性能以促进植物生长,最终达到利用植被实现永久固沙的效果。基于前述设... 详细信息

沙漠化治理是一个全球性的难题。相较于传统的沙漠固沙技术,作为环境友好型固化材料的生物高分子聚合物,不仅能有效胶结沙漠砂以抵抗风蚀作用,还能提高沙漠砂的促生性能以促进植物生长,最终达到利用植被实现永久固沙的效果。基于前述设想,通过表面硬度试验、保水性能试验和植物生长试验研究了黄原胶(XG)、瓜尔胶(GG)以及二者的等质量混合胶(MG)生态固沙的效果。表面硬度试验表明生物高分子聚合物能有效胶结沙漠砂颗粒,质量分数为0.1%的XG、GG和MG溶液分别将沙漠砂的表面压力强度提高了9.4倍、5.3倍和8.0倍;保水性能试验表明生物高分子聚合物对沙漠砂保水性能的提升效果随溶液质量分数的增大而增大,在40℃高温养护条件下,生物高分子聚合物保水性能的比较结果为:XG>MG>GG;植物生长试验表明,在室内条件下,生物高分子聚合物能缩短植物出苗时间、提升植物的出苗率和幼苗高度,明显提高沙漠砂的促生性能。本文的研究初步表明,采用生物高分子聚合物实现生态固沙具备理论上的可行性。

关键词：生物高分子聚合物生态固沙表面硬度保水性能

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大数据证明的司法适用与理论检视

北京科技大学学报（社会科学版） 2025年第1期41卷 69-78页

作者：孙珊中国人民武装警察部队海警学院维权执法系宁波315801

在刑事司法活动中,业已出现了有异于传统证明的大数据证明方式。通过对我国当下司法实践中适用案件的观察性分析,可归纳出大数据在刑事司法领域中的证明作用主要表现为:证明涉案主体的同一性、信息载体的关联性、海量信息的涉案数额、... 详细信息

在刑事司法活动中,业已出现了有异于传统证明的大数据证明方式。通过对我国当下司法实践中适用案件的观察性分析,可归纳出大数据在刑事司法领域中的证明作用主要表现为:证明涉案主体的同一性、信息载体的关联性、海量信息的涉案数额、犯罪行为、犯罪构成中的特征信息五个方面。与传统司法证明相比,大数据证明最鲜明的特点体现为智能化、模型化及特殊相关性,要认识其内在原理与运行机制,可采取一种“海量信息+数据处理+结论”的要素思维。文章基于司法适用和内在机理对大数据证明进行理论上的检视,认为首先应当确立能够作为定案依据的大数据证明结论证据本位的法律属性规范,其次厘清其作为机器意见的事实认定原理,最后尝试以算法应用场景的稳定性为标准建立类案通用型和个案专门型二元分化的审查进路范式。

关键词：大数据证明司法适用事实认定司法审查

Mismatch loss analysis of solar array output power on stratospheric airship during flight

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Chinese Journal of Aeronautics 2024年第2期37卷 371-384页

作者： Siyu LIU Kangwen sun Haoquan LIANG Xinzhe JI tong ZOU Chuan shan School of Aeronautic Science and Engineering Beihang UniversityBeijing 100191China Yunnan Innovation Institute Beihang UniversityKunming 650233China Institute of Unmanned System Beihang UniversityBeijing 100191China

Stratospheric airships are long-endurance aerostats and have broad *** of the energy required for their operation is obtained from solar radiation,which makes accurate calculation of the energy output from the solar array crucial to the design and flight planning of the ***,the status of each photovoltaic module in the solar array may differ due to the airship curvature,resulting in mismatch losses and lowered output power,which has not been widely *** this paper,an irradiation model and a thermal model are established based on the actual arrangement of the *** output power model is established considering the non-uniform radiation in the *** mismatch losses of the array are analyzed under different flight *** output power of the solar array is decreased by up to 31.6%compared to the ideal ***,the proportion of mismatch losses increases with latitude,but the maximum mismatch loss power occurs at ***,an array reconfiguration method is proposed based on the irradiance dispersion index and position dispersion *** reconfigured array increases output power by 11.5%and can maintain energy balance in continuous *** results can be used to correct the overestimation of the output power during the airship design or to guide the configuration of the solar array.

关键词： Stratospheric airship Solar panels Solar energy Non-uniform irradiation Mismatch loss assessment Reconfiguration

Establishing a new testing protocol of the electrochemical stability window for electric double-layer capacitors

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Science China Chemistry 2025年第01期 217-225页

作者： Ruilin Hou Xiaoxi Zhao Tingting Liang Qingyun Dou shan Xu Xingbin Yan School of Materials Science and Engineering Sun Yat-sen University Laboratory of Clean Energy Chemistry and Materials Lanzhou Institute of Chemical Physics Chinese Academy of Sciences College of Engineering and Applied Sciences Nanjing University Center of Industrial Analysis and Testing Guangdong Academy of Science

The electrochemical stability window(ESW) is crucial for determining the energy density of electric double-layer capacitors(EDLCs). However, current ESW testing protocols of EDLCs are strongly affected by artificial factors, thereby leading to unreliable result. To solve this problem, we first identify the key shortcomings of the traditional protocols by analyzing their test principles. Subsequently, taking an aqueous carbon-based EDLC as an example, we design a side reaction descriptor to represent the response difference in the charging capacitance to side reactions between the cyclic voltammetry and galvanostatic chargedischarge methods. With the aid of this descriptor, we propose a new ESW testing protocol, which is not only able to completely avoid the adverse influence of subjective factors but also fully consider the operating condition limitations. The protocol can be extended from the single electrode to the full device. This work proposes a more rigorous definition of ESW and provides a reliable protocol for evaluating the ESW of EDLCs.

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The Role of Barrier Layer in Southeastern Arabian Sea During the Development of Positive Indian Ocean Dipole Events

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Journal of Ocean University of China 2013年第2期12卷 245-252页

作者： GUO Feiyan LIU Qinyu ZHENG Xiao-tong sun shan Physical Oceanography Laboratory and Key Laboratory of Ocean-Atmosphere Interaction and Climate in Universities of shandong Ocean University of China NOAA Earth System Research Laboratory 325 BroadwayBoulderColorado 80305USA

Using data from Argo and simple ocean data assimilation (SODA), the role of the barrier layer (BL) in the southeastern Arabian Sea (SEAS: 60°E-75°E, 0°-10°N) is investigated during the development of positive Indian Ocean Dipole (IOD) events from 1960 to 2008. It is found that warmer sea surface temperature (SST) in the northern Indian Ocean appears in June in the SEAS. This warm SST accompanying anomalous southeastern wind persists for six months and a thicker BL and a corresponding thinner mixed layer in the SEAS contribute to the SST warming during the IOD formation period. The excessive precipitation during this period helps to form a thicker BL and a thinner mixed layer, resulting in a higher SST in the SEAS. Warm SST in the SEAS and cold SST to the southeast of the SEAS intensify the southeasterly anomaly in the tropical Indian Ocean, which transports more moisture to the SEAS, and then induces more precipitation there. The ocean-atmosphere interaction process among wind, precipitation, BL and SST is very important for the anomalous warming in the SEAS during the development of positive IOD events.

关键词： sea surface temperature (SST) mixed layer barrier layer Indian Ocean Dipole (IOD) persistence precipitation southeastern Arabian Sea

Persistent greening against drying in northeast Asian semiarid grasslands:Asymmetrical responses of direct and legacy effects to intensified drought

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Advances in Climate Change Research 2024年第1期15卷 9-20页

作者： Yu-tong MA Hai-shan CHEN Yao-Ming SONG Bo-Tao ZHOU shan-Lei sun Xin-Guan DU Yue sun Key Laboratory of Meteorological Disaster Ministry of Education/Joint International Research Laboratory of Climate and Environment Change/Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters Nanjing University of Information Science and TechnologyNanjing 210044China School of Atmospheric Sciences Nanjing University of Information Science and TechnologyNanjing 210044China

Despite experiencing a decadal shift towards drought conditions at the end of the 2Oth century,semiarid grasslands in northeast Asia(NEA)exhibited an evident greening trend from 1982 to ***,the mechanism behind this phenomenon remains ***,we analysed the interdecadal changes in vegetation response to drought on the basis of the standardised precipitation evapotranspiration index(SPEI)and Global Inventory Modelling and Mapping Studies LAI4g datasets,with an emphasis on the differences between direct and legacy effects(as measured by resilience),to explore the mechanism of persistent grassland *** revealed that during the post-drought shift period(2000-2020),the sudden decrease in the water content of the intermediate soil layer triggered an intensified vegetation response to ***,although direct effects and resilience were amplified,they exhibited asymmetric *** was stronger than direct effects,and this difference increased with increasing drought(drought recovery)*** combined effects may account for persistent greening against intensified drying in the semiarid grasslands in *** the projected exacerbation of future droughts,this study holds notable importance for comprehending the long-term change dynamics of dryland ecosystems.

关键词： Semiarid grassland Drought decadal shift Direct effect Legacy effect(resilience) Northeast Asia